International Paint Singapore Pte Ltd

Safety Data Sheet

PHI849 INTERTHANE 990 STONE GREY PART A
Version Number 3 Revision Date 11/22/17

1. Product and company identification

1.1. Product identifier INTERTHANE 990 STONE GREY PART A

Product Code PHI849
1.2. Relevant identified uses of the substance or mixture and uses advised against
Intended use Refer Technical Data Sheet.
For professional use only.
Application Method Refer Technical Data Sheet.
1.3. Details of the supplier of the safety data sheet
Importer or
Manufacturer International Paint Singapore Pte Ltd
3 Neythal Road
Jurong Town
Singapore 628570

Telephone No. +65 6261 5033

Fax No. +65 6264 4612
1.4. Emergency telephone number (24 hour) +65 6261 5033
For Poisons Advice telephone For Advice to Doctors & Hospitals only

2. Hazard identification of the product

2.1. Classification of the substance or mixture

Flam. Liq. 3;H226 Flammable liquid and vapour.
Skin Irrit. 2;H315 Causes skin irritation.
Eye Irrit. 2;H319 Causes serious eye irritation.

2.2. Label elements

Using the Toxicity Data listed in section 11 & 12 the product is labelled as follows.

Warning
H226 Flammable liquid and vapour.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
[Prevention]:
P210 Keep away from heat / sparks / open flames / hot surfaces - No smoking.
P235 Keep cool.
P240 Ground / bond container and receiving equipment.
P241 Use explosion-proof electrical / ventilating / light / equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P260 Do not breathe mist / vapours / spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash thoroughly after handling.
P273 Avoid release to the environment.
P280 Wear protective gloves / eye protection / face protection.
[Response]:
P301+310 IF SWALLOWED: Immediately call a POISON CENTER or doctor / physician.
P302+352 IF ON SKIN: Wash with soap and water.
P303+361+353 IF ON SKIN (or hair): Remove / Take off immediately all contaminated clothing. Rinse skin
with water / shower.
P305+351+338 IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if
present and easy to do - continue rinsing.
P321 Specific treatment (see information on this label).
P331 Do NOT induce vomiting.
P337+313 If eye irritation persists: Get medical advice / attention.
P362 Take off contaminated clothing and wash before reuse.
P370+378 In case of fire: Use alcohol resistant foam, CO2, powder, water spray for extinction. Do not use
water jet.
[Storage]:
P403+233 Store in a well ventilated place. Keep container tightly closed.
[Disposal]:
P501 Dispose of contents / container in accordance with local / national regulations.
2.3. Other hazards
This product contains no PBT/vPvB chemicals.

3. Composition/information on ingredients

This product contains the following substances that present a hazard within the meaning of the Workplace
Safety and Health Act.
Ingredient/Chemical Designations Weight % GHS Classification Notes
Acrylic Polymer 25- <50 [1]
CAS Number: Not Available
Solvent naphtha (petroleum), light aromatic 10- <25 Flam. Liq. 3;H226 [1]
CAS Number: 0064742-95-6 Asp. Tox. 1;H304
STOT SE 3;H335
STOT SE 3;H336
Aquatic Chronic 2;H411
Xylene 10- <25 Flam. Liq. 3;H226 [1][2]
CAS Number: 0001330-20-7 Acute Tox. 4;H332
Acute Tox. 4;H312
Skin Irrit. 2;H315
Asp. Tox. 1;H304
Eye Irrit. 2;H319
STOT SE 3;H335
Ethylbenzene 2.5- <10 Flam. Liq. 2;H225 [1][2]
CAS Number: 0000100-41-4 Acute Tox. 4;H332
 STOT RE 2;H373
Asp. Tox. 1;H304
Skin Irrit. 2;H315
Eye Irrit. 2;H319
STOT SE 3;H335
2-Methoxy-1-Methylethyl Acetate 1- <2.5 Flam. Liq. 3;H226 [1]
CAS Number: 0000108-65-6
[1] Substance classified with a health or environmental hazard.
[2] Substance with a workplace exposure limit.
[3] PBT-substance or vPvB-substance.

*The full texts of the Hazard (H) phrases are shown in Section 16.

There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence do not
require reporting in this section.

4. First aid measures

4.1. Description of first aid measures

General
In all cases of doubt, or when symptoms persist, seek medical attention.

Never give anything by mouth to an unconscious person.

Inhalation
Remove to fresh air, keep patient warm and at rest. If breathing is irregular or stopped, give artificial
respiration. If unconscious place in the recovery position and obtain immediate medical attention. Give
nothing by mouth.

Skin Contact
Remove contaminated clothing. Wash skin thoroughly with soap and water or use a recognised skin
cleanser. Do NOT use solvents or thinners.

Eye Contact
Irrigate copiously with clean fresh water for at least 10 minutes, holding the eyelids apart and seek medical
attention.

Ingestion
If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting.

4.2. Most important symptoms and effects, both acute and delayed
No data available
4.3. Indication of any immediate medical attention and special treatment needed and notes for
physician
No data available

5. Fire-fighting measures

5.1. Extinguishing media

Recommended extinguishing media; alcohol resistant foam, CO2, powder, water spray.

Do not use - water jet.

Note; Fire will produce dense black smoke. Decomposition products may be hazardous to health. Avoid
exposure and use breathing apparatus as appropriate.
Cool closed containers exposed to fire by spraying them with water. Do not allow run off water and
contaminants from fire fighting to enter drains or water courses.
5.2. Special hazards arising from the substance or mixture
Fire will produce dense black smoke. Decomposition products may include the following materials: carbon
monoxide, carbon dioxide, smoke, oxides of nitrogen.
Avoid exposure and use breathing apparatus as appropriate.
5.3. Advice for fire-fighters
Cool closed containers exposed to fire by spraying them with water. Do not allow run off water and
contaminants from fire fighting to enter drains or water courses.

6. Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Remove sources of ignition, do not turn lights or unprotected electrical equipment on or off. In case of a
major spill or spillage in a confined space evacuate the area and check that solvent vapour levels are
below the Lower Explosive Limit before re-entering. Ventilate the area and avoid breathing vapours. Take
the personal protective measures listed in section 8.
6.2. Environmental precautions
Do not allow spills to enter drains or watercourses.
6.3. Methods and material for containment and cleaning up
Ventilate the area and avoid breathing vapours. Take the personal protective measures listed in section 8.

Contain and absorb spillage with non-combustible materials e.g. sand, earth, vermiculite. Place in closed
containers outside buildings and dispose of according to the Waste Regulations. (See section 13).

Clean, preferably with a detergent. Do not use solvents.

Do not allow spills to enter drains or watercourses.

If drains, sewers, streams or lakes are contaminated, inform the local water company immediately. In the
case of contamination of rivers, streams or lakes the Environmental Protection Agency should also be
informed.

7. Handling and storage

7.1. Precautions for safe handling

Handling
This coating contains solvents. Solvent vapours are heavier than air and may spread along floors. Vapours
may form explosive mixtures with air. Areas of storage, preparation and application should be ventilated to
prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour
concentrations higher than the occupational exposure limits.

In Storage
Handle containers carefully to prevent damage and spillage.
Naked flames and smoking should not be permitted in storage areas. It is recommended that fork lift trucks
and electrical equipment are protected to the appropriate standard.
This coating contains solvents. Solvent vapours are heavier than air and may spread along floors. Vapours
may form explosive mixtures with air. Areas of storage, preparation and application should be ventilated to
prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour
concentrations higher than the occupational exposure limits.

7.2. Conditions for safe storage, including any incompatibilities

Keep away from the following materials: oxidising agents, strong alkalis, strong acids.
Avoid skin and eye contact. Avoid inhalation of vapours and spray mists. Observe label precautions. Use
personal protection as shown in section 8.

Smoking, eating and drinking should be prohibited in all preparation and application areas.

Never use pressure to empty a container; containers are not pressure vessels.
There are no exposure scenarios, see details in section 1.

7.3. Specific end use(s)

Store in a well ventilated, dry place away from sources of heat and direct sunlight.

Store on concrete or other impervious floor, preferably with bunding to contain any spillage. Do not stack
more than 3 pallets high.

Keep container tightly closed. Containers which are opened must be carefully resealed and kept upright to
prevent leakage. Keep in the original container or one of the same material.

Prevent unauthorised access.

All sources of ignition (hot surfaces, sparks, open flames etc) should be excluded from areas of
preparation and application. All electrical equipment (including torches) should be protected (Ex) to the
appropriate standard.

The product may charge electrostatically. Always use earthing leads when pouring solvents and
transferring product. Operators should wear clothing which does not generate static (at least 60% natural
fibre) and antistatic footwear; floors should be of conducting type.

8. Exposure controls and personal protection

8.1. Control parameters

From the listed Exposure Standards for Atmospheric Contaminants given in the Workplace Safety and
Health(General Provisions) Regulations.

Material PEL (Short Term) PEL (Long Term) Comments

ppm mg/m³ ppm mg/M3
Calcium carbonate - - - 10
Ethylbenzene 125 543 100 434
Titanium dioxide - - - 10
Xylene 150 651 100 434
(P) Peak exposure limit
(R) Suppliers Recommended Limit
(Sk) There is a risk of absorption through unbroken skin
(Sen) Sensitiser
(Cat1) Category 1 - established human carcinogen
(Cat2) Category 2 - probable human carcinogen
(Cat3) Category 3 - substances suspected of having carcinogenic potential

DNEL/PNEC values
No Data Available

8.2. Exposure controls

Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local
exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of
particulates and any vapour below occupational exposure limits suitable respiratory protection must be
worn.
Eye Protection
Wear safety eyewear, e.g. safety spectacles, goggles or visors to protect against the splash of liquids.
Eyewear should comply with the appropriate standard.

Wear a full face shield if mixing or pouring operations pose a risk of splashes.

An eyewash station is suggested as a good work place practice.

Skin Protection
Gloves of an appropriate material should be worn during mixing and application.

Other
Overalls which cover the body, arms and legs should be worn. Skin should not be exposed. Barrier creams
may help to protect areas which are difficult to cover such as the face and neck. They should however not
be applied once exposure has occurred. Petroleum jelly based types such as Vaseline should not be used.
All parts of the body should be washed after contact.

Respiratory Protection
When concentrations exceed the exposure limits shown above workers must wear appropriate approved
respirators. Provision of other controls such as exhaust ventilation should be considered if practical.

Thermal hazards
No Data Available

9. Physical and chemical properties

Colour Grey Liquid

Odour Smell of Solvent
Odour threshold Not Measured
pH N/A
Melting point / freezing point (°C) Not Measured
Initial boiling point and boiling range (°C) 108
Flash Point (C) 34
Evaporation rate (Ether = 1) Not Measured
Flammability (solid, gas) Not Applicable
Upper/lower flammability or explosive limits Lower Explosive Limit: 1.1 Xylene
Upper Explosive Limit: 6.6 Xylene
Vapour pressure (Pa) Not Measured
Vapour Density Heavier than air.
Specific Gravity 1.25
Solubility in Water Immiscible
Partition coefficient n-octanol/water (Log Kow) Not Measured
Autoignition Temperature (C) Not Measured
Decomposition temperature Not Measured
Viscosity (cSt) N/A

9.2. Other information

No further information

10. Stability and reactivity

10.1. Reactivity
No data available
10.2. Chemical stability
Stable under recommended storage and handling conditions (see section 7). When exposed to high
temperatures may produce hazardous decomposition products such as carbon monoxide, carbon dioxide,
oxides of nitrogen and smoke.

Keep away from oxidising agents, strongly alkaline and strongly acid materials in order to avoid possible
exothermic reactions.
10.3. Possibility of hazardous reactions
May react exothermically with: oxidising agents, strong alkalis, strong acids.
10.4. Conditions to avoid
Stable under recommended storage and handling conditions (see section 7).
10.5. Incompatible materials
Keep away from the following materials: oxidising agents, strong alkalis, strong acids.
10.6. Hazardous decomposition products
Fire will produce dense black smoke. Decomposition products may include the following materials: carbon
monoxide, carbon dioxide, smoke, oxides of nitrogen.
Avoid exposure and use breathing apparatus as appropriate.

11. Toxicological information

Acute toxicity

Exposure to solvent vapour concentrations from the component solvents in excess of the stated
occupational exposure limits may result in adverse health effects such as mucous membrane and
respiratory system irritation and adverse effects on the kidneys, liver and central nervous system.
Symptoms include headache, nausea, dizziness, fatigue, muscular weakness, drowsiness and in extreme
cases, loss of consciousness.

Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin
resulting in dryness, irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed
through the skin. Splashes of liquid in the eyes may cause irritation and soreness with possible reversible
damage.

The preparation has been assessed using the Acute Toxicity Data listed below, and classified for
toxicological hazards accordingly. See section 2 for details.

Oral LD50, Skin LD50, Inhalation Inhalation

Ingredient Vapour LD50, Dust/Mist LD50,
mg/kg mg/kg
mg/L/4hr mg/L/4hr
2-Methoxy-1-Methylethyl Acetate - (108- 8,532.00, Rat 5,000.00, Rabbit Not Available Not Available
65-6)
Acrylic Polymer - (Not Available) Not Available Not Available Not Available Not Available
Ethylbenzene - (100-41-4) 3,500.00, Rat 15,433.00, Rabbit 17.20, Rat Not Available
Solvent naphtha (petroleum), light 6,800.00, Rat 3,400.00, Rabbit Not Available Not Available
aromatic - (64742-95-6)
Xylene - (1330-20-7) 4,299.00, Rat 1,548.00, Rabbit Not Available 20.00, Rat

Item Category Hazard

Acute Toxicity (mouth) Not Classified Not Applicable
Acute Toxicity (skin) Not Classified Not Applicable
Acute Toxicity (inhalation) Not Classified Not Applicable
Skin corrosion/irritation 2 Causes skin irritation.
Eye damage/irritation 2 Causes serious eye irritation.
Sensitization (respiratory) Not Classified Not Applicable
Sensitization (skin) Not Classified Not Applicable
Germ toxicity Not Classified Not Applicable
Carcinogenicity Not Classified Not Applicable
Reproductive Toxicity Not Classified Not Applicable
Specific target organ systemic toxicity Not Classified Not Applicable
(single exposure)
Specific target organ systemic Toxicity Not Classified Not Applicable
(repeated exposure)
Aspiration hazard Not Classified Not Applicable

12. Ecological information

12.1. Toxicity
The preparation has been assessed according to the GHS criteria and is classified as dangerous for the
environment, using the toxicity data listed below.

There are no data available on the product itself.

The product should not be allowed to enter drains or water courses.

Aquatic Ecotoxicity

96 hr LC50 fish, 48 hr EC50 crustacea, ErC50 algae,

Ingredient
mg/l mg/l mg/l
Acrylic Polymer - (Not Available) Not Available Not Available Not Available
Solvent naphtha (petroleum), light 6.14, Daphnia magna 19.00 (72 hr), Selenastrum
aromatic - (64742-95-6) 9.22, Oncorhynchus capricornutum
mykiss
Xylene - (1330-20-7) Not Available Not Available Not Available
Ethylbenzene - (100-41-4) 2.93, Daphnia magna
4.20, Oncorhynchus 3.60 (96 hr), Pseudokirchneriella
mykiss subcapitata
2-Methoxy-1-Methylethyl Acetate - 100.00, Salmo 500.00, Daphnia Not Available
(108-65-6) gairdneri magna

12.2. Persistence and degradability

There is no data available on the preparation itself.
12.3. Bioaccumulative potential
Not Measured
12.4. Mobility in soil
No data available
12.5. Results of PBT and vPvB assessment
This product contains no PBT/vPvB chemicals.
12.6. Other adverse effects
No data available

13. Disposal considerations

13.1. Waste treatment methods
Do not allow into drains or water courses. Wastes and empty containers should be disposed of in
accordance with local regulations.

Using information provided in this data sheet advice should be obtained from the local Waste Regulation
Authority as to whether special waste regulations apply.

14. Transport information

14.1. UN number 1263

14.2. UN proper shipping name Paint
14.3. Transport hazard class(es)

Road and Rail Transport 1263, Paint, 3, III, 3[Y]

IMDG Class/Div 3 Sub Class

reference :

Ems F-E,S-E

ICAO/IATA Class 3 Sub Class

14.4. Packing group III

14.5. Environmental hazards

Road and Rail Environmentally Hazardous: No

Transport

IMDG Marine Pollutant: No

reference :

14.6. Special precautions for user

No further information
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not Applicable

15. Regulatory information

This product and all its components complies with the chemical and transport regulations from the country
listed in section 1.3.
Other regulatory information specific to the hazardous chemical(s):

None noted.

16. Other information

The information on this SDS is based upon the present state of our knowledge and on current laws.
The product should not be used for purposes other than shown in the product data sheet without first
obtaining written advice.
It is always the responsibility of the user to take all necessary steps to meet the demands of applicable
legislation.

The full text of the phrases appearing in section 3 is:

H226 Flammable liquid and vapour.

H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness and dizziness.
H372 Causes damage to organs through prolonged or repeated exposure.
H411 Toxic to aquatic life with long lasting effects.

This SDS is valid for 5 years from the revised date on page 1.
The revision date is in American format (e.g. MM/DD/YY).

End of document

All information concerning this product and/or suggestions for handling and use contained herein are
offered in good faith and are believed to be reliable. Akzo Nobel however makes no warranty as to
the accuracy of and/or sufficiency of such information.