Unit Operations - FExam-2 - 2021
Unit Operations - FExam-2 - 2021
Unit Operations - FExam-2 - 2021
PROBLEM-2
Two very large tanks, maintained at 332 K and 1 atm total system pressure, are connected by a
0.1-m-diameter circular duct which is 5 m in length. Tank 1 contains a uniform gas of 55 mol%
acetone and 45 mol% air, whereas tank 2 contains a uniform gas of 15 mol% acetone and 85
mol% air. Determine the initial rate of acetone transfer between the two tanks. The gas
diffusivity of acetone in air at 298 K and 1 atm is 0.093 cm2/s.
PROBLEM-3
Determine the Schmidt number for
a. Oxygen in air at 300 K and 1.0 atm; and
b. Oxygen in liquid water at 300 K.
At 300 K, the diffusion coefficient of oxygen in liquid water is 1.5×10-9 m2/s.
PROBLEM-4
A liquid solution containing 49 moles of benzene and 21 moles of toluene is slowly heated to
368 K and a pressure of 1.013×105 Pa in a closed container.
a. What would be the composition of the liquid phase and the gas phase in equilibrium at
368 K and 1.013×105 Pa? At 368 K, the vapor pressure of benzene is 1.354×105 Pa and
the vapor pressure of toluene is 5.41×105 Pa.
b. Determine the amount of liquid that would be present after this mixture is heated to 368 K.
PROBLEM-5
A 1-m square thin plate of solid naphthalene is oriented parallel to a stream of air flowing at 22
m/s. The air is at 310 K and 1.013×105 Pa. The naphthalene remains at 290 K; at this
temperature, the diffusivity of naphthalene in air is 5.62×10-6 m2/s and its vapor pressure is 25.8
Pa. Determine
a. The value of the mass-transfer coefficient at a point 0.3 m downstream from the leading
edge.
b. The moles of naphthalene per hour lost from the section of the plate 0.5–0.75 m
downstream from the leading edge.