Parishram (2024) : Alcohol, Phenol and Ether

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Parishram (2024)
Alcohol, Phenol and Ether DPP-02

1. Glycerol has 8. The reaction of ethylmagnesium iodide with


(1) One 1° and two 2° alcoholic group acetaldehyde gives after acidification
(2) One 1° and one 2° alcoholic group (1) 2-Butanol
(3) Two 1° and one 2° alcoholic group (2) 1-Butanol
(4) All are 2° alcoholic group (3) 2-Methyl-2-propanol
(4) 2-Methylpropanol
OH
|
2. CH3CH 2  C  CH3 cannot be prepared by 9. To prepare 2-propanol from methyl magnesium
| bromide, the other chemical required is
Ph
(1) HCHO (2) CH3CHO
(1) CH3CH2COCH3 + PhMgX
(3) C2H5OH (4) CH3COCH3
(2) PhCOCH3 + CH3CH2MgX
(3) PhCOCH2CH3 + CH3MgX
10. The common name of 2-methyl-1-propanol
(4) HCHO + PhCH(CH3) CH2MgX
(1) 2-methyl-2-propanol
(2) Sec-Butyl alcohol
3. Oxymercuration-demercuration reaction of (3) Isobutyl alcohol
1-methylcyclohexene gives (4) Tert-Butyl alcohol
(1) Trans-2-methyl cyclohexanol
(2) Cis-2-methylcyclohexanol 11. Which one of the following is a secondary
(3) 1-methylcyclohexanol alcohol?
(4) Mixture of cis- and trans-2-methylcyclo-hexanol (1) 2-Methyl-1-propanol
(2) 2-Methyl-2-propanol
4. The product of the following reaction is (3) 2-Butanol
(i) BH /THF
 (4) 1-Butanol

3
(ii) H 2O2 , OH

(1) 2-pentanol (2) pentane 12. In the reaction (CH3)2–CH–CH=CH–CH3


(3) pentan-2-one (4) 1-pentanol (i) Hg(OAC)2 , THF, H 2O
(ii) NaBH 4
5. Ortho-dihydroxy benzene is: x, x will be
(1) Carvacrol (2) Resorcinol
(1) (CH3)2–CH–CH2–CH(OH)CH3
(3) Catechol (4) Orcinol
(2) (CH3)2–CH–CH(OH)–CH2–CH3
6. Isopropyl alcohol on oxidation forms: (3) (CH3)2–C(OH)–CH3CH2CH3
(1) Acetone (2) Ether (4) CH3–CH(OH)–(CH2)3CH3
(3) Ethylene (4) Acetaldehyde
13. What is the correct order of reactivity of alcohols
7. Which of the following alkenes when passed in the following reaction?
ZnCl
through conc. H2SO4 followed by hydrolysis with R  OH  HCl 
2 R  Cl  H2O
boiling water would give tert-butyl alcohol? (1) 1° > 2° > 3° (2) 1° < 2° > 3°
(1) Ethylene (2) Isobutylene (3) 3° > 2° > 1° (4) 3° > 1° > 2°
(3) Propylene (4) 1-Butene
2

Conc. H SO 15. CH3CH2OH can be converted into CH3CHO by


14. C2 H5OH 
2 4Z
443K
______.
In the above reaction Z is identified as (1) catalytic hydrogenation
(1) C2H5–O–C2H5 (2) treatment with LiAlH4
(2) C2H5CHO (3) treatment with pyridinium chlorochromate
(3) CH2=CH2 (4) treatment with KMnO4
(4) C2H5OSO4
3

Note: Kindly find the Video Solution of DPPs Questions in the DPPs Section.
Answer Key
1. (3) 9. (2)
2. (4) 10. (3)
3. (3) 11. (3)
4. (4) 12. (2)
5. (3) 13. (3)
6. (1) 14. (3)
7. (2) 15. (3)
8. (1)

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