Class'B

Precipitation oxidation Reduction

reactions in solution

5042 Cr

04210043
Croft
Croft Ming
Cr2072 Ming
given solid solution of given
sample solid sample

aaaaaB BEAR
aa a
aaaq
appear BAM
base Bata waka
acid

Dry tests wet tests wet tests

 INORGANIC CHEMISTRY
TM

Path to success KOTA (RAJASTHAN)

– +
MnO4 ,H Distinction
decolourise
+ Cr2O , H 2– + Boomer from CO2
H
SO2
7
ODED
Green

B0aa
(suffocating) Ca(OH)2 SO2 Ca(HSO3)2

BBE
CaSO3
(white) (excess) (Soluble)

SO32–
BaCl2
BaSO3
Kwei
(white)
air or
Br2–H2O or HNO3
BaSO4
(white) job
SO32–
Baat
AgNO3

BB interfuse in analysis of
Ag2SO3 [AgSO3]
–

some acid radicals (White) (soluble)

basic radicals They are identified and

removed before analysing basic radicals (CH3COO)2Pb
PbS
For H +
H2S 2–
Cr2O7 , H
+
(Black)
Green
(Rotten egg
Eaaootoe
ooa.gg
like smell) MnO4 , H
– +

Decolourise
2–
S Na2[Fe(CN) 5NO] Na4[Fe(CN)5(NOS)]

+3
Fe , N, N-Dimethyl–
oadBgqg
(violet/purple colur)
(not ppt)

Bagdad
Methylene blue
p-phenylenediamine
(water soluble dye)

2
 INORGANIC CHEMISTRY
TM

Path to success KOTA (RAJASTHAN)

H
+
disproportionates aan
HNO2 HNO3 + NO og
– (unstable)
pqa.BA O2
NO2

gggozgaIE
NO
EBggg
2
FeSO4 +acid + (Red-Brown)
[Fe(H2O)5 (NO)] SO4
(Brown ring)

Cr2O72–, H+
Green

EE
+ – +
H + SO2 MnO4 , H
S decolourise

Egg
(White)

I
S2O2–3 Ca(OH)2 excess
Ca(HSO3)2
CaSO3
SO2

BodEBGg8gBH
(white) (soluble)
Ag+ Ag+ a
[Ag(S2O3)2]
3–
Ag2S2O3 On stand Ag2S
Body
(soluble) (white) (Black)

Group ‘B’ : -
Anions which produce gases or acid vapours with con. H2SO4 (all anions of group ‘A’ are included in it)
(F– , Cl– , Br– , I– , NO3–, BO33– , CH3COO– , C2O42– )

H
+ SiO2 H2O 2–
H2F2 SiF4 SiF6

es
zio
(Greasy
CaCl2 appearance)
F
–
CaF 2
(white)
AgNO3
NO ppt
3
 INORGANIC CHEMISTRY
TM

Path to success KOTA (RAJASTHAN)

+
H
Hoodooed
NH4OH
HCl White fumes of NH4Cl
Edge
(pungent)

Bad
KI, starch
MnO2 + H
+
Blue
oooo
Cl2
(Green-yellow) moist

AgNO3
litmus Edda
Bleached
– NH4OH
Cl AgCl [Ag(NH 3) 2]
+

BE
(White) (excess)
GBao
(soluble)

(CH3COO)2Pb
PbCl2
(Soluble) Beta
Hot water

Gf
(White) in Excess Cl
–

K2Cr2O7, H2SO4 NaOH

Haq CH3COOH +

dEdg't idgaf
CrO2Cl2 Na2CrO4 PbCrO4
Bdd
(Red) (Yellow soln) (CH3COO)2Pb (yellow)

FEET
Con. H2SO4 or

Goof
+ Br2
MnO2 + H (Brown)

H3PO4 NH4OH
HBr NH4Br (white fumes)
(White)
Br–
AgNO3
Bogo
AgBr
(yellow)
Cl2 water
(CCl4)
EB0
CCl4 layer turns
o
Brown (due to Br2) BESET
excess Cl2
BrCl
(Yellow soln)

4
 INORGANIC CHEMISTRY
TM

Path to success KOTA (RAJASTHAN)

Con. H2SO4 or
I2 colourless
HEE
+
MnO2 , H (Violet)

H3PO4 5024NH OH Green

EG Booster milky
NH I (white fumes)
son
4
suffocating
HI 4

AgNO3
AgI

SB
Basozt
(yellow)
White c Basket
white
insoluble

BB
HgCl2
oI
exc.
–

BB
–
HgI2 [HgI4]
2–

I (Red)

Bi
+3 Agios exc. I
– 5031
Ag
(soluble)

Chile
Baat
–
BiI3 [BiI ]
Hogg
4

(Black) (Orange soln)

od
CuSO4
CuI + I2

FET (white) I–

Baas
I3–
(Brown soln)
Cl2(H2O), CCl4
CCl4 layer turns Pbst Black
Cl2(excess)

mots
HIO3

Gottenegg
Hast violet (due to I2)
Sade
Green
(colourless)

like colourless
Con. H2SO4 4
Felong Nos NO2
(Red-Brown)
EBB
violet son
+
oooo
FeSO + con. H SO
[Fe(H O) (NO)]SOblue
4 2 4
NO3
methylene 2 5 4

BTtBmg
(Brown ring)
ht –
Zn or Al, OH Dye
NH 3

5
 INORGANIC CHEMISTRY
TM

Path to success KOTA (RAJASTHAN)

3– Con. H2SO4 , CH3OH

BO3
1(white)HNO2
B(OH)3 B(OCH3)3
No No
864 FBBTdggBGanog (Burns with green .
edged flame)

Brown complex redbrown

ring
dil. H2SO4
CH3COOH

tBeqqa
(Vinegar smell)
Con. H2SO4
SO + CH COOH
2 3
Green
(masks smell of CH 3COOH)
CH3COO – St
+
H, soap
CH3COOC2H5 (ester)
colourless
C2H5OH
AgNO3
Bagshot milky
(Fruit like smell)
Solh
CH3COOAg

Ag Gouged
5203125
Ag52031
(white)
FeCl3, Agast
oooo write
Red ppt
Black

Con. H2SO4

Botsford
CO + CO2
(Burns with (Brisk effervescence)
blue flame)
CaCl2
HFT SifCaC2O4
Insoluble in
CHHasiFg
oily
BE
C2O2–
4 3COOH

atg
(white)

MnO4– ,H+
Cafat white
decolourise
Good
soluble
Agf 6
 INORGANIC CHEMISTRY
TM

Path to success KOTA (RAJASTHAN)

GROUP ‘C’ : Anions which are identified by precipitation reaction.

(SO42–, PO43–)
con
Hat Naga whitefumes
BaCl2 Insoluble in Blue Iz starch
Azt BaSO
tazza
Greenyellow
(white)
4 dil. mineral acid
(HCl)
Soluble in
colourless
Boiling H SO
2 4
(CH3COO)2Pb
SO
2–
PbSO4

Eff Gag soluble

4
(white)

AgNO3
Ag2SO4 Boiling
Soluble in hot Kao
Excess aq. NH

Bea Pbt
3

Egypt (white)
Con HCl

s can 20241 109240 Pbcroft

Grange
AgNO 3
Ag3PO4 yellow yellow
Goose
(yellow)

(MgCl2 +NH4Cl + NH4OH)

3–
Brared brown Mg(NH )PO
(Magnesia mixture) 4 4

PO 4
(white)
(NH4)2 [MoO4]

jodhpurs NHaBrt White

(NH4)3 [P(Mo3O10)4]
HBr
FeCl
(yellow)
3
FePO4
Brt soluble
Ag Tfi
(yellow)

lightyellow
Bra Bra
yellow
7

É FEEizqj.IE
 INORGANIC CHEMISTRY
TM

EEuthitetgin EE wife
ingrates teens
Path to success KOTA (RAJASTHAN)

T E S T F O R C A T I O N S O F G R O U P-I ( g r o u p r e a g e n t : d il. H C l)

RE-
AGENTS (Pb2+)
Is violet (Ag+) (Hg22+)
Dil.HC A white ppt in cold solution if the acid is not two dilute
Ag C AgCl Hg 2
2
2C Hg 2Cl2
Pb 2 2C PbCl 2 White ppt dissolves in conc. HC , aq. NH3, excess KCN and excess White

HI NHI whitefumes
White
Na2S 2O3 . ppt. is insoluble in dilute acids aqueous NH3 converts the ppt. into a
mixture of Hg metal and mercury(II) amidochloride.

insoluble
Iget Ej
H2S(Gas) A black ppt of PbS is obtained. 2
2Ag H 2S Ag 2S Hg 2 H 2S Hg 2S
or
Pb 2 H 2S Black Black Black
Saturated Hot and conc. HNO3 decomposes Ag2S and S remains in the form of a
PbS decomposes on adding conc. HNO , when a white ppt of sulphur Aqua-regia dissolves ppt leaving white ppt of S.
aq.Solution 3
white ppt.
is ontained.

Aq.
NH 3 2
HgIzt
red
White ppt of which is insoluble in excess of reagent. Brown ppt of Ag2 O HIM colorless A black ppt which is a mixture of mercury metal and basic mercury (II)
amido nitrate (white).
Pb 2NH 3 2H 2O Pb(OH) 2 2Ag 2NH3 H 2O Ag 2O

BIEN Biff orange soln

2+ –
white Brown 2Hg2 + NO3 + 4NH3+ H2O
ppt dissolves in excess reagent but remain insoluble in excess NaOH.

NaOH White ppt which dissolves in excess reagent.

Black Brown ppt of Ag2 O
Hg + HgO.Hg(NH2 )NO3

Black ppt of Hg2 O

Thile I
(aq.) Pb 2 2OH Pb(OH)2 Hg 22 2OH Hg 2O
2Ag 2OH Ag 2O
White Black

brownson
Brown

K 2 CrO 4 A yellow ppt of PbCrO4. A red ppt of Ag2CrO4

Iz ppt is insoluble in excess reagent but readily dissolves in dilute HNO3.

Red crystalline ppt of Hg2CrO4

2
Pb 2
CrO 2
PbCrO4 2Ag CrO Ag 2CrO4 Hg 2
2
CrO 4
2
Re d
colorless
4

Iz 44 HIB
4 Re d
Yellow

Ciolet
KI(aq.) Yellow ppt of PbI2 Yellow ppt of AgI when added in cold solution green ppt of Hg2I2
Pb2+ + 2I– yellow Hg 2
2
2I green
Ag I yellow
ppt is soluble in boiling water.
Insoluble in aq. NH3, but readily dissolves in KCN(ex) In excess of KI disproportionation takes place.

a N24 red brown

Brown ring complex

NHzT Ha white fumes

8
 INORGANIC CHEMISTRY
TM

Path to success KOTA (RAJASTHAN)

T E S T F O R C A T I O N S O F G R O U P-I I A (g r o u p r e a g e n t : H 2 S + H C l)

RE- BLOHM BLOCH

3
AGENTS Hg2+ Cu2+ Cd2+ Bi3+
Burnswithgreen
H2S(g) Black ppt of HgS Black ppt of CuS
flame Yellow ppt of CdS
Cd2+ + H2S
Black ppt of Bi2S3.
2Bi3
aokotfbfgpggdafa.iq'the
Hg 2 3H S
iheartmedia
H2S Black Cu 2 H 2S H
Black ppt is soluble in HNO3. eFBMMBaoaaamaaaoagaot
2
Black

Aqua-regia dissolves the ppt. *Hot conc. HNO3 dissolves the ppt leaving behind s .
gag
*Hot dil HNO3 dissolves the ppt leaving white ppt of S.

NH3 (aq) White ppt of basic mercury(II) amidonitrate. CH3COOH

Blue ppt
vinegarsmell White ppt of Cd(OH) White basic salt.

SEBBBGEB
2

MotoGp
Hg 2 NO3 NH3 HgO.Hg(NH 2 )(NO3 ) Excess reagent dissolves the ppt.
2Cu 2 2NH 3 2H 2O
Tanzania
Bi3 NO3 2NH 3 2H 2O

tTBBBgg
Cd(OH) 2 4NH 3 [Cd(NH 3 )4 ]2

soy chzcoon
Blue Cu ( OH )2

ppt is soluble in excess reagent.

(Colourless)

white Bi(OH) NO
2 3
iahBdMMBBmgqq
Cu(OH) NH2Cu(NH ) Blue soln.
3 3 4
2

mammonist
insluble in excess reagent.

NaOH Yellow ppt of HgO

Meosaoooooo ester fruit like smell
Cu 2 2OH Cu(OH) 2 Cd 2 2OH Cd(OH) 2 Bi3 3OH Bi(OH)3
Hg 2
2OH
Emanates smoothness Blue White
Bootstraps White

MMkMBBa White
BtBzBoah0aooCH3COOAGI
Yellow
Insoluble in excess NaOH ppt is insoluble in excess NaOH.
ppt insoluble in excess reagent but soluble in dilute
acids.

KI
oooaaqmoaoqgmiq.NET
Red Pbt
Red ppt of HgI2, soluble in excess KI.

Hg2+ + 2I–

EBd.BE
HgI2
White ppt of CuI is obtained but the solution is
intensily brown due to formation of I3 –
No ppt forms Black ppt of BiI3,
Bi 3 3I BiI 3

Footages
Red Black

2Cu2+ + 5I– CuI ppt dissolves in excess reagent

HgI 2 2I [HgI4 ] 2–
BBmaggqqq
White

ppt is soluble is ex.KI

BiI3 I BiI4
Orange

CuI + 3KI K 3 [CuI 4 ]

so luble

cot Coat
Cacaqt CHzcoon
White
pants Coat

9
 INORGANIC CHEMISTRY
TM

Path to success KOTA (RAJASTHAN)

T E S T F O R C A T I O N S O F G R O U P-III ( g r o u p r e a g e n t : N H 4 O H + N H 4 C l)
RE-
AGENTS
A 3+
Cr3+ Fe3+
GREEN ppt of Cr(OH)3 soluble in cold in excess NH3 REDDISH-BROWN ppt

cicadas
ggq.EEBdtTBdg BBtE
3+
A + 3NH 3 + 3H 2O Al(OH)3

qq.gg
Cr3

osEgg
3N H 3 3H 2 O Fe3 3NH 3 3H 2 O
white
NH3 (aq) G REEN Re d Brown
Fe(OH)3
Cr(OH)3 NH 3 [Cr(NH 3 )6 ]3
violet & pink

EE
NaOH White ppt of Al(OH)3 A greeen ppt of Cr(OH)3 REDDISH BROWN ppt of Fe(OH)3

gigged
oEeBBdshoaagaat eo3B3sgggT
assuaging
C r3

geEro
ppt is soluble is excess of NaOH, Al(OH) 3 OH [Al(OH)4]– 3O H G R EEN Fe3 3OH Fe(OH)3
ppt is soluble in excess of NaOH red brown

Cr(OH)3 OH [Cr(OH) 4 ] ppt is insoluble in ex. NaOH

GREEN

Baagagaoo E3t Bts

(NH4 )2 S White ppt of Al(OH)3 is obtained. Green ppt of Cr(OH)3 is obtained. In neutral solution, a black ppt of FeS and S is formed.
2Al 3S 6H 2 O Cmi EggEtoB
Eddadtthaooooagoosagg
3
Al(OH)32

gggtstoted 2Cr 3
3S 2
6H 2 O Cr(OH)3
2Fe3 3S2 FeS S
black

agggggaggeraotaooooodroadorrect
White Green

*Al2S3 does not exist in aqueous solution owing to almost complete hydrolysis. *Cr2S3 does not exist in aqueous solution owing to almost complete hydrolysis.

Ag
2504 agggmsgg
Specific Na2HPO4: White ppt of A PO4 . Sodium Carbonate : KCN : Red brown ppt of Fe(CN)3

Botswana
Reagent A grey-green ppt of Cr(OH)3 is formed.

astuteteamed
3 2
A HPO 4 AlPO 4 H Fe3 3CN Red.Brown
White
2Cr 3
3CO 3
2
3H 2O Cr(OH) 3 ppt dissolves in excess of KCN.
Grey Green
F.oBBGagg.AT
Fe(CN)3 3CN Fe(CN) 6
(so ln)
3

NH4 SCN(aq) : In slightly acidic solution, a deep-red colouration is

Birdseed
taggTaaoa
produced Fe3 3SCN Fe(SCN)3 deep red.

Ag312041 yellow
MgNH Pott
White
NH PCMoz01034 A
Canary yellow
Fepoat yellow

As of 0142114004 Ivry As Moz

01074 I
yellow 10
 Basic radicals INORGANIC CHEMISTRY
TM

Analysis of
Path to success KOTA (RAJASTHAN)

T E S T F O R C A T I O N S O F G R O U P I V ( g r o u p r e a g e n t : N H C l + N H O H + H S)
4 4 2

RE-

Group
AGENTS

NaOH(aq)
ionsZn 2+

Go reagent Mn2+
plots
Zn 2 2OH Zn(OH) 2 Mn 2 2OH White

Pbt
I Effettgsgggagat Agt iodhqa
did aqHI eeae aodoecd white
a.org
oaa
(white)

Agee 00
The ppt is insoluble in excess NaOH. It rapidly oxidises on exposure to air, becoming brown when hydrated
the ppt is soluble is excess of NaOH and in acids .

Hgat
manganese dioxide is formed
Pby Hgauz
34 CUT FLINT
NH3 (aq) White ppt of Zn(OH)2, readily soluble is excess NH3(aq) and in solutions of NH4+ salts owing to the production

qqqggq oooggessaegooeaaoooooaoooooosasooassaoooooooo Partial precipitation of (initially) Mn(OH)2, Mn

agapanthuses 0000dg
2
of [Zn(NH3)4 ]2+.
2NH 3 2H 2O Mn(OH) 2

(NH4)2S(aq) White ppt of ZnS, dissolve into dilute mineral acids. Pink ppt of MnS. It is readily soluble in dilute mineral acids

IIA Cdt Cut Bit actress

eaqootogggoos

É
Haoofgagggggggaoooooooeotated
in
Zn 2 S2 White (colloidal) Mn 2 S2 Pink ’

Has
Esta presence GTows'Es wn black
of Phrae
Specific K4[Fe(CN)6](aq) : PbO2 and conc. HNO3 :

9ft Angst
imessage oeaeF BEgtgga
Reagents
3Zn 2 2k 2[Fe(CN)6 ]4 K 2 Zn 3[Fe(CN) 6 ]2 5PbO 2 2Mn 2 4H HMnO

die Battersea
4

that
excess White violet (permanganic acid)

HU
ppt is soluble in ex NaOH *Pb3 O4 also give the same product.

Ent sntÉÉst3
Bedsteads apogee
2 4
K 2 Zn 3[Fe(CN) 6 ]2 12OH [Zn(OH) 4 ] [Fe(CN) 6 ] K

IB Ast Has in Sns 5h52 95253,95255

presenceof 56253985255
Sbt Sbt's die Ha rangeyellow
in
Alt Crt Fet Presenceof Allows Crows Felons
3g at tha Mtf white Green Brown
I 2nt Mnt cot with Has in presence 2ns Mns Cos Nis
Fat af for ofNtyontntawhite Rink Black Black
11
 INORGANIC CHEMISTRY
TM

Path to success KOTA (RAJASTHAN)

RE-
AGENTS Co2+ Ni2+
warming with excess NaOH, a pink ppt of Co(OH)2 . 2

EaEE
Green ppt of Ni(OH)2 Ni 2OH Ni(OH) 2

tFEEEEEE foaoagoaBe
NaOH

gg
2 Warm green
Co OH Co(OH)2
excess The ppt is insoluble in excess NaOH.
NH3 (aq) precipitate the basic salt. Green ppt of Ni(OH)2 which dissolves in excess of reagent

isagoge
Co 2 NH 3 H 2 O NO3 Co(OH)(NO3 ) Ni 2 2NH 3 2H 2O Green

qt Eff FI afqgggggggfBdTtd
blue

*Excess NH3 dissolves the ppt. stumble insf

ubgsn'some
Ni OH
Hayley 6NH 3 [Ni(NH 3 )6 ]2 tegttteglnn.at
puppet
Fragmented
2

N Whites
deep blue so ln

Co OH NO 6NH 3 3 [Co(NH3 )6 ]2
TAN

aaEfE
(NH4)2S(aq) Black ppt of CoS
adored
Black ppt of NiS

T.ME
Pbst Agast Hghtags
2 2 2 2
Co S Black Ni S Black

Grey Black
Black
Bootz
aqua. regia dissolves the ppt.
Black
It dissolves in aqua. regia.

KCN(aq) Co2 2CN Red Brown Ni 2

2CN Green

i
BoqdB5agB
ppt dissolves in excess reagent.

Pbytized Yi Agg If
ppt is readily soluble in excess KCN.

potty Yi
insoluble insoluble
Specific With dmg/OH–
Co CN 2
4CN Brown[Co(CN)6 ]4
goosesteps
Agents's
Ni CN
soluble 2
2
2CN [Ni(CN) 4 ]2
yellow

aoootogoagoo.IT
KNO2. Co 7NO 2 2H 3K K 3[Co(NO 2 ) 6 ]

fggtTBggFdF
Reagetns Ni 2 2dmg 2OH [Ni(dmg) 2 ] yellow
red

bloat Iain flatmate

2

park fi
2
NH4SCN(s) : Co
insoluble 4SCN [Co(SCN)4 ]

East
blue

soluble
T EST F OR GRO UP
Pbcroat yellow Agecroft Brickred
V C A T I O N S : ( g r o u p r e a g e n t : N H 4 C l + N H 4 OHgacroat
H + ( N H 4)2 C O 3) Brick red
insoluble
RE-
AGENTS
PbIat yellow
Ba2+
AgIt yellow Sr2+ f insoluble
HgIad D Ca2+
Hgtthgist
(NH 4 )2 CO 3
Ba 2
2
Sr 2 CO32 White
205s soluble green
Ca 2 CO32 white

F.EE Estenssoro
CO3 White

(NH 4 )2 CrO 4
EE ppt is soluble in mineral acids and in AcOH both.
2
ae
ppt is soluble in mineral acids and in AcOH both

Sr 2 CrO24 Yellow Ca 2 CrO 24

Etheredge
ppt is soluble in dil. mineral acids and in AcOH

yellow

Bothersome
Ba 2 CrO 4 Yellow

(NH4 )2 SO 4 Ba 2
soluble in mineral acids but insoluble in AcOH.

SO 4
2
white
9iFaeTEEsoaoaaao
soluble in BOTH, the mineral acids and in AcOH

Sr 2 SO 42 White
iEoaBE_oo
soluble in both, the mineral acids and in AcOH.

Ca 2 SO 42 white

iBook engrossed
Fisher
Insoluble in mineral acids Insoluble in mineral acids Partially soluble in mineral acids
On boiling with conc. H2SO4 ppt dissolves.
Boil
BaSO4 H 2SO4
conc.

(NH 4 ) 2 C 2 O 4

iodoforms
Sr 2 C2O 42 Ca 2 C2O 42

YEdtdfaheeo
2

Effeteness
Ba 2
C2O 4 white WHITE white
Soluble in both the mineral acids and in AcOH Soluble in mineral acis but insoluble in AcOH. Soluble in mineral acids but insoluble in AcOH.

12
 INORGANIC CHEMISTRY
TM

Path to success KOTA (RAJASTHAN)

T E S T F O R C A T I O N S O F G R O U P V I A N D N H 4+

Test of Mg2+ ions :

1. W it h NH 3(aq) - Precipitation white gelatinous Mg(OH)2.

Bottega
Mg 2 2NH 3 2H 2 O
2. With NaOH(aq) : - White ppt of Mg(OH)2 , insoluble in excess NaOH or
Mg 2 2OH white cdyset
3.
Black
Disodium hydrogenphosphate solution: -
Black ow
A white ppt of Mg(NH4) PO4.6H2O in the presence of NH4C to prevent pptn of Mg(OH)2 and NH3 solution
Mg 2 NH 3 HPO 42 White
MCCdlNHIJBiconist
Pbt g insoluble
aconlztyg fainnjt.GL
Blue I2t colorless white Is
insoluble

Ecootorsttereaooadted
i
belonkt
Hqgtenow
insoluble
coffin in insoluble
Bigg p
insoluble
RE-
AGENTS
K+ Blue NH4+ (Zero Group)

Na3 3 3

Beetham
3K Co NO 2 K 3 [Co(NO 2 ) 6 ] 3NH 4 Co NO2 (NH 4 )3[Co(NO 2 ) 6 ]

Hget Bi II
[Co(NO2)6] 6 6

my
yellow Yellow

HC O4 K C O4 KClO 4 2NH4 PtC

2
(NH 4 ) 2 [PtCl 6 ]
BIT organs

Bt
gggg I 1120
6

Hotdogs
white yellow

H 2 PtCl6 2K PtC 6
2
K 2 [PtCl6 ]
yellow
NH 4 C O4 NH 4ClO 4
white BioIt
WITH NESSLER’S REAGENT : corange
cut'tky Felony NH 4 2 HgI 4
2
4OH HgO.Hg(NH 2 )I

Cy FeCNN I Langseth
Brown ppt or Brown-yellow colouration.

Chocolate brown

13
 INORGANIC CHEMISTRY
TM

Path to success KOTA (RAJASTHAN)

IM P O RTA N T P R E CIPI TAT E S T O L E A R N

White ppt.

t's.no
PbCl2, AgCl, Hg2Cl2, PbSO4,

sinsoiuseAlgh3t
Pb(OH)2, PbCO3, AgCN, Bi(OH)3,
CuI, CuSCN, Cd(OH)2,Pink Brown
K2Fe[Fe(CN)6],
Al(OH)3,
Fi
Mn(OH)2,
NaAlcon it Nalcrotha Feconst Eg
Zn(OH)2, ZnS,
insoluble
K2Zn3[Fe(CN)6]2, BaCO3,
soluble Light BaC2O4,
son Crown
SrCgreen
BaSO4,

kit
SrCO3, SrSO4, O,
2 4
CaCO3,
CaSO4, CaC2O4, Mg(OH)2, Mg(NH4)PO4,
Has4 colonist Hast
Algy KClO4,
PbBr2,
Ag2CO3,
CaF2, green
Ag2SO3,
Ag2SO4
Fightfthite
Ag2S2O3,
pet'tHast
Red ppt. Pink ppt. Blue ppt. Green ppt.
Alpoat
Hg2CrO4,
HgI2,
Co(OH)2
MnS,
Co[Hg(SCN)4],
Fe4[Fe(CN)6]3
Hg I ,
FEGLEY 2 2
Cr(OH)
kz Felon6
3
Ag2CrO4, Cu(OH)2,
It Ni(OH)2
[Ni(dmg)2]
Eff tt
Cu(OH)2.CuCO3
Fe(OH)2
felscnlii
Brown ppt.
Ag2O, Ag3AsO4, SnS, Cu2[Fe(CN)6]
Fe(OH)3
Black ppt.
PbS, PbO2, Hg2O, Ag2S,
HgS, Bi2S3, BiI3, CuS,
FeS, CoS, NiS, MnO(OH)2,
Yellow ppt.
PbCrO4, PbI2, Hg2CO3, AgI,
Ag3PO4, HgO, CdS, K2[PtCl6],
Ag3AsO3, (NH4)3[P(Mo3O10)4] SnS2, BaCrO4,
K3[Co(NO2)6], SrCrO4, (NH4)3[Co(NO2)6], (NH4)2[PtCl6].
14