Scribd Logo
Upload

Welcome to Scribd!

  • 17 views

    Important Name Reactions

    Uploaded by

    bibek64m5
    The document describes several important name reactions in organic chemistry including: 1) The Sandmeyer reaction which is used to synthesize aryl halides from aryl diazonium salts. 2) The Gatterman reaction in which bromine and chlorine are introduced into the benzene ring by preparing the diazonium salt solution with the corresponding halogen acid. 3) The Balz-Schiemann reaction where arene-diazonium chloride reacts to yield aryl fluoride on heating.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd

    Important Name Reactions

    Uploaded by

    bibek64m5
    17 views10 pages
    The document describes several important name reactions in organic chemistry including: 1) The Sandmeyer reaction which is used to synthesize aryl halides from aryl diazonium salts. 2) The Gatterman reaction in which bromine and chlorine are introduced into the benzene ring by preparing the diazonium salt solution with the corresponding halogen acid. 3) The Balz-Schiemann reaction where arene-diazonium chloride reacts to yield aryl fluoride on heating.

    Original Description:

    name reactions

    Original Title

    IMPORTANT NAME REACTIONS

    Copyright

    © © All Rights Reserved

    Available Formats

    DOCX, PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    The document describes several important name reactions in organic chemistry including: 1) The Sandmeyer reaction which is used to synthesize aryl halides from aryl diazonium salts. 2) The Gatterman reaction in which bromine and chlorine are introduced into the benzene ring by preparing the diazonium salt solution with the corresponding halogen acid. 3) The Balz-Schiemann reaction where arene-diazonium chloride reacts to yield aryl fluoride on heating.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    17 views10 pages

    Important Name Reactions

    Uploaded by

    bibek64m5
    The document describes several important name reactions in organic chemistry including: 1) The Sandmeyer reaction which is used to synthesize aryl halides from aryl diazonium salts. 2) The Gatterman reaction in which bromine and chlorine are introduced into the benzene ring by preparing the diazonium salt solution with the corresponding halogen acid. 3) The Balz-Schiemann reaction where arene-diazonium chloride reacts to yield aryl fluoride on heating.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    of 10

    IMPORTANT NAME REACTIONS

    Sandmeyer Reaction :- The Sandmeyer reaction is a chemical reaction


    which is used to synthesize aryl halides from aryl diazonium salts. This
    reaction is a method for substitution of an aromatic amino group by
    preparing diazonium salt that is followed by its displacement and copper
    salts often catalyze it.

    Gatterman Reaction :- Bromine and Chlorine can be present in the benzene


    ring by preparing the benzene diazonium salt solution with similar
    halogen acid present with copper powder. This is the Gattermann Reaction.

    Balz-Schiemann Reaction :- When arene-diazonium chloride is prepared with


    fluoroboric acid, arene diazonium fluoroborate is precipitated and
    decomposes to yield aryl fluoride on heating.

    Finkelstein Reaction :- In the Finkelstein Reaction Alkyl iodides are


    prepared easily by the reaction of alkyl chlorides with Nal in dry
    acetone.

    Swarts Reaction :- When alkyl chloride is heated in the presence of a


    metallic fluoride like AgF, Hg2F2, SbF3 or CoF2, we get alkyl fluorides.
    Wurtz Reaction :- When Alkyl halides get reacted with sodium with dry
    ether, we get hydrocarbons that include the double number of carbon atoms
    present in the halide. This is known as the Wurtz Reaction

    Wurtz-Fittig reaction :- When a mixture of alkyl halide and aryl halide


    gets treated with sodium in dry ether, we get an alkyl arene.

    Fittig reaction :- Aryl halides prepared with sodium in dry ether to give
    analogous compounds where two aryl groups joined

    Reimer-Tiemann Reaction:
    When preparing phenol with chloroform in the presence of sodium hydroxide,
    -CHO group is present at the ortho position of the benzene ring which
    results into salicylaldehyde.

    Kolbe’s reaction :- reacts with sodium hydroxide to give sodium phenoxide


    which then reacts with carbon dioxide in acidic medium to give
    hydroxybenzoic acid.
    Friedel-Crafts Alkylation : -

    Rosenmund reaction :-

    Stephen reaction :-
    Friedel-Crafts Acylation :-

    Etard reaction :- Chromyl chloride oxidizes methyl group to get chromium


    complex which on hydrolysis provides corresponding benzaldehyde.

    Gatterman – Koch reaction:-


    Tollen’s Test :-
    Heating an aldehyde with fresh prepared ammoniacal silver nitrate solution
    produces a bright silver mirror due to the formation of silver metal.

    Fehling’s test :-
    Fehling’s solution A (aqueous copper sulfate) and Fehling solution B
    (alkaline sodium potassium tartrate) are mixed in equal amounts before the
    test. A reddish brown precipitate is obtained when an aldehyde is heated
    with Fehling’s reagent.

    Aldol condensation :-

    Kolbe’s electrolysis :-
    Cross Aldol condensation :-

    Cannizaro reaction :-

    Hell-Volhard-Zelinsky(HVZ) reaction :-
    Carboxylic acids having a α-hydrogen are halogenated at the α-position
    give α-halo carboxylic acids on treatment with chlorine or bromine in the
    presence of small amount of red phosphorus.

    Gabriel phthalimide synthesis :-


    Hoffmann Bromamide degradation :-

    Carbylamine reaction :-
    The isocyanide identifies as a foul smelling product.

    Hinsberg test :-

    Schimidt reaction :-
    Perkin reaction :-

    Schotten Baumann reaction:-

    Liebermann’s nitroso reaction :-

    Kolbe – Schimidt reaction :-

    Hunsdiecker reaction :-

    Hofmann’s ammonolysis :-

    Iodoform reaction :-
    Fries rearrangement :-

    Esterification :-

    Diazotisation :-

    Claisen reaction :-

    Claisen condensation :-

    Benzoin reaction :-
    Balg-Schiemann reaction :-

    Benzoylation reaction :-

    You might also like