beats IFIRST YEAR HIGHER SECONDARY IMPROVEMENT/SUPPLEMENTARY | EXAMINATION, SEPTEMBER 2023 Part — IIT Time : 2 Hours CHEMISTRY Cool-off time : 15 Minutes Maximum : 60 scores General Instructions to Candidates : © There is a ‘Cool-off time’ of 15 minutes in addition to the writing time. © Use the ‘Cool-off time’ to get familiar with questions and to plan your answers. * Read questions carefully before answering. ‘* Read the instructions carefully. © Calculations, figures and graphs should be shown in the answer sheet itself. * Malayalam version of the questions is also provided. * Give equations wherever necessary. «Electronic devices except non-programmable calculators are not allowed in the Examination Hall. Alaysdaclacianas an1nmibageosma8 : © élay rawaraiay ajoon 15 alg’ “yA Boas onse’ gersoalalanye: © B48 Boas’ So’ GaIBJEND alGlswagJsoMjo BODEN GAM}@msMo OalQOMJe Qalewauiana>, © LOMA aNNOMOld ani ea10a\sn (avoaHBgQJoa1ow1anaM0. © Mdaquramd aysaImyo (YAvInNBQJo A1NDIaasMo. * eames’ @1genaB, aflyand, WoaD}OWB, aHea PEMA! OHM Qmeowialaname. © canajend aemogomielje mgfasyme. 8 aRA\QEB MuDEIETAY Moaaioe\sMAB Ha05}296Mo. © cpinwromad® saigomacram aocienjceignad avinamjes &0} MeISeSoAMIe’ Qaisoemarye aidlassoanges DaowoeAlsajaio0 alosigy. ) F-3225 1 P.T.O.Answer any four questions from 1 to 5. Each carries 1 score. (4x1=4) The mass of 2 moles of CH, The IUPAC name of an element with atomic number 109 is Which among the following is an example for a Lewis acid ? (@ NH, (&) HET © BF; (@ #80, During Lassaigne’s test, halogens are precipitated as The cold dilute aqueous solution of KMnO, is known as Answer any eight questions from 6 to 15. Each carries 2 scores. (8x2=16) NO and NO, are two oxides of nitrogen. (@) Which law of chemical combination is illustrated by these compounds 2 a (b) State the Jaw mentioned above. @ Name any four spectral lines’of Hydrogen atom. (i) Write the n and / values of 4p electron, a) Gif State Aufbau principle. ) F-3225 * 2 ‘9. Electron gain enthalpy is an important periodic property. @__ Define electron gain enthalpy: | @ Gi) Why is the electron gain enthalpy of Fluorine less negative than that of Chlorine ? a 10. (i) Whats ionization enthalpy ? a Gi) First ionization enthalpy of Boron is less than that of Beryllium. Why ? @ 11. (i) Whatis state function ? . gd) (ii) Write any two examples for State function. qa) 12. Write the conjugate acid and conjugate base of the following : @ NH; ag Gi) HS0; w@ 13. Using stock notation, represent the following compounds : @ HAuCl, qa (i) Mn0, @ 14. Write the IUPAC name of the compounds given below : @ CH;-CH, ~CH-CH,-CH - CH, @ | I OH CH, i) CH; -CO-CH, - CH, - CH, - COOH qa) 15. Write any two differences between homolytic and heterolytic bond fission. F-3225 420. 21. 22. Answer any eight questions from 16 to 26, Ench carries 3 scores. Ina chemical reaction 6 g Hydrogen reacts with 40 g Oxygen to give water. (i) Identify the limiting reagent in this reaction. (ii) Calculate the amount of H,0 produced. (ii) Define limiting reagent. (i Write any two characteristic properties of cathode rays. (ii) What is photoelectric effect ? What are its characteristics ? A cation is smaller than the corresponding neutral atom, while anion is larger. Give reason. (Write the molecular orbital electronic configuration of Fluorine molecule. (ii) Find the bond order of Fluorine molecule. (i) Write any two postulates of Valence Shell Electron Pair Repulsion (VSEPR) theory. (ii) Write the hybridization of Sulphur in SF,. (i) What is spontaneous process ? Gi) Find the temperature above which the reaction MgO, + Cy, > Mg + CO) becomes spontaneous. (AH = 490 kJ/mol, AS = 198 JK/mol) Explain how the value of equilibrium constant is useful in predicting the extent of a reaction. F-3225 6 (8x 3=24) (1) q m0) a) Q) @ Q) @ @ Q@ @23, (i) "Define the electronic concept of oxidation and reduction. @ (ii) What is disproportionation reaction ? Give example. @) 24. Different methods are used to purify organic compounds. (i) Write the name of any two methods. @ (ii) Which method is suitable for the separation of a mixture of aniline and water? (1) (iii) Which compound is responsible for the prussian blue colour in the Lassaigne’s test for nitrogen ? @ 25. Write the name of the products formed in the following chemical reaction : a Red hot Fe tube @. 3cH= cH ® i w Gi) gg +30, ® (i) 2CH,-Br+2Ne—_, : ® 26. Analkene on ozonolysis gives two molecules of ethanal. (i) Identify the alkene. qd) (ii) Write the chemical equation of this reaction. qd) iii) Draw the geometrical isomeric forms of this alkene. @ Answer any four questions from 27 to 31. Each carries 4 scores. (4x 4=16) 27. (i) Write any two postulates put forward by Rutherford in his nuclear model of atom. Q) (ii) State Heisenberg’s uncertainty principle. Write mathematical equation for it - (2) F-3225 829 Gy «th 29. (i) Gi) 30. (i) Gi) ii) 31. Gi) F-3225 Define dipole moment. Dipole moment of BF; is zero. Why ? Explain the shape and bond angle of NH, molecule using VSEPR theory. Define extensive and intensive properties. Give one example for each. ‘The equilibrium constant for a reaction is 5. What will be the value of AG? ? (R= 8.314 JK" mol, T= 300 K) Define ionic product of water. Give an application of Common ion effect. Calculate the pH of a 0.1 M solution of NaOH. Explain any two types of electron displacement effects in covalent bonds. Name two methods used to estimate the presence of nitrogen in an organic compound, 10 @ a) @) @ @) () @ @ 8) @,