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Code: 1122-23 CH-A

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CLASS-XI
CHEMISTRY (THEORY) (043)
ANNUAL EXAM (2022-23)
Marimum Marks: 70
Timealloued :3 hours
General Instruction
(a) There are 35 questions in this question paper with internal choice.
mark each.
(b) Section A consists of 18 multiple choice questions carrying I
2 marks each.
c) Section B consists of 7 very short ansuer questions carrying
short questions carrying 3 marks each.
d Section C consists of 5 answer

marks each.
(e) Section D consists of 2 case based questions carrying4
long ansuer questions carrying 5 marks each.
Section E consists of 3
All questions are compulsory.

(h)Use of log tables and calculators is not allowed.

15 minute time has been allotted to read the question paper.

Section-AA

The following questions are multiple-choice questions with one correet answer.

Each question carries 1 mark. There s no internal choice in this section.

In a chemical reaction X + 2Y XY2, if Y 1s acting as a limiting reagent, then ehoose

the correct option

a)5moles 10 moles

(b) 10 moles 20 moles

C moles 3 moles

moles 20moles
2 The energy of an orbital in a multielectron atom dependn on the

(a
Principal quantum number
(b) Principal and azimuthal quantum number

(e) Principal, azimuthal and magnetic quantum numbers

d Principal, azimuthal and spin quantum numbers

The reaction 3CIO (aq)3CI0, (aq) 2C1 (aq) in an exampie o

(a) Oxidation reaction only

b Reduction reaction only

Disproportionation reaction
d Thermal decomposition reaction

3
4 Given that: Sg) O218 s0g)+ 2x kl

sO2g) O2g) »S0a(g)+y kJ

The enthalpy of formation of SO,g will be :

(a x +y (b)xy
(c) 2x+y (d 2x-y
6. The IUPAC name of the following compound in
:

CH-CH-C-CH,
CH CH

(a) 5,5,6-Trimethyloctane

(b) 3,4.4-Trimethyloctane

(e) 2-Butyl-2- methyl-3-ethyibutane

d 4-Butyl-3,4-dimethypentane
In Duma's method, the gas collected in the upper part of graduated tube of nitrometer

is :
(a) NO (b) NH
(e) (d) H,
The momentum of a particle having de Broglie wavelength of 0.1 nm is
Given h = 6.626 x 10- Js)

(a) 6.626 x 10 Kg m » (b) 6.626 x

10 Kg mns
(c) 6.626 x 10" Kg ms' (d) 6.626 x 10-4 Kg ms

Identify the correct statement in relation to the following reaction :

Zn 2HCI ZnC1, + H
(a) Zinc is acting as an oxidant

(b) Chlorine is acting as a reductant

ion is acting as an oxidant

(e) Hydrogen

(d) Zanc ion is acting as a reductant

10. During Lassaigne's test, S and N present in the compound change into :

(a)NaS and NaCN (b) Nn,so, and NaCN

(c) Na,S and NaCNO d) NaCN

che
 n the given diagram, i f C, is rotated anticlockwise 60 about 2 *ond, the

resulting conformer will be

C2 carbon
1 carbon- in rear
n tront

(a Staggered b) Partially eclipsed

e)Eclipsed d Skew

12 Glycerol can be separated from spent lye in soap industry by using the technique

a) Steam distillation

b) Distillation under reduced pressure

(c)Diflerentialextraction
d) Fractional distillation

13. According to Fajan's rules, the covalent bornd i8 favoured by

(a) Small cation and small anion

cauon and snall anion

Arke
D
and large anion
c ) L a r g e cation

Small cation and large anion

d
14 I f CO, is allowed to escape from the Tolowing reaction at equilibrium

Co2 H,0 H,co 2H 2 HCo

(b) pH will remain constant
(a)pH will decrease
Porward reaction will be favoured
C ) p Hw i l l increase
(d
 labelled Assertion
to 18 two s t a t e m e n t s
are given one
numbers 15
For Question correct answer to these questions
Reason (R). Seleet the
A) and the other labelled
below
and (d), as given
(a), ib), (e)
from
the codes statements, and Reason
(R) 18
Keason (R) are c o r r e c t
Both Assertion (A) a n d
a
the correet explanation of the Assertion 1A

but Reason R) 1s
statements
and Reason (R) are correct
bBoth Assertion
1A (Al
NOT the correct explanation of the Assertion
statemernt
incorrect
but Reason iR)
1s
1s corect
Assertion
(A
Assertion (A) is incorrect but Reason (R) is correct statement.
d
in a

increases from left to rnght

Assertion A): lonization enthalpy generally
15

PT orbitals in the same

added to the
successive electrons are
Reason (R): When
of electrons does not
of inner core
level, the shielding etfect
pincapalquantum to the
increased attracti1on of electrons
the
increase very much to compensate for

nucieus
molecules are sp
Assertion (A) : Though the central atom of both NH, and
H,O
16
smaller than the bond angle of water

of ammonia is
hybridised. yet bond angle
molecule
atom in

in ammonia has one lone pair and oxygen

(R): Nitrogen atom
Reason

water has two lone pairs.

reaction
Assertion (A) : In the following

aqSCN aq |FeSCN aq
FeYellow Colourles Deep Red
acid.
of red colour
decreases on adding oxalie
the intensity
the equilibrium in
ions react with ternic 1ons thereby shitting
Reason
(R): Oxalate
backward direction

of resonanee hybid
is equal to the average ot energies of
Assertion (A): Energy
all canonical torms
single structure.
be presented by a
Reason (R): Resonance hybrid cannot
 Section-B

internal choice
in two questions
Tnisseetion contains 7 questions with

0lowing questions are very short

a n s w e r type and carry
2 marks eact
n *o
20 g NaOH
19. Calculate molarity of a solution which is prepared by adding
1.05 g em".
of water. Density of solution is

(Given: Molar mass of NaOH » 40 g mol

can be m e a s u
20. A table tennis ball has a mass of 10 g and speed of 90 ms. 1f speed
within an aceuracy of 5 . 6 , determine the uncertainty in speed and posIEOn

OR
Arsenic
The threshold frequeney for the emission of electron from the metal
of emission
Hz. Caleulate the work funetion of the metal and wavelength
10*
electron.

isoelectronic with N=
21. (a) Give example of one cation and one anion that will be
with electron=
(b)Prediet the position of an element in the periodie table
configuration (n-1d'ns", for n =4.

medium
following redox reaction equation in basic
:
22. Balance the

ICnOH)nq H,O2 taq) Cro,(ag H,O

OR

in acidie medium:
Balance the following redox reaction equation
Cu NO, (ag Cu twgt NO,
23. (a) State Hund's rule of maximum multiplicity.

(b) Write the electronic configuration of an element with atomic number 24.

24. Butan-2-one and pentan-2-one are the ozonolysis products of an alkene. Write the-
10PAC name of the alkene and draw its cis and trans isomers

Che
25 Explain the tollowing observations

(a Ethyne shows acidie character

douDe
it contains three
ordinarily stable although
nene

is extra
SectionC

This seeton contains 5 questions with internal choice in two q u e o The

marks eae
and earry 3
Tolow inE questiens are short answer type
in n
transition of an electron aom
a c u a t e the energy in Joule for the emission

at 2116 pm
476.1 pm and ends
t starts from the orbit having radius
t
elements according to property
mentioned against -
Aange the tollowing

1aSi. Be, Mg. Na, P (increasing order of metallie

character
size)
(b) 0. 0 , 0 1decreasing order of
enthalpy)
order of electron gain
CI. Br. I (decreasing
(c) F.
DR

of e l e m e n t s
he tollowing trends in the penodie properties
Explain
to right in the
of elements increases on moving trom left
aElectronegativity

periodie able.

to bottom.
lonization enthalpy decreases
in a group trom top
(b)

c) First 1onization enthalpy of nitrogen is more than that of oxygen.

reaction at 300 K if AH =
40.8 k mol and
the feasibility of a
Predict
2 a
AS =
110 J R mol

leading to more randomness s alway8 spontaneous.

An exotherInie procss
bi

Explain
structural tormula of metamer of diethyl ether
29 a
Write the
 isomerism shown by
the of structural
Identify type

CH-0-CH-CH2-CH, and CH-0-CH-CH-CH3

CH CH
CH3
out of the tollowing
dentity the electrophiles and nucleophiles
6
OH
BP,.CH,NH, CH CH, intermediates
in the

show the formation of reactive

y usinaK curved arrows,

following cases

(1Heterolytic fission of CH,

Homolytic fission of CH,CT

n
of an o r g a n i e phosphorvu
a n estimation of phosphorous by Carius method, 0. 25 g ot phosphorous
percentage
Calculate the
mpound gave 0.444 g of MP,O.
present in the given organie compound 31)
P
= 222 g m o l ,
atomic
mass ot
e n M o l a r mass
of Mg,P,0, their stability
order of
in the inereas1ng
b ArTange the following
species
CH3
CHCHCH
CH3 CHTH H -
CH3

Section-D
internal
questions. Each question has an

are case-based
The following questions

choice and carries marks each.

2+2
answer the questions that follow:
and
carefully
31. Read the passage
of a compou nd
defines its chemical identity, and chemica
makeup
The elemental When a
of representing this elemental makeup.
most succinet way
formulas are the constituent
mass ot each of its
he

compounds
formula 1s unknown,
heas uning formula
in the process ot determining the
often the isrt tep
elements 1s
of the
these measurements permit the calculation
exper mentally.
The results
o of each element
defined as the percentage by mass
composition,
compounds percent useful tor evaluating the relative
composition is also
Fercent
in the compound
 aDundance of a
given element in
different compounds o*
enple, consider the common
nitrogen containing fertalizera hium nitrate
a molar mass- 80 g) and urea
(NH,CONH, molar mass K
r g e n (atomic masn- 14u) in the nctive ingredient for ngricultural purposes,
e mass peroentage of nitrogen in the compound is a practical and economie
concern for consumers choosing among these fertilizers Any experi mentally aderivea

data derive the corresponding numbers ot

involving
the compound
mass must be used to
This is accomplished using molar masses to conveert the mass of each
atoms in
element to a number of moles. These mlar amounta are used to compute whole

the empirical formula of the substance

number ratios that can be used to derive

and ammonium nitrate.

Calculate the mass percentage of Nitrogen in urea
(a)

and 0.320 g of Oxygern

(b) The sample ofa compound contains 0.140 g of Nitrogen
Derive the empirical formula of the compound

OR
molar mass is 150 g mol
and its
Empincal formula of a compound is CH,O
Derive its molecular formula.
follow: Ix=4
questions that
32 Read the passage carefully
and
answer the
out in such a way
be reversible, if a change is brought
said to
A process or change is
infinitesimal change. A
moment be reversed by an
at any
that the process could, such
of equihbrium states
by a series
reversible proceeds infinitely slowly
process, each other
with
always in near equilibnum
s u r r o u n d i n g s are
that system and the irrevers1ble processes. We
are known as
reversible processes
Processes other than reversible conditions by
of the system under
work to internal pressure
can relate

writung

Pin dp' dv
We

write
we can
fhall
x dv is ver
Sihoe
dp

Pa P n l N
Wre
 reversibie change ?
isothermal
correct option for an
" * the following is

(i)
- P, V, -V,
(t#) - nRT In ;

RT lo
V

vacuum. The work done

mholes of an ideal gas is expanded spontaneously into
will be

(1) Infine

Tero

C Thee work dorne during expansion of a gas from a volume of 4 L to 6 L against

constant external pressure of 3 atm is (1 L atm = 101.32 J)

- 6 J b 608J
C) S04 J d 3 304 J

OR

When an ideal gas is compresed reversibly or irreversibly from V, to V, then

(a) (b)

(c) W>re pex AV

a e Te
d) The work done during compression of a gas is always :

a)Intinite Positive

c) Negative d ero

Secuon-E

3 a)Decnbe the eeet

)addition of NH,

1)ncrease i i prennure
on the equilibrium o the reacton

N2 *) 3H2 *) 2NHs*"

e
 (b) The values of Ksp of two slightly soluble salts XY and AB, are 1.0 x
10
saturatedd
4.0 x 10 "respectively 298 K. Caleulate the molarities ot
at
the 3
solutions and identify the salt which is more soluble.

34. (a) Write the molecular orbital configuration of N; and O* and also predict une
2
magnetic nature. moment

moments and resultant dipole

epresent diagrammatically the bond
D
in NF, molecule.
VSEPR mode.
molecule using
(c) Discuss the shape of CIF,
OK
2
below
a r e given
compounds
( a ) S r u c t u r e s
of molecules of two
OH OH çO

OH
B)
A)
(B).
present in (A) and
of H- bonding
Name the type point
i) higher melting
will show
compounds
above t w o
(ii) Which
of the Give reason
increasing
1onic
eharacter.

order of 2
bonds in
Arrange
the following
(b)
answer.

your
to support
0-H
C-H and
N-H, F-H,
hybrid orbitals
associated
with
sp
and
dsp
(c)
Write the shapes from 3-ethylpent
obtained
products
of the major
organic 3
structures
conditions:
(a) Give the reaction
35. following
2-ene
under each of the
of peroxide
presence
HBr i n
(i)

in
presence
of
Ce
(i) Br
ii) Hg* / H,O"
 (b) ow the following conversions with suitable chemical equation

)ethane to butane

(ii) ethyne to ethanoic acid

OR
(a)
Complete the following reactions

Cl2
Anhyd. AIC

OH
(iin)
Zn

(b) Name the product obtained when

benzene is treated with
presence of Anhyd. 2-Chloropropane in
AlCl
(c) State any two
characteristics ot the tollowing compound
aromatic nature. hat explains its