Name: Razel P.

Centino Program: BSECE - 1A

Instructor: Rhea Mae Biñar Date: 13/11/2023

SELF ASSESSMENT 1

Balance the following chemical equations:

1. PCl5(s) + H2O(1) → POC13(l) + HCl(aq)
= PCl5 + H2O → POC13 + 2HCl
2. Cu(s) + HNO3(aq) → Cu(NO3)2(aq) + H2O(l) + NO(g)
= 3Cu + 2HNO3 → 3Cu(NO3)2 + 4H2O + 2NO
3. H2(g) +I2(s) → HI(s)
= H2 + I2 → 2HI
4. Fe(s) + O2(g) → Fe2O3(s)
= 4Fe + 3O2 → 2Fe2O3
5. Na(s) + H2O(l) → NaOH(aq) + H2(g)
= 2Na + 2H2O → 2NaOH + H2
6. (NH4)2Cr2O7(s) → Cr2O3(s) + N2(g) + H2O(g)
= (NH4)2Cr2O7(s) → Cr2O3(s) + N2(g) + 4H2O(g)
7. P4(s) + Cl2(g) → PCl3(l)
= P4 + 6Cl2 → 4PCl3
8. PtCl4(s) → Pt(s) + Cl2(g)
= PtCl4(s) → Pt(s) + 2Cl2(g)
9. Ag(s) + H2S(g) + O2(g) → Ag2S(s) + H2O(l)
= 4Ag + 2H2S + O2 → 2Ag2S + 2H2O
10. P4(s) + O2(g) → P4010(s)
= P4(s) + 5O2(g) → P4010(s)

SELF ASSESSMENT 2

11. Hydrogen gas reacts with carbon monoxide to yield methanol (CH3OH). How many
grams of methanol are formed when 15.6 g of hydrogen reacts with excess carbon
monoxide? H2 + CO → CH3OH

Sol’n:
H2 + CO → CH3OH
Balanced chemical equation: 2H2 + CO → CH3OH

To find the molar mass:

For H2: 2(1.008 g/mol) = 2.016 g/mol
For CH3OH: 1(12.01 g/ml) + 4(1.008 g/mol) + 1(16 g/mol) = 32.042 g/mol
 1 𝑚𝑜𝑙 𝐻2 1 𝑚𝑜𝑙 𝐶𝐻3𝑂𝐻 32.042 𝑔 𝐶𝐻3𝑂𝐻
15.6 g H2 x 2.016 𝑔 𝐻2 x 2 𝑚𝑜𝑙 𝐻2 x 1 𝑚𝑜𝑙 𝐶𝐻3𝑂𝐻
= 123.97 g CH3OH

12. How many moles of carbon dioxide are formed in the fermentation of 75 g of
glucose? C6H12O6 → CO2 + C2H5OH

Sol’n:

C6H12O6 → CO2 + C2H5OH

Balanced chemical equation: C6H12O6 → 2CO2 + 2C2H5OH

To find the molar mass:

For C6H12O6: 6(12.01 g/mol) + 12(1.008 g/mol) + 6(16 g/mol) = 180.156 g/mol

1 𝑚𝑜𝑙 𝐶6𝐻12𝑂6 2 𝑚𝑜𝑙 𝐶𝑂2

75 g C6H12O6 x 180.156 𝑔 𝐶6𝐻12𝑂6 x 1 𝑚𝑜𝑙 𝐶6𝐻12𝑂6
= 0.8326 mol CO2

13. The thermite reaction (Fe2O3 + Al → Fe + Al2O3) can be used to ignite solid-fuel
rockets or bombs. How much aluminum (in g) is needed to react with 10.0 g of
Fe2O3?

Sol’n:

Fe2O3 + Al → Fe + Al2O3
Balanced chemical equation: Fe2O3 + 2Al → 2Fe + Al2O3

To find the molar mass:

For FE2O3: 2(55.845 g/mol) + 3(16 g/mol) = 159.69 g/mol
For Al: 1(26.982 g/mol) = 26.982 g/mol

1 𝑚𝑜𝑙 𝐹𝐸2𝑂3 2 𝑚𝑜𝑙 𝐴𝑙 25.982 𝑚𝑜𝑙 𝐴𝑙

10.0 g FE2O3 x 159.69 𝑔 𝐹𝐸2𝑂3 x 1 𝑚𝑜𝑙 𝐹𝐸2𝑂3 x 1 𝑚𝑜𝑙 𝐴𝑙
= 3.379 g Al

24
14. How many moles of H2O can be formed in a combustion of 4. 125𝑥10 molecules
of CH4?

Sol’n:

24
4.125𝑥10
Moles of CH4 = 23 Moles of H2O = 2 x 7
6.022𝑥10
Moles of CH4 = 7 moles Moles of H2O = 14 mol
 15. How many grams of ethanol is produced in the fermentation of 2.108 x 10^25
molecules of glucose? C6H12O6 → CO2 + C2H5OH

Sol’n:
Convert moles to gram:
24
4.125𝑥10 46.07 𝑔
Moles of C6H12O6 = 23 35 mol x 1 𝑚𝑜𝑙
6.022𝑥10
Moles of C6H12O6 = 35 mol = 1,612.45 g

SELF ASSESSMENT 3

16. Identify the limiting reactant and how much ammonia gas can be produced when 7.2
g of nitrogen gas react with 1.5 g of hydrogen gas by the use of the Haber process: H2
+ N2 → NH3.

Sol’n:

H2 + N2 → NH3
Balanced chemical equation: 3H2 + N2 → 2NH3

To find the molar mass:

For N2: 2(14.01 g/mol) = 28.02 g/mol
For H2: 2(1.008 g/mol) = 2.016 g/mol
For NH3: 1(14.01 g/mol) + 3(1.008 g/mol) = 17.034 g/mol

Use the molar masses and mole ratios to set up the calculation: For each reactant, compute
the amount of product that would be formed.

For N2:
1 𝑚𝑜𝑙 𝑁2 2 𝑚𝑜𝑙 𝑁𝐻3 17.034 𝑚𝑜𝑙 𝑁𝐻3
7.2 g N2 x 28.02 𝑔 𝑁2 x 1 𝑚𝑜𝑙 𝑁2 x 1 𝑚𝑜𝑙 𝑁𝐻3
= 8.75 g NH3
For H2:
1 𝑚𝑜𝑙 𝐻2 2 𝑚𝑜𝑙 𝑁𝐻3 17.034 𝑚𝑜𝑙 𝑁𝐻3
1.5 g H2 x 2.016 𝑔 𝐻2 x 3 𝑚𝑜𝑙 𝐻2 x 1 𝑚𝑜𝑙 𝑁𝐻3
= 8.45 g NH3

Therefore, the limiting reactant is H2.

17. Identify the limiting reactant and how much carbon dioxide gas can be produced
when 15.2 g of methane react with 18.5 g of oxygen gas to produce water and carbon
dioxide. CH4 + O2 →CO2 + H2O.

Sol’n:
 CH4 + O2 →CO2 + H2O
Balanced chemical equation: CH4 + 2O2 →CO2 + 2H2O

To find the molar mass:

For CH4: 1(12.01 g/mol) + 4(1.008 g/mol) = 16.042 g/mol
For O2: 2(16 g/mol) = 32 g/mol
For CO2: 1(12.01 g/mol) + 2(16 g/mol) = 44.01 g/mol

Use the molar masses and mole ratios to set up the calculation: For each reactant, compute
the amount of product that would be formed.

For CH4:
1 𝑚𝑜𝑙 𝐶𝐻4 1 𝑚𝑜𝑙 𝐶𝑂2 44.01 𝑚𝑜𝑙 𝐶𝑂2
15.2 g CH4 x 16.042 𝑔 𝐶𝐻4 x 1 𝑚𝑜𝑙 𝐶𝐻4 x 1 𝑚𝑜𝑙 𝐶𝑂2
= 41.70 g CO2
For O2:
1 𝑚𝑜𝑙 𝑂2 1 𝑚𝑜𝑙 𝐶𝑂2 44.01 𝑚𝑜𝑙 𝐶𝑂2
18.5 g O2 x 32 𝑔 𝑂2 x 2 𝑚𝑜𝑙 𝑂2 x 1 𝑚𝑜𝑙 𝐶𝑂2
= 12.72 g CO2

Therefore, the limiting reactant is O2.

18. Identify the limiting reactant and how much nitric acid can be produced when 60.0 g
of nitrogen dioxide reacts with 18.5 g of water to produce nitric acid and nitrogen
monoxide. NO2 +H2O → HNO3 + NO.

Sol’n:

NO2 + H2O → HNO3 + NO

Balanced chemical equation: 3NO2 + H2O → 2HNO3 + NO

To find the molar mass:

For NO2: 1(14.007 g/mol) + 2(16 g/mol) = 46.007 g/mol
For H2O: 2(1.008 g/mol) + 1(16 g/mol) = 18.016 g/mol
For HNO3: 1(1.008 g/mol) + 1(14.007 g/mol) + 3(16 g/mol) = 63.015 g/mol

Use the molar masses and mole ratios to set up the calculation: For each reactant, compute
the amount of product that would be formed.

For NO2:
1 𝑚𝑜𝑙 𝑁𝑂2 2 𝑚𝑜𝑙 𝐻𝑁𝑂3 63.015 𝑚𝑜𝑙 𝐻𝑁𝑂3
60.0 g NO2 x 46.007 𝑔 𝑁𝑂2 x 3 𝑚𝑜𝑙 𝑁𝑂2 x 1 𝑚𝑜𝑙 𝐻𝑁𝑂3
= 54.79 g HNO3
For H2O:
 1 𝑚𝑜𝑙 𝐻2𝑂 2 𝑚𝑜𝑙 𝐻𝑁𝑂3 63.015 𝑚𝑜𝑙 𝐻𝑁𝑂3
18.5 g H2O x 18.016 𝑔 𝐻2𝑂 x 1 𝑚𝑜𝑙 𝐻2𝑂 x 1 𝑚𝑜𝑙 𝐻𝑁𝑂3
= 129.42 g HNO3

Therefore, the limiting reactant is NO2.

19. Identify the limiting reactant and how much aspirin (C9H8O4) can be produced when
52.3 g of salicylic acid (C8H6O3) react with 25.0 g of acetic acid (CH3CO2H):
C8H6O3 + CH3CO2H → C9H8O4 + H2O.

Sol’n:

C8H6O3 + CH3CO2H → C9H8O4 + H2O

Balanced chemical equation: 8C8H6O3 + 13CH3CO2H → 10C9H8O4 + 10H2O

To find the molar mass:

For C8H6O3: 8(12.0 g/mol) + 6(1.008 g/mol) + 3(16 g/mol) = 150.128 g/mol
For CH3CO2H: 2(12.0 g/mol) + 4(1.008 g/mol) + 2(16 g/mol) = 60.052 g/mol
For C9H8O4: 9(12.0 g/mol) + 8(1.008 g/mol) + 4(16 g/mol) = 180.064 g/mol

Use the molar masses and mole ratios to set up the calculation: For each reactant, compute
the amount of product that would be formed.

For C8H6O3:
1 𝑚𝑜𝑙 𝐶8𝐻6𝑂3 10 𝑚𝑜𝑙 𝐶9𝐻8𝑂4 180.064 𝑚𝑜𝑙 𝐶9𝐻8𝑂4
52.3 g C8H6O3 x 150.128 𝑔 𝐶8𝐻6𝑂3 x 8 𝑚𝑜𝑙 𝐶8𝐻6𝑂3 x 1 𝑚𝑜𝑙 𝐶9𝐻8𝑂4
= 78.41 g C9H8O4
For CH3CO2H:
1 𝑚𝑜𝑙 𝐶𝐻3𝐶𝑂2𝐻 10 𝑚𝑜𝑙 𝐶9𝐻8𝑂4 180.064 𝑚𝑜𝑙 𝐶9𝐻8𝑂4
25.0 g CH3CO2H x 60.052 𝑔 𝐶𝐻3𝐶𝑂2𝐻 x 13 𝑚𝑜𝑙 𝐶𝐻3𝐶𝑂2𝐻 x 1 𝑚𝑜𝑙 𝐶9𝐻8𝑂4
= 57.66 g C9H8O4

Therefore, the limiting reactant is CH3CO2H.

20. Calculate the percentage yield if 6.3 g of ammonia were produced in self-assessment
no.16.

Sol’n:
𝑎𝑐𝑡𝑢𝑎𝑙 𝑦𝑖𝑒𝑙𝑑
% yield = 𝑡ℎ𝑒𝑜𝑟𝑒𝑡𝑖𝑐𝑎𝑙 𝑦𝑖𝑒𝑙𝑑 x 100
6.3 𝑔 𝑁𝐻3
= 8.45 𝑔 𝑁𝐻3 x 100
% yield = 74.56%
21. Calculate the percentage yield if 12.4 g of carbon dioxide were produced in
self-assessment no.17.

Sol’n:

𝑎𝑐𝑡𝑢𝑎𝑙 𝑦𝑖𝑒𝑙𝑑
% yield = 𝑡ℎ𝑒𝑜𝑟𝑒𝑡𝑖𝑐𝑎𝑙 𝑦𝑖𝑒𝑙𝑑 x 100
12.4 𝑔 𝐶𝑂2
= 12.72 𝑔 𝐶𝑂2 x 100
% yield = 97.48%

22. Calculate the percentage yield if 51 g of nitric acid were produced in self-assessment
no.18.

Sol’n:
𝑎𝑐𝑡𝑢𝑎𝑙 𝑦𝑖𝑒𝑙𝑑
% yield = 𝑡ℎ𝑒𝑜𝑟𝑒𝑡𝑖𝑐𝑎𝑙 𝑦𝑖𝑒𝑙𝑑 x 100
51 𝑔 𝐻𝑁𝑂3
= 54.79 𝑔 𝐻𝑁𝑂3 x 100
% yield = 93.08%

23. Calculate the percentage yield if 31 g of aspirin were produced in self-assessment

no.19.

Sol’n:
𝑎𝑐𝑡𝑢𝑎𝑙 𝑦𝑖𝑒𝑙𝑑
% yield = 𝑡ℎ𝑒𝑜𝑟𝑒𝑡𝑖𝑐𝑎𝑙 𝑦𝑖𝑒𝑙𝑑 x 100
31 𝑔 𝐶9𝐻8𝑂4
= 57.66 𝑔 𝐶9𝐻804 x 100
% yield = 53.76%

24. A teaspoon of table sugar contains about 0.01 mol sucrose. What is the molarity of
sucrose if a teaspoon of sugar has been dissolved in a cup of tea with a volume of 200
mL?

Sol’n:

𝑚𝑜𝑙𝑒𝑠 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑒
M= 𝐿 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛
0.01 𝑚𝑜𝑙
M= 1𝐿
200 𝑚𝐿 𝑥 1000 𝑚𝐿
𝑚𝑜𝑙
M = 0.05 𝐿
or 0.5 mol

25. Calculate the molarity of 6.52 g of CoCl2 (129.8 g/mol) dissolved in an aqueous
solution with a total volume of 75.0 mL.
 Sol’n:

To find the moles of COCl2:

1 𝑚𝑜𝑙 𝐶𝑂𝐶𝑙2
6.52 g COCl2 x 128.9 𝑔 𝐶𝑂𝐶𝑙2
mol = 0.05058 mol

0.05058 𝑚𝑜𝑙
M= 1𝐿
75.0 𝑚𝐿 𝑥 1000 𝑚𝐿
0.05058 𝑚𝑜𝑙
M= 0,075 𝐿
𝑚𝑜𝑙
M= 0.6744 𝐿 or 0.6744 M

26. How many grams of CaCl2 (110.98 g/mol) are contained in 250.0 mL of a 0.200-M
solution of calcium chloride?

Sol’n:

𝑚𝑜𝑙𝑒𝑠 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑒 1𝐿
M= 𝐿 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛
250.0 mL x 1000 𝑚𝐿 = 0.25 L
𝑚𝑜𝑙 𝑚𝑜𝑙𝑒𝑠 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑒
0.200 𝐿 = 0.25 𝐿
𝑚𝑜𝑙
M solute = (0.200 𝐿 ) ( 0.25 L)
M solute = 0.05 mol CaCl2

27. What volume of a 1.50-M KBr solution contains 66.0 g KBr?

Sol’n:

To find the molar mass:

For KBr: 1(39.098 g/mol) + 1(79.904 g/mol) = 119.002 g/mol

1 𝑚𝑜𝑙 𝐾𝐵𝑟
66.0 g KBr x 119.002 𝑔 𝐾𝐵𝑟 = 0.5546 mol KBr

To find the V solution:

𝑚𝑜𝑙𝑒𝑠 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑒
M= 𝐿 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛
𝑚𝑜𝑙 0.5546 𝑚𝑜𝑙 𝐾𝐵𝑟
1.50 𝐿
= 𝑣 𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛
0.5546 𝑚𝑜𝑙 𝐾𝐵𝑟
V solution = 𝑚𝑜𝑙
1.50 𝐿
 V solution = 0.37 L

28. What volume (in milliliters) of 0.150 M HCl is required to react completely with
0.503 g of dry Na2CO3? Na2CO3 + HCl → NaCl + H2O + CO2
Sol’n:

Na2CO3 + HCl → NaCl + H2O + CO2

Balanced chemical equation: Na2CO3 + 2HCl → 2NaCl + H2O + CO2

To find the molar mass:

For NA2CO3: 2(22.990 g/mol) + 1(12.01 g/mol) + 3(16 g/mol) = 105.99 g/mol

1 𝑚𝑜𝑙 𝑁𝐴2𝐶𝑂3 2 𝑚𝑜𝑙 𝐻𝐶𝑙 −3

0.503 g NA2CO3 x 105.99 𝑔 𝑁𝐴2𝐶𝑂3 x 1 𝑚𝑜𝑙 𝑁𝐴2𝐶𝑂3 = 9. 49𝑥10 mol HCl
𝑚𝑜𝑙𝑒𝑠 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑒
M= 𝐿 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛
−3
𝑚𝑜𝑙 9.49𝑥10 𝑚𝑜𝑙 𝐻𝐶𝑙
0.150 𝐿
= 𝑣 𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛
−3
9.49𝑥10 𝑚𝑜𝑙 𝐻𝐶𝑙
V solution = 𝑚𝑜𝑙
0.150 𝐿

V solution = 0.0633 L

Convert L to mL:
1 𝑚𝐿
0.0633 L x 0.001 𝐿
V solution = 63.3 mL

29. Analysis of a solution of NaOH showed that 42.67 mL of 0.485 M HNO3 was needed
to titrate a 25.00-mL sample of NaOH. What is the concentration of the NaOH
solution? HNO3 + NaOH → NaNO3 + H2O

Sol’n:

HNO3 + NaOH → NaNO3 + H2O

Balanced chemical equation: HNO3 + NaOH → NaNO3 + H2O

𝑚𝑜𝑙 1𝐿
0.485 𝐿
x (42.6 mL x 1000 𝑚𝐿 ) = 0.02 mol HNO3
1 𝑚𝑜𝑙 𝑁𝐴𝑂𝐻
0.02 mol HNO3 x 1 𝑚𝑜𝑙 𝐻𝑁𝑂3 = 0.02 mol NAOH

𝑚𝑜𝑙𝑒𝑠 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑒
M= 𝐿 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛
0.02 𝑚𝑜𝑙 𝑁𝐴𝑂𝐻
M= 1𝐿
25.00 𝑚𝐿 𝑥 1000 𝑚𝐿
 0.02 𝑚𝑜𝑙 𝑁𝐴𝑂𝐻
M= 0,025 𝐿
M = 0.8 M

30. What volume of 2.00 M HNO3 will react completely with 25.0 mL of 6.00 M NaOH?

Sol’n:

For NAOH: For HNO3:

V solution = 25.0 mL NAOH = 0.025 L M = 2.00 M HNO3

n = M x V = 0.025 L x 6.00 M NAOH

n = 0.15 mol

𝑚𝑜𝑙𝑒𝑠 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑒
M= 𝐿 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛

𝑚𝑜𝑙 0.15 𝑚𝑜𝑙 𝑁𝐴𝑂𝐻

2.00 𝐿
= 𝐿 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛

0.15 𝑚𝑜𝑙 𝑁𝐴𝑂𝐻

V solution = 𝑚𝑜𝑙
2.00 𝐿
𝐻𝑁𝑂3

V solution = 0.075 L