SAFETY DATA SHEET

Issue Date 09-Nov-2020 Revision Date 17-Oct-2023 Version 2.1 Page 1 / 14

Section 1: PRODUCT AND COMPANY IDENTIFICATION

Product identifier
Product Code(s) 2105569-LM
Product Name DPD Free Chlorine Reagent

Other means of identification

Safety data sheet number M00109

Recommended use of the chemical and restrictions on use

Recommended Use Water Analysis. Determination of chlorine.
Restrictions on use Please refer to the product labeling and packaging for information about appropriate use.
Uses advised against Consumer use

Details of the supplier of the safety data sheet

Supplier Address
Hexis Cientifica Ltda CNPJ: 53.276.010 / 00001-10 Av. Antonieta Piva Barranqueiros, 385 - Industrial District - Jundiai - SP -
Phone: 11 4589-2672

Manufacturer Address
Hach Company, P.O. Box 389, Loveland, CO 80539, USA, +1(970) 669-3050

Emergency telephone number

Argentina
Argentina: +(54)-1159839431
Ecuador
Ecuador: +593-01 800 000 906 (Access Code: 334846)
Costa Rica
Costa Rica - National Poison Center: +506-2223-1028
Colombia
Colombia: +57 601 7942539 / 01-800-7102151
United States of America
+1(303) 623-5716 - 24 Hour Service

Section 2: HAZARDS IDENTIFICATION

GHS Classification

Skin corrosion/irritation Category 2

Serious eye damage/eye irritation Category 2A
Specific target organ toxicity (repeated exposure) Category 2

Label elements

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Signal word - Warning

Hazard statements
H315 - Causes skin irritation
H319 - Causes serious eye irritation
H373 - May cause damage to organs through prolonged or repeated exposure

Precautionary statements
P280 - Wear protective gloves, protective clothing, eye protection, and face protection
P302 + P352 - IF ON SKIN: Wash with plenty of water and soap
P332 + P313 - If skin irritation occurs: Get medical attention
P362 + P364 - Take off all contaminated clothing and wash it before reuse
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing
P337 + P313 - If eye irritation persists: Get medical attention
P260 - Do not breathe dust/fume/gas/mist/vapors/spray
P314 - Get medical advice/attention if you feel unwell
P501 - Dispose of contents/ container to an approved waste disposal plant

Other Hazards Known

Other hazards which do not result in classification

No information available
0 % of the mixture consists of ingredient(s) of unknown acute oral toxicity
0 % of the mixture consists of ingredient(s) of unknown acute dermal toxicity
0 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (dust/mist)
0 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (vapor)
0 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (gas)

Section 3: COMPOSITION/INFORMATION ON INGREDIENTS

Substance
Not applicable

Mixture

Pure substance/mixture Mixture

Chemical Name Not applicable

Chemical Family Mixture

CAS No Not applicable

Chemical nature No information available.

Chemical name CAS No Percent Range

Carboxylate Salt - 60 - 70%
Phosphoric acid, disodium salt 7558-79-4 30 - 40%
Salt of N,N-Diethyl-p-Phenylenediamine - 1 - 5%
Disodium EDTA 139-33-3 1 - 5%

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Section 4: FIRST AID MEASURES

Description of necessary first aid measures
General advice Show this safety data sheet to the doctor in attendance.

Inhalation Remove to fresh air. Get medical attention immediately if symptoms occur.

Skin contact Wash off immediately with soap and plenty of water for at least 15 minutes. Get medical
attention if irritation develops and persists.

Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep
eye wide open while rinsing. Remove contact lenses, if present and easy to do. Continue
rinsing. Get medical attention if irritation develops and persists. Do not rub affected area.

Ingestion Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth
to an unconscious person. Do NOT induce vomiting. Call a physician.

For emergency responders

Self-protection of the first aider Avoid contact with skin, eyes or clothing.

Most important symptoms/effects, acute and delayed

Symptoms Burning sensation.

Indication of immediate medical attention and special treatment needed, if necessary

Note to physicians Treat symptomatically.

Section 5: FIRE FIGHTING MEASURES

Extinguishing media
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment. Product itself does not burn.

Unsuitable Extinguishing Media No information available

Specific hazards arising from the chemical

Specific hazards arising from the No information available.
chemical

Flammable properties
Can burn in fire, releasing toxic vapors.

Explosive properties
Not classified according to GHS criteria.

Hazardous combustion products Carbon monoxide, Carbon dioxide. Phosphorus oxides. Nitrogen oxides.

Specific/special fire-fighting measures

Specific/special fire-fighting No information available.
measures

Special protective equipment and precautions for fire-fighters

Special protective equipment for Firefighters should wear self-contained breathing apparatus and full firefighting turnout gear.
fire-fighters Use personal protection equipment.

Section 6: ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

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Personal precautions Ensure adequate ventilation. Use personal protective equipment as required. Evacuate
personnel to safe areas. Avoid contact with skin, eyes or clothing.

For emergency responders Use personal protective equipment as required.

Environmental precautions
Environmental precautions Prevent further leakage or spillage if safe to do so.

Methods and material for containment and cleaning up

Methods for containment Prevent further leakage or spillage if safe to do so.

Methods for cleaning up Take up mechanically, placing in appropriate containers for disposal.

Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.

Other Information Refer to protective measures listed in Sections 7 and 8.

Reference to other sections See section 8 for more information.

See section 13 for more information.

Section 7: HANDLING AND STORAGE

Preventive measures for safe handling
Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Ensure adequate
ventilation. Avoid contact with skin, eyes or clothing. Do not eat, drink or smoke when using
this product. Take off contaminated clothing and wash before reuse.

Precautions for safe handling

General Hygiene Considerations Wear suitable gloves and eye/face protection. Do not eat, drink or smoke when using this
product. Avoid contact with skin, eyes or clothing.

Conditions for safe storage, including any incompatibilities

Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place.

Incompatible materials Strong acids. Strong bases. Strong oxidizing agents.

Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Guidelines This product, as supplied, does not contain any hazardous materials with occupational
exposure limits established by the region specific regulatory bodies

Legend See section 16 for terms and abbreviations

Appropriate engineering controls

Engineering Controls Showers
Eyewash stations
Ventilation systems. Technical measures and appropriate working operations should be
given priority over the use of personal protective equipment.

Individual protection measures, such as personal protective equipment

Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits are
exceeded or irritation is experienced, ventilation and evacuation may be required.

Hand Protection Wear suitable gloves. Impervious gloves. Gloves must be inspected prior to use. The
selected protective gloves have to satisfy the specifications of EU Directive 2016/425 and
the standard EN 374 derived from it. Chemical resistant gloves made of butyl rubber or
nitrile rubber category III according to EN 374-1:2016. Barrier creams may help to protect

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the exposed areas of skin.

Eye/face protection If splashes are likely to occur, wear safety glasses with side-shields.

Skin and body protection Wear suitable protective clothing. Long sleeved clothing. Avoid contact with eyes, skin and
clothing. Wash contaminated clothing before reuse.

General Hygiene Considerations Wear suitable gloves and eye/face protection. Do not eat, drink or smoke when using this
product. Avoid contact with skin, eyes or clothing.

Environmental exposure controls Local authorities should be advised if significant spillages cannot be contained. Do not allow
into any sewer, on the ground or into any body of water.

Thermal hazards None under normal processing.

Section 9: PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Physical state Solid

Appearance powder Color White to light pink
White to brown
Odor Odorless Odor threshold No data available

Property Values Remarks • Method

Molecular weight No data available

pH 6.35 1% @ 20°C

Melting point / freezing point 110 °C / 230 °F

Initial boiling point and boiling range No data available

Evaporation rate Not applicable

Vapor pressure Not applicable

Relative vapor density No data available

Specific gravity - VALUE 1 1.76

Partition coefficient log Kow ~ 0

Soil Organic Carbon-Water Partition log Koc ~ 0

Coefficient
Autoignition temperature No data available

Decomposition temperature 110 °C / 230 °F

Dynamic viscosity Not applicable

Kinematic viscosity Not applicable

Solubility(ies)

Water solubility

Water solubility classification Water solubility Water Solubility Temperature

Completely soluble > 10000 mg/L 25 °C / 77 °F

Solubility in other solvents

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Chemical Name Solubility classification Solubility Solubility Temperature

Acid Soluble > 1000 mg/L 25 °C / 77 °F

Other information

Metal Corrosivity

Steel Corrosion Rate No data available

Aluminum Corrosion Rate No data available

Volatile Organic Compounds (VOC) Content

Not applicable

Chemical name CAS No Volatile organic compounds CAA (Clean Air Act)
(VOC) content
Carboxylate Salt - No data available -
Phosphoric acid, disodium salt 7558-79-4 No data available -
Salt of - Not applicable -
N,N-Diethyl-p-Phenylenediamine
Disodium EDTA 139-33-3 No data available -

Explosive properties

Upper explosion limit No data available

Lower explosion limit No data available

Flammable properties

Flash point Not applicable

Flammability Limit in Air

Upper flammability limit: No data available
Lower flammability limit: No data available

Oxidizing properties No data available.

Bulk density No data available

Section 10: STABILITY AND REACTIVITY

Reactivity
Not applicable.

Chemical stability
Stability Stable under normal conditions.

Explosion data
Sensitivity to Mechanical Impact None
Sensitivity to Static Discharge None.

Possibility of hazardous reactions

Possibility of Hazardous Reactions None under normal processing.

Hazardous polymerization

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None under normal processing.

Conditions to avoid
Conditions to avoid None known based on information supplied.

Incompatible materials
Incompatible materials Strong acids. Strong bases. Strong oxidizing agents.

Hazardous decomposition products

Carbon dioxide. Carbon monoxide. Phosphorus oxides. Nitrogen oxides.

Section 11: TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Product Information

Inhalation May cause irritation of respiratory tract.

Eye contact Irritating to eyes. Causes serious eye irritation.

Skin contact Causes skin irritation.

Ingestion Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.

Symptoms Redness. May cause redness and tearing of the eyes.

Acute toxicity
Based on available data, the classification criteria are not met

Mixture
No data available.

Ingredient Acute Toxicity Data

Test data reported below.

Oral Exposure Route

Chemical name Endpoint Reported Exposure Toxicological effects Key literature references and
type dose time sources for data
Salt of Rat 695 mg/kg None reported None reported Outside testing
N,N-Diethyl-p-Phenyl LD50
enediamine
(1 - 5%)
CAS#: -
Disodium EDTA Rat 2000 mg/kg None reported None reported RTECS
(1 - 5%) LD50
CAS#: 139-33-3

Inhalation (Dust/Mist) Exposure Route

Unknown Acute Toxicity

0% of the mixture consists of ingredient(s) of unknown toxicity.

Acute Toxicity Estimations (ATE)

The following values are calculated based on chapter 3.1 of the GHS document

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Oral LD50 No information available mg/kg

Dermal LD50 No information available
Mist 136.40 mg/L
Vapor No information available
Gas No information available

Skin corrosion/irritation
Classification based on data available for ingredients. Irritating to skin.

Mixture
No data available.

Ingredient Skin Corrosion/Irritation Data

Test data reported below.

Chemical name Test method Species Reported Exposure Results Key literature
dose time references and
sources for data
Phosphoric acid, Standard Draize Rabbit 500 mg 24 hours Skin irritant RTECS
disodium salt Test
(30 - 40%)
CAS#: 7558-79-4
Disodium EDTA Standard Draize Rabbit 500 mg 20 hours Not corrosive or ECHA
(1 - 5%) Test irritating to skin
CAS#: 139-33-3

Serious eye damage/irritation

Classification based on data available for ingredients. Irritating to eyes.

Mixture
No data available.

Ingredient Eye Damage/Eye Irritation Data

Test data reported below.

Chemical name Test method Species Reported Exposure Results Key literature
dose time references and
sources for data
Phosphoric acid, Standard Draize Rabbit 500 mg 24 hours Eye irritant RTECS
disodium salt Test
(30 - 40%)
CAS#: 7558-79-4
Disodium EDTA Standard Draize Rabbit 50 mg None reported Mild eye irritant ECHA
(1 - 5%) Test
CAS#: 139-33-3

Respiratory or skin sensitization

Based on available data, the classification criteria are not met.

Mixture
No data available.

Ingredient Sensitization Data

No data available.

STOT - single exposure

Based on available data, the classification criteria are not met.

Mixture
No data available.

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Ingredient Specific Target Organ Toxicity Single Exposure Data

No data available.

STOT - repeated exposure

May cause damage to organs.

Mixture
No data available.

Ingredient Specific Target Organ Toxicity Repeat Exposure Data

No data available.

Carcinogenicity
Based on available data, the classification criteria are not met.

Mixture
No data available.

Ingredient Carcinogenicity Data

No data available.

Chemical name CAS No ACGIH IARC NTP OSHA

Carboxylate Salt - - - - -
Phosphoric acid, disodium 7558-79-4 - - - -
salt
Salt of - - - - -
N,N-Diethyl-p-Phenylenedi
amine
Disodium EDTA 139-33-3 - - - -

Legend

ACGIH (American Conference of Governmental Industrial Hygienists) Does not apply

IARC (International Agency for Research on Cancer) Does not apply
NTP (National Toxicology Program) Does not apply
OSHA Does not apply

Germ cell mutagenicity

Based on available data, the classification criteria are not met.

Mixture invitro Data

No data available.

Substance invitro Data

Test data reported below.

Chemical name Test Cell Strain Reported Exposure Results Key literature
dose time references and
sources for data
Disodium EDTA Cytogenetic Hamster lung 200 mg/L None reported Positive test result for RTECS
(1 - 5%) analysis mutagenicity
CAS#: 139-33-3

Mixture invivo Data

No data available.

Substance invivo Data

No data available.

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Reproductive toxicity
Based on available data, the classification criteria are not met.

Mixture
No data available.

Ingredient Reproductive Toxicity Data

No data available.

Aspiration hazard
Based on available data, the classification criteria are not met.

Section 12: ECOLOGICAL INFORMATION

Ecotoxicity Based on available data, the classification criteria are not met.

Unknown Aquatic Toxicity 0% of the mixture consists of components(s) of unknown hazards to the aquatic
environment.

Mixture

Aquatic Acute Toxicity

No data available.

Aquatic Chronic Toxicity

No data available.

Substance

Aquatic Acute Toxicity

Test data reported below.

Fish

Chemical name Exposure Species Endpoint Reported dose Key literature references and
time type sources for data
Disodium EDTA 96 hours Lepomis macrochirus LC50 159 mg/L Vendor SDS
(1 - 5%)
CAS#: 139-33-3

Crustacea

Chemical name Exposure Species Endpoint Reported dose Key literature references and
time type sources for data
Salt of 48 Hours Daphina magna EC50 10.8 mg/L Internal Data
N,N-Diethyl-p-Phenyl
enediamine
(1 - 5%)
CAS#: -

Algae

Chemical name Exposure Species Endpoint Reported dose Key literature references and
time type sources for data
Disodium EDTA 72 Hours None reported EC50 300 mg/L ECHA
(1 - 5%)
CAS#: 139-33-3

Aquatic Chronic Toxicity

No data available.

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Persistence and degradability

Mixture
No data available.

Bioaccumulation
MATERIAL DOES NOT BIOACCUMULATE.
Mixture
No data available.

Partition coefficient log Kow ~ 0

Mobility

Soil Organic Carbon-Water Partition Coefficient log Koc ~ 0

Other adverse effects

No information available

Section 13: DISPOSAL CONSIDERATIONS

Disposal methods

Waste from residues/unused Dispose of in accordance with local regulations. Dispose of waste in accordance with
products environmental legislation.

Contaminated packaging Do not reuse empty containers.

Section 14: TRANSPORT INFORMATION

DOT Not regulated

IMDG Not regulated

IATA Not regulated

ADR Not regulated

Additional information

Section 15: REGULATORY INFORMATION

International Inventories
TSCA Complies
DSL/NDSL Complies
EINECS/ELINCS Complies
ENCS Complies
IECSC Complies
KECL Complies
PICCS Complies
TCSI Complies
AICS Complies
NZIoC Complies

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TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
TCSI - Taiwan Chemical Substances Inventory
AICS - Australian Inventory of Chemical Substances
NZIoC - New Zealand Inventory of Chemicals

Country Regulations

Brazil
Federal Decree 10.088 / 2019
Standard ABNT NBR 14725-3
Ordinance no. 2.770 / 2022
Resolution no. 5.998 / 2022 - ANTT
Ordinance no. 426 / 2021
Ordinance no. 256 / 2018
Federal Decree 10.030 / 2019
Ordinance no. 118 / 2019
Law no. 12.305 / 10
Law no. 10.357 / 2001
Ordinance no. 204 / 2022
Ordinance no. 577 / 2021

Argentina
SRT 3359/2015
Resolution 801/2015
Law of Health and Safety and Work (Law 19,587)
Decree 351/79
Regulatory Law 19587

Columbia
Law 253, 1996: Basel Convention on the Control of Transboundary Movements of Hazardous Wastes and their Disposal.
Resolution 2400/1979: Ministry of Labour and Social Security, ACGIH Exposure Limits.
Decision 602, Andean Regulation for the Control of chemical substances used in the illegal manufacture of narcotic drugs and
psychotropic substances.
Law 29/1992: Montreal Protocol on Substances that Deplete the Ozone Layer and its Amendments.
Law 55/1993: Recommendation No. 177 on the International Work Conference on Safety in the Use of Chemical Products at Work.
Law 30/1990: Vienna Convention for the Protection of the Ozone Layer.
Law 55/1993: Convention No. 170 on the General Conference of the ILO.

Uruguay
Law 16.157: Approval of the Montreal Protocol on Substances that Deplete the Ozone Layer.
Law 17.283: Regarding environmental protection and management of hazardous wastes.
Presidential Decree 346/11: Implementation of GHS for all manufactured or distributed products.
Presidential Decree 519/984: Regulates the activities relating to the use of radioactive materials and ionizing radiation throughout
the country.

Ecuador
Law No. 37 - Environmental Management Act
NTE INEN 2266:2013 - Requirements for Transport, Storage and Handling of Hazardous Materials
Unified Text of Secondary Legislation of the Environment Ministry: Book VI

Section 16: OTHER INFORMATION

Key or legend to abbreviations and acronyms used in the safety data sheet

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ACGIH ACGIH (American Conference of Governmental Industrial Hygienists)

ATSDR ATSDR (Agency for Toxic Substances and Disease Registry)
CCRIS CCRIS (Chemical Carcinogenesis Research Information System)
CDC CDC (Center for Disease Control)
CEPA CEPA (Canadian Environmental Protection Agency)
CICAD CICAD (Concise International Chemical Assessment Documents)
ECHA ECHA (The European Chemicals Agency)
EEA EEA (European Environment Agency)
EPA EPA (Environmental Protection Agency)
ERMA ERMA (New Zealands Environmental Risk Management Authority)
ECOSARS Estimation through ECOSARS v1.11 part of the Estimation Programs Interface (EPI) SuiteÔ
FDA FDA (Food & Drug Administration)
GESTIS GESTIS (Information System on Hazardous Substances of the German Social Accident
Insurance)
HSDB HSDB (Hazardous Substances Data Bank)
INERIS INERIS (The National Industrial Environment and Risks Institute)
IPCS INCHEM IPCS INCHEM (International Programme on Chemical Safety)
IUCLID IUCLID (The International Uniform Chemical Information Database)
NITE Japan National Institute of Technology and Evaluation (NITE)
NIH NIH (National Institutes of Health)
NIOSH NIOSH (National Institute for Occupational Safety and Health)
LOLI LOLI (List of Lists - An International Chemical Regulatory Database)
NDF no data
NICNAS Australia National Industrial Chemicals Notification and Assessment Scheme (NICNAS)
NIOSH IDLH Immediately Dangerous to Life or Health
OSHA OSHA (Occupational Safety and Health Administration of the US Department of Labor)
PEEN PEEN (Pan European Ecological Network)
RTECS RTECS (Registry of Toxic Effects of Chemical Substances)
SIDS SIDS (Screening Information Dataset) for High Volume Chemicals
SYKE The Finnish Environment Institute (SYKE)
USDA USDA (United States Department of Agriculture)
USDC USDC (United States Department of Commerce)
WHO WHO (World Health Organization)

Legend - Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit)

Ceiling Ceiling Limit Value MAC Maximum Allowable Concentration

X Listed Vacated These values have no official status. The only

binding levels of contaminants are those listed
in the final OSHA PEL. These lists are for
reference purposes only. Please note that
some reference state regulations of these
"liberated" exposure limits in their state
regulations.

SKN* Skin designation SKN+ Skin sensitization

RSP+ Respiratory sensitization ** Hazard Designation
C Carcinogen R Reproductive toxicant
M mutagen

NIOSH (RTECS) Number None reported

Key literature references and sources for data

See Section 11: TOXICOLOGICAL INFORMATION
See Section 12: ECOLOGICAL INFORMATION

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Prepared By Kimyasal Değerlendirme Uzmanı: Gözde Goetz

KDU01-20-01
08.06.2027
[email protected]

Issue Date 09-Nov-2020

Revision Date 17-Oct-2023

Revision Note None

Restrictions on use Please refer to the product labeling and packaging for information about appropriate use

This material safety data sheet has been prepared according to Brazilian legislation and ABNT NBR 14725:2009

Disclaimer

USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site
safety programs in accordance with applicable hazard communication standards and regulations.

THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE. HOWEVER, NO

WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE
OBTAINED FROM THE USE THEREOF.

Ó2023
HACH COMPANYÓ

End of Safety Data Sheet

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