Module 2

Question Bank template for internal exam 2 - Part A - 3 mark questions
Questio Question Mark Bloom’s CO

n No taxonomy level
1 1. Distinguish between absorption spectrum and emission spectrum? 3 2 2
2. Compare IR & UV spectra 3 2 2
3. Explain absorption and intensity shifts. 3 2 2
2 1. Which of the following nuclei can show NMR spectra a) 1H b) 19F 3 3 2

c) 12C d)16O
2. Which of the following molecules can give IR spectrum : O2 , N2 , 3 3 2

HCN , HCl
3. Which of the following molecules show UV-visible absorption 3 3 2

spectrum? Explain.
a) Methane b) Benzene c) 1,3- butadiene d) Cyclohexene
3 1. What is the selection rule for IR? 3 1 2

2. What is electromagnetic spectrum? 3 1 2
3. Define Chemical Shift? 3 1 2
4 1. Predict the number of signals, their relative position & multiplicity 3 2 2
for Ethyl acetate?
2.How many chemical shift signals are shown by the following 3 2 2
molecules in H-NMR : Acetone , 1-Bromopropane
3.The C=C stretching absorbs at higher wave number(~1600cm-1) 3 2 2

compared to C-C stretching (~1200cm-1). Give reason
5 1. Why TMS is selected as a standard reference in NMR? 3 3 2

2. Explain the reason for broadening of UV-Visible spectrum. 3 3 2
3. Write any three applications of IR spectroscopy. 3 3 2
6 1. Arrange the following in the increasing order of tau value. Give 3 2 2
Reason? CH3F , CH3-O-CH3 , (CH3)3N , CH3-CH3
2. A solution of thickness 3cm transmits 30% incident light. Calculate 3 2 2
the concentration of the solution , given Extinction coefficient =
4000 dm3mol-1 cm-1.
3. What is the requirement for a molecule to be IR active? Write two 3 2 2
examples for IR active and inactive molecules.
Question Bank template for internal exam 2 - Part B - 14 mark questions

Questio Question Mark Bloom’s CO
n No
taxonomy level
1A. Explain spin-spin splitting? Distinguish between 1-propanol and 2- 10 2 2
7
propanol by NMR?
4 3 12
1B .Write any four applications of NMR.
2A. Explain chemical shift? What are the factors affecting chemical shift? 10 2 2
2B. Explain the term shielding and deshielding in NMR spectroscopy 4 3 2
3A Explain the theory of NMR 10 2 2
3B Write a brief note on MRI as an application of NMR spectroscopy. 4 3 2

1A. Explain stretching and bending vibrations by taking water molecule as 3 2
8 10
example?
4 2 2
1B. The fundamental vibrational frequency of CO is 2140cm-1. Calculate
the force constant of the molecule. Given atomic masses 12C = 19.9 10-27kg
and 16O = 26.6×10-27 kg.
2A What are the various modes of vibrations possible for CO2. Which of 10 3 2
them areIR active? Give reason?
2B Calculate the force constant of HF molecule if it shows IR absorption at 4 2 2

4138 cm-1. Given the atomic masses of Hydrogen and Flourine are 1u and
19u respectively.
3A What are the various types of electronic transitions possible in organic 10 3 2
molecules? Give examples of each.
3B Suggest structural formula for the following compounds such that they 4 2 2
give a single signal in proton NMR spectroscopy. a) C9H18O and b) C12H18
1A. Sketch the molecular orbital energy diagram of 1,3-butadiene and show 10 2 2
9
HOMO and LUMO transition. What happens to wavelength of absorption
maximum when more double bonds come in conjugation?
1B. State and explain the law governing absorption of electromagnetic 4 2 2
radiation by matter. Give any one limitation of this law.
2A. Explain the instrumentation of UV-Visible spectrophotometer with a 8 2 2
neat diagram.
2B. Explain the different types of electronic transitions. 6 2 2
3A. What are the different types of NMR active nuclei? How many spin 10 2 2
orientations are possible in a magnetic field when I=1/2 and I=1. Give
examples.
3B. Calculate the concentration of a solution if it shows a transmittance of 4 2 2
20% when taken in a cell of 2.5cm thickness. (Molar absorption coefficient
is 12000 dm3mol-1cm-1).
10. 1A. Sketch the modes of vibration possible for HCl, CO 2 and H2O.Predict 10 2 2
the IR activity of each mode of vibration
1B. Write any four applications of NMR spectroscopy 4 2 2
2A How many vibrational modes are possible for the molecules CO, 8 2 2
NO,CO2, and H2O? Draw the vibrational modes of CO 2 and H2O and
explain their IR active modes.
2B. Each compound gives only one signal in its 1H-NMR spectrum. Propose 6 2 2
a structural formula for each a) C8H18 and b) C8H18O
3A Define Beer Lambert law and deduce the integrated form. Discuss the 8 2 2
plot of absorbance verses concentration, what does the slope of the graph
represents?
3B The CO molecule absorbs infrared radiation of wavenumber 2154 cm-1. 6 3 2

Calculate the force constant of the chemical bond, given that atomic masses
of C =12 amu and O=16 amu (Given that 1 amu = 1.66 x 10-27Kg)
11 1A Explain the principle of vibrational spectroscopy. Deduce the formula 10 2 2
for finding the fundamental vibrational frequency of a molecule.
1B How will you distinguish inter and intra molecular hydrogen bonding? 4 1 2
2A Write a note on magnetic resonance imaging (MRI). List applications of 8 2 2

it in medical diagnosis
2BPredict high resolution 1H NMR spectra of 1-Chloroethane and 2- 6 1 2

Chloropropane.
3A Explain the principle of NMR spectroscopy. Which of the following 10 2 2

nuclei can have a presence in NMR spectrum?1) 16O8 2)13C6 and 3) 2H1.
Write the reason for your answer.
3B CHCl3 gives a singlet at 7.26 ppm while CH 3Cl shows singlet at 3.06 4 2 2
ppm in the 1H NMR spectrum. Give reason.
12 1A Draw the molecular orbital energy diagram of i) Ethene, ii) 1, 3- 10 2 2

butadiene iii)1,3,5-hexatriene and iv) benzene to explain their UV-Vis
absorption.
1B CHCl3 gives a singlet at 7.26 ppm, while CH3Cl shows singlet at 3.06 4 2 2
ppm in the1H NMR spectrum. Give reason.
2A Discuss the principle of IR spectroscopy. Arrive at the expression for 10 2 2

vibrationalenergy states of a diatomic molecule. Draw the potential energy
diagram.
2B An organic compound C3H6O contains a carbonyl group. How will its 4 2 2
NMRspectrum decide whether it is an aldehyde or a ketone?
3A How can we differentiate NMR spectrum of CH 3CH2Cl and CH3CHCl2 8 2 2
using the concept of spin-spin splitting.
3B Comment on various electronic transitions that are possible in the 6 2 2
following molecules 1)C2H6 2)CH3CH2OH and 3) 1,3-butadiene

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Question Bank template for internal exam 2 - Part A - 3 mark questions

Questio Question Mark Bloom’s CO

3. Explain absorption and intensity shifts. 3 2 2

2 1. Which of the following nuclei can show NMR spectra a) 1H b) 19F 3 3 2

2. Which of the following molecules can give IR spectrum : O2 , N2 , 3 3 2

3. Which of the following molecules show UV-visible absorption 3 3 2

3 1. What is the selection rule for IR? 3 1 2

3.The C=C stretching absorbs at higher wave number(~1600cm-1) 3 2 2

5 1. Why TMS is selected as a standard reference in NMR? 3 3 2

Question Bank template for internal exam 2 - Part B - 14 mark questions

2B. Explain the term shielding and deshielding in NMR spectroscopy 4 3 2

3A Explain the theory of NMR 10 2 2

3B Write a brief note on MRI as an application of NMR spectroscopy. 4 3 2

2B Calculate the force constant of HF molecule if it shows IR absorption at 4 2 2

3B The CO molecule absorbs infrared radiation of wavenumber 2154 cm-1. 6 3 2

2A Write a note on magnetic resonance imaging (MRI). List applications of 8 2 2

2BPredict high resolution 1H NMR spectra of 1-Chloroethane and 2- 6 1 2

3A Explain the principle of NMR spectroscopy. Which of the following 10 2 2

12 1A Draw the molecular orbital energy diagram of i) Ethene, ii) 1, 3- 10 2 2

2A Discuss the principle of IR spectroscopy. Arrive at the expression for 10 2 2

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