First Page PDF

Download as pdf or txt
Download as pdf or txt
You are on page 1of 1

1

Fundamentals
of Hydrocarbon
Phase Behavior

A PHASE IS DEFINED AS ANY homogeneous part of a system that is physically distinct and
separated from other parts of the system by definite boundaries. For example, ice, liquid
water, and water vapor constitute three separate phases of the pure substance H2O,
because each is homogeneous and physically distinct from the others; moreover, each is
clearly defined by the boundaries existing between them. Whether a substance exists in a
solid, liquid, or gas phase is determined by the temperature and pressure acting on the
substance. It is known that ice (solid phase) can be changed to water (liquid phase) by
increasing its temperature and, by further increasing the temperature, water changes to
steam (vapor phase). This change in phases is termed phase behavior.
Hydrocarbon systems found in petroleum reservoirs are known to display multiphase
behavior over wide ranges of pressures and temperatures. The most important phases that
occur in petroleum reservoirs are a liquid phase, such as crude oils or condensates, and a
gas phase, such as natural gases.
The conditions under which these phases exist are a matter of considerable practical
importance. The experimental or the mathematical determinations of these conditions are
conveniently expressed in different types of diagrams, commonly called phase diagrams.
The objective of this chapter is to review the basic principles of hydrocarbon phase
behavior and illustrate the use of phase diagrams in describing and characterizing the vol-
umetric behavior of single-component, two-component, and multicomponent systems.

Single-Component Systems
The simplest type of hydrocarbon system to consider is that containing one component. The
word component refers to the number of molecular or atomic species present in the substance.

You might also like