9343apni Kaksha

JEE ADVANCED PAPER – 1
CLASS 12th APNI KAKSHA STAR BATCH
Time : 3 Hours Maximum Marks : 180

ANSWER KEY
&
SOLUTION WITH EXPLANATION
Solution Sheet Available Only for 24 Hours

PART – 1 : MATHEMATICS
SECTION - 1 (Maximum Marks : 12)

• This section contains THREE (03) questions.
• Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four
option(s) is(are) correct answer(s).
• For each question, choose the option(s) corresponding to (all) the correct answer(s).
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : + 𝟒 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks : + 𝟑 If all the four options are correct but ONLY three options are chosen;
Partial Marks : + 𝟐 If three or more options are correct but ONLY two options are chosen,
both of which are correct;
Partial Marks : + 𝟏 If two or more options are correct but ONLY one option is chosen and it
is a correct option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −𝟐 In all other cases.
[x] 3[x] 5[x] (2n−1)[x] π

limn→∞ (1+n2 + 2+n2 + 3+n2 + ⋯ + ), x ≠
n+n2
1. Let f: R → R be defined as f(x) = { 2
π
1, x= 2
where [y] denotes largest integer ≤ y, then which of the following statement(s) is(are) correct?
(A) f(x) is injective but not surjective.
π
(B) f(x) is non-derivable at x = 2 .
π
(C) f(x) is discontinuous at all integers and continuous at x = 2 .
(D) f(x) is unbounded function.

Ans. (C,D)
APNI KAKSHA 1
3π
2. Let f(x) = Max. (sin−1 x , , cos −1 x) ∀ x ∈ [−1,1] then
4
1
(A) f(x) is non-derivable at x =
√2
1
(B) f(x) is discontinuous at x = .
√2
π 3π
(C) f (4 ) = 4
−1
(D) f(x) is continuous but non-derivable at x =
√2
Ans. (C,D)
3. Which of the following statement(s) is(are) correct?

ex 1
(A) Let f: R → R be defined as f(x) = 1+e2x then f(c) = 4 for some c ∈ R.
(B) If f(a) and f(b) possesses opposite signs then there must exist atleast one solution of the
equation f(x) = 0 in (a, b).
(C) If the function y = f(x) is continuous at x = x0 such that f(x0 ) ≠ 0 then
f(x). f(x0 ) > 0 ∀ x ∈ (x0 − h, x0 + h) where h is sufficiently small positive quantity.
(D) Let f be a real valued continuous function on R and satisfying f(−x) − f(x) = 0 ∀ x ∈ R.
If f(−5) = 5, f(−2) = 4, f(3) = −2 and f(0) = 0 then the equation f(x) = 0 has atleast 5
real roots.
Ans. (A,C,D)

• This section contains FOUR (04) questions.
• Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the
correct answer.
• For each question, choose the option corresponding to the correct answer.
Full Marks : +𝟑 If ONLY the correct option is chosen;
Negative Marks : −𝟏 In all other cases.
4. The number of 3-digit numbers formed using the digits in set S = {0,1,2,3,4,5}, so that the
digits either increase or decrease, is
(A) 24 (B)30 (C) 45 (D) 56
Ans. (B)
APNI KAKSHA 2
5. In the expansion of (x secθ + x −1 cosecθ)12, if p be the least value of the term independent of
π π π π
x when 8 ≤ θ ≤ 4 and q be the least value of the term independent of x when 16 < θ ≤ 8, then
p
=
q
1 1
(A) 8 (B) 64 (C) 1 (D) 8
Ans. (A)
6. Let the half circle y = 1 + √4 − x 2 and the line y = mx + 4 − 2m have two distinct points of
intersection. Then the complete set of range of the values of ' m '.
5 3 5 3 3 12 3 12
(A) [12 , 4] (B) (12 , 4] (C) [4 , 5 ] (D) (4 , 5 ]
Ans. (B)
7. If Limx→∞ (ln(x 2 + 5x) − 2ln(cx + 1)) = −2 then

(A) c = e−1 (B) c = e−2 (C) c = e (D) limit is independent of c
Ans. (C)

• This section contains 𝐒𝐈𝐗(06) questions.
• The answer to each question is a NON-NEGATIVE INTEGER.
• For each question, enter the correct integer corresponding to the answer using the mouse and
the on-screen virtual numeric keypad in the place designated to enter the answer.
Full Marks : +𝟒 If ONLY the correct integer is entered;
Zero Marks : 𝟎 In all other cases.
8. The largest integer in the range of f(x) = −x 3 + x 2 − x + cos −1 x , is

Ans. 6
b
9. If the range of f(x) = (tan−1 x)3 + (cot −1 x)3 is [a, b) then find the value of [√ ]
a
where [.] denotes greatest integer function.

Ans. 5
APNI KAKSHA 3
−1
10. If p = limx→∞ (sin√x 2 + 1 − sin|x|) and q = limx→−∞ [sin (cos (√|x| − x 3 ) )] (where [.]
denotes greatest integer function), then p − q =

Ans. 0
tan [x2 ]π
+ ax 3 + b, 0<x≤1 1 π 26
11. If f(x) = { ax2 is differentiable in (0,2), then a = k and b = 4 − k .
2cosπx + tan−1 x, 1<x≤2 1 2
Find k1 2 + k22 { where [.] denotes greatest integer function }.

Ans. 180
12. For any real number x, let [x] denote the largest integer less than or equal to x. Let f be a real
−x − [−x] if [x] is even
valued function defined on the interval [−3,3] by f(x) = { .
x − [x] if [x] is odd
If L denotes the number of points of discontinuity and M denotes the number of points of
non-derivability of f(x), then find (L + M)
Ans. 8
13. Find the natural number ' a ' for which ∑nk=1 f(a + k) = 16(2n − 1) where the function ‘f’
satisfies the relation f(x + y) = f(x) ⋅ f(y) for all natural numbers x, y and further f(1) = 2
Ans. 3

• This section contains FOUR (04) Matching List Sets.
• Each set has ONE Multiple Choice Question.
• Each set has TWO lists: List-I and List-II.
• List-I has Four entries (A), (B), (C) and (D) and List-II has Five entries (P), (Q), (R), (S) and (T).
• FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY
ONE of these four options satisfies the condition asked in the Multiple Choice Question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 ONLY if the option corresponding to the correct combination is
chosen;
APNI KAKSHA 4
f(x) g(x)
14. Given limx→0 x2+4x3 = 5 and limx→0 x−sin x = 12. Now match the following
Column-I Column-II
ef(x) −1 2
(A) limx→0 (P) 5
g(x)
esin (f(x)) −1
(B) limx→0 (Q) 2
1−cos x
eg(x) −1
(C) limx→0 (R) 5
x3
g(x)
ln (1+ )
f(x)
(D) limx→0 (S) 10
ln (1+x)
(T) Does not exist.

(A) A → T; B → S; C → P; D → Q
(B) A → S; B → T; C → Q; D → P
(C) A → T; B → S; C → Q; D → P
(D) A → S; B → T; C → P; D → Q
Ans. (C)
15. Column-I Column-II

lnx
(A) Limx→1 (P) 2
x4 −1
3ex −x3 −3x−3 2
(B) Limx→0 (Q) 3
tan2 x
π−2tan−1 x 3
(C) Limx→∞ 1 (R) 2
ln(1+ )
x
2sinx−sin2x 1
(D) Limx→0 (S) 8
x(cosx−cos2x)
1
(T) 4
(A) A → T; B → R; C → P; D → Q
(B) A → R; B → T; C → Q; D → P
(C) A → T; B → R; C → Q; D → P
(D) A → R; B → T; C → P; D → Q
Ans. (A)
APNI KAKSHA 5
16. Column I Column II
(A) Let f and g be differentiable function satisfying g ′ (a) = 2,
g(a) = b and fog = I (identity function). Then, f ′ (b) is equal to (P) -1
1
2
(B) If f(x) = {x ex x ≠ 0 then f ′ (0− ) = (Q) non-existent
0 x=0
x+y f(x)+f(y) 1
(C) Let f be differentiable function satisfying f ( )= for all real (R) 2
2 2
values of x and y. If f ′ (0) exists and equals -1 and f(0) = 1,

then f(2) is equal to
[x]
(D) If f(x) = , x ≠ 0 where [.] denotes the greatest integer function,
|x|
then f ′ (1) is (S) 0

(T) 1
(A) A → R; B → S ; C → Q; D → P (B) A → S; B → R; C → Q; D → P
(C) A → S; B → R; C → P; D → Q (D) A → R; B → S ; C → P; D → Q
Ans. (D)
17. Column I Column II

(A) If ax + by − 5 = 0 is the equation of the chord of the circle
(x − 3)2 + (y − 4)2 = 4, which passes through (2,3) and at the (P) 6
greatest distance from the centre of the circle, then |a − b| is equal to
(B) Let O be the origin and P be a variable point on the circle (Q) 0
x 2 + y 2 + 2x + 2y = 0. If the locus of mid-point of OP is
x 2 + y 2 + 2gx + 2fy = 0, then the value of (g + f) is equal to
(C) The x-coordinates of the centre of the smallest circle (R) 4
which cuts the circle x 2 + y 2 + 2x − 4y − 4 = 0 and
x 2 + y 2 − 10x + 12y + 52 = 0 orthogonally, is
(D) If θ be the angle between two tangents which are drawn to the (S) 1
circle x 2 + y 2 − 6√3x − 6y + 27 = 0 from the origin, then
2√3tanθ equals to (T) 2
(A) A → S; B → Q; C → T; D → P
(B) A → Q; B → S; C → T; D → P
(C) A → S; B → Q; C → P; D → T
(D) A → Q; B → S; C → P; D → T
Ans. (B)
APNI KAKSHA 6
PART – 2 : PHYSICS

18. In the adjoining figure of a potentiometer arrangement, B is the main battery, C is the cell
whose e.m.f. is to be determined, WW’ is the potentiometer uniform wire, G is the galvanometer
and J is the jockey which may touch any point on the wire WW’. Choose the correct alternative
(s) for the potentiometer to work properly:
(A) The emf of B must be greater than the emf C.

(B) Two batteries B and C must be joined so that the same polarity terminals are joined
together.
(C) The positive terminals of two cells must be joined together to end W
(D) The galvanometer resistance must be less than the resistance of potentiometer wire.
Ans: (A,B)
APNI KAKSHA 7
Sol:
The potentiometer is used to measure the emf of a cell using null deflection method. We get C’s
emf when the current does not flow through the galvanometer(G). For this to happen, C’s emf =
WJ’s emf. The maximum limit of WJ’s is WW’ which is nothing other than B’s emf. Hence, C’s
emf has to be less than B’s emf. Moreover, the voltage difference measured along WJ has to be
equal to that of across C. This difference could either be positive or negative. To ensure that we
at least get a null point. Given we fulfill the first condition, the negative terminals of both B and
C have to be joined together.
 options A and B are correct.
19. A micrometer has a resistance of 100  and a full-scale range of 50μA. It can be used as a
voltmeter or a higher range ammeter provided a resistance is added to it. Pick the correct range
and resistance combination(s).
(A) 50 V range with 10 kΩ resistance in series.
(B) 10 V range with 200 kΩ resistance in series.
(C) 5 mA range with 1Ω resistance in parallel.
(D) 10 mA range with 1 kΩ resistance in parallel.
Ans: (B,C)
Sol: Correct options are (B) and (C)
Given the Microammeter has a resistance of 100 ohms and a full range of 50μA. Ammeter can
function as a voltmeter when it is connected in series with a large resistance R. The value of R is
determined by the maximum voltage that will be measured.
Checking for option A, 50 V to produce a full-scale deflection of a voltmeter containing a 100 Ω -
ammeter with a 50μA sensitivity. Then 50 V applied to the meter must produce a current of
V 50
50μA. R total = R + r = = 50×10−6 = R ≃ 1000kΩ
i
Checking for option B 10 V to produce a full-scale deflection of a voltmeter containing a 100 Ω -

ammeter with a 50μA Sensitivity. Then 10V applied to the meter must produce a current of
V 10
50μA. R total = R + r = = 50×10−6 = R ≃ 200kΩ
i
Microammeter has a resistance of 100 ohms and a full range of 50μ amps Substituting them in
G 100
the formula for shunt of Ammeter, we have S = i =S= i
−1 −1
ig 50×10−6
Option C has values of i and S that satisfy this equation. Option B and C are correct.
APNI KAKSHA 8
20. Current I is being driven through a cell of e.m.f. E and internal resistance r as shown in the
figure. Choose the following correct statements:
(A) The cell absorbs energy at the rate of EI.

(B) The cell stores chemical energy at the rate of (EI − I2 r).
(C) The potential difference across the cell is E + Ir.
(D) Some heat is produced in the cell.
Ans: (A,B,C,D)
Sol: Correct options are A,B,C and D
Rate of absorption of energy is power of the battery
P = IV
P = EI
The potential difference across the cell
ΔV = E − Ir
So, power = I(E = Ir) = EI − I2 r VA + Ir + E = VB
VB − VA = E + Ir
As there is resistance in the cell, so it must generate heat as, H = I2 R

correct answer.
21. A cylindrical conductor has uniform cross-section. Resistivity of its material increases linearly
from left end to right end. If a constant current is flowing through it and at a section of distance
x from left end, then magnitude of electric field intensity is E. Which of the following graphs is
correct?
APNI KAKSHA 9
(A) (B)
(C) (D)
Ans: (B)
Sol: If we take resistivity at a distance x from left end as ρ = (ρ0 + αx), then electric field intensity
iρ
at this point will be E = A , where i is the current flowing through the conductor.
i
Therefore, E ∝ ρ and E(x) = A (ρ0 + αx)
 Hence, (B) is correct.
22. A source of constant potential difference is connected across a conductor having irregular
cross-section as shown. Then :
(A) electric field intensity at P is greater than that at Q

(B) rate of electrons crossing per unit area of cross-section at P is less than that at Q
(C) the rate of generation of heat per unit length at P is greater than at Q
(D) mean kinetic energy of free electrons at P is greater than that at Q
Ans: (B)
Sol: When a source is connected, a current starts to flow through the conductor. Let it be I. Then,
current density at a section is equal to I/A, where A = cross-sectional area. Since cross-sectional
area at P is maximum, therefore current density at P is minimum. Hence (B) is correct. Since
J′ ℓ ℓρ
electric field is (= Aσ = ), therefore at P electric field is minimum while that at Q is
σ A
ℓ2 ρ
maximum. Rate of generation of heat per unit length at a section will be equal to . It is
A
1
minimum at P and maximum at Q. The mean kinetic energy of free electrons = 2 mvd2
Which is minimum at P and maximum at Q.  Hence (B) is correct.

APNI KAKSHA 10
23. Electric field, in a straight solid uniform cylindrical conductor of radius R = 2 cm is along the
axis of the cylinder and is given by E = K r where K = 1 × 108 and r is the distance from the axis
of the cylinder. If current in the cylinder is I = 16π micro ampere and find the specific
conductivity
(A) 3 × 10−8 siemen (B) 1.5 × 10−8 siemen
(C) 3 × 108 siemen (D) 1.5 × 108 siemen
Ans: (A)
R σk2πR3
Sol: I = ∫ jdA = ∫ σEdA = ∫0 σkr ⋅ 2πrdr = 3
3I 3×16π×10−6
∴ σ = 2πkR3 = 2 3
= 3 × 10−8
2π×108 ×( )
100
24. Total momentum of electrons in a straight wire of length ℓ carrying a current I is P. If mass of
electron is doubled keeping its charge constant and length of the wire is also doubled keeping
current constant, find the new value of momentum becomes
(A) 2P (B) 3P (C) 4P (D) 5P
Ans: (C)
miℓ
Sol: Total momentum P = e
i′ = i; ℓ′ = 2ℓ; m′ = 2m ⇒ P′ = 4P

25. To measure a potential difference across a resistor of resistance R Ω, a voltmeter of resistance

R v is used. To measure the potential with a minimum accuracy of 95%, then R ≥ nR. Find n?
Ans: (19)
Sol: Potential difference across
R v = iR
APNI KAKSHA 11
iR
iv =
R + Rv
Potential difference as measured by voltmeter
iRR v
V2 = R v × iv =
R + Rv
v2
≥ 0.95
v1
Rv
≥ 0.95 ⇒ R v ≥ 0.95R v + 0.95R ⇒ 0.05R v ≥ 0.95R ⇒ R v ≥ 19R
R + Rv
26. ABCD is a square of side a meters and is made of wires of resistance x ohms/meter. Similar
wires are connected across the diagonals AC and BD. The effective resistance between the
corners A and C is ax(2 − √α). Find  .
Ans: (2)
Sol:
1 1 1 1 1 1 1 √2 + 1
= + + = (1 + ) = ( )
R 2ax 2ax √2ax ax √2 ax √2
ax√2
R= = ax√2(√2 − 1) ⇒ R = ax(2 − √2)
√2 + 1
APNI KAKSHA 12
27. A battery of 10 volt is connected to a resistance of 20 ohm through a variable resistance R. The
amount of charge which has passed in the circuit in 4 minutes, if the variable resistance R is
increased at the rate of 5 ohm/min, is N log e 2 coulomb. Find N.
Ans: (120)
dq V
Sol: I= =R
dt
dq dR V
⋅ =
dR dt R
dR
dq = 12V
R
40
dR
q = 12V ∫
20 R
= 12V(log e 4 0 − log e 2 0) = 12 × 10 × log e 2 = 120 log e 2
28. In the circuit shown, current through the resistance 2Ω is i1 and current through the resistance
i
30Ω is i2 . Find the ratio i1 .
2
Ans: (9)
Sol: Potential are indicated in figure
10−(−5) 15
Current in 2Ω = = = 7.5A, leftwards
2 2
10−(−15) 25 5
Current in 30Ω = = 30 = 6 A, downwards
30
i1
=9
i2
APNI KAKSHA 13
29. Three 200Ω resistors are connected as shwon in figure. The maximum power that can be
dissipated in any one of the resistor is 50 W. Find the total power dissipated (in W) in the
circuit for maximum voltage across the terminals A and B.
Ans: (75)
50 1
Sol: The maximum current that can be passed through any resistor is = √200 = 2 A.
1
To keep all resistors safe I ≤ 2 A …(i)
I 1
and also 2 ≤ 2 ⇒ I ≤ 1A …(ii)
1 1 (150)2
This means I < 2 A. (VA − VB )max = IR eq = 2 × 300 = 150 V = P = = 75W
300
30. 300 numbers of identical galvanic cells, each of internal resistance 9Ω are arranged as several
in-series groups of cells connected in parallel. The arrangement has been laid out so that power
output in an externaly connected resistance of value 27Ω is maximum. If n number of cells are
connected in every series group that form parallel combination, then find value of n.
Ans: (30)
Sol: Power developed in R is maximum when req = R
nr
= R (N = total numbers of cells)
N/n
RN
(n = cells in one series group) n = √ Using values R = 27Ω, N = 300, r = 9Ω, n = 30
r
APNI KAKSHA 14

chosen;
31. Match the following columns :

Column-I (Situation) Column-II (Values in MKS units)
Magnitude of electric field at (1,1,1) if
(A) 1 1 1 (P) 0.4
potential is given by V = − x − y − z is
The charge flowing through a resistance 6Ω

(B) varies with t as Q = 4t − 2t 2 . The total heat (Q) 3
produced in resistance is
A milliammeter of range 10 mA has a coil of
resistance 0.99Ω. To use it as an ammeter of
(C) (R) 0.01
range 1 A, the required shunt must have a
resistance of
Two unlike point charges of same magnitude
10mC are placed on x-axis at a separation of 8
cm. If both charges placed symmetrically about
(D) origin in external electric field ⃗E = 500Vm−1 î. (S) 32
Then potential energy of the system may be
[Assume potential energy to be zero when
dipole is perpendicular to electric field]
APNI KAKSHA 15
Choose the correct:
(A) (A − P); (B − S); (C − R); (D − Q)
(B) (A − Q); (B − R); (C − S); (D − P)
(C)(A − Q); (B − S); (C − R); (D − P)
(D)(A − P); (B − R); (C − S); (D − Q)
Ans: (C)
∂V ∂V ∂V 1 1 1
Sol: For (A) ⃗E = − ∂x î − ∂y ĵ − ∂z k̂ = x2 î + y2 ĵ + z2 k̂
⃗ | = |î + ĵ + k̂| = √3
⇒ |E
dQ
For (B) I = = 4 − 4t, current will be zero at t = 1 s
dt
Total heat produced

1 1 1
2 2 (6)dt
(1 − t)2
∫ I R dt = ∫ (4 − 4t) = (16 × 6) [ ] = 32
0 0 −3 0
For (C) (10mA)(R g ) = (990mA)(s)

0.99
⇒s= = 0.01Ω
99
⃗ ⋅ ⃗E
For (D) U = −p
Here p
⃗ = ±qdî = ±(10 × 10−3 )(8 × 10−2 )
= ±(8 × 10−4 )î
⇒ U = ±(8 × 10−4 )(500) = ±0.4
32. The diagram shows a circuit with two identical resistors. The battery has a negligible internal
resistance. What will the effect on the ammeter and voltmeter be if the switch S is closed?
APNI KAKSHA 16
Column-I Column-II
(A) Ammeter reading (P) Increases

(B) Voltmeter reading (Q) Decreases
(C) Equivalent resistance of circuit (R) Does not change
(D) Power dissipated across R in right branch (S) Becomes zero
(T) Cannot be determined
Choose the correct:

(A)(A − Q); (B − P); (C − P); (D − Q, S)
(B)(A − P); (B − Q); (C − P); (D − T)
(C)(A − P); (B − P); (C − Q); (D − Q, S)
(D)(A − P); (B − Q); (C − P, S); (D − T)
Ans: (C)
Sol: After closing the switch net resistance decreases therefore there will be increases in the
current. Initially V = V1 + V2 after closing the switch V2 becomes zero hence V = V1 .
After short circuiting current in the resistance becomes zero therefore power become zero.
APNI KAKSHA 17
33. Figure shows two cylindrical uniform specimen of electrical resistances with their
characteristics.
Resistivity : ρ1 = ρ ρ2 = 2ρ
Length : ℓ1 = ℓ ℓ2 = 2ℓ
A
Area of cross-section : A1 = A A2 = 2
R 1 and R 2 are connected in circuit as shown in figure. Voltmeter and ammeter connected in
the circuit are ideal. Comparison of electric field, drift speed and power dissipated per unit
volume should be done only if R 1 carries current (both the materials have same electron
density).
Column-I Column-II
(A) S1 is open S2 is closed (P) Reading of voltmeter is maximum
(B) S1 is closed S2 is open (Q) Reading of ammeter is maximum
(C) S1 and S2 both are closed (R) Magnitude of electric field in R 2 is greater than in R1
(D) S1 and S2 both are open (S) Drift speed of electrons is greater in R 2 than in R1
Power dissipated per unit volume is greater in R 2

(T)
than in R1
APNI KAKSHA 18
Choose the correct:
(A) (A − T); (B − P, Q); (C − P); (D − R, T)
(B) (A − R); (B − P, Q); (C − Q); (D − R, S, T)
(C) (A − R, T); (B − P); (C − P, Q); (D − R, S, T)
(D) (A − R, T); (B − P); (C − P, Q); (D − R, T)
Ans: (C)
Sol: Since material have same electron density, thus i ∝ AVdrift
V = iR
V ρ
⇒E= =i
ℓ A
i2 R i2 ρ
Power volume = =
Aℓ A2
For A when S1 is open and S2 closed, current through R1 = 2 current through R 2
2iρ
 E in R1 = A
i×2ρ×2 4iρ
E in R 2 = =
A A
P 4i2 ρ
(volume) in R1 = ,
A2
P i2 ×2ρ×4 8i2 ρ
( ) in R 2 = =
volume A2 A2
For B when S1 is closed and S2 open, current in R1 = 0
Thus no comparison is to be done.
Voltmeter reads maximum potential drop = ε
For C when S1 and S2 are closed, current in R1 = 0
 No comparison is to be done.
Voltmeter reads  and ammeter reads maximum current
Fir D when S1 and S2 both are open, current in R1 = Current in R 2
Thus (R1 S and T)
APNI KAKSHA 19
34. In the figure potentiometer is shown. Length of wire PQ is 4.5 m.
Column – I Column – II
(a) x = 1m (p) i=0
(b) x = 2m (q) i > 0 (i is positive)
(c) x = 3m (r) i < 0 (i is negative)
(d) x = 4.5m (s) Current in PN = current in NQ
(t) Current in PN = 1 Amp
Ans. (D)
(A) (a-q); (b-p,t); (c-r); (d-s)
(B) (a-p); (b-p,s,); (c-s); (d-r)
(C) (a-s); (b-q,r); (c-p); (d-q)
(D) (a-r); (b-p,s,t); (c-q); (d-q)
Sol: Null point at x = 2
Current from 200V for x < 2
Current to 200 V for x > 2
APNI KAKSHA 20
PART – 3 : CHEMISTRY

35. Select the correct statement(s).

(A) In a reversible process G is always zero in a closed system.
(B) In a reversible process Suniv is always zero in a closed system.
(C) In a reversible process Ssys is always zero in a closed system.
(D) In a reversible process Ssys is always zero in an isolated system.
Ans. (B,D)
36. Which of the following bidentate ligand having identical donor sites and considered as
symmetrical ligand.
(A) Propylene diamine
(B) oxine −1
(C) Ethylene diamine

(D) Acetyl acetonate
Ans. (C,D)
APNI KAKSHA 21
37. Which of the following will show optical isomerism as well as geometrical isomerism
(A) (B)
(C) (D)
Ans. (A,B,C)
Sol. They are optically active if the compound have no plane of symmetry and no centre of
symmetry.
They can show geometrical isomer as there is restricted solution and different group on
terminal carbon.

correct answer.
38. At 500 K for an isobaric process,

kJ kJ
Ssystem = – 10 and Ssurr = 12
mol K mol K
Therefore, G for the entire process is-

(A) –500 kJ/mol
(B) –1000 kJ/mol
(C) –600 kJ/mol
(D) –1100 kJ/mol
Ans. (B)
Sol. T. Stotal = G or –500 x (–10 + 12) = G = G = –1000
APNI KAKSHA 22
39. The F − N − F bond angle in NF3 is 102∘ 30′ , whereas H − N − H bond angle in NH3 is 107∘ 48′ .
This difference in bond angle can be explained based on
(A) VSEPR theory that the repulsion between bond pairs is less in NF3 than in NH3
(B) VSEPR theory that the repulsion between bond pairs is more in NF3 than in NH3
(C) molecular orbital theory that predicts low bond order for NF3 molecule
(D) the fact that the first ionization energy of fluorine is higher than that of hydrogen
Ans. (A)
Sol. According to VSEPR theory electronegativity of surrounding atom also affect B-A-B bond angle
in ABn type species. F is more electronegative than N hence repulsion between bond pairs is
less in NF3 than in NH3 .
40. Which of the following have zero dipole moment?

(A) p-Dichlorobenzene (B) Benzene-1, 4-diol
(C) lactic acid (D) Maleic acid
Ans. (A)
Sol. p-Dichlorobenzene Has zero dipole moment due to symmetrical structure
41. The crystal of a solid is square packing of identical spheres in each layer and spheres of one
layer are placed just above the voids made by spheres in previous layer. The packing efficiency
of such crystal is. ( = 3.15, 2 = 1.4)
(A) 68% (B) 75% (C) 82% (D) 84%

Ans. (B)
APNI KAKSHA 23

42. A diatomic gas is used in a Carnot engine as a working substance. In an adiabatic expansion,
volume of gas increases two times then what is the percentage efficiency of Carnot engine?
Ans. 0024
43. No. of enantiomeric pair of [Ma2 bcde] complex = P

No. of geometrical isomers for [PdCl3 Br(SCN)
(NO2 )]2− = Q
No. of unpaired electron in non axial d-orbital of
[Co(H2 O)6 ]3+ = R
Sum of P + Q + R is :
Ans. 10.00
P = 6, Q = 4, R = 0.
44. Find a+b for following compound if –

(a) How many chiral centers does cholesterol have?
(b) What is the maximum number of stereoisomers that cholesterol can have?
Ans. 264
APNI KAKSHA 24
Sol.
chiral centre present is 8
Stereoisomer will be 2n = 28 = 256
total stereoisomer = 256 + 8 = 264
45. 0.50 mol of an ideal gas initially at a temperature of 300 K and at a pressure of 2 atm in
expanded isothermally in three steps. In each step, the pressure is dropped suddenly and held
constant until equilibrium is reestablished. The pressure at each of the three stages of
expansion are 1.6, 1.2 and 1 atm.
Calculate the work done (|W|) (in atm - litre) in this process. [Use R = 0.08 atm- litre / mole. K]
Ans. 7.4
Sol. Since pressure is constant is each step
nRT 0.5  0.08  300
V1 =   6litre
P1 2
0.5  0.08  300

V2 =
P2
0.5  0.08  300

  7.5litre
1.6
0.5  0.08  300 12
V3 =   10 liter
P3 1.2
12 12
V4 =   12 liter
P4 1.0
Wtotal = w1 + w2 + w3
here w1 = –P2 (V2 –V1)  – 1.6 × (1.5)  – 2.4 litre
w2 = – P3 (V3 –V2)  1.2 × (2.5)  – 2 litre atm
w3  –P4 (V4 –V3)  – 1 × (2)  – 2 litre atm
 wtotal = w1 + w2 + w3  –2.4 –3.0 – 2.0
wtotal  – 7.4 atm litre
|wtotal|  7.4 atm litre
APNI KAKSHA 25
46. As per C.F.T. Cl-Mn-Cl angle in [MnCl4 ]2− is 109∘ 28′ what is the angle between e-orbital of
central metal and the ligand is -
(If your answer is 84∘ 32′ then you have to fill 84.32 in OMR)
Ans. 54.44
47. The vapour pressure of water at 310 K is 25 torr. If the standard state pressure is defined as
(750 torr) estimate the DGº [lin kJ/mol] for the process.
H2O (l) → H2O (g) at 310 K
(Neglect variation of H and S with pressure for liquid )
𝑙𝑛𝑋
Use [R = 8.3 JK–1 mol–1 ; 𝑙𝑜𝑔𝑋 = 2.3, log 3 = 0.48]
Ans. 28525
Sol.
ΔG∘ = ΔG1 + ΔG2 + ΔG3

750
ΔG∘ = neglecter + 0 + 2.3RT log 25
= 2.3 × 8.3 × 310log 3 = 28525/mol

chosen;
APNI KAKSHA 26
14. Match the list : (Atomic number of Ni = 28, Ir = 77, Pt = 78, Co = 27 )
List- I List- II
(Co-ordination compounds) (Characteristics of coordination compounds)
(P) K 2 [NiBr2 (NO3 )2 (en)] (1) It exhibit structural isomerism
(Q) [IrCl (SCN)(H2 O)(NH3 )3 ] (2) High spin complex
(R) [Pt(gly)2 (NO2 )2 ] (3) Low spin complex
(S) [Co(gly) (H2 O)2 (NH3 )2 ][Cu(NO2 )4 ] (4) Electron migrates from ( n − 1) d
subshell of central metal cation to its higher
energy subshell
(5) Total number of optically active isomers
are equal to two.
The CORRECT option is -
(A) P → 5; Q → 1,3,4,5; R → 1,3; S → 1,3,4 (B) P → 2,5; Q → 3,4,5; R → 3,5; S → 1,2,5
(C) P → 2,4; Q → 3,4,5; R → 1,3,4; S → 1,4 (D) P → 1,2; Q → 3,5; R → 1,2; S → 1,4,5
Ans. (A)
15. Match the column:

Column I Column I
(P) (1) Conformation of maximum torsional strain
(Q) (2) Conformation with strong intramolecular hydrogen bond
(R) (3) Highest boiling point
(S) (4) Conformation of minimum Vander Waal strain
APNI KAKSHA 27
Options :
(A) P → 2, Q → 3, R → 1, S → 4
(B) P → 3, Q → 2, R → 1, S → 4
(C) P → 3, Q → 2, R → 4, S → 1
(D) P → 3, Q → 1, R → 2, S → 4
Ans. (B)
Sol.
16.
List-I List-II
(P) C2 (1) Same bond order as that of CN −
Bond order of π bond is more than σ bond whenever ' σ ' bond(s) is/are
(Q) B2 (2)
also present)
Ions obtain by adding and removing one electron, shows same magnetic
(R) O2 (3)
nature.
(S) N2 (4) Ionisation energy is lower as compare to corresponding atomic form
(5) sp mixing is possible
APNI KAKSHA 28
The CORRECT option is
(A) P → 2,3,4,5; Q → 2,3,4,5; R → 3; S → 1,3,4,5
(B) P → 1,2,3; Q → 1,2,3; R → 4; S → 3,5
(C) P → 2,3,5; Q → 2,3,5, ; R → 3,4; S → 1,2,3,5
(D) P → 3,5; Q → 3,5; R → 3,4; S → 1,2,3,5
Ans. (D)
Sol. (P) C ⇒ σ1 s2 < σ∗ 1 s 2 < σ2 s 2 < π ∗ 2p2x ≈ π2p2y B.O. = 2, ( B.O. )σ = 0, ( B.O. )π = 2
(Q) B2 ⇒ σ1 s 2 < σ∗ 1 s 2 < σ2 s 2 < σ∗ 2p2 < π2p1x ≈ π2py 1
B.O. = 1, ( B.O. )σ = 0, ( B.O. )π = 1
(R) O2 ⇒ σ1 s 2 < σ ∗ 1 s 2 < σ2 s 2 < σ ∗ 2 s2 <
σ∗ 2pz 2 < π2px 2 ≈ π2py 2 < π ∗ 2px 1 ≈ π ∗ 2py 1
B.O. = 2, ( B.O. )σ = 1, ( B.O. )π = 1
(S) N2 ⇒ σ1 s2 < σ ∗ 1 s2 < σ2 s 2 < σ ∗ 2 s 2 < π2p2x ≈ π2p2y < σ2p2z
B.O. = 3, ( B.O. )σ = 1, ( B.O. )π = 2
If in molecule electron is removed from B.M.O. than ionisation energy of molecule is more than
atom. If in molecule electron is removed ABMO from than ionisation energy of molecule is more
than atom.
17. Match the column :

Column I Column II
(1) (P) Erythro
(2) (Q) Threo
(3) (R) Meso
(4)
APNI KAKSHA 29
(A) 1 → R, 2 → Q, 3 → P, 4 → R
(B) 1 → R, 2 → P, 3 → R, 4 → Q
(C) 1 → P, 2 → R, 3 → Q, 4 → R
(D) 1 → R, 2 → P, 3 → Q, 4 → R
Ans. (D)
Sol.
APNI KAKSHA 30

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JEE ADVANCED PAPER – 1

CLASS 12th APNI KAKSHA STAR BATCH

Time : 3 Hours Maximum Marks : 180

Solution Sheet Available Only for 24 Hours

SECTION - 1 (Maximum Marks : 12)

[x] 3[x] 5[x] (2n−1)[x] π

(D) f(x) is unbounded function.

3. Which of the following statement(s) is(are) correct?

SECTION - 2 (Maximum Marks : 12)

7. If Limx→∞ (ln(x 2 + 5x) − 2ln(cx + 1)) = −2 then

SECTION - 3 (Maximum Marks : 24)

8. The largest integer in the range of f(x) = −x 3 + x 2 − x + cos −1 x , is

where [.] denotes greatest integer function.

denotes greatest integer function), then p − q =

Find k1 2 + k22 { where [.] denotes greatest integer function }.

SECTION - 4 (Maximum Marks : 12)

(T) Does not exist.

15. Column-I Column-II

values of x and y. If f ′ (0) exists and equals -1 and f(0) = 1,

then f ′ (1) is (S) 0

17. Column I Column II

SECTION - 1 (Maximum Marks : 12)

(A) The emf of B must be greater than the emf C.

Checking for option B 10 V to produce a full-scale deflection of a voltmeter containing a 100 Ω -

(A) The cell absorbs energy at the rate of EI.

SECTION - 2 (Maximum Marks : 12)

 Hence, (B) is correct.

(A) electric field intensity at P is greater than that at Q

Which is minimum at P and maximum at Q.  Hence (B) is correct.

SECTION - 3 (Maximum Marks : 24)

25. To measure a potential difference across a resistor of resistance R Ω, a voltmeter of resistance

SECTION - 4 (Maximum Marks : 12)

31. Match the following columns :

The charge flowing through a resistance 6Ω

Total heat produced

For (C) (10mA)(R g ) = (990mA)(s)

(A) Ammeter reading (P) Increases

Choose the correct:

(A) S1 is open S2 is closed (P) Reading of voltmeter is maximum

(B) S1 is closed S2 is open (Q) Reading of ammeter is maximum

Power dissipated per unit volume is greater in R 2

(A) (A − T); (B − P, Q); (C − P); (D − R, T)

(B) (A − R); (B − P, Q); (C − Q); (D − R, S, T)

(C) (A − R, T); (B − P); (C − P, Q); (D − R, S, T)

(D) (A − R, T); (B − P); (C − P, Q); (D − R, T)

Sol: Since material have same electron density, thus i ∝ AVdrift

For A when S1 is open and S2 closed, current through R1 = 2 current through R 2

For B when S1 is closed and S2 open, current in R1 = 0

Thus no comparison is to be done.

Voltmeter reads maximum potential drop = ε

For C when S1 and S2 are closed, current in R1 = 0

Voltmeter reads  and ammeter reads maximum current

Fir D when S1 and S2 both are open, current in R1 = Current in R 2

Thus (R1 S and T)

(t) Current in PN = 1 Amp

(A) (a-q); (b-p,t); (c-r); (d-s)

(B) (a-p); (b-p,s,); (c-s); (d-r)

(C) (a-s); (b-q,r); (c-p); (d-q)

(D) (a-r); (b-p,s,t); (c-q); (d-q)