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    Fe-Nb-Ni (Iron-Niobium-Nickel) : Binary Systems

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    abdul basit
    The document summarizes recent work on evaluating and modeling the Fe-Nb-Ni ternary phase diagram through computed isothermal sections. A 2009 study by Matheson et al. used a Calphad-type assessment to compute seven isothermal sections between 450-1291°C and determined the phase relations within the system. The assessment agreed well with experimental data and found the liquid, FCC, and BCC phases formed solid solutions while intermediate phases like C14 and D85 existed in a continuous solid solution at temperatures below 950°C.

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    Fe-Nb-Ni (Iron-Niobium-Nickel) : Binary Systems

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    abdul basit
    13 views4 pages
    The document summarizes recent work on evaluating and modeling the Fe-Nb-Ni ternary phase diagram through computed isothermal sections. A 2009 study by Matheson et al. used a Calphad-type assessment to compute seven isothermal sections between 450-1291°C and determined the phase relations within the system. The assessment agreed well with experimental data and found the liquid, FCC, and BCC phases formed solid solutions while intermediate phases like C14 and D85 existed in a continuous solid solution at temperatures below 950°C.

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    s11669-010-9654-3

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    The document summarizes recent work on evaluating and modeling the Fe-Nb-Ni ternary phase diagram through computed isothermal sections. A 2009 study by Matheson et al. used a Calphad-type assessment to compute seven isothermal sections between 450-1291°C and determined the phase relations within the system. The assessment agreed well with experimental data and found the liquid, FCC, and BCC phases formed solid solutions while intermediate phases like C14 and D85 existed in a continuous solid solution at temperatures below 950°C.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    13 views4 pages

    Fe-Nb-Ni (Iron-Niobium-Nickel) : Binary Systems

    Uploaded by

    abdul basit
    The document summarizes recent work on evaluating and modeling the Fe-Nb-Ni ternary phase diagram through computed isothermal sections. A 2009 study by Matheson et al. used a Calphad-type assessment to compute seven isothermal sections between 450-1291°C and determined the phase relations within the system. The assessment agreed well with experimental data and found the liquid, FCC, and BCC phases formed solid solutions while intermediate phases like C14 and D85 existed in a continuous solid solution at temperatures below 950°C.

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    of 4

    Section II: Phase Diagram Evaluations JPEDAV (2010) 31:180–183

    DOI: 10.1007/s11669-010-9654-3
    1547-7037 ÓASM International

    Fe-Nb-Ni (Iron-Niobium-Nickel)
    V. Raghavan

    The early review of this ternary system by [1992Rag]


    presented a tentative isothermal section at 1000 °C from the
    studies of [1989Sav]. The updates by [2004Rag] and
    [2007Rag] presented an isothermal section at 1200 °C from
    [2001Tak] and [2005Tak]. Recently, [2009Mat] carried out a
    Calphad-type assessment of this ternary system and calcu-
    lated a number of isothermal sections. This work will be
    reviewed briefly in this update.

    Binary Systems

    The Fe-Nb phase diagram [2000Tof] depicts two inter-


    mediate phases: Fe2Nb (C14, MgZn2-type hexagonal) and
    Fe7Nb6 (D85, Fe7W6-type rhombohedral). In the Fe-Ni
    phase diagram [1991Swa], a continuous face-centered cubic
    solid solution (denoted c) forms between cFe and Ni and is
    stable over a wide range of temperature. At 517 °C, an
    ordered phase FeNi3 (L12, AuCu3-type cubic) forms con-
    gruently from c. The Nb-Ni phase diagram [2006Che,
    1996Bol], has the following intermediate phases: Nb7Ni6
    (D85, Fe7W6-type rhombohedral), NbNi3 (D0a, Cu3Ti-type
    orthorhombic) and NbNi8 (tetragonal). Computed phase Fig. 2 Fe-Nb-Ni computed isothermal section at 1250 °C
    [2009Mat]
    diagrams of the above systems were given by [2009Mat].

    Fig. 1 Fe-Nb-Ni computed isothermal section at 1291 °C Fig. 3 Fe-Nb-Ni computed isothermal section at 1200 °C
    [2009Mat] [2009Mat]

    180 Journal of Phase Equilibria and Diffusion Vol. 31 No. 2 2010


    Phase Diagram Evaluations: Section II

    Computed Isothermal Sections models, providing for ternary solubility. In addition, the
    modeling included metastable phases L10, D022 and C15, to
    The liquid, disordered fcc and disordered bcc phases facilitate the future extension of the thermodynamic
    were modeled as substitutional solutions by [2009Mat]. The description to higher order systems. Ab-initio calculations
    magnetic contribution to the Gibbs energy of the bcc and fcc were done by [2009Mat] to estimate the enthalpies of
    phases was taken into account. The binary phases C14, D85, formation of the elements and the compounds on the basis
    D0a and L12 were described by appropriate sublattice of the Density Functional Theory, using the Generalized

    Fig. 4 Fe-Nb-Ni computed isothermal section at 1000 °C Fig. 6 Fe-Nb-Ni computed isothermal section at 800 °C
    [2009Mat] [2009Mat]

    Fig. 5 Fe-Nb-Ni computed isothermal section at 950 °C Fig. 7 Fe-Nb-Ni computed isothermal section at 450 °C
    [2009Mat] [2009Mat]

    Journal of Phase Equilibria and Diffusion Vol. 31 No. 2 2010 181


    Section II: Phase Diagram Evaluations

    Fig. 8 Fe-Nb-Ni tentative reaction sequence

    Gradient Approximation method. The ab-initio values were present in the system. Solid-state transition reactions occur
    used in the optimization. Detailed discussion and compar- below 950 °C (Fig. 5), to yield the phase distribution seen at
    ison of the modeling, the magnetic contribution and the 800 and 450 °C (Fig. 6 and 7). Based on the computed
    ab-initio calculations were presented by [2009Mat]. The isothermal sections of [2009Mat] and the binary systems, a
    available experimental phase diagram data, with the excep- tentative reaction sequence is shown in Fig. 8.
    tion of one or two results, were used in the optimization.
    The optimized parameters were listed.
    [2009Mat] computed seven isothermal sections at 1291,
    References
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    Phase Diagram Evaluations: Section II

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    Journal of Phase Equilibria and Diffusion Vol. 31 No. 2 2010 183

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