Introduction

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CHAPTER 1

Introduction

Thermodynamics, defined

1. deals with the conversion of mechanical energy into thermal energy and the reverse
process, the conversion of heat into work [Webber et al., 1974].

2. physics of energy and mechanical actions [Microsoft Encarta, 2007].

3. the branch of physics that deals with the conversions from one to another of various
forms of energy and how these affect temperature, pressure, volume, mechanical
action, and work [Microsoft Encarta, 2007].

4. the science of energy [Cengel and Boles, 1998].

5. The name “thermodynamics” stems from the Greek words, therme (heat) and dynamis
(power), which is the description of the early efforts to convert heat into power. Today
the same name is broadly interpreted to include all aspects of energy and energy
transformations, including power production, refrigeration, and relationships among the
properties of matter [Cengel and Boles, 1998].

History

The term thermodynamics was first used in a publication by Lord Kelvin in 1849. The first
thermodynamics textbook was written in 1859 by William Rankine, a professor at the
University of Glasgow.

Conversion Factors

Length
1 in = 2.54 cm
1 ft = 12 in
1 m = 100 cm = 1000 mm = 3.28 ft
1 cm = 10 mm
1 yd = 3 ft
1 statute mi or land mi = 5280 ft = 1.609 km
The statute mile was so-named because it was defined by an English Act of
Parliament in 1593, during the reign of Queen Elizabeth I.
1 nautical mi = 6076 ft = 1.852 km
Mass
1 kg = 2.2 lb = 1000 g
1 lb = 454.5 g = 16 oz = 7000 grains
1 slug = 14.59 kg = 32.2 lb
1 metric ton = 1000 kg = 2200 lb
1 British ton = 1016 kg
=joik1 US ton = 907.2 kg
1fshort ton = 2000 lb
1 long ton = 2240 lb
1 stone = 6.35 kg

Area
1 acre = 4046.8 m2
1 hectare = 10,000 m2

Volume
1 m3 = 1000 L = 264.17 US gal
1 L = 1000 cc = 1000 mL
1 ft3 = 7.481 US gal = 28.317 L
1 US gal = 3.785 L = 4 qt
1 British gal = 1.20 US gal
1 barrel = 115.63 L
1 bushel = 35.24 L
1 oz = 29.57 cm3
1 board foot = 1 ft x 1 ft x 1 in.
(volume of a board that is one foot square and 1 in thick)

Force, Weight
F = ma W = mg
1 N = 1 kgm/s2
1 dyn = 1 gcm/s2
1 lbF = 1 slug-ft/s2
1 N = 105 dyn
1 lbF = 4.45 N
1 kgF = 9.81 N
1 dyn = 2.25x10-6lbF

Pressure
P = F/A
1 Pa = 1 N/m2
1 psi = 1 lbF/in2
1 mm Hg = 1 torr
1 bar = 105 Pa
1 atm = 14.7 psi = 101,325 N/m2 = 1.01325 bar = 1.033 kgF/cm2 1
atm = 760 mm Hg at 0ºC = 29.92 in Hg at 0ºC = 33.90 ft H20 at 4ºC
1 psi = 6.89x104 dyn/cm2 = 6.89x103 N/m2
1 psi = 2.036 in Hg at 0ºC = 2.311 ft H20 at 70ºF = 51.715 mm Hg at 0ºC
Power
W
P VI
==
t
1 W = 1 J/s = VA
1 ft-lbF/s = slug-ft2/s3
1 hp = 746 W = 550 ft-lbF/s = 0.707 Btu/s = 42.42 Btu/min = 2545
Btu/hr 1 boiler hp = 35,322 kJ/hr
1 W = 1 J/s = 14.34 cal/min = 3.412 Btu/hr
1kW = 1.34 hp = 1000 W

Energy, Heat, Work


W=Fd
W E Pt = =
1 J = 1 Nm = 1 kg-m2/s2
1 ft-lbF = 1 slug-ft2/s2
1 erg = 1 g-cm2/s2
1 Btu = 252 cal = 1055 J = 1.055 kJ = 778 ft-lbF
1 J = 107 ergs
1 cal = 4.187 J
1 ft-lbF = 1.356 J
1 kWhr = 3412 Btu

Universal gas constant

PV R
= nT
cal Btu
R 1.987 1.987
==
gmol K lbmol K
−−
atm m atm L
R 0.08205 82.05
−−

==
kgmol K kgmol K
−−
3

kJ kPa m
R 8.314 8.314
==
kgmol K kgmol K
−−
3


atm ft R 0.7302
lbmol ºR
3


=

psi ft R 10.731
lbmol ºR
3

=

ft lb R 1545.3
lbmol

ºR−

=
−F

Prefixes for Powers of Ten


Less than 1 prefixes

Prefix Abbreviation Power

yocto y 10-24

zepto z 10-21

atto a 10-18

fempto f 10-15

pico p 10-12

nano n 10-9

micro μ 10-6

milli m 10-3

centi c 10-2

deci d 10-1

Greater than 1 prefixes

Prefix Abbreviation Power

yotta Y 1024
zetta Z 1021

exa E 1018

peta P 1015

tera T 1012

giga G 109

mega M 106

kilo k 103

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