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    Calculos Practica 10

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    Yanin Ramírez
    This document summarizes the results of an experiment measuring the Gibbs free energy (ΔG) of a zinc-copper galvanic cell at different temperatures. It provides the masses of zinc and copper sheets before and after the experiment. It also lists the voltage, current, and calculated ΔG values at 13°C, 22°C, and 45°C. The ΔH values were calculated using the ΔG and ΔS values. A graph is shown of f*e*m vs. temperature and of ΔG vs. temperature.

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    Calculos Practica 10

    Uploaded by

    Yanin Ramírez
    19 views3 pages
    This document summarizes the results of an experiment measuring the Gibbs free energy (ΔG) of a zinc-copper galvanic cell at different temperatures. It provides the masses of zinc and copper sheets before and after the experiment. It also lists the voltage, current, and calculated ΔG values at 13°C, 22°C, and 45°C. The ΔH values were calculated using the ΔG and ΔS values. A graph is shown of f*e*m vs. temperature and of ΔG vs. temperature.

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    calculos practica 10

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    This document summarizes the results of an experiment measuring the Gibbs free energy (ΔG) of a zinc-copper galvanic cell at different temperatures. It provides the masses of zinc and copper sheets before and after the experiment. It also lists the voltage, current, and calculated ΔG values at 13°C, 22°C, and 45°C. The ΔH values were calculated using the ΔG and ΔS values. A graph is shown of f*e*m vs. temperature and of ΔG vs. temperature.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    19 views3 pages

    Calculos Practica 10

    Uploaded by

    Yanin Ramírez
    This document summarizes the results of an experiment measuring the Gibbs free energy (ΔG) of a zinc-copper galvanic cell at different temperatures. It provides the masses of zinc and copper sheets before and after the experiment. It also lists the voltage, current, and calculated ΔG values at 13°C, 22°C, and 45°C. The ΔH values were calculated using the ΔG and ΔS values. A graph is shown of f*e*m vs. temperature and of ΔG vs. temperature.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    of 3

    Inicio Final

    Lamina Cu 0.6719 g 0.6733g


    Lamina Zn 1.2977g 1.3022g

    Tubo Temperatura C mL E=f*e*m


    1 13 2.78 0.00278
    2 22 18.72 0.01892
    3 45 143.17 0.14317

    Ánodo 𝑍𝑛0 (se oxida)= -0.792 en volts


    Cátodo 𝐶𝑢2+ (se reduce)= + 0.318
    V=w/A W=J/S

    Constante de Faraday: 96485.3399 C/mol

    9648 .3399 𝑐
    𝐺 = (− 2) ( ) ( − 0 .792 )
    𝑚𝑜𝑙
    ∆𝐺 0 = (−2) (9648.3399𝑐) (0.318) = 61364.67
    𝑚𝑜𝑙
    0
    ∆𝐺 =214197.44

    T: 13

    𝐸
    9648.3399𝑐 𝐽
    ∆𝐺 = (−2) ( ) (0.00278𝑣) = −536.4582
    𝑚𝑜𝑙 𝑚𝑜𝑙
    T: 22℃
    9648.3399𝑐 𝐽
    ∆𝐺 = (−2) ( ) (0.0189𝑣) = −3,647.14
    𝑚𝑜𝑙 𝑚𝑜𝑙

    T: 45℃
    9648.3399𝑐
    ∆𝐺 = (−2) ( ) (0.1437𝑣) = −27,627.6122
    𝑚𝑜𝑙

    T℃ 𝑻 °𝑲 I, mv ∆𝑮, 𝑱/𝒎𝒐𝒍 ∆𝑯, 𝑱/𝒎𝒐𝒍 K


    13 286 2.78 -536.45 -242, 127,721.8 J/mol 1

    22 295 18.92 -3647.0 -242, 123,539.5 J/mol 1


    45 318 143.17 -27627.6122 -269245967.9 J/mol 1

    𝒁𝒏 → 𝒁𝒏𝟐+ + 𝟐𝒆−

    𝑪𝒖𝟐+ + 𝟐𝒆− → 𝑪𝒖(𝒔)

    𝑪𝒖𝑺𝑶𝟒 = 𝟎. 𝟓 𝑴

    𝒁𝒏𝑺𝑶𝟒 = 𝟎. 𝟓 𝑴
    𝒅𝑬
    ∆𝑺 = −𝒏 ∗ 𝑭 ( ) 𝒑
    𝒅𝑻

    𝟑𝟑𝟗𝟗𝒄 𝟏𝟒𝟎.𝟑𝟗
    ∆𝑺 = −(𝟐)(𝟗𝟔𝟒𝟖𝟓. )( )=--846598.5543
    𝒎𝒐𝒍 𝟑𝟐

    ∆𝐻 = ∆𝐺 + 𝑇∆𝑆

    ∆𝑯 = −(𝟓𝟑𝟔. 𝟒𝟓) + (𝟐𝟖𝟔)(-846598.5543)=-242, 127,721.8 J/mol


    ∆𝑯 = −(𝟑𝟔𝟒𝟕) + (𝟐𝟖𝟔)(-846598.5543)=- -242, 123,539.5 J/mol
    ∆𝑯 = −(𝟐𝟕𝟔𝟐𝟕. 𝟔𝟏𝟐𝟐)(𝟐𝟖𝟔)(-846598.5543)=-269245967.9 J/mol
    Grafica de f*e*m vs T

    ∆𝑮 𝒗𝒔 𝑻 𝒅𝒆 𝒕𝒓𝒂𝒃𝒂𝒋o

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