Group Meeting Problems 2023/01/21
Group Meeting Problems 2023/01/21
Group Meeting Problems 2023/01/21
Pd(PPh3)4 (5 mol%)
MeO2C
1 BocO DMAP (20 mol%)
OHC
CO2Me OH
O + CH2Cl2, 40 C O
N OBoc 5 h, Ar N
Me Me
87%, dr = 18:1
2
PMBO OPMB
O
TBSO OH
H NaHMDS O
TBS O
Me THF Me
PhMe2Si –80 to –15 °C
O PhMe2Si
80%