Cambridge IGCSE™

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CHEMISTRY  0620/05
Paper 5 Practical Test For examination from 2023

SPECIMEN PAPER 1 hour 15 minutes

You must answer on the question paper.

You will need: The materials and apparatus listed in the confidential instructions

INSTRUCTIONS
● Answer all questions.
● Use a black or dark blue pen. You may use an HB pencil for any diagrams or graphs.
● Write your name, centre number and candidate number in the boxes at the top of the page.
● Write your answer to each question in the space provided.
● Do not use an erasable pen or correction fluid.
● Do not write on any bar codes.
● You may use a calculator.
● You should show all your working and use appropriate units.

INFORMATION
● The total mark for this paper is 40.
● The number of marks for each question or part question is shown in brackets [ ].
● Notes for use in qualitative analysis are provided in the question paper.

For Examiner’s Use

Total

This document has 10 pages. Any blank pages are indicated.

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1 You are going to investigate the reaction between dilute hydrochloric acid and two different
aqueous solutions of sodium hydroxide labelled solution A and solution B.

Read all of the instructions carefully before starting the experiments.

Instructions
You are going to do two experiments.

(a) Experiment 1

• Rinse a burette with dilute hydrochloric acid.

• Fill the burette with dilute hydrochloric acid.
• Run some of the dilute hydrochloric acid out of the burette so that the level of dilute
hydrochloric acid is on the burette scale.
• Record the initial burette reading in Table 1.1.
• Use a measuring cylinder to pour 25 cm3 of solution A into a conical flask.
• Add five drops of thymolphthalein indicator to the conical flask.
• While swirling the conical flask, slowly add the dilute hydrochloric acid from the burette to
the flask until the solution just changes colour.
• Record the final burette reading in Table 1.1 and complete the table.

Experiment 2

• Fill the burette with dilute hydrochloric acid.

• Run some of the dilute hydrochloric acid out of the burette so that the level of dilute
hydrochloric acid is on the burette scale.
• Record the initial burette reading in Table 1.1.
• Empty the conical flask and rinse it with distilled water.
• Use the measuring cylinder to pour 25 cm3 of solution B into the conical flask.
• Add five drops of thymolphthalein indicator to the conical flask.
• While swirling the conical flask, slowly add the dilute hydrochloric acid from the burette to
the flask until the solution just changes colour.
• Record the final burette reading in Table 1.1 and complete the table.

Table 1.1

Experiment 1 Experiment 2
3
final burette reading / cm
initial burette reading / cm3
volume of dilute hydrochloric acid added / cm3
[4]

(b) State the colour change observed in Experiment 1.

from ................................................................ to ................................................................ [1]

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(c) (i) State which solution of sodium hydroxide, solution A or solution B, is the more
concentrated.

Explain your answer.

............................................................................................................................................

....................................................................................................................................... [1]

(ii) Deduce the simplest whole number ratio of concentration of solution A : concentration of
solution B.

....................................................................................................................................... [1]

(d) State the volume of hydrochloric acid needed if Experiment 1 is repeated using 10 cm3 of
solution A.

............................................................................................................................................... [2]

(e) In Experiment 2 the conical flask is rinsed with distilled water.

(i) Suggest why the conical flask is rinsed with distilled water.

....................................................................................................................................... [1]

(ii) The conical flask is not dried after it is rinsed with distilled water.

Suggest why the conical flask is not dried.

....................................................................................................................................... [1]

(f) State the effect, if any, on the volume of dilute hydrochloric acid used in Experiment 1 if the
solution of sodium hydroxide is warmed before adding the dilute hydrochloric acid.

Give a reason for your answer.

effect on volume ........................................................................................................................

reason ........................................................................................................................................
[2]

(g) (i) Suggest how the reliability of the results from Experiment 1 and Experiment 2 can be
confirmed.

....................................................................................................................................... [1]

(ii) Suggest a more accurate method of measuring the volume of the solution of
sodium hydroxide.

....................................................................................................................................... [1]

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(h) Aqueous sodium hydroxide reacts with aqueous barium chloride to form a white precipitate of
barium hydroxide.

Use this information to suggest a different method of finding out which of the solutions of
sodium hydroxide, solution A or solution B, is more concentrated.

In your answer, state how your results show which solution of sodium hydroxide, solution A or
solution B, is more concentrated.

....................................................................................................................................................

....................................................................................................................................................

....................................................................................................................................................

............................................................................................................................................... [3]

 [Total: 18]

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BLANK PAGE

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2 You are provided with two solids, solid C and solid D.

Do the following tests on solid C and solid D, recording all of your observations at each stage.

tests on solid C

(a) Describe the appearance of solid C.

............................................................................................................................................... [1]

(b) Place about half of solid C in a hard-glass test-tube. Heat the solid gently then strongly.

Record your observations.

....................................................................................................................................................

............................................................................................................................................... [2]

Add the rest of solid C to about 10 cm3 of distilled water in a boiling tube. Stopper the boiling tube
and shake it to dissolve solid C and form solution C.

Divide solution C into four approximately equal portions in four test-tubes.

(c) Test the pH of the first portion of solution C.

pH = ........................................................... [1]

(d) To the second portion of solution C, add about 1 cm depth of dilute nitric acid followed by a
few drops of aqueous silver nitrate.

Record your observations.

............................................................................................................................................... [1]

(e) To the third portion of solution C, add about 1 cm depth of dilute nitric acid followed by a few
drops of aqueous barium nitrate.

Record your observations.

............................................................................................................................................... [1]

(f) To the fourth portion of solution C, add aqueous ammonia dropwise and then in excess.

Record your observations.

....................................................................................................................................................

............................................................................................................................................... [2]

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(g) Identify solid C.

............................................................................................................................................... [2]

tests on solid D

(h) Do a flame test on solid D.

Record your observations.

............................................................................................................................................... [1]

Add the rest of solid D to about 10 cm3 of distilled water in a boiling tube. Stopper the boiling tube
and shake it to dissolve solid D and form solution D.

Divide solution D into two approximately equal portions in two test-tubes.

(i) To the first portion of solution D, add aqueous sodium hydroxide dropwise and then in excess.

Record your observations.

....................................................................................................................................................

............................................................................................................................................... [2]

(j) To the second portion of solution D, add about 1 cm depth of dilute nitric acid followed by a
few drops of aqueous silver nitrate.

Record your observations.

............................................................................................................................................... [1]

(k) Identify solid D.

....................................................................................................................................................

............................................................................................................................................... [2]

 [Total: 16]

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3 The label on a bottle of orange drink states ‘contains no artificial colours’.

A scientist thinks that the orange colour in the drink is a mixture of two artificial colours:

• Sunset Yellow E110

• Allura Red E129.

Plan an experiment to show that the orange colour in the drink does not contain these two artificial
colours.

Your plan should describe the use of common laboratory apparatus and samples of E110, E129
and the orange colouring from the drink.

You may draw a diagram to help answer the question.

...........................................................................................................................................................

...........................................................................................................................................................

...........................................................................................................................................................

...........................................................................................................................................................

...........................................................................................................................................................

...........................................................................................................................................................

...........................................................................................................................................................

...........................................................................................................................................................

...........................................................................................................................................................

...........................................................................................................................................................

...........................................................................................................................................................
 [6]

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Notes for use in qualitative analysis

Tests for anions

anion test test result

2−
carbonate, CO3 add dilute acid, then test for carbon effervescence, carbon dioxide
dioxide gas produced
chloride, Cl − acidify with dilute nitric acid, then white ppt.
[in solution] add aqueous silver nitrate
bromide, Br− acidify with dilute nitric acid, then cream ppt.
[in solution] add aqueous silver nitrate
iodide, I− acidify with dilute nitric acid, then yellow ppt.
[in solution] add aqueous silver nitrate
nitrate, NO3− add aqueous sodium hydroxide, ammonia produced
[in solution] then aluminium foil; warm carefully
sulfate, SO42− acidify with dilute nitric acid, then white ppt.
[in solution] add aqueous barium nitrate
sulfite, SO32− add a small volume of acidified the acidified aqueous potassium
aqueous potassium manganate(VII) manganate(VII) changes colour
from purple to colourless

Tests for aqueous cations

cation effect of aqueous sodium hydroxide effect of aqueous ammonia

3+
aluminium, Al white ppt., soluble in excess, giving white ppt., insoluble in excess
a colourless solution
ammonium, NH4+ ammonia produced on warming –
2+
calcium, Ca white ppt., insoluble in excess no ppt. or very slight white ppt.
3+
chromium(III), Cr green ppt., soluble in excess grey-green ppt., insoluble in excess
copper(II), Cu2+ light blue ppt., insoluble in excess light blue ppt., soluble in excess,
giving a dark blue solution
iron(II), Fe2+ green ppt., insoluble in excess, green ppt., insoluble in excess,
ppt. turns brown near surface on ppt. turns brown near surface on
standing standing
iron(III), Fe3+ red-brown ppt., insoluble in excess red-brown ppt., insoluble in excess
2+
zinc, Zn white ppt., soluble in excess, giving white ppt., soluble in excess, giving
a colourless solution a colourless solution

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Tests for gases

gas test and test result

ammonia, NH3 turns damp red litmus paper blue
carbon dioxide, CO2 turns limewater milky
chlorine, Cl 2 bleaches damp litmus paper
hydrogen, H2 ‘pops’ with a lighted splint
oxygen, O2 relights a glowing splint
sulfur dioxide, SO2 turns acidified aqueous potassium manganate(VII) from purple to colourless

Flame tests for metal ions

metal ion flame colour

lithium, Li+ red
sodium, Na+ yellow
potassium, K+ lilac
calcium, Ca2+ orange-red
2+
barium, Ba light green
2+
copper(II), Cu blue-green

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