Scribd Logo
Upload

Welcome to Scribd!

  • 25 views

    Exercises 6

    Uploaded by

    ITZEL GUADALUPE CORDERO JASSO
    The document contains 6 problems involving vapor-liquid equilibrium calculations for mixtures of liquids. Problem 1 asks about the composition of a liquid mixture that boils at 90°C at 0.50 atm based on the vapor pressures of the pure components. Problem 2 involves calculating the total pressure and liquid composition of an ideal mixture where the vapor mole fraction of one component is given. Problem 3 determines if a binary solution is ideal and calculates its initial vapor composition. Problem 4 calculates the total pressure and vapor composition for a nearly ideal dibromoethene-dibromopropene solution. Problem 5 calculates vapor pressure and compositions for an equimolar benzene-toluene solution during boiling. Problem 6 involves plotting a temperature-composition

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd

    Exercises 6

    Uploaded by

    ITZEL GUADALUPE CORDERO JASSO
    25 views1 page
    The document contains 6 problems involving vapor-liquid equilibrium calculations for mixtures of liquids. Problem 1 asks about the composition of a liquid mixture that boils at 90°C at 0.50 atm based on the vapor pressures of the pure components. Problem 2 involves calculating the total pressure and liquid composition of an ideal mixture where the vapor mole fraction of one component is given. Problem 3 determines if a binary solution is ideal and calculates its initial vapor composition. Problem 4 calculates the total pressure and vapor composition for a nearly ideal dibromoethene-dibromopropene solution. Problem 5 calculates vapor pressure and compositions for an equimolar benzene-toluene solution during boiling. Problem 6 involves plotting a temperature-composition

    Copyright

    © © All Rights Reserved

    Available Formats

    PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    The document contains 6 problems involving vapor-liquid equilibrium calculations for mixtures of liquids. Problem 1 asks about the composition of a liquid mixture that boils at 90°C at 0.50 atm based on the vapor pressures of the pure components. Problem 2 involves calculating the total pressure and liquid composition of an ideal mixture where the vapor mole fraction of one component is given. Problem 3 determines if a binary solution is ideal and calculates its initial vapor composition. Problem 4 calculates the total pressure and vapor composition for a nearly ideal dibromoethene-dibromopropene solution. Problem 5 calculates vapor pressure and compositions for an equimolar benzene-toluene solution during boiling. Problem 6 involves plotting a temperature-composition

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    25 views1 page

    Exercises 6

    Uploaded by

    ITZEL GUADALUPE CORDERO JASSO
    The document contains 6 problems involving vapor-liquid equilibrium calculations for mixtures of liquids. Problem 1 asks about the composition of a liquid mixture that boils at 90°C at 0.50 atm based on the vapor pressures of the pure components. Problem 2 involves calculating the total pressure and liquid composition of an ideal mixture where the vapor mole fraction of one component is given. Problem 3 determines if a binary solution is ideal and calculates its initial vapor composition. Problem 4 calculates the total pressure and vapor composition for a nearly ideal dibromoethene-dibromopropene solution. Problem 5 calculates vapor pressure and compositions for an equimolar benzene-toluene solution during boiling. Problem 6 involves plotting a temperature-composition

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 1

    Exercises 6, EFQ

    1.-At 90°C, the vapour pressure of methylbenzene is 53.3 kPa and that of 1,2-
    dimethylbenzene is 20.0 kPa. What is the composition of a liquid mixture that boils at
    90°C when the pressure is 0.50 atm? What is the composition of the vapour produced?

    Mariel 2.- The vapour pressure of pure liquid A at 300 K is 76.7 kPa and that of pure liquid B
    is 52.0 kPa. These two compounds form ideal liquid and gaseous mixtures. Consider
    the equilibrium composition of a mixture in which the mole fraction of A in the vapour
    is 0.350. Calculate the total pressure of the vapour and the composition of the liquid
    mixture.

    Lu 3.- It is found that the boiling point of a binary solution of A and B with xA=0.6589 is
    88°C. At this temperature the vapour pressures of pure A and B are 127.6 kPa and
    50.60 kPa, respectively. (a) Is this solution ideal? (b) What is the initial composition of
    the vapour above the solution?

    Mike 4.- Dibromoethene ( P o = 22.9 kPa at 358 K) and dibromopropene ( P o = 17.1 kPa at
    358 K) form a nearly ideal solution. If zdibromoethene = 0.60, what is (a) PT when the
    system is all liquid, (b) the composition of the vapour when the system is still almost
    all liquid?

    5.- Benzene and toluene form nearly ideal solutions. Consider an equimolar solution of
    Mats benzene and toluene. At 20°C the vapour pressures of pure benzene and toluene are
    9.9 kPa and 2.9 kPa, respectively. The solution is boiled by reducing the external
    pressure below the vapour pressure. Calculate (a) the pressure when boiling begins,
    (b) the composition of each component in the vapour, and (c) the vapour pressure
    when only a few drops of liquid remain. Assume that the rate of vaporization is low
    enough for the temperature to remain constant at 20°C.

    Mariel 6.- The following temperature/composition data were obtained for a mixture of
    octane and methylbenzene at 1.00 atm, where x is the mole fraction in the liquid and y
    the mole fraction in the vapour at equilibrium.

     / oC 110.9 112.0 114.0 115.8 117.3 119.0 121.1 123.0


    xmethylbenzene 0.908 0.795 0.615 0.527 0.408 0.300 0.203 0.097
    ymethylbenzene 0.923 0.836 0.698 0.624 0.527 0.410 0.297 0.164

    The boiling points are 110.6°C and 125.6°C, for M and O, respectively. Plot the
    temperature/composition diagram for the mixture. What is the composition of the
    vapour in equilibrium with the liquid of composition (a) xmethylbenzene = 0.250 and (b)
    xoctane = 0.250?

    You might also like