Factory Filled Oils
Factory Filled Oils
Factory Filled Oils
1. GENERAL
3. MOTOR OIL
4. GEARBOX
5. AXLES
7. COMPRESSOR
8. SHANK LUBRICATION
10. COOLANT
1. GENERAL
All fluids and greases mentioned in this instruction are hazardous to health and to the
environment.
ENVIRONMENT POLLUTION HAZARD!
Dispose of all fluids and greases in accordance with local
regulations.
3. MOTOR OIL
These characteristics are typical of current production. Whilst future production will conform
to Shell's specification, variations in these characteristics may occur.
Manufacturer/Supplier : oy Shell ab
(0113882-9)
PO Box 16
FI-01300 Vantaa
Emergency Telephone : Poison Information Centre. tel 09-4711 or 09-471 977 (24h).
Number Stenbäckinkatu 11,
Other Information : KT code: 35 Lubricants and additivesTOL code: I602 Other
ground transport.
2. HAZARDS IDENTIFICATION
Health Hazards : Not expected to be a health hazard when used under normal
conditions. Prolonged or repeated skin contact without proper
cleaning can clog the pores of the skin resulting in disorders
such as oil acne/folliculitis. Used oil may contain harmful
impurities.
Signs and Symptoms : Oil acne/folliculitis signs and symptoms may include formation
of black pustules and spots on the skin of exposed areas.
Ingestion may result in nausea, vomiting and/or diarrhoea.
Safety Hazards : Not classified as flammable but will burn.
Environmental Hazards : Not classified as dangerous for the environment.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Components
Additional Information : The highly refined mineral oil contains <3% (w/w) DMSO-
extract, according to IP346. Refer to chapter 16 for full text of
EC R-phrases.
Exposure limits apply to the following components: Highly
General Information : Not expected to be a health hazard when used under normal
conditions.
Inhalation : No treatment necessary under normal conditions of use. If
symptoms persist, obtain medical advice.
Skin Contact : Remove contaminated clothing. Flush exposed area with water
and follow by washing with soap if available. If persistent
irritation occurs, obtain medical attention.
Eye Contact : Flush eye with copious quantities of water. If persistent
irritation occurs, obtain medical attention.
Ingestion : In general no treatment is necessary unless large quantities
are swallowed, however, get medical advice.
Advice to Physician : Treat symptomatically.
If the patient is not feeling ill, give him as soon as possible 1-2
dl cream or ice-cream followed by 50 - 100 g medicinal carbon
suspended in water.
Avoid contact with spilled or released material. For guidance on selection of personal protective
equipment see Chapter 8 of this Material Safety Data Sheet. See Chapter 13 for information on
disposal. Observe all relevant local and international regulations.
Protective measures : Avoid contact with skin and eyes. Use appropriate containment
to avoid environmental contamination. Prevent from spreading
or entering drains, ditches or rivers by using sand, earth, or
other appropriate barriers.
Clean Up Methods : Slippery when spilt. Avoid accidents, clean up immediately.
Prevent from spreading by making a barrier with sand, earth or
other containment material. Reclaim liquid directly or in an
absorbent. Soak up residue with an absorbent such as clay,
sand or other suitable material and dispose of properly.
Additional Advice : Local authorities should be advised if significant spillages
cannot be contained.
Exposure Controls : The level of protection and types of controls necessary will vary
depending upon potential exposure conditions. Select controls
based on a risk assessment of local circumstances.
Appropriate measures include: Adequate ventilation to control
airborne concentrations. Where material is heated, sprayed or
mist formed, there is greater potential for airborne
concentrations to be generated.
Personal Protective : Personal protective equipment (PPE) should meet
Equipment recommended national standards. Check with PPE suppliers.
Respiratory Protection : No respiratory protection is ordinarily required under normal
conditions of use. In accordance with good industrial hygiene
practices, precautions should be taken to avoid breathing of
material. If engineering controls do not maintain airborne
concentrations to a level which is adequate to protect worker
health, select respiratory protection equipment suitable for the
specific conditions of use and meeting relevant legislation.
Check with respiratory protective equipment suppliers. Where
air-filtering respirators are suitable, select an appropriate
combination of mask and filter. Select a filter suitable for
combined particulate/organic gases and vapours [boiling point
>65 °C (149 °F)] meeting EN141.
Hand Protection : Where hand contact with the product may occur the use of
gloves approved to relevant standards (e.g. Europe: EN374,
US: F739) made from the following materials may provide
suitable chemical protection: PVC, neoprene or nitrile rubber
gloves. Suitability and durability of a glove is dependent on
usage, e.g. frequency and duration of contact, chemical
resistance of glove material, glove thickness, dexterity. Always
seek advice from glove suppliers. Contaminated gloves should
be replaced. Personal hygiene is a key element of effective
hand care. Gloves must only be worn on clean hands. After
using gloves, hands should be washed and dried thoroughly.
Application of a non-perfumed moisturizer is recommended.
Eye Protection : Wear safety glasses or full face shield if splashes are likely to
occur. Approved to EU Standard EN166.
Protective Clothing : Skin protection not ordinarily required beyond standard issue
work clothes.
Monitoring Methods : Monitoring of the concentration of substances in the breathing
zone of workers or in the general workplace may be required to
confirm compliance with an OEL and adequacy of exposure
controls. For some substances biological monitoring may also
be appropriate.
Environmental Exposure : Minimise release to the environment. An environmental
Controls assessment must be made to ensure compliance with local
environmental legislation.
Stability : Stable.
Conditions to Avoid : Extremes of temperature and direct sunlight.
Materials to Avoid : Strong oxidising agents.
Hazardous : Hazardous decomposition products are not expected to form
Decomposition Products during normal storage.
Basis for Assessment : Information given is based on data on the components and the
toxicology of similar products.
Acute Oral Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rat
Acute Dermal Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rabbit
Acute Inhalation Toxicity : Not considered to be an inhalation hazard under normal
conditions of use.
Skin Irritation : Expected to be slightly irritating. Prolonged or repeated skin
contact without proper cleaning can clog the pores of the skin
resulting in disorders such as oil acne/folliculitis.
Eye Irritation : Expected to be slightly irritating.
Respiratory Irritation : Inhalation of vapours or mists may cause irritation.
Sensitisation : Not expected to be a skin sensitiser.
Repeated Dose Toxicity : Not expected to be a hazard.
Mutagenicity : Not considered a mutagenic hazard.
Carcinogenicity : Product contains mineral oils of types shown to be non-
carcinogenic in animal skin-painting studies. Highly refined
mineral oils are not classified as carcinogenic by the
International Agency for Research on Cancer (IARC). Other
components are not known to be associated with carcinogenic
effects.
Reproductive and : Not expected to be a hazard.
Developmental Toxicity
Additional Information : Used oils may contain harmful impurities that have
accumulated during use. The concentration of such impurities
will depend on use and they may present risks to health and
the environment on disposal. ALL used oil should be handled
with caution and skin contact avoided as far as possible.
Continuous contact with used engine oils has caused skin
cancer in animal tests.
Ecotoxicological data have not been determined specifically for this product. Information given is
based on a knowledge of the components and the ecotoxicology of similar products.
Acute Toxicity : Poorly soluble mixture. May cause physical fouling of aquatic
organisms. Expected to be practically non toxic: LL/EL/IL50 >
100 mg/l (to aquatic organisms) (LL/EL50 expressed as the
nominal amount of product required to prepare aqueous test
extract). Mineral oil is not expected to cause any chronic
effects to aquatic organisms at concentrations less than 1 mg/l.
Mobility : Liquid under most environmental conditions. Floats on water. If
it enters soil, it will adsorb to soil particles and will not be
mobile.
Persistence/degradability : Expected to be not readily biodegradable. Major constituents
are expected to be inherently biodegradable, but the product
contains components that may persist in the environment.
Bioaccumulation : Contains components with the potential to bioaccumulate.
Other Adverse Effects : Product is a mixture of non-volatile components, which are not
ADR
This material is not classified as dangerous under ADR regulations.
RID
This material is not classified as dangerous under RID regulations.
ADNR
This material is not classified as dangerous under ADNR regulations.
IMDG
This material is not classified as dangerous under IMDG regulations.
The regulatory information is not intended to be comprehensive. Other regulations may apply to this
material.
R-phrase(s)
Not classified.
R38 Irritating to skin.
R41 Risk of serious damage to eyes.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
MSDS Revisions : A vertical bar (|) in the left margin indicates an amendment
from the previous version.
MSDS Regulation : Regulation 1907/2006/EC
MSDS Distribution : The information in this document should be made available to
all who may handle the product.
Disclaimer : This information is based on our current knowledge and is
intended to describe the product for the purposes of health,
safety and environmental requirements only. It should not
therefore be construed as guaranteeing any specific property
of the product.
4. GEARBOX
3UHYLRXV1DPH6KHOO'RQD[70
These characteristics are typical of current production. Whilst future production will conform
to Shell's specification, variations in these characteristics may occur.
6KHOO/XEULFDQWV¤'
Page 1 of 1
Shell Spirax S1 ATF TASA
Version 1.0
Effective Date 14.12.2010
Regulation 1907/2006/EC
Safety Data Sheet
2. HAZARDS IDENTIFICATION
Health Hazards : Not expected to be a health hazard when used under normal
conditions. Prolonged or repeated skin contact without proper
cleaning can clog the pores of the skin resulting in disorders
such as oil acne/folliculitis. Used oil may contain harmful
impurities.
Signs and Symptoms : Oil acne/folliculitis signs and symptoms may include formation
of black pustules and spots on the skin of exposed areas.
Ingestion may result in nausea, vomiting and/or diarrhoea.
Safety Hazards : Not classified as flammable but will burn.
Environmental Hazards : Not classified as dangerous for the environment.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Components
Additional Information : The highly refined mineral oil contains <3% (w/w) DMSO-
extract, according to IP346. Refer to chapter 16 for full text of
1/7
Print Date 17.12.2010 MSDS_NL
Shell Spirax S1 ATF TASA
Version 1.0
Effective Date 14.12.2010
Regulation 1907/2006/EC
Safety Data Sheet
EC R-phrases.
General Information : Not expected to be a health hazard when used under normal
conditions.
Inhalation : No treatment necessary under normal conditions of use. If
symptoms persist, obtain medical advice.
Skin Contact : Remove contaminated clothing. Flush exposed area with water
and follow by washing with soap if available. If persistent
irritation occurs, obtain medical attention.
Eye Contact : Flush eye with copious quantities of water. If persistent
irritation occurs, obtain medical attention.
Ingestion : In general no treatment is necessary unless large quantities
are swallowed, however, get medical advice.
Advice to Physician : Treat symptomatically.
Avoid contact with spilled or released material. For guidance on selection of personal protective
equipment see Chapter 8 of this Material Safety Data Sheet. See Chapter 13 for information on
disposal. Observe the relevant local and international regulations.
Protective measures : Avoid contact with skin and eyes. Use appropriate containment
to avoid environmental contamination. Prevent from spreading
or entering drains, ditches or rivers by using sand, earth, or
other appropriate barriers.
Clean Up Methods : Slippery when spilt. Avoid accidents, clean up immediately.
Prevent from spreading by making a barrier with sand, earth or
other containment material. Reclaim liquid directly or in an
absorbent. Soak up residue with an absorbent such as clay,
sand or other suitable material and dispose of properly.
Additional Advice : Local authorities should be advised if significant spillages
cannot be contained.
2/7
Print Date 17.12.2010 MSDS_NL
Shell Spirax S1 ATF TASA
Version 1.0
Effective Date 14.12.2010
Regulation 1907/2006/EC
Safety Data Sheet
Exposure Controls : The level of protection and types of controls necessary will vary
depending upon potential exposure conditions. Select controls
based on a risk assessment of local circumstances.
Appropriate measures include: Adequate ventilation to control
airborne concentrations. Where material is heated, sprayed or
mist formed, there is greater potential for airborne
concentrations to be generated.
Personal Protective : Personal protective equipment (PPE) should meet
Equipment recommended national standards. Check with PPE suppliers.
Respiratory Protection : No respiratory protection is ordinarily required under normal
conditions of use. In accordance with good industrial hygiene
practices, precautions should be taken to avoid breathing of
material. If engineering controls do not maintain airborne
3/7
Print Date 17.12.2010 MSDS_NL
Shell Spirax S1 ATF TASA
Version 1.0
Effective Date 14.12.2010
Regulation 1907/2006/EC
Safety Data Sheet
4/7
Print Date 17.12.2010 MSDS_NL
Shell Spirax S1 ATF TASA
Version 1.0
Effective Date 14.12.2010
Regulation 1907/2006/EC
Safety Data Sheet
Stability : Stable.
Conditions to Avoid : Extremes of temperature and direct sunlight.
Materials to Avoid : Strong oxidising agents.
Hazardous : Hazardous decomposition products are not expected to form
Decomposition Products during normal storage.
Basis for Assessment : Information given is based on data on the components and the
toxicology of similar products.
Acute Oral Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rat
Acute Dermal Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rabbit
Acute Inhalation Toxicity : Not considered to be an inhalation hazard under normal
conditions of use.
Skin Irritation : Expected to be slightly irritating. Prolonged or repeated skin
contact without proper cleaning can clog the pores of the skin
resulting in disorders such as oil acne/folliculitis.
Eye Irritation : Expected to be slightly irritating.
Respiratory Irritation : Inhalation of vapours or mists may cause irritation.
Sensitisation : Not expected to be a skin sensitiser.
Repeated Dose Toxicity : Not expected to be a hazard.
Mutagenicity : Not considered a mutagenic hazard.
Carcinogenicity : Product contains mineral oils of types shown to be non-
carcinogenic in animal skin-painting studies. Highly refined
mineral oils are not classified as carcinogenic by the
International Agency for Research on Cancer (IARC). Other
components are not known to be associated with carcinogenic
effects.
Reproductive and : Not expected to be a hazard.
Developmental Toxicity
Additional Information : Used oils may contain harmful impurities that have
accumulated during use. The concentration of such impurities
will depend on use and they may present risks to health and
the environment on disposal. ALL used oil should be handled
with caution and skin contact avoided as far as possible.
Ecotoxicological data have not been determined specifically for this product. Information given is
based on a knowledge of the components and the ecotoxicology of similar products.
Acute Toxicity : Poorly soluble mixture. May cause physical fouling of aquatic
organisms. Expected to be practically non toxic: LL/EL/IL50 >
100 mg/l (to aquatic organisms) (LL/EL50 expressed as the
nominal amount of product required to prepare aqueous test
extract). Mineral oil is not expected to cause any chronic
5/7
Print Date 17.12.2010 MSDS_NL
Shell Spirax S1 ATF TASA
Version 1.0
Effective Date 14.12.2010
Regulation 1907/2006/EC
Safety Data Sheet
Other Adverse Effects : Product is a mixture of non-volatile components, which are not
expected to be released to air in any significant quantities. Not
expected to have ozone depletion potential, photochemical
ozone creation potential or global warming potential.
ADR
This material is not classified as dangerous under ADR regulations.
RID
This material is not classified as dangerous under RID regulations.
ADNR
This material is not classified as dangerous under ADNR regulations.
IMDG
This material is not classified as dangerous under IMDG regulations.
6/7
Print Date 17.12.2010 MSDS_NL
Shell Spirax S1 ATF TASA
Version 1.0
Effective Date 14.12.2010
Regulation 1907/2006/EC
Safety Data Sheet
The regulatory information is not intended to be comprehensive. Other regulations may apply to this
material.
R-phrase(s)
Not classified.
R20/22 Harmful by inhalation and if swallowed.
R38 Irritating to skin.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R53 May cause long-term adverse effects in the aquatic environment.
MSDS Revisions : A vertical bar (|) in the left margin indicates an amendment
from the previous version.
MSDS Regulation : Regulation 1907/2006/EC
MSDS Distribution : The information in this document should be made available to
all who may handle the product.
Disclaimer : This information is based on our current knowledge and is
intended to describe the product for the purposes of health,
safety and environmental requirements only. It should not
therefore be construed as guaranteeing any specific property
of the product.
7/7
Print Date 17.12.2010 MSDS_NL
Factory filled oils, lubricants and coolants for underground rigs
Normal conditions
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Shell Spirax S4 TXM
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet
Manufacturer/Supplier : Univar OY
Y-tunnus (Company number): 0536122-7
FI-01670
Vanha Nurmijärventie 62 E 28
Vantaa
Telephone : 09-3508650
Fax : 09-35086550
Email Contact for : [email protected]
MSDS
2. HAZARDS IDENTIFICATION
Health Hazards : Not expected to be a health hazard when used under normal
conditions. Prolonged or repeated skin contact without proper
cleaning can clog the pores of the skin resulting in disorders
such as oil acne/folliculitis. Used oil may contain harmful
impurities.
Signs and Symptoms : Oil acne/folliculitis signs and symptoms may include formation
of black pustules and spots on the skin of exposed areas.
Ingestion may result in nausea, vomiting and/or diarrhoea.
Safety Hazards : Not classified as flammable but will burn.
Environmental Hazards : Not classified as dangerous for the environment.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Components
1/7
Print Date 24.12.2010 MSDS_FI
Shell Spirax S4 TXM
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet
Additional Information : The highly refined mineral oil contains <3% (w/w) DMSO-
extract, according to IP346. Refer to chapter 16 for full text of
EC R-phrases.
Exposure limits apply to the following components: Highly
refined mineral oil.
General Information : Not expected to be a health hazard when used under normal
conditions.
Inhalation : No treatment necessary under normal conditions of use. If
symptoms persist, obtain medical advice.
Skin Contact : Remove contaminated clothing. Flush exposed area with water
and follow by washing with soap if available. If persistent
irritation occurs, obtain medical attention.
Eye Contact : Flush eye with copious quantities of water. If persistent
irritation occurs, obtain medical attention.
Ingestion : In general no treatment is necessary unless large quantities
are swallowed, however, get medical advice.
Advice to Physician : Treat symptomatically.
If the patient is not feeling ill, give him as soon as possible 1-2
dl cream or ice-cream followed by 50 - 100 g medicinal carbon
suspended in water.
Avoid contact with spilled or released material. For guidance on selection of personal protective
equipment see Chapter 8 of this Material Safety Data Sheet. See Chapter 13 for information on
disposal. Observe the relevant local and international regulations.
Protective measures : Avoid contact with skin and eyes. Use appropriate containment
to avoid environmental contamination. Prevent from spreading
or entering drains, ditches or rivers by using sand, earth, or
other appropriate barriers.
Clean Up Methods : Slippery when spilt. Avoid accidents, clean up immediately.
Prevent from spreading by making a barrier with sand, earth or
2/7
Print Date 24.12.2010 MSDS_FI
Shell Spirax S4 TXM
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet
Exposure Controls : The level of protection and types of controls necessary will vary
depending upon potential exposure conditions. Select controls
based on a risk assessment of local circumstances.
Appropriate measures include: Adequate ventilation to control
airborne concentrations. Where material is heated, sprayed or
mist formed, there is greater potential for airborne
concentrations to be generated.
3/7
Print Date 24.12.2010 MSDS_FI
Shell Spirax S4 TXM
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet
4/7
Print Date 24.12.2010 MSDS_FI
Shell Spirax S4 TXM
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet
Stability : Stable.
Conditions to Avoid : Extremes of temperature and direct sunlight.
Materials to Avoid : Strong oxidising agents.
Hazardous : Hazardous decomposition products are not expected to form
Decomposition Products during normal storage.
Basis for Assessment : Information given is based on data on the components and the
toxicology of similar products.
Acute Oral Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rat
Acute Dermal Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rabbit
Acute Inhalation Toxicity : Not considered to be an inhalation hazard under normal
conditions of use.
Skin Irritation : Expected to be slightly irritating. Prolonged or repeated skin
contact without proper cleaning can clog the pores of the skin
resulting in disorders such as oil acne/folliculitis.
Eye Irritation : Expected to be slightly irritating.
Respiratory Irritation : Inhalation of vapours or mists may cause irritation.
Sensitisation : Not expected to be a skin sensitiser.
Repeated Dose Toxicity : Not expected to be a hazard.
Mutagenicity : Not considered a mutagenic hazard.
Carcinogenicity : Product contains mineral oils of types shown to be non-
carcinogenic in animal skin-painting studies. Highly refined
mineral oils are not classified as carcinogenic by the
International Agency for Research on Cancer (IARC). Other
components are not known to be associated with carcinogenic
effects.
Reproductive and : Not expected to be a hazard.
Developmental Toxicity
Additional Information : Used oils may contain harmful impurities that have
accumulated during use. The concentration of such impurities
will depend on use and they may present risks to health and
the environment on disposal. ALL used oil should be handled
with caution and skin contact avoided as far as possible.
Ecotoxicological data have not been determined specifically for this product. Information given is
based on a knowledge of the components and the ecotoxicology of similar products.
5/7
Print Date 24.12.2010 MSDS_FI
Shell Spirax S4 TXM
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet
Acute Toxicity : Poorly soluble mixture. May cause physical fouling of aquatic
organisms. Expected to be practically non toxic: LL/EL/IL50 >
100 mg/l (to aquatic organisms) (LL/EL50 expressed as the
nominal amount of product required to prepare aqueous test
extract). Mineral oil is not expected to cause any chronic
effects to aquatic organisms at concentrations less than 1 mg/l.
Mobility : Liquid under most environmental conditions. Floats on water. If
it enters soil, it will adsorb to soil particles and will not be
mobile.
Persistence/degradability : Expected to be not readily biodegradable. Major constituents
are expected to be inherently biodegradable, but the product
contains components that may persist in the environment.
Bioaccumulation : Contains components with the potential to bioaccumulate.
Other Adverse Effects : Product is a mixture of non-volatile components, which are not
expected to be released to air in any significant quantities. Not
expected to have ozone depletion potential, photochemical
ozone creation potential or global warming potential.
ADR
This material is not classified as dangerous under ADR regulations.
RID
This material is not classified as dangerous under RID regulations.
ADNR
This material is not classified as dangerous under ADNR regulations.
IMDG
6/7
Print Date 24.12.2010 MSDS_FI
Shell Spirax S4 TXM
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet
The regulatory information is not intended to be comprehensive. Other regulations may apply to this
material.
R-phrase(s)
Not classified.
R38 Irritating to skin.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R53 May cause long-term adverse effects in the aquatic environment.
MSDS Revisions : A vertical bar (|) in the left margin indicates an amendment
from the previous version.
MSDS Regulation : Regulation 1907/2006/EC
MSDS Distribution : The information in this document should be made available to
all who may handle the product.
Disclaimer : This information is based on our current knowledge and is
intended to describe the product for the purposes of health,
safety and environmental requirements only. It should not
therefore be construed as guaranteeing any specific property
of the product.
7/7
Print Date 24.12.2010 MSDS_FI
Factory filled oils, lubricants and coolants for underground rigs
Normal conditions
Kinematic Viscosity
@ 40°C cSt 14.1 31.6 42.4 64.9
100°C cSt 4.2 6.3 8.4 12.1
(ASTM D 445)
These characteristics are typical of current production. Whilst future production will conform to Shell’s
specification variations in these characteristics may occur.
Manufacturer/Supplier : oy Shell ab
(0113882-9)
Neilikkatie 17
FI-01300 Vantaa
Emergency Telephone :
Number Poison Information Centre. tel 09-4711 or 09-471 977 (24h).
Stenbäckinkatu 11, 00290 Helsinki.
2. HAZARDS IDENTIFICATION
Health Hazards : Not expected to be a health hazard when used under normal
conditions. Prolonged or repeated skin contact without proper
cleaning can clog the pores of the skin resulting in disorders
such as oil acne/folliculitis. High-pressure injection under the
skin may cause serious damage including local necrosis. Used
oil may contain harmful impurities.
Signs and Symptoms : Local necrosis is evidenced by delayed onset of pain and
tissue damage a few hours following injection. Oil
acne/folliculitis signs and symptoms may include formation of
black pustules and spots on the skin of exposed areas.
Ingestion may result in nausea, vomiting and/or diarrhoea.
Safety Hazards : Not classified as flammable but will burn.
Environmental Hazards : Not classified as dangerous for the environment.
3. COMPOSITION/INFORMATION ON INGREDIENTS
General Information : Not expected to be a health hazard when used under normal
conditions.
1/7
Print Date 03.04.2008 MSDS_FI
Shell Naturelle Fluid HF-E 46
Version 1.
Effective Date 05.03.2008
Avoid contact with spilled or released material. For guidance on selection of personal protective
equipment see Chapter 8 of this Material Safety Data Sheet. See Chapter 13 for information on
disposal. Observe all relevant local and international regulations.
Protective measures : Avoid contact with skin and eyes. Use appropriate containment
to avoid environmental contamination. Prevent from spreading
or entering drains, ditches or rivers by using sand, earth, or
other appropriate barriers.
Clean Up Methods : Slippery when spilt. Avoid accidents, clean up immediately.
Prevent from spreading by making a barrier with sand, earth or
2/7
Print Date 03.04.2008 MSDS_FI
Shell Naturelle Fluid HF-E 46
Version 1.
Effective Date 05.03.2008
Exposure Controls : The level of protection and types of controls necessary will vary
depending upon potential exposure conditions. Select controls
based on a risk assessment of local circumstances.
Appropriate measures include: Adequate ventilation to control
airborne concentrations. Where material is heated, sprayed or
mist formed, there is greater potential for airborne
concentrations to be generated.
Personal Protective : Personal protective equipment (PPE) should meet
Equipment recommended national standards. Check with PPE suppliers.
Respiratory Protection : No respiratory protection is ordinarily required under normal
conditions of use. In accordance with good industrial hygiene
practices, precautions should be taken to avoid breathing of
material. If engineering controls do not maintain airborne
concentrations to a level which is adequate to protect worker
health, select respiratory protection equipment suitable for the
specific conditions of use and meeting relevant legislation.
Check with respiratory protective equipment suppliers. Where
air-filtering respirators are suitable, select an appropriate
combination of mask and filter. Select a filter suitable for
combined particulate/organic gases and vapours [boiling point
3/7
Print Date 03.04.2008 MSDS_FI
Shell Naturelle Fluid HF-E 46
Version 1.
Effective Date 05.03.2008
Stability : Stable.
Conditions to Avoid : Extremes of temperature and direct sunlight.
Materials to Avoid : Strong oxidising agents.
Hazardous : Hazardous decomposition products are not expected to form
Decomposition Products during normal storage.
4/7
Print Date 03.04.2008 MSDS_FI
Shell Naturelle Fluid HF-E 46
Version 1.
Effective Date 05.03.2008
Basis for Assessment : Information given is based on data on the components and the
toxicology of similar products.
Acute Oral Toxicity : Expected to be of low toxicity: LD50 >2000 mg/kg , Rat
Acute Dermal Toxicity : Expected to be of low toxicity: LD50 >2000 mg/kg , Rabbit
Acute Inhalation Toxicity : Not considered to be an inhalation hazard under normal
conditions of use.
Skin Irritation : Expected to be slightly irritating. Prolonged or repeated skin
contact without proper cleaning can clog the pores of the skin
resulting in disorders such as oil acne/folliculitis.
Eye Irritation : Expected to be slightly irritating.
Respiratory Irritation : Inhalation of vapours or mists may cause irritation.
Sensitisation : Not expected to be a skin sensitiser. May cause an allergic
skin reaction in sensitive individuals.
Repeated Dose Toxicity : Not expected to be a hazard.
Mutagenicity : Not considered a mutagenic hazard.
Carcinogenicity : Components are not known to be associated with carcinogenic
effects.
Reproductive and : Not expected to be a hazard.
Developmental Toxicity
Additional Information : Used oils may contain harmful impurities that have
accumulated during use. The concentration of such impurities
will depend on use and they may present risks to health and
the environment on disposal. ALL used oil should be handled
with caution and skin contact avoided as far as possible. High
pressure injection of product into the skin may lead to local
necrosis if the product is not surgically removed.
Information given is based on product data, a knowledge of the components and the
ecotoxicology of similar products.
Acute Toxicity : Poorly soluble mixture. May cause physical fouling of aquatic
organisms. Expected to be practically non toxic: LL/EL/IL50 >
100 mg/l (to aquatic organisms) (LL/EL50 expressed as the
nominal amount of product required to prepare aqueous test
extract).
Mobility : Liquid under most environmental conditions. Floats on water. If
it enters soil, it will adsorb to soil particles and will not be
mobile.
Persistence/degradability : Readily biodegradable.
Bioaccumulation : Contains components with the potential to bioaccumulate.
Other Adverse Effects : Product is a mixture of non-volatile components, which are not
expected to be released to air in any significant quantities. Not
expected to have ozone depletion potential, photochemical
ozone creation potential or global warming potential.
5/7
Print Date 03.04.2008 MSDS_FI
Shell Naturelle Fluid HF-E 46
Version 1.
Effective Date 05.03.2008
ADR
This material is not classified as dangerous under ADR regulations.
RID
This material is not classified as dangerous under RID regulations.
ADNR
This material is not classified as dangerous under ADNR regulations.
IMDG
This material is not classified as dangerous under IMDG regulations.
The regulatory information is not intended to be comprehensive. Other regulations may apply to this
material.
6/7
Print Date 03.04.2008 MSDS_FI
Shell Naturelle Fluid HF-E 46
Version 1.
Effective Date 05.03.2008
R-phrase(s)
Not classified.
MSDS Revisions : A vertical bar (|) in the left margin indicates an amendment
from the previous version.
MSDS Regulation : Regulation 1907/2006/EG
MSDS Distribution : The information in this document should be made available to
all who may handle the product.
Disclaimer : This information is based on our current knowledge and is
intended to describe the product for the purposes of health,
safety and environmental requirements only. It should not
therefore be construed as guaranteeing any specific property
of the product.
7/7
Print Date 03.04.2008 MSDS_FI
Shell Naturelle Fluid HF-E 68
Version 1.
Effective Date 07.03.2008
Manufacturer/Supplier : oy Shell ab
(0113882-9)
Neilikkatie 17
FI-01300 Vantaa
Emergency Telephone :
Number Poison Information Centre. tel 09-4711 or 09-471 977 (24h).
Stenbäckinkatu 11, 00290 Helsinki.
2. HAZARDS IDENTIFICATION
Health Hazards : Not expected to be a health hazard when used under normal
conditions. Prolonged or repeated skin contact without proper
cleaning can clog the pores of the skin resulting in disorders
such as oil acne/folliculitis. High-pressure injection under the
skin may cause serious damage including local necrosis. Used
oil may contain harmful impurities.
Signs and Symptoms : Local necrosis is evidenced by delayed onset of pain and
tissue damage a few hours following injection. Oil
acne/folliculitis signs and symptoms may include formation of
black pustules and spots on the skin of exposed areas.
Ingestion may result in nausea, vomiting and/or diarrhoea.
Safety Hazards : Not classified as flammable but will burn.
Environmental Hazards : Not classified as dangerous for the environment.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Components
1/7
Print Date 03.04.2008 MSDS_FI
Shell Naturelle Fluid HF-E 68
Version 1.
Effective Date 07.03.2008
General Information : Not expected to be a health hazard when used under normal
conditions.
Inhalation : No treatment necessary under normal conditions of use. If
symptoms persist, obtain medical advice.
Skin Contact : Remove contaminated clothing. Flush exposed area with water
and follow by washing with soap if available. If persistent
irritation occurs, obtain medical attention. When using high
pressure equipment, injection of product under the skin can
occur. If high pressure injuries occur, the casualty should be
sent immediately to a hospital. Do not wait for symptoms to
develop. Obtain medical attention even in the absence of
apparent wounds.
Eye Contact : Flush eye with copious quantities of water. If persistent
irritation occurs, obtain medical attention.
Ingestion : In general no treatment is necessary unless large quantities
are swallowed, however, get medical advice.
Advice to Physician : Treat symptomatically. High pressure injection injuries require
prompt surgical intervention and possibly steroid therapy, to
minimise tissue damage and loss of function. Because entry
wounds are small and do not reflect the seriousness of the
underlying damage, surgical exploration to determine the
extent of involvement may be necessary. Local anaesthetics or
hot soaks should be avoided because they can contribute to
swelling, vasospasm and ischaemia. Prompt surgical
decompression, debridement and evacuation of foreign
material should be performed under general anaesthetics, and
wide exploration is essential.
Avoid contact with spilled or released material. For guidance on selection of personal protective
equipment see Chapter 8 of this Material Safety Data Sheet. See Chapter 13 for information on
disposal. Observe all relevant local and international regulations.
2/7
Print Date 03.04.2008 MSDS_FI
Shell Naturelle Fluid HF-E 68
Version 1.
Effective Date 07.03.2008
Protective measures : Avoid contact with skin and eyes. Use appropriate containment
to avoid environmental contamination. Prevent from spreading
or entering drains, ditches or rivers by using sand, earth, or
other appropriate barriers.
Clean Up Methods : Slippery when spilt. Avoid accidents, clean up immediately.
Prevent from spreading by making a barrier with sand, earth or
other containment material. Reclaim liquid directly or in an
absorbent. Soak up residue with an absorbent such as clay,
sand or other suitable material and dispose of properly.
Additional Advice : Local authorities should be advised if significant spillages
cannot be contained.
Exposure Controls : The level of protection and types of controls necessary will vary
depending upon potential exposure conditions. Select controls
based on a risk assessment of local circumstances.
Appropriate measures include: Adequate ventilation to control
airborne concentrations. Where material is heated, sprayed or
mist formed, there is greater potential for airborne
concentrations to be generated.
Personal Protective : Personal protective equipment (PPE) should meet
Equipment recommended national standards. Check with PPE suppliers.
Respiratory Protection : No respiratory protection is ordinarily required under normal
conditions of use. In accordance with good industrial hygiene
practices, precautions should be taken to avoid breathing of
material. If engineering controls do not maintain airborne
concentrations to a level which is adequate to protect worker
3/7
Print Date 03.04.2008 MSDS_FI
Shell Naturelle Fluid HF-E 68
Version 1.
Effective Date 07.03.2008
4/7
Print Date 03.04.2008 MSDS_FI
Shell Naturelle Fluid HF-E 68
Version 1.
Effective Date 07.03.2008
Stability : Stable.
Conditions to Avoid : Extremes of temperature and direct sunlight.
Materials to Avoid : Strong oxidising agents.
Hazardous : Hazardous decomposition products are not expected to form
Decomposition Products during normal storage.
Basis for Assessment : Information given is based on data on the components and the
toxicology of similar products.
Acute Oral Toxicity : Expected to be of low toxicity: LD50 >2000 mg/kg , Rat
Acute Dermal Toxicity : Expected to be of low toxicity: LD50 >2000 mg/kg , Rabbit
Acute Inhalation Toxicity : Not considered to be an inhalation hazard under normal
conditions of use.
Skin Irritation : Expected to be slightly irritating. Prolonged or repeated skin
contact without proper cleaning can clog the pores of the skin
resulting in disorders such as oil acne/folliculitis.
Eye Irritation : Expected to be slightly irritating.
Respiratory Irritation : Inhalation of vapours or mists may cause irritation.
Sensitisation : Not expected to be a skin sensitiser.
Repeated Dose Toxicity : Not expected to be a hazard.
Mutagenicity : Not considered a mutagenic hazard.
Carcinogenicity : Components are not known to be associated with carcinogenic
effects.
Reproductive and : Not expected to be a hazard.
Developmental Toxicity
Additional Information : Used oils may contain harmful impurities that have
accumulated during use. The concentration of such impurities
will depend on use and they may present risks to health and
the environment on disposal. ALL used oil should be handled
with caution and skin contact avoided as far as possible. High
pressure injection of product into the skin may lead to local
necrosis if the product is not surgically removed.
Information given is based on product data, a knowledge of the components and the
ecotoxicology of similar products.
Acute Toxicity : Poorly soluble mixture. May cause physical fouling of aquatic
organisms. Expected to be practically non toxic: LL/EL/IL50 >
100 mg/l (to aquatic organisms) (LL/EL50 expressed as the
nominal amount of product required to prepare aqueous test
extract).
Mobility : Liquid under most environmental conditions. Floats on water. If
it enters soil, it will adsorb to soil particles and will not be
mobile.
Persistence/degradability : Readily biodegradable.
Bioaccumulation : Contains components with the potential to bioaccumulate.
5/7
Print Date 03.04.2008 MSDS_FI
Shell Naturelle Fluid HF-E 68
Version 1.
Effective Date 07.03.2008
Other Adverse Effects : Product is a mixture of non-volatile components, which are not
expected to be released to air in any significant quantities. Not
expected to have ozone depletion potential, photochemical
ozone creation potential or global warming potential.
ADR
This material is not classified as dangerous under ADR regulations.
RID
This material is not classified as dangerous under RID regulations.
ADNR
This material is not classified as dangerous under ADNR regulations.
IMDG
This material is not classified as dangerous under IMDG regulations.
The regulatory information is not intended to be comprehensive. Other regulations may apply to this
material.
6/7
Print Date 03.04.2008 MSDS_FI
Shell Naturelle Fluid HF-E 68
Version 1.
Effective Date 07.03.2008
exempt.
TSCA : All components
listed.
R-phrase(s)
Not classified.
R38 Irritating to skin.
R53 May cause long-term adverse effects in the aquatic environment.
MSDS Revisions : A vertical bar (|) in the left margin indicates an amendment
from the previous version.
MSDS Regulation : Regulation 1907/2006/EG
MSDS Distribution : The information in this document should be made available to
all who may handle the product.
Disclaimer : This information is based on our current knowledge and is
intended to describe the product for the purposes of health,
safety and environmental requirements only. It should not
therefore be construed as guaranteeing any specific property
of the product.
7/7
Print Date 03.04.2008 MSDS_FI
Shell Tellus Oils S
Zinc-free hydraulic oils for severe duty
Shell Tellus Oils S are 'top-tier', anti-wear hydraulic oils formulated to be the
ultimate 'high reference oil' in the hydraulics industry.
Based on advanced 'zinc and chlorine free' technology, Shell Tellus Oils S are
formulated to ensure exceptional performance in hydraulic fluid power
transmission systems subjected to severe duty.
hydraulic vane pumps. In addition, outstanding
Applications performance is also observed when applying
z Primary application in industrial, marine Shell in-house test conditions. These test the
and mobile hydraulic and fluid power fluids over the complete range of pump
transmission systems. operating conditions. The results have proven
that Shell Tellus Oils S are capable of providing
the ultimate protection under the extremes of
operation found in real service.
Performance features
z Outstanding oil life FZG gear rig test
Typically two to four times that of many Gear rig tests are sometimes used for
anti-wear hydraulic oils. evaluating hydraulic oils and the best known is
z Peace of mind the FZG rig (Forschungsstelle für Zahnräder
Through longer component life and und Getriebebau - Technical Institute for the
trouble free operation. study of Gears and Drive Mechanisms).
The rig utilises a pair of specially designed
z Lower ecological impact
case-hardened spur gears and, for hydraulic
Zinc and chlorine free formulations unique
oils, it is run at a pitch line velocity of 8.3 m/s,
to Shell.
with an oil temperature of 90°C. The test is
carried out by running the gears for 15 minutes
Long life in the test oil then weighing the gears, after
which the machine is reassembled and the
The length of a hydraulic oil's life depends load increased. This procedure is carried out
mainly on its ability to resist oxidation due to until at least 10 mg weight loss is recorded
heat in the presence of air, water and metal between the stages, or until the gears appear
catalysts such as copper. Oxidation results in scuffed.
the formation of sludge and acidic products.
Tellus S achieves an 11th Fail stage.
A standard test of oxidation properties is the
Turbine Oil Stability Test (TOST), in which the Thermal stability
oil is heated at 95°C in the presence of water
An oil's thermal stability is the measure of its
and oxygen with copper and iron as catalysts.
ability to resist degradation and attack of
The test results are expressed as time taken metals at high temperature. An accelerated
(hours) for the acid value to reach 2 mg test for this is to maintain the oil at a
KOH/g. temperature of 135°C for one week in the
presence of steel and copper.
In this test, Shell Tellus Oils S have an
oxidation life of two to four times that of many Tests with Shell Tellus Oils S show negligible
other anti-wear hydraulic oils. weight changes of the metals, whilst the steel
remains bright and there is only slight
Vane pump wear performance discolouration of the copper; many anti-wear
hydraulic oils cause the copper to become
Shell Tellus Oils S have been subjected to a black.
number of vane pump tests which are some of
the most severe for evaluating steel-on-steel Piston pump performance
anti-wear properties.
Many piston pumps utilise brass components
Excellent performance has been achieved in and in particular brass slippers which fit onto
the standard industry tests using Vickers the heads of steel pistons and slide on a steel
(V104C and 35VQ25M) and Denison (T6-C) surface. These bronze slippers are usually the
Kinematic Viscosity
@ 0°C cSt 180 336 576 1038 1780
20°C cSt 55 90 135 220 330
40°C cSt 22 32 46 68 100
100°C cSt 4.3 5.4 6.8 8.7 11.2
(IP 71)
Viscosity Index (IP226) 100 99 98 97 96
Density @ 15°C (IP 365) kg/l 0.871 0.872 0.876 0.883 0.890
Flash Point (IP 34) (PMCC) °C 204 207 218 222 234
Pour Point (IP 15) °C -30 -30 -30 -30 -24
The physical characteristics shown are typical of current production. Whilst future production will
conform to Shell's specification, variations in these characteristics may occur.
0 10 20 30 40 50 60 70 80 90 100 O il A in [ % ]
500.000
200.000
100.000
50.000
10.000
5.000
1.000
500
300
200
Kinematic Viscosity [mm²/s]
100
Shell Tellus Oils S
50
40
30
20
10
9 100
8
7
68
6
5 46
4
32
22
3
2,4
-20 -15 -10 -5 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 110 120
Temperature [°C]
7. COMPRESSOR
These characteristics are typical of current production. Whilst future production will conform
to Shell's specification, variations in these characteristics may occur.
Manufacturer/Supplier : oy Shell ab
Neilikkatie 17
FI-01300 Vantaa
Emergency Telephone :
Number Poison Information Centre. tel 09-4711 or 09-471 977 (24h).
Stenbäckinkatu 11, 00290 Helsinki.
2. HAZARDS IDENTIFICATION
Health Hazards : Not expected to be a health hazard when used under normal
conditions. Prolonged or repeated skin contact without proper
cleaning can clog the pores of the skin resulting in disorders
such as oil acne/folliculitis. Used oil may contain harmful
impurities.
Signs and Symptoms : Oil acne/folliculitis signs and symptoms may include formation
of black pustules and spots on the skin of exposed areas.
Ingestion may result in nausea, vomiting and/or diarrhoea.
Safety Hazards : Not classified as flammable but will burn.
Environmental Hazards : Not classified as dangerous for the environment.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Components
Additional Information : The highly refined mineral oil contains <3% (w/w) DMSO-
extract, according to IP346. Refer to chapter 16 for full text of
EC R-phrases.
1/7
Print Date 03.04.2008 MSDS_FI
Shell Corena Oil D 46
Version 1.
Effective Date 19.02.2008
General Information : Not expected to be a health hazard when used under normal
conditions.
Inhalation : No treatment necessary under normal conditions of use. If
symptoms persist, obtain medical advice.
Skin Contact : Remove contaminated clothing. Flush exposed area with water
and follow by washing with soap if available. If persistent
irritation occurs, obtain medical attention.
Eye Contact : Flush eye with copious quantities of water. If persistent
irritation occurs, obtain medical attention.
Ingestion : In general no treatment is necessary unless large quantities
are swallowed, however, get medical advice.
Advice to Physician : Treat symptomatically.
If the patient is not feeling ill, give him as soon as possible 1-2
dl cream or ice-cream followed by 50 - 100 g medicinal carbon
suspended in water.
Avoid contact with spilled or released material. For guidance on selection of personal protective
equipment see Chapter 8 of this Material Safety Data Sheet. See Chapter 13 for information on
disposal. Observe all relevant local and international regulations.
Protective measures : Avoid contact with skin and eyes. Use appropriate containment
to avoid environmental contamination. Prevent from spreading
or entering drains, ditches or rivers by using sand, earth, or
other appropriate barriers.
Clean Up Methods : Slippery when spilt. Avoid accidents, clean up immediately.
Prevent from spreading by making a barrier with sand, earth or
other containment material. Reclaim liquid directly or in an
absorbent. Soak up residue with an absorbent such as clay,
sand or other suitable material and dispose of properly.
Additional Advice : Local authorities should be advised if significant spillages
cannot be contained.
2/7
Print Date 03.04.2008 MSDS_FI
Shell Corena Oil D 46
Version 1.
Effective Date 19.02.2008
Exposure Controls : The level of protection and types of controls necessary will vary
depending upon potential exposure conditions. Select controls
based on a risk assessment of local circumstances.
Appropriate measures include: Adequate ventilation to control
airborne concentrations. Where material is heated, sprayed or
mist formed, there is greater potential for airborne
concentrations to be generated.
Personal Protective : Personal protective equipment (PPE) should meet
Equipment recommended national standards. Check with PPE suppliers.
Respiratory Protection : No respiratory protection is ordinarily required under normal
conditions of use. In accordance with good industrial hygiene
practices, precautions should be taken to avoid breathing of
material. If engineering controls do not maintain airborne
concentrations to a level which is adequate to protect worker
health, select respiratory protection equipment suitable for the
specific conditions of use and meeting relevant legislation.
Check with respiratory protective equipment suppliers. Where
air-filtering respirators are suitable, select an appropriate
combination of mask and filter. Select a filter suitable for
combined particulate/organic gases and vapours [boiling point
>65 °C (149 °F)] meeting EN141.
3/7
Print Date 03.04.2008 MSDS_FI
Shell Corena Oil D 46
Version 1.
Effective Date 19.02.2008
Hand Protection : Where hand contact with the product may occur the use of
gloves approved to relevant standards (e.g. Europe: EN374,
US: F739) made from the following materials may provide
suitable chemical protection: PVC, neoprene or nitrile rubber
gloves. Suitability and durability of a glove is dependent on
usage, e.g. frequency and duration of contact, chemical
resistance of glove material, glove thickness, dexterity. Always
seek advice from glove suppliers. Contaminated gloves should
be replaced. Personal hygiene is a key element of effective
hand care. Gloves must only be worn on clean hands. After
using gloves, hands should be washed and dried thoroughly.
Application of a non-perfumed moisturiser is recommended.
Eye Protection : Wear safety glasses or full face shield if splashes are likely to
occur. Approved to EU Standard EN166.
Protective Clothing : Skin protection not ordinarily required beyond standard issue
work clothes.
Monitoring Methods : Monitoring of the concentration of substances in the breathing
zone of workers or in the general workplace may be required to
confirm compliance with an OEL and adequacy of exposure
controls. For some substances biological monitoring may also
be appropriate.
Environmental Exposure : Minimise release to the environment. An environmental
Controls assessment must be made to ensure compliance with local
environmental legislation.
Stability : Stable.
Conditions to Avoid : Extremes of temperature and direct sunlight.
Materials to Avoid : Strong oxidising agents.
Hazardous : Hazardous decomposition products are not expected to form
Decomposition Products during normal storage.
4/7
Print Date 03.04.2008 MSDS_FI
Shell Corena Oil D 46
Version 1.
Effective Date 19.02.2008
Basis for Assessment : Information given is based on data on the components and the
toxicology of similar products.
Acute Oral Toxicity : Expected to be of low toxicity: LD50 >2000 mg/kg , Rat
Acute Dermal Toxicity : Expected to be of low toxicity: LD50 >2000 mg/kg , Rabbit
Acute Inhalation Toxicity : Not considered to be an inhalation hazard under normal
conditions of use.
Skin Irritation : Expected to be slightly irritating. Prolonged or repeated skin
contact without proper cleaning can clog the pores of the skin
resulting in disorders such as oil acne/folliculitis.
Eye Irritation : Expected to be slightly irritating.
Respiratory Irritation : Inhalation of vapours or mists may cause irritation.
Sensitisation : Not expected to be a skin sensitiser. May cause an allergic
skin reaction in sensitive individuals.
Repeated Dose Toxicity : Not expected to be a hazard.
Mutagenicity : Not considered a mutagenic hazard.
Carcinogenicity : Product contains mineral oils of types shown to be non-
carcinogenic in animal skin-painting studies. Highly refined
mineral oils are not classified as carcinogenic by the
International Agency for Research on Cancer (IARC). Other
components are not known to be associated with carcinogenic
effects.
Reproductive and : Not expected to be a hazard.
Developmental Toxicity
Additional Information : Used oils may contain harmful impurities that have
accumulated during use. The concentration of such impurities
will depend on use and they may present risks to health and
the environment on disposal. ALL used oil should be handled
with caution and skin contact avoided as far as possible.
Ecotoxicological data have not been determined specifically for this product. Information given is
based on a knowledge of the components and the ecotoxicology of similar products.
Acute Toxicity : Poorly soluble mixture. May cause physical fouling of aquatic
organisms. Expected to be practically non toxic: LL/EL/IL50 >
100 mg/l (to aquatic organisms) (LL/EL50 expressed as the
nominal amount of product required to prepare aqueous test
extract). Mineral oil is not expected to cause any chronic
effects to aquatic organisms at concentrations less than 1 mg/l.
Mobility : Liquid under most environmental conditions. Floats on water. If
it enters soil, it will adsorb to soil particles and will not be
mobile.
Persistence/degradability : Expected to be not readily biodegradable. Major constituents
are expected to be inherently biodegradable, but the product
contains components that may persist in the environment.
Bioaccumulation : Contains components with the potential to bioaccumulate.
Other Adverse Effects : Product is a mixture of non-volatile components, which are not
expected to be released to air in any significant quantities. Not
5/7
Print Date 03.04.2008 MSDS_FI
Shell Corena Oil D 46
Version 1.
Effective Date 19.02.2008
ADR
This material is not classified as dangerous under ADR regulations.
RID
This material is not classified as dangerous under RID regulations.
ADNR
This material is not classified as dangerous under ADNR regulations.
IMDG
This material is not classified as dangerous under IMDG regulations.
The regulatory information is not intended to be comprehensive. Other regulations may apply to this
material.
6/7
Print Date 03.04.2008 MSDS_FI
Shell Corena Oil D 46
Version 1.
Effective Date 19.02.2008
listed.
Sensitiser not sufficient to : Contains calcium sulphonate. May produce an allergic
classify reaction.
R-phrase(s)
Not classified.
R36/38 Irritating to eyes and skin.
R43 May cause sensitization by skin contact.
MSDS Revisions : A vertical bar (|) in the left margin indicates an amendment
from the previous version.
MSDS Regulation : Regulation 1907/2006/EG
MSDS Distribution : The information in this document should be made available to
all who may handle the product.
Disclaimer : This information is based on our current knowledge and is
intended to describe the product for the purposes of health,
safety and environmental requirements only. It should not
therefore be construed as guaranteeing any specific property
of the product.
7/7
Print Date 03.04.2008 MSDS_FI
Factory filled oils, lubricants and coolants for underground rigs
Normal conditions
8. SHANK LUBRICATION
Performance Benefits
x Oil mist lubrication applications
x Reliable wear & corrosion protection Shell Air Tool Oil can also be
Shell Air Tool Oil S2 A has been used in applications requiring
developed to provide excellent mist lubrication, such as air tool
lubricity and anti-wear properties to installations commonly found in
protect percussion tools including manufacturing.
rock drills operating under arduous
conditions. x Other applications
It also provides high levels of May be used in certain gear and
corrosion protection even under bearing lubrication systems
severe water wash conditions. subject to water ingress.
Manufacturer/Supplier : Univar OY
Y-tunnus (Company number): 0536122-7
FI-01670
Vanha Nurmijärventie 62 E 28
Vantaa
Telephone : 09-3508650
Fax : 09-35086550
Email Contact for : [email protected]
MSDS
2. HAZARDS IDENTIFICATION
Health Hazards : Not expected to be a health hazard when used under normal
conditions. Prolonged or repeated skin contact without proper
cleaning can clog the pores of the skin resulting in disorders
such as oil acne/folliculitis. Used oil may contain harmful
impurities.
Signs and Symptoms : Oil acne/folliculitis signs and symptoms may include formation
of black pustules and spots on the skin of exposed areas.
Ingestion may result in nausea, vomiting and/or diarrhoea.
Safety Hazards : Not classified as flammable but will burn.
Environmental Hazards : Not classified as dangerous for the environment.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Additional Information : The highly refined mineral oil contains <3% (w/w) DMSO-
extract, according to IP346.
Exposure limits apply to the following components: Highly
refined mineral oil.
1/7
Print Date 24.12.2010 MSDS_FI
Shell Air Tool Oil S2 A 100
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet
General Information : Not expected to be a health hazard when used under normal
conditions.
Inhalation : No treatment necessary under normal conditions of use. If
symptoms persist, obtain medical advice.
Skin Contact : Remove contaminated clothing. Flush exposed area with water
and follow by washing with soap if available. If persistent
irritation occurs, obtain medical attention.
Eye Contact : Flush eye with copious quantities of water. If persistent
irritation occurs, obtain medical attention.
Ingestion : In general no treatment is necessary unless large quantities
are swallowed, however, get medical advice.
Advice to Physician : Treat symptomatically.
If the patient is not feeling ill, give him as soon as possible 1-2
dl cream or ice-cream followed by 50 - 100 g medicinal carbon
suspended in water.
Avoid contact with spilled or released material. For guidance on selection of personal protective
equipment see Chapter 8 of this Material Safety Data Sheet. See Chapter 13 for information on
disposal. Observe the relevant local and international regulations.
Protective measures : Avoid contact with skin and eyes. Use appropriate containment
to avoid environmental contamination. Prevent from spreading
or entering drains, ditches or rivers by using sand, earth, or
other appropriate barriers.
Clean Up Methods : Slippery when spilt. Avoid accidents, clean up immediately.
Prevent from spreading by making a barrier with sand, earth or
other containment material. Reclaim liquid directly or in an
absorbent. Soak up residue with an absorbent such as clay,
sand or other suitable material and dispose of properly.
Additional Advice : Local authorities should be advised if significant spillages
cannot be contained.
2/7
Print Date 24.12.2010 MSDS_FI
Shell Air Tool Oil S2 A 100
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet
Exposure Controls : The level of protection and types of controls necessary will vary
depending upon potential exposure conditions. Select controls
based on a risk assessment of local circumstances.
Appropriate measures include: Adequate ventilation to control
airborne concentrations. Where material is heated, sprayed or
mist formed, there is greater potential for airborne
concentrations to be generated.
Personal Protective : Personal protective equipment (PPE) should meet
Equipment recommended national standards. Check with PPE suppliers.
Respiratory Protection : No respiratory protection is ordinarily required under normal
conditions of use. In accordance with good industrial hygiene
practices, precautions should be taken to avoid breathing of
3/7
Print Date 24.12.2010 MSDS_FI
Shell Air Tool Oil S2 A 100
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet
4/7
Print Date 24.12.2010 MSDS_FI
Shell Air Tool Oil S2 A 100
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet
Stability : Stable.
Conditions to Avoid : Extremes of temperature and direct sunlight.
Materials to Avoid : Strong oxidising agents.
Hazardous : Hazardous decomposition products are not expected to form
Decomposition Products during normal storage.
Basis for Assessment : Information given is based on data on the components and the
toxicology of similar products.
Acute Oral Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rat
Acute Dermal Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rabbit
Acute Inhalation Toxicity : Not considered to be an inhalation hazard under normal
conditions of use.
Skin Irritation : Expected to be slightly irritating.
Eye Irritation : Expected to be slightly irritating.
Respiratory Irritation : Inhalation of vapours or mists may cause irritation.
Sensitisation : Not expected to be a skin sensitiser.
Repeated Dose Toxicity : Not expected to be a hazard.
Mutagenicity : Not considered a mutagenic hazard.
Carcinogenicity : Product contains mineral oils of types shown to be non-
carcinogenic in animal skin-painting studies. Highly refined
mineral oils are not classified as carcinogenic by the
International Agency for Research on Cancer (IARC). Other
components are not known to be associated with carcinogenic
effects.
Reproductive and : Not expected to be a hazard.
Developmental Toxicity
Additional Information : Used oils may contain harmful impurities that have
accumulated during use. The concentration of such impurities
will depend on use and they may present risks to health and
the environment on disposal. ALL used oil should be handled
with caution and skin contact avoided as far as possible.
Ecotoxicological data have not been determined specifically for this product. Information given is
based on a knowledge of the components and the ecotoxicology of similar products.
Acute Toxicity : Poorly soluble mixture. May cause physical fouling of aquatic
organisms. Expected to be practically non toxic: LL/EL/IL50 >
100 mg/l (to aquatic organisms) (LL/EL50 expressed as the
nominal amount of product required to prepare aqueous test
extract). Mineral oil is not expected to cause any chronic
effects to aquatic organisms at concentrations less than 1 mg/l.
5/7
Print Date 24.12.2010 MSDS_FI
Shell Air Tool Oil S2 A 100
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet
Other Adverse Effects : Product is a mixture of non-volatile components, which are not
expected to be released to air in any significant quantities. Not
expected to have ozone depletion potential, photochemical
ozone creation potential or global warming potential.
ADR
This material is not classified as dangerous under ADR regulations.
RID
This material is not classified as dangerous under RID regulations.
ADNR
This material is not classified as dangerous under ADNR regulations.
IMDG
This material is not classified as dangerous under IMDG regulations.
6/7
Print Date 24.12.2010 MSDS_FI
Shell Air Tool Oil S2 A 100
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet
The regulatory information is not intended to be comprehensive. Other regulations may apply to this
material.
R-phrase(s)
Not classified.
MSDS Revisions : A vertical bar (|) in the left margin indicates an amendment
from the previous version.
MSDS Regulation : Regulation 1907/2006/EC
MSDS Distribution : The information in this document should be made available to
all who may handle the product.
Disclaimer : This information is based on our current knowledge and is
intended to describe the product for the purposes of health,
safety and environmental requirements only. It should not
therefore be construed as guaranteeing any specific property
of the product.
7/7
Print Date 24.12.2010 MSDS_FI
Factory filled oils, lubricants and coolants for underground rigs
Normal conditions
Spirax S3 AX 80W-90
SAE Viscosity grade SAE J 306 80W-90
Kinematic Viscosity ISO 3104
at 40°C mm2/s 169.0
at 100°C mm2/s 16.8
Density at 15°C kg/m3 ISO 12185 900
Flash Point COC °C ISO 2592 220
Pour Point °C ISO 3016 -30
These characteristics are typical of current production. Whilst future production will conform
to Shell's specification, variations in these characteristics may occur.
6KHOO/XEULFDQWV¤'
Page 1 of 1
Shell Spirax S3 AX 80W-90
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet
Manufacturer/Supplier : Univar OY
Y-tunnus (Company number): 0536122-7
FI-01670
Vanha Nurmijärventie 62 E 28
Vantaa
Telephone : 09-3508650
Fax : 09-35086550
Email Contact for : [email protected]
MSDS
2. HAZARDS IDENTIFICATION
Health Hazards : Not expected to be a health hazard when used under normal
conditions. Prolonged or repeated skin contact without proper
cleaning can clog the pores of the skin resulting in disorders
such as oil acne/folliculitis. Used oil may contain harmful
impurities.
Signs and Symptoms : Oil acne/folliculitis signs and symptoms may include formation
of black pustules and spots on the skin of exposed areas.
Ingestion may result in nausea, vomiting and/or diarrhoea.
Safety Hazards : Not classified as flammable but will burn.
Environmental Hazards : Harmful to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Components
Additional Information : The highly refined mineral oil contains <3% (w/w) DMSO-
extract, according to IP346. Refer to chapter 16 for full text of
EC R-phrases.
Exposure limits apply to the following components: Highly
refined mineral oil.
General Information : Not expected to be a health hazard when used under normal
conditions.
Inhalation : No treatment necessary under normal conditions of use. If
symptoms persist, obtain medical advice.
Skin Contact : Remove contaminated clothing. Flush exposed area with water
and follow by washing with soap if available. If persistent
irritation occurs, obtain medical attention.
Eye Contact : Flush eye with copious quantities of water. If persistent
irritation occurs, obtain medical attention.
Ingestion : In general no treatment is necessary unless large quantities
are swallowed, however, get medical advice.
Advice to Physician : Treat symptomatically.
If the patient is not feeling ill, give him as soon as possible 1-2
dl cream or ice-cream followed by 50 - 100 g medicinal carbon
suspended in water.
Avoid contact with spilled or released material. For guidance on selection of personal protective
equipment see Chapter 8 of this Material Safety Data Sheet. See Chapter 13 for information on
disposal. Observe the relevant local and international regulations.
Protective measures : Avoid contact with skin and eyes. Use appropriate containment
to avoid environmental contamination. Prevent from spreading
or entering drains, ditches or rivers by using sand, earth, or
2/8
Print Date 24.12.2010 MSDS_FI
Shell Spirax S3 AX 80W-90
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet
Exposure Controls : The level of protection and types of controls necessary will vary
depending upon potential exposure conditions. Select controls
based on a risk assessment of local circumstances.
Appropriate measures include: Adequate ventilation to control
3/8
Print Date 24.12.2010 MSDS_FI
Shell Spirax S3 AX 80W-90
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet
4/8
Print Date 24.12.2010 MSDS_FI
Shell Spirax S3 AX 80W-90
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet
Stability : Stable.
Conditions to Avoid : Extremes of temperature and direct sunlight.
Materials to Avoid : Strong oxidising agents.
Hazardous : Hazardous decomposition products are not expected to form
Decomposition Products during normal storage.
Basis for Assessment : Information given is based on data on the components and the
toxicology of similar products.
Acute Oral Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rat
Acute Dermal Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rabbit
Acute Inhalation Toxicity : Not considered to be an inhalation hazard under normal
conditions of use.
Skin Irritation : Expected to be slightly irritating. Prolonged or repeated skin
contact without proper cleaning can clog the pores of the skin
resulting in disorders such as oil acne/folliculitis.
Eye Irritation : Expected to be slightly irritating.
Respiratory Irritation : Inhalation of vapours or mists may cause irritation.
Sensitisation : Not expected to be a skin sensitiser.
Repeated Dose Toxicity : Not expected to be a hazard.
Mutagenicity : Not considered a mutagenic hazard.
Carcinogenicity : Product contains mineral oils of types shown to be non-
carcinogenic in animal skin-painting studies. Highly refined
mineral oils are not classified as carcinogenic by the
International Agency for Research on Cancer (IARC). Other
components are not known to be associated with carcinogenic
effects.
Reproductive and : Not expected to be a hazard.
Developmental Toxicity
Additional Information : Used oils may contain harmful impurities that have
accumulated during use. The concentration of such impurities
will depend on use and they may present risks to health and
the environment on disposal. ALL used oil should be handled
with caution and skin contact avoided as far as possible.
5/8
Print Date 24.12.2010 MSDS_FI
Shell Spirax S3 AX 80W-90
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet
Ecotoxicological data have not been determined specifically for this product. Information given is
based on a knowledge of the components and the ecotoxicology of similar products.
Acute Toxicity : Poorly soluble mixture. May cause physical fouling of aquatic
organisms. Expected to be harmful: LL/EL/IL50 10-100 mg/l (to
aquatic organisms) (LL/EL50 expressed as the nominal
amount of product required to prepare aqueous test extract).
Mobility : Liquid under most environmental conditions. Floats on water. If
it enters soil, it will adsorb to soil particles and will not be
mobile.
Persistence/degradability : Expected to be not readily biodegradable. Major constituents
are expected to be inherently biodegradable, but the product
contains components that may persist in the environment.
Bioaccumulation : Contains components with the potential to bioaccumulate.
Other Adverse Effects : Product is a mixture of non-volatile components, which are not
expected to be released to air in any significant quantities. Not
expected to have ozone depletion potential, photochemical
ozone creation potential or global warming potential.
Contains alkyl phosphate. Very toxic: LC/EC/IC50 0.1 - 1 mg/l
(to aquatic organisms)
ADR
This material is not classified as dangerous under ADR regulations.
RID
This material is not classified as dangerous under RID regulations.
ADNR
This material is not classified as dangerous under ADNR regulations.
6/8
Print Date 24.12.2010 MSDS_FI
Shell Spirax S3 AX 80W-90
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet
IMDG
This material is not classified as dangerous under IMDG regulations.
The regulatory information is not intended to be comprehensive. Other regulations may apply to this
material.
R-phrase(s)
MSDS Revisions : A vertical bar (|) in the left margin indicates an amendment
from the previous version.
MSDS Regulation : Regulation 1907/2006/EC
7/8
Print Date 24.12.2010 MSDS_FI
Shell Spirax S3 AX 80W-90
Version 1.0
Effective Date 16.12.2010
Regulation 1907/2006/EC
Safety Data Sheet
8/8
Print Date 24.12.2010 MSDS_FI
Factory filled oils, lubricants and coolants for underground rigs
Normal conditions
10. COOLANT
The Carcoolant 774C is a high quality product from the leading manufacturers in
Europe.
774C is free from nitrite, amine and phosphate but contains silicate in order to give the
best possible protection against corrosion of the engines light metal parts (aluminum,
magnesium).
774C guarantees safe functionality and good protection against corrosion following
most of the occurring car manufacturer’s specifications.
Use
The cooling system should contain at least 30% engine coolant of high quality in order to
give best possible corrosion protection up to 3 years. Also during the summer months is it
important to have glycol in the cooling system. The boiling point will increase to about 105 ºC
and protects the engine against overheating.
Follow the guidance in the car manual regarding choice of engine coolant. Do not jeopardize
the function of the engine by choosing a low quality. This is most important for heavy duty
vehicles or vehicles with a high demand of reliability. The added cost of a quality engine
coolant is minimal compared to the cars total operating cost per year.
Approvals
Univar Carcoolant 774C meets the performance requirements of the relevant OEM´s
Mixing table
Color: Blue
Contains: 1,2 – ethanediol > 90%
Is diluted with pure water
Safety
The main component in Carcoolant 774C is, like in most other engine coolants,
mono ethylene glycol that is toxic when ingested. Make sure that the products are stored
safely and prevent spillage in nature or streams.
Our Security Data Sheet gives you all information about labeling, environmental impact,
handling, health aspects etc. www.univar.se
Used glycol
Used glycol can be left at an approved collection point for hazardous waste. Do not pour the
glycol in the sink, in nature or in streams.
Packages
The information in this product sheet is only guiding and we reserve ourselves the right to without
further notice change text or facts
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Normal conditions
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Shell Gadus S2 V220 2
Version 1.0
Effective Date 30.11.2010
Manufacturer/Supplier : Univar OY
Telephone : 09-3508650
Fax : 09-35086550
Email Contact for : [email protected]
MSDS
2. HAZARDS IDENTIFICATION
Health Hazards : Not expected to be a health hazard when used under normal
conditions. Prolonged or repeated skin contact without proper
cleaning can clog the pores of the skin resulting in disorders
such as oil acne/folliculitis. High-pressure injection under the
skin may cause serious damage including local necrosis. Used
grease may contain harmful impurities.
Signs and Symptoms : Local necrosis is evidenced by delayed onset of pain and
tissue damage a few hours following injection. Oil
acne/folliculitis signs and symptoms may include formation of
black pustules and spots on the skin of exposed areas.
Ingestion may result in nausea, vomiting and/or diarrhoea.
Safety Hazards : Not classified as flammable but will burn.
Environmental Hazards : Not classified as dangerous for the environment.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Components
1/7
Print Date 03.12.2010 MSDS_FI
Shell Gadus S2 V220 2
Version 1.0
Effective Date 30.11.2010
Additional Information : The highly refined mineral oil contains <3% (w/w) DMSO-
extract, according to IP346. Refer to chapter 16 for full text of
EC R-phrases.
Exposure limits apply to the following components: Highly
refined mineral oil.
General Information : Not expected to be a health hazard when used under normal
conditions.
Inhalation : No treatment necessary under normal conditions of use. If
symptoms persist, obtain medical advice.
Skin Contact : Remove contaminated clothing. Flush exposed area with water
and follow by washing with soap if available. If persistent
irritation occurs, obtain medical attention. When using high
pressure equipment, injection of product under the skin can
occur. If high pressure injuries occur, the casualty should be
sent immediately to a hospital. Do not wait for symptoms to
develop. Obtain medical attention even in the absence of
apparent wounds.
Eye Contact : Flush eye with copious quantities of water. If persistent
irritation occurs, obtain medical attention.
Ingestion : In general no treatment is necessary unless large quantities
are swallowed, however, get medical advice.
Advice to Physician : Treat symptomatically. High pressure injection injuries require
prompt surgical intervention and possibly steroid therapy, to
minimise tissue damage and loss of function. Because entry
wounds are small and do not reflect the seriousness of the
underlying damage, surgical exploration to determine the
extent of involvement may be necessary. Local anaesthetics or
hot soaks should be avoided because they can contribute to
swelling, vasospasm and ischaemia. Prompt surgical
decompression, debridement and evacuation of foreign
material should be performed under general anaesthetics, and
wide exploration is essential.
If the patient is not feeling ill, give him as soon as possible 1-2
dl cream or ice-cream followed by 50 - 100 g medicinal carbon
suspended in water.
2/7
Print Date 03.12.2010 MSDS_FI
Shell Gadus S2 V220 2
Version 1.0
Effective Date 30.11.2010
Avoid contact with spilled or released material. For guidance on selection of personal protective
equipment see Chapter 8 of this Material Safety Data Sheet. See Chapter 13 for information on
disposal. Observe the relevant local and international regulations.
Protective measures : Avoid contact with skin and eyes. Use appropriate containment
to avoid environmental contamination. Prevent from spreading
or entering drains, ditches or rivers by using sand, earth, or
other appropriate barriers.
Clean Up Methods : Shovel into a suitable clearly marked container for disposal or
reclamation in accordance with local regulations.
3/7
Print Date 03.12.2010 MSDS_FI
Shell Gadus S2 V220 2
Version 1.0
Effective Date 30.11.2010
4/7
Print Date 03.12.2010 MSDS_FI
Shell Gadus S2 V220 2
Version 1.0
Effective Date 30.11.2010
Stability : Stable.
Conditions to Avoid : Extremes of temperature and direct sunlight.
Materials to Avoid : Strong oxidising agents.
Hazardous : Hazardous decomposition products are not expected to form
Decomposition Products during normal storage.
Basis for Assessment : Information given is based on data on the components and the
toxicology of similar products.
Acute Oral Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rat
Acute Dermal Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rabbit
Acute Inhalation Toxicity : Not considered to be an inhalation hazard under normal
conditions of use.
Skin Irritation : Expected to be slightly irritating. Prolonged or repeated skin
contact without proper cleaning can clog the pores of the skin
resulting in disorders such as oil acne/folliculitis.
Eye Irritation : Expected to be slightly irritating.
Respiratory Irritation : Inhalation of vapours or mists may cause irritation.
Sensitisation : Not expected to be a skin sensitiser.
Repeated Dose Toxicity : Not expected to be a hazard.
Mutagenicity : Not considered a mutagenic hazard.
Carcinogenicity : Product contains mineral oils of types shown to be non-
carcinogenic in animal skin-painting studies. Highly refined
mineral oils are not classified as carcinogenic by the
International Agency for Research on Cancer (IARC). Other
components are not known to be associated with carcinogenic
effects.
Reproductive and : Not expected to be a hazard.
Developmental Toxicity
Additional Information : Used grease may contain harmful impurities that have
accumulated during use. The concentration of such harmful
impurities will depend on use and they may present risks to
health and the environment on disposal. ALL used grease
should be handled with caution and skin contact avoided as far
5/7
Print Date 03.12.2010 MSDS_FI
Shell Gadus S2 V220 2
Version 1.0
Effective Date 30.11.2010
Ecotoxicological data have not been determined specifically for this product. Information given is
based on a knowledge of the components and the ecotoxicology of similar products.
Acute Toxicity : Poorly soluble mixture. May cause physical fouling of aquatic
organisms. Expected to be practically non toxic: LL/EL/IL50 >
100 mg/l (to aquatic organisms) (LL/EL50 expressed as the
nominal amount of product required to prepare aqueous test
extract). Mineral oil is not expected to cause any chronic
effects to aquatic organisms at concentrations less than 1 mg/l.
Mobility : Semi-solid under most environmental conditions. Floats on
water. If it enters soil, it will adsorb to soil particles and will not
be mobile.
Persistence/degradability : Expected to be not readily biodegradable. Major constituents
are expected to be inherently biodegradable, but the product
contains components that may persist in the environment.
Bioaccumulation : Contains components with the potential to bioaccumulate.
Other Adverse Effects : Product is a mixture of non-volatile components, which are not
expected to be released to air in any significant quantities. Not
expected to have ozone depletion potential, photochemical
ozone creation potential or global warming potential.
ADR
This material is not classified as dangerous under ADR regulations.
RID
This material is not classified as dangerous under RID regulations.
6/7
Print Date 03.12.2010 MSDS_FI
Shell Gadus S2 V220 2
Version 1.0
Effective Date 30.11.2010
ADNR
This material is not classified as dangerous under ADNR regulations.
IMDG
This material is not classified as dangerous under IMDG regulations.
The regulatory information is not intended to be comprehensive. Other regulations may apply to this
material.
R-phrase(s)
Not classified.
R38 Irritating to skin.
R41 Risk of serious damage to eyes.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
MSDS Revisions : A vertical bar (|) in the left margin indicates an amendment
from the previous version.
MSDS Regulation : Regulation 1907/2006/EC
MSDS Distribution : The information in this document should be made available to
all who may handle the product.
Disclaimer : This information is based on our current knowledge and is
intended to describe the product for the purposes of health,
safety and environmental requirements only. It should not
therefore be construed as guaranteeing any specific property
of the product.
7/7
Print Date 03.12.2010 MSDS_FI
Factory filled oils, lubricants and coolants for underground rigs
Normal conditions
Polyamideimide S S S
2500
Acetal S U U
2000
Phenolic S S Su
1500
Epoxy resin S S S
1000
S: Suitable
500
Su: Suitable with some exceptions
0
U: unsuitable -20 -10 0 10 20 30 40 50
Temperature (C)
Us: Unsuitable with some exceptions
2 www.honeywell.com
Lubricants Leak detection to high-temperature sources (such as
Genetron® 134a is being used with Use leak detectors for pinpointing leaks welding, brazing and open flames) until
polyalkylene glycol (PAG) and with polyol or for monitoring an entire room on a they have been thoroughly cleaned and
ester lubricants. Most automotive original continual basis. Leak detection is found free of vapours or liquid. Cylinders
equipment manufacturers have chosen important for refrigerant conservation, must never be exposed to welding,
specific PAG lubricants for their systems. equipment protection and performance, brazing or open flames. Exposure to high
For non-automotive applications, most reduction of emission and protection of temperatures can cause fire, explosion
compressor manufacturers are those coming in contact with the system. and decomposition of Genetron® 134a.
recommending specific polyol ester Never use air to perform leak detection. This may result in the formation of toxic
lubricants. Users should check with the or corrosive compounds.
equipment manufacturer for the
recommended lubricants for their system. Storage and handling When possible, maintenance or cleaning
Bulk and cylinder of equipment should be performed
Genetron® 134a cylinders must be clearly without entering the vessel. If a tank or
Safety marked and kept in a cool, dry and any confined space must be entered,
Honeywell recommends reading the properly ventilated storage area away then formal confined space entry
Material Safety Data Sheet (MSDS) from heat, flames, corrosive chemicals, procedures must be followed. These
before using Genetron® 134a. fumes, explosives — and be otherwise procedures require that a fully qualified
protected from damage. Under no work team be used and a confined
Toxicity circumstances should an empty cylinder space entry form be completed and
Genetron 134a can be safely used in
®
be refilled with anything other than virgin placed at the job site.
all of its intended applications, based on product. Once empty, properly close the
data developed by the Program for cylinder valve and replace the valve cap.
Alternative Fluorocarbon Toxicity Testing Return empty cylinders to your Honeywell
(PAFT 1). distributor.
www.honeywell.com 3
Available literature Pressure-Enthalpy Diagram
Honeywell has a wide range of literature
available on topics including: retrofitting Genetron® 134a-SI
procedures, product specifications and
10 115 130
product descriptions.
g-K
J/k
180
Please ask for Honeywell’s software
.70 k
T=-20°C -5 10 25 40 50 70 85 100 250
185
py= 1
169
package containing Refrigerant Properties,
Entro
0
114
19
Cycle Analysis and Pipe Sizing. 77.0
5
19
52.0
200
All literature and information can be found at:
35.0
www.honeywellrefrigerants.com 1
5
24.0
20
Pressure, MPa
16.0
0
21
11.0
7.0
3
kg/m
Density= 5.0
0.1
0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
0.01
100 150 200 250 300 350 400 450 500 550
Enthalpy, kJ/kg
Disclaimer
Although all statements and information contained herein are believed to be accurate and reliable, they are presented without guarantee
or warranty of any kind, express or implied. Information provided herein does not relieve the user from the responsibility of carrying out
its own tests and experiments, and the user assumes all risks and liability for use of the information and results obtained. Statements or
suggestions concerning the use of materials and processes are made without representation or warranty that any such use is free of patent
infringement and are not recommendations to infringe any patent. The user should not assume that all toxicity data and safety measures
are indicated herein or that other measures may not be required.
Disclaimer
Although all statements and information contained herein are believed to be accurate and reliable, they are presented without guar-
antee or warranty of any kind, express or implied. Information provided herein does not relieve the user from the responsibility of car-
rying out its own tests and experiments, and the user assumes all risks and liability for use of the information and results obtained.
Statements or suggestions concerning the use of materials and processes are made without representation or warranty that any
such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume that all
toxicity data and safety measures are indicated herein or that other measures may not be required.
Honeywell Chemicals
Honeywell Chemicals
Northern & Central Europe
Haasrode Research Park,
Grauwmeer 1
B-3001 Heverlee (Leuven)
Belgium
Tel: +32 16-391 278
Fax: +32 16-391 277
Honeywell Chemicals
Southern Europe, Middle East & Africa
Viale A. De Gasperi 19,
I-20020 Lainate MI
Italia
SF-UK-HRE 1005-1
Tel: +39 02-9379 6777
October 2005
Fax: +39 02-9379 6761 © 2005 Honeywell International Inc.
www.honeywell.com
SAFETY DATA SHEET
according to Regulation (EU) No. 1907/2006
Product information
Trade name : HFC-134a, Genetron® 134a
Company/Undertaking Identification
Company : Honeywell Fluorine Products Europe B.V.
Laarderhoogtweg 18
1101 EA Amsterdam
Telephone : (31) 020 5656911
Telefax : (31) 020 5656600
Emergency telephone : (32) 14584545
For further information, : [email protected]
please contact:
2. HAZARDS IDENTIFICATION
See Section 11 for more detailed information on health effects and symptoms.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical characterization
Hazardous components
Chemical Name CAS-No. EC-No. Index-No. Classification Concentration
[%]
Norflurane 811-97-2 212-377-0 <= 100
Page 1 / 6
SAFETY DATA SHEET
according to Regulation (EU) No. 1907/2006
Notes to physician
Treatment : Do not give adrenaline or similar drugs.
See Section 11 for more detailed information on health effects and symptoms.
5. FIRE-FIGHTING MEASURES
Handling
Advice on safe handling : Open drum carefully as content may be under pressure.
The product should only be used in areas from which all naked
Page 2 / 6
SAFETY DATA SHEET
according to Regulation (EU) No. 1907/2006
Storage
Further information on : Store in original container.
storage conditions Keep away from direct sunlight.
Keep containers tightly closed in a cool, well-ventilated place.
Appearance
Form : Liquefied gas
Page 3 / 6
SAFETY DATA SHEET
according to Regulation (EU) No. 1907/2006
Colour : colourless
Odour : weak
Safety data
Melting point/range : -101 °C
Conditions to avoid : Heating will cause pressure rise with risk of bursting
Pressurized container. Protect from sunlight and do not expose
to temperatures exceeding 50 °C.
Do not pierce or burn, even after use. Do not spray on a naked
flame or any incandescent material.
Page 4 / 6
SAFETY DATA SHEET
according to Regulation (EU) No. 1907/2006
ADR
UN Number : 3159
Description of the goods : 1,1,1,2-TETRAFLUOROETHANE
Class : 2
Classification Code : 2A
Hazard identification No : 20
Hazard Label : 2.2
IATA
UN Number : 3159
Description of the goods : 1,1,1,2-Tetrafluoroethane
Class : 2.2
Hazard Label : 2.2
Packing instruction (cargo : 200
Page 5 / 6
SAFETY DATA SHEET
according to Regulation (EU) No. 1907/2006
aircraft)
Packing instruction : 200
(passenger aircraft)
IMDG
UN Number : 3159
Description of the goods : 1,1,1,2-TETRAFLUOROETHANE
Class : 2.2
Hazard Label : 2.2
EmS Number : F-C
Marine pollutant : no
RID
UN Number : 3159
Description of the goods : 1,1,1,2-TETRAFLUOROETHANE
Class : 2
Classification Code : 2A
Hazard identification No : 20
Hazard Label : 2.2
Further information
The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is not
to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text. Final determination of suitability of any
material is the sole responsibility of the user.
This information should not constitute a guarantee for any specific product properties.
Page 6 / 6
Factory filled oils, lubricants and coolants for underground rigs
Normal conditions