GroupTheory VV

Group Theory
First Term 2001 Office Hours:

D. D. Vvedensky ([email protected]) Tu 2-3, Fr 11-12 (Blackett 807)
1. Introduction
a. Symmetry in physics
b. Discrete and continuous symmetries
c. Symmetry in quantum mechanics
2. Mathematical Background for Discrete Groups
a. Groups
b. Subgroups
c. Cosets
d. Conjugacy classes
3. Representations of Groups
a. Reducible and irreducible representations
b. Schur’s lemmas and the Great Orthogonality Theorem
c. Character tables
d. Direct products and their decomposition
4. Physical Applications of Discrete Groups
a. The group of the Hamiltonian
b. Eigenfunctions and irreducible representations
c. Bloch’s theorem
d. Selection rules
5. Continuous Groups, Lie Groups, and Lie Algebras
a. Linear transformation groups
b. Infinitesimal generators
c. Algebra of infinitesimal generators
6. Irreducible Representations of SO(2) and SO(3)
a. Orthogonality relations and the density function
b. Basis functions for irreducible representations of SO(2)
c. Spherical Harmonics and characters for SO(3)
7. Unitary Groups
a. Unitary groups and particle physics
b. Basis states for SU(N)
c. Multiparticle states and direct products
d. Young tableaux
Recommended Books
Basic course material:
H.F. Jones, Groups, Representations and Physics (Adam Hilger, Bristol, 1998)
M. Tinkham, Group Theory and Quantum Mechanics (McGraw–Hill, 1964)
Related and advanced treatments:
R. Hermann, Lie Groups for Physicists (Benjamin, 1966)
D.B. Lichtenberg, Unitary Symmetry and Elementary Particles (Academic, 1978)
Chapter 1
Introduction
As far as I can see, all a priori statements in physics have their origin
in symmetry.
—Hermann Weyl1
1.1 Symmetry in Physics

Symmetry is a fundamental human concern, as evidenced by its pres-
ence in the artifacts of virtually all cultures. Symmetric objects are
aesthetically appealing to the human mind and, in fact, the Greek
work symmetros was meant originally to convey the notion of “well-
proportioned” or “harmonious.” This fascination with symmetry first
found its rational expression around 400 B.C. in the Platonic solids and
continues to this day unabated in many branches of science.
1.1.1 What is a Symmetry?

An object is said to be symmetric, or to have a symmetry, if there is
a transformation, such as a rotation or reflection, whereby the object
looks the same after the transformation as it did before the transforma-
tion. In Fig. 1.3, we show an equilateral triangle, a square, and a circle.
The triangle is indistinguishable after rotations of 13 π and 23 π around
its geometric center, or symmetry axis. The square is indistinguishable
1
In Symmetry (Princeton University Press, 1952)
1
2 Introduction
after rotations of 12 π, π, and 32 π, and the circle is indistinguishable after

all rotations around their symmetry axes. These transformations are
said to be symmetry transformations of the corresponding object, which
are said to be invariant under such transformations. The more symme-
try transformations that an object admits, the more “symmetric” it is
said to be. One this basis, the circle is “more symmetric” than the
square which, in turn, is more symmetric than the triangle. Another
property of the symmetry transformations of the objects in Fig. 1.3
that is central to this course is that those for the triangle and square
are discrete, i.e., the rotation angles have only discrete values, while
those for the circle are continuous.
(a) (b) (c)
Figure 1.1: An equilateral triangle (a), square (b) and circle (c). These ob-
jects are invariant to particular rotations about axes that are perpendicular
to their plane and pass through their geometric centers (indicated by dots).
1.1.2 Symmetry in Physical Laws

In the physical sciences, symmetry is of fundamental because there are
transformations which leave the laws of physics invariant. Such trans-
formations involve changing the variables within a physical law such
that the equations describing the law retain their form when expressed
in terms of the new variables. The relationship between symmetry
and physical laws began with Newton, whose equations of motion were
found to be the same in different frames of reference related by Galilean
transformations. Symmetry was also the guiding principle that en-
abled Lorentz and Poincaré to derive the transformations, now known
as Lorentz transformations, which leave Maxwell’s equations invari-
ant. The incompatibility between the Lorentz invariance of Maxwell’s
Introduction 3
equations and the Galilean invariance of Newtonian mechanics was, of

course, resolved by Einstein’s special theory of relativity.
As an example of a symmetry in a physical law, consider the prop-
agation of an impulse at the speed of light c. This is governed by the
wave equation, which is obtained from Maxwell’s equations:
1 ∂2u ∂ 2u ∂2u ∂ 2u
= + + . (1.1)
c2 ∂t2 ∂x2 ∂y 2 ∂z 2
The Lorentz transformation of space-time coordinates corresponding to
a velocity v = (v, 0, 0) is
µ ¶
v
x0 = γ(x − vt), y 0 = y, z 0 = z, t0 = γ t − x , (1.2)
c2
where γ = (1−v 2 /c2 )−1/2 . When expressed in terms of the transformed
coordinates (x0 , y 0 , z 0 , t0 ), the wave equation (1.1) is found to retain its
form under this transformation:
1 ∂ 2 u0 ∂ 2 u 0 ∂ 2 u0 ∂ 2 u 0
= + 02 + 02 . (1.3)
c2 ∂t02 ∂x02 ∂y ∂z
This implies that the wave propagates in the same way with the same
velocity in two inertial frames that are in uniform motion with respect
to one another. The Lorentz transformation is thus a symmetry trans-
formation of the wave equation (1.1) and this equation is said to be
covariant with respect to these transformations. In general, symmetry
transformations of physical laws involve the space-time coordinates,
which are sometimes called geometrical symmetries, and/or internal co-
ordinates, such as spin, which are called internal symmetries.
1.1.3 Noether’s Theorem

Identifying appropriate symmetry transformations is one of the central
themes of modern physics since their mathematical expression affects
the structure and predictions of physical theories. Work by both math-
ematicians and physicists, culminating with Emmy Noether, led to the
demonstration that there was a deep relationship between symmetry
and conservation laws. This is now known as Noether’s Theorem:
4 Introduction
Noether’s Theorem. The covariance of the equations of motion with

respect to a continuous transformation with n parameters implies the
existence of n quantities, or constants of motion, i.e., conservation laws.
In classical mechanics, the conservation of linear momentum results

from the translational covariance of Newton’s equations of motion, i.e.,
covariance with respect to transformations of the form r 0 = r + a, for
any vector a. The conservation of angular momentum similarly results
from rotational covariance, i.e., covariance with respect rotations in
space: r 0 = Rr, where R is a 3 × 3 rotation matrix. Finally, the con-
servation of energy results from the covariance of Newton’s equations
to translations in time, i.e., transformations of the form t0 = t + τ .
1.1.4 Symmetry and Quantum Mechanics

The advent of quantum mechanics and later quantum field theory fos-
tered entirely new avenues for investigating the consequences of sym-
metry. London and Weyl introduced a type of transformation known as
a gauge transformation into quantum theory, with total electric charge
as the conserved quantity. In the early 1960s, Gell–Mann and Ne’eman
proposed the unitary symmetry SU(3) for the strong interactions. This
led to the proposal by Gell–Mann and Zweig of a new, deeper, level
of quanta, “quarks,” to account for this symmetry. Heisenberg, Gold-
stone and Nambu suggested that the ground state (i.e., the vacuum)
of relativistic quantum field theory may not have the full global sym-
metry of the Hamiltonian, and that massless excitations (Goldstone
bosons) accompany this “spontaneous symmetry breaking.” Higgs and
others found that for spontaneously broken gauge symmetries there are
no Goldstone bosons, but instead massive vector mesons. This is now
known as the Higgs phenomenon and its verification verification has
been the subject of extensive experimental effort.
Another aspect of symmetry, also due to the quantum mechanical
nature of matter, arises from the arrangement of atoms in molecules
and solids. The symmetry of atomic arrangements, whether in a sim-
ple diatomic molecule or a complex crystalline material such as a high-
temperature superconductor, affects many aspects of their electronic
Introduction 5
and vibrational properties and especially their response to external

thermal, mechanical, and electromagnetic perturbations. The trans-
formation properties of wavefunctions in quantum mechanics are an
example of what is known as Representation Theory, which was devel-
oped by the mathematicians Frobenius and Schur near the turn of the
20th century. This inspired a huge effort by physicists and chemists
to determine the physical consequences of the symmetries of wavefunc-
tions which continues to this day. Notable examples include Bloch’s
work on wavefunctions in periodic potentials, which forms the basis of
the quantum theory of solids, Pauling’s work on the chemical interpre-
tation orbital symmetries, and Woodward and Hoffman’s work on how
the conservation of orbital symmetry determines the course of chemical
reactions. Recent scientific advances that highlight the prominent role
that symmetry maintains in condensed-matter physics is the discov-
ery of quasicrystals, which have rotational symmetries (e.g., fivefold, as
shown in Fig. 1.2) which are incompatible with the translational sym-
metry of ordinary crystals and are thus sometimes called aperiodic, and
the C60 form of carbon, known as “Buckminsterfullerene,” or “Buck-
yballs”, a name derived from its resemblance to structures (geodesic
domes) proposed by R. Buckminster Fuller as an alternative to conven-
tional architecture.
Figure 1.2: A section of a Penrose tile, which has a fivefold rotational

symmetry, but no translational symmetry. This two-dimensional structure
shares a number of features with quasicrystals.
6 Introduction
1.2 Examples from Quantum Mechanics

1.2.1 One-Dimensional Systems
To appreciate how symmetry enters into the description of quantum me-
chanical systems, we consider the time-independent Schrödinger equa-
tion for the one-dimensional motion of a particle of mass m bound by
a potential V (x):
· ¸
h̄2 d2
− + V (x) ϕ(x) = Eϕ(x) , (1.4)
2m dx2
where h̄ = h/2π, h is Planck’s constant, ϕ is the wavefunction, and E
is the energy eigenvalue. By writing this equation as Hϕ = Eϕ, we
identify the coordinate representation of the Hamiltonian operator as
h̄2 d2
H=− + V (x) . (1.5)
2m dx2
In the following discussion, we will utilize the fact that the energy eigen-
values of one-dimensional quantum mechanical problems such as that
in (1.4) are nondegenerate, i.e., each energy eigenvalue is associated
with one and only one eigenfunction.2
Suppose that the potential in (1.4) is an even function of x. The
mathematical expression of this fact is the invariance of this potential
under the inversion transformation x → −x:
V (−x) = V (x) . (1.6)
Examples of such potentials are the symmetric square well and the
harmonic oscillator (Fig. 1.3), but the particular form of the potential
is unimportant for this discussion. The kinetic energy term in (1.4) is
also invariant under the same inversion transformation as the potential,
since
d2 d2
= (1.7)
d(−x)2 dx2
2
This follows directly from the fact that this equation, together with appropri-
ate boundary conditions, constitute a Sturm–Liouville problem. Other well-known
properties of solutions of Schrödinger’s equation (real eigenvalues, discrete eigen-
values for bound states, and orthogonality of eigenfunctions) also follow from the
Sturm–Liouville theory.
Introduction 7
Figure 1.3: The first four eigenfunctions of the Schrödinger equation (1.4)
for an infinite square-well potential, V (x) = 0 for |x| ≤ L and V (x) → ∞
for |x| > L (left), and a harmonic oscillator potential, V (x) = 12 kx2 , where
k is the spring constant of the oscillator (right). The abscissa is the spatial
position x and the ordinate is the energy E, with the vertical displacement of
each eigenfunction given by its energy. The origins are indicated by broken
lines.
Thus, the Hamiltonian operator in (1.5) is itself invariant under inver-

sion, i.e., inversion is a symmetry transformation of this Hamiltonian.
We now use this property of H to change variables from x to −x in
(1.4) and thereby obtain the Schrödinger equation for ϕ(−x):
· ¸
h̄2 d2
− + V (x) ϕ(−x) = Eϕ(−x) (1.8)
2m dx2
Since E is nondegenerate, there can be only one eigenfunction associ-
ated with this eigenvalue, so the ϕ(−x) cannot be linearly independent
of ϕ(x). The only possibility is that ϕ(−x) is proportional to ϕ(x):
ϕ(−x) = Aϕ(x) (1.9)
where A is a constant. Changing x to −x in this equation,
ϕ(x) = Aϕ(−x) (1.10)
and then using (1.9) to replace ϕ(−x), yields
ϕ(x) = A2 ϕ(x) (1.11)
8 Introduction
This requires that A2 = 1, i.e., A = 1 or A = −1. Combining this result

with (1.9) shows that the eigenfunctions ϕ of (1.4) must be either even
ϕ(−x) = ϕ(x) (1.12)
or odd
ϕ(−x) = −ϕ(x) (1.13)
under inversion. As we know from the solutions of Schrödinger’s equa-
tion for square-well potentials and the harmonic oscillator (Fig. 1.3),
both even and odd eigenfunctions are indeed obtained. Thus, not all
eigenfunctions have the symmetry of the Hamiltonian, although the
ground state usually does.3 Nevertheless, the symmetry (1.6) does pro-
vide a classification of the eigenfunctions according to their parity under
inversion. This is a completely general result which forms one of the
central themes of this course.
1.2.2 Symmetries and Quantum Numbers

The example discussed in the preceding section showed how symmetry
enters explicitly into the solution of Schrödinger’s equation. In fact, we
can build on our discussion in Sec. 1.1.2, and especially Noether’s theo-
rem, to establish a general relationship between continuous symmetries
and quantum numbers.
Consider the time-dependent Schrödinger equation for a free particle
of mass m in one dimension:
∂ϕ h̄2 ∂ 2 ϕ
ih̄ =− . (1.14)
∂t 2m ∂x2
The solutions to this equation are plane waves:
ϕ(x, t) = ei(kx−ωt) , (1.15)
where k and ω are related to the momentum and energy by p = h̄k

and E = h̄ω. In other words, the quantum numbers k and ω of the
3
A notable exception to this is the phenomenon of spontaneous symmetry-
breaking discussed in Sec. 1.1, where the symmetry of the equations of motion
and the boundary conditions is not present in the observed solution for the ground
state.
Introduction 9
solutions to Eq. (1.14) correspond to the momentum and energy which,

because of the time- and space-translational covariance of this equation,
correspond to conserved quantities. Thus, quantum numbers are asso-
ciated with the symmetries of the system. Similarly, for systems with
rotational symmetry, such the hydrogen atom or, indeed, any atom,
the appropriate quantum numbers are the energy and the angular mo-
mentum, the latter producing two quantum numbers, as required by
Noether’s theorem, because the transformations have two degrees of
freedom.
1.2.3 Matrix Elements and Selection Rules

One of the most important uses of symmetry is to identify the matrix
elements of an operator which are required to vanish. Continuing with
the example in the preceding section, we consider the matrix elements
of an operator H0 whose position representation H0 (x) has a definite
parity. The matrix elements of this operator are given by
Z
0
Hij = ϕi (x)H0 (x)ϕj (x) dx (1.16)
where the range of integration is symmetric about the origin. If H0

has even parity, i.e., if H0 (−x) = H0 (x), as in (1.6), then these matrix
elements are nonvanishing only if ϕi (x) and ϕj (x) are both even or both
odd, since only in these cases is the integrand an even function of x.
This is called a selection rule, since the symmetry of H0 (x) determines,
or selects, which matrix elements are nonvanishing.
Suppose now that H0 (x) has odd parity, i.e., H0 (−x) = −H0 (x).
The matrix elements in (1.16) now vanishes if ϕi (x) and ϕj (x) are
both even or both odd, since these choices render the integrand an
odd function of x. In other words, the selection rule now states that
only eigenfunctions of opposite parity are coupled by such an operator.
Notice, however, that the use of symmetry only identifies which matrix
elements must vanish; it provides no information about the magnitude
of the nonvanishing matrix elements.
Suppose that
H0 (x) = Ax (1.17)
10 Introduction
where A is a constant, i.e., H0 (x) is proportional to the coordinate x.

Such operators arise in the quantum theory of transitions induced by
an electromagnetic field.4 H0 (x) clearly has odd parity, so the matrix
elements (1.16) are nonvanishing only if ϕi (x) and ϕj (x) have opposite
parity. But, if
h̄2 d2
H0 (x) = − (1.18)
2m dx2
which is the coordinate representation of the kinetic energy operator,
then the matrix elements (1.16) are nonvanishing only if ϕi (x) and
ϕj (x) have the same parity.
Selection rules are especially useful if there are broken symmetries.
For example, the Hamiltonian of an atom, which is the sum of the
kinetic energies of the electrons and their Coulomb potentials, is in-
variant under all rotations. But when an atom is placed in an electric
or magnetic field, the Hamiltonian acquires an additional term which
is not invariant under all rotations, since the field now defines a pre-
ferred direction. These are the Stark and Zeeman effects, respectively.
A similar situation is encountered in quantum field theory when, be-
ginning with a Lagrangian that is invariant under certain symmetry
operations, a term is added which does not have this invariance. If
the symmetry-breaking terms in these cases are small, then selection
rules enter into the perturbative calculation around the solutions of the
symmetric theory.
1.3 Summary
The notion of symmetry implicit in all of the examples cited in this
chapter is endowed with the algebraic structure of “groups.” This is a
topic in mathematics that had its beginnings as a formal subject only
in the late 19th century. For some time, the only group that was know
and whose properties were studied were permutation groups. Cauchy
played a major part in developing the theory of permutations, but it
was the English mathematician Cayley who first formulated the notion
of an abstract group and used this to identify matrices and quaternions
4
E. Merzbacher, Quantum Mechanics 2nd edn. (Wiley, New York, 1970), Ch. 18.
Introduction 11
as groups. In a later paper, Cayley showed that every finite group could
be represented in terms of permutations, a result that we will prove in
this course. The fact that geometric transformations, as discussed in
this chapter, and permutations, share the same algebraic structure is
part of the richness of the subject and is rooted in its history as an
adjunct to the study of algebraic solutions of equations. In the next
chapter, we discuss the basic properties of groups that form the basis
of this course.
12 Introduction
Chapter 2
Elements of Abstract Group

Theory
Mathematics is a game played according to certain simple rules with

meaningless marks on paper.
—David Hilbert1
The importance of symmetry in physics, and for quantum mechanics

in particular, was discussed in the preceding chapter. In this chapter,
we begin our development of the algebraic structure which enables us
to formalize what we mean by “symmetry” by introducing the notion
of a group and some related concepts. In the following chapters we will
explore the consequences of this algebraic structure for applications to
physics.
2.1 Groups: Definitions and Examples

The motivation for introducing an algebraic structure to describe sym-
metry in physical problems is based on transformations. But the def-
inition of a group is based on a much more abstract notion of what a
“transformation” entails. Accordingly, we first set out the conditions
1
As quoted in, N. Rose, Mathematical Maxims and Minims (Rome Press,
Raleigh, North Carolina, 1988).
13
14 Elements of Abstract Group Theory
that an abstract group must satisfy and then consider both abstract
and concrete examples.
Definition. A group G is a set of elements {a, b, c, . . .} together with

a binary composition law, called multiplication, which has the following
properties:
1. Closure. The composition of any two elements a and b in G, called
the product and written ab, is itself an element c of G: ab = c.
2. Associativity. The composition law is associative, i.e., for any

elements a, b, and c in G, (ab)c = a(bc).
3. Identity. There exists an element, called the unit or identity and

denoted by e, such that ae = ea = a for every element a in G.
4. Inverses. Every element a in G has an inverse, denoted by a−1 ,

which is also in G, such that a−1 a = aa−1 = e.
The closure property ensures that the binary composition law does
not generate any elements outside of G. Associativity implies that
the computation of an n-fold product does not depend on how the
elements are grouped together.2 For example, the product abc is un-
ambiguous because the two interpretations allowed by the existence of
a binary composition rule, (ab)c and a(bc), are equal. As will be shown
in Sec. 2.3, the left and right identities are equal and unique, as are
the left and right inverses of each element. Thus we can replace the
existence of an identity and inverses in the definition of a group with
the more “minimal” statements:
3.0 Identity. There exists a unique element, called the unit or identity
and denoted by e, such that ae = a for every element a in G.
4.0 Inverses. Every element a in G has a unique inverse, denoted by

a−1 , which is also in G, such that a−1 a = e.
2
In abstract algebra (the theory of calculation), binary composition can be asso-
ciative or non-associative. The most important non-associative algebras in physics
are Lie algebras, which will be discussed later in this course.
Elements of Abstract Group Theory 15
The terms “multiplication,” “product,” and “unit” used in this def-

inition are not meant to imply that the composition law corresponds to
ordinary multiplication. The multiplication of two elements is only an
abstract rule for combining an ordered pair of two group elements to
obtain a third group element. The difference from ordinary multiplica-
tion becomes even more apparent from the fact that the composition
law need not be commutative, i.e., the product ab need not equal ba for
distinct group elements a and b. If a group does have a commutative
composition law, it is said to be commutative or Abelian.
Despite the somewhat abstract tone of these comments, a moment’s
reflection leads to the realization that the structure of groups is ideally
suited to the description of symmetry in physical systems. The group
elements often correspond to coordinate transformations of either ge-
ometrical objects or of equations of motion, with the composition law
corresponding to matrix multiplication or the usual composition law
of functions,3 so the associativity property is guaranteed.4 If two op-
erations each correspond to symmetry operations, then their product
clearly must as well. The identity corresponds to performing no trans-
formation at all and the inverse of each transformation corresponds
to performing the transformation in reverse, which must exist for the
transformation to be well-defined (cf. Example 2.4).
Example 2.1. Consider the set of integers,
. . . , −3, −2, −1, 0, 1, 2, 3, . . .
with the composition rule being ordinary addition. The sum of any two
integers is an integer, thus ensuring closure, addition is an associative
operation, 0 is the identity, and the inverse of n is −n, which is clearly
an integer. Thus, the integers form a group under addition. This group
is denoted by Z (derived from the German word Zahlen for integers).
3
For two functions f (x) and g(x), the application of f , followed by the application
of g is g[f (x)], and the application of g followed by the application of f is f [g(x)].
4
The associativity of linear operations in general, and matrices in particular,
is discussed by Wigner in Group Theory (Academic, New York, 1959), along with
other group properties.
Since the order in which two integers are added is immaterial, Z is an

Abelian group.
Example 2.2. The importance of the composition law for determining

whether a set of elements forms a group can be seen by again considering
the integers, but now with ordinary multiplication as the composition
rule. The product of any two integers is again an integer, multiplication
is associative, the unit is 1, but the inverse of n is 1/n, which is not an
integer if n 6= 1. Hence, the integers with ordinary multiplication do
not form a group.
Example 2.3. Consider the elements {1, −1} under ordinary multipli-
cation. This set is clearly closed under multiplication and associativity
is manifestly satisfied. The unit element is 1 and each element is its
own inverse. Hence, the set {1, −1} is a two-element group under mul-
tiplication.
Example 2.4. Consider the set of 2×2 matrices with real entries
Ã !
a b
, (2.1)
c d
such that the determinant, ad − bc, is non-zero. The composition law
is the usual rule for matrix multiplication:
Ã !Ã ! Ã !
a1 b1 a2 b2 a1 a2 + b 1 c 2 a1 b2 + b1 d2
= .
c1 d1 c2 d2 c1 a2 + d1 c2 c1 b2 + d1 d2
To determine if this set of matrices forms a group, we must first show
that the product of two matrices with non-zero determinant is also a
matrix with non-zero determinant. This follows from that fact that
for any pair of 2×2 matrices A and B, their determinants, denoted
by det(A) and det(B), satisfy det(AB) = (detA)(detB). Associativity
can be verified with a straightforward, but laborious, calculation. The
identity is
Ã !
1 0
0 1
and the inverse of (2.1) is

Ã !
1 d −b
,
ad − bc −c a
which explains the requirement that ad − bc 6= 0. This group is denoted
by GL(2,R), for general linear group of 2×2 matrices with real entries.
Note that the elements of this group form a continuous set, so GL(2,R)
is a continuous group.
2.2 Permutation Groups

A permutation of n objects is a rearrangement of those objects. When
combined with the usual rule for function composition for successive
permutations (see below), these permutations are endowed with the
structure of a group, which is denoted by Sn . At one time, permuta-
tion groups were the only groups studied by mathematicians and they
maintain a special status in the subject through Cayley’s theorem, which
establishes a relationship between Sn and every group with n elements.
In this section, we will examine the structure of S3 , both as an abstract
group and as the symmetry group of an equilateral triangle.
The group S3 is the set of all permutations of three distinguishable
objects, where each element corresponds to a particular permutation
of the three objects from a given reference order. Since the first object
can be put into any one of three positions, the second object into either
of two positions, and the last object only into the remaining position,
there are 3 × 2 × 1 = 6 elements in the set. These are listed below:
Ã ! Ã ! Ã !
1 2 3 1 2 3 1 2 3
e= a= b=
1 2 3 2 1 3 1 3 2
Ã ! Ã ! Ã !
1 2 3 1 2 3 1 2 3
c= d= f=
3 2 1 3 1 2 2 3 1
In this notation, the top line represents the initial, or reference, order
of the objects and the bottom line represents the effect of the per-
mutation. The composition law corresponds to performing successive
permutations and is carried out by rearranging the objects according to

the first permutation and then using this as the reference order to rear-
range the objects according to the second permutation. As an example,
consider the product ad, where we will use the convention that opera-
tions are performed from right to left, i.e., permutation d is performed
first, followed by permutation a. Element d permutes the reference
order (1, 2, 3) into (3, 1, 2). Element a then permutes this by putting
the first object in the second position, the second object into the first
position, and leaves the third object in position three, i.e.,
Ã ! Ã !
1 2 3 3 1 2
a= = .
2 1 3 1 3 2
Notice that it is only the permutation of the distinct objects, not their
labelling, which is important for specifying the permutation. Hence,
Ã !
1 2 3
ad = = b,
1 3 2
An analogous procedure shows that
Ã !Ã ! Ã !
2 1 3 1 2 3 1 2 3
da = = = c,
3 2 1 2 1 3 3 2 1
which shows that the composition law is not commutative, so S3 is a
non-Abelian group.
A geometric realization of S3 can be established by considering the
symmetry transformations of an equilateral triangle (Fig. 2.1). The
elements a, b, and c correspond to reflections through lines which in-
tersect the vertices at 3, 1, and 2, respectively, and d and f correspond
to clockwise rotations of this triangle by 23 π and 43 π radians, respec-
tively. The effects of each of these transformations on the positions
of the vertices of the triangle is identical with the corresponding ele-
ment of S3 . Thus, there is a one-to-one correspondence between these
transformations and the elements of S3 . Moreover, this correspondence
is preserved by the composition laws in the two groups. Consider for
example, the products ad and da calculated above for S3 . For the equi-
lateral triangle, the product ad corresponds to a rotation followed by
2 1 3
1 3 2 3 1 2
e a b
2 1 3
3 1 3 2 2 1
c d f
Figure 2.1: The symmetry transformations of an equilateral triangle labelled

by the corresponding elements of S3 . The lines in the diagram corresponding
to the identity are lines through which reflections of transformations a, b and
c are taken. The transformations d and f are rotations.
a reflection. Thus, beginning with the standard order shown for the
identity the successive application of these transformations is shown
below:
2 1 3
d a
1 3 3 2 1 2
By comparing with Fig. 2.1, we see that the result of these transfor-
mations is equivalent to the transformation b. Similarly, one can show
that da = c and, in fact, that all the products in S3 are identical to
those of the symmetry transformations of the equilateral triangle. Two
such groups that have the same algebraic structure are said to be iso-
morphic to one another and are, to all intents and purposes, identical.
This highlights the fact that it is the algebraic structure of the group
which is important, not any particular realization of the group. Further

discussion of this point will be taken up in the next chapter.
2.3 Elementary Properties of Groups

The examples in the preceding section showed that all groups are en-
dowed with several general properties. In this section, we deduce some
additional properties which, although evident in particular examples,
can be shown generally to follow from the properties of abstract groups.
Theorem 2.1. (Uniqueness of the identity) The identity element in

a group G is unique.
Proof. Suppose there are two identity elements e and e0 in G. Then,

according to the definition of a group, we must have that
ae = a
and
e0 a = a
for all a in G. Setting a = e0 in the first of these equations and a = e

in the second shows that
e0 = e0 e = e ,
so e = e0 .
This theorem enables us to speak of the identity e of a group. The

notation e is derived from the German word Einheit for unity.
Another property common to all groups is the cancellation of com-
mon factors within equations. This property owes its existence to the
associativity of the group composition rule.
Theorem 2.2. (Cancellation) In a group G, the left and right cancel-

lation laws hold, i.e., ab = ac implies b = c and ba = ca implies b = c.
Proof. Suppose that ab = ac. Let a−1 be an inverse of a. Then, by

left-multiplying by this inverse,
a−1 (ab) = a−1 (ac)
and invoking associativity,
(a−1 a)b = (a−1 a)c ,
we obtain
eb = ec ,
so b = c. Similarly, beginning with ba = ca and right-multiplying by

a−1 shows that b = c in this case also.
Notice that the proof of this theorem does not require the inverse
of a group element to be unique; only the existence of an inverse was
required. In fact, the cancellation theorem can be used to prove that
inverses are, indeed, unique.
Theorem 2.3. (Uniqueness of inverses) For each element a in a

group G, there is a unique element b in G such that ab = ba = e.
Proof. Suppose that there are two inverses b and c of a. Then ab = e

and ac = e. Thus, ab = ac, so by the Cancellation Theorem, b = c.
As in the case of the identity of a group, we may now speak of the

inverse of every element in a group, which we denote by a−1 . As was
discussed in Sec. 2.1, this notation is borrowed from ordinary multipli-
cation, as are most other notations for the group composition rule. For
example, the n-fold product of a group element g with itself is denoted
by g n . Similarly g n g m = g n+m , which conforms to the usual rule of ex-

ponents for real numbers. However, there are some notable exceptions.
For two group elements a and b, the equality of (ab)n and an bn does
not generally hold. As the examples in Sec. 2.1 demonstrated, as long
as this notation is interpreted in the context of the appropriate group
composition rule, no confusion should arise.
2.4 Discrete and Continuous Groups

Groups are divided into two general categories: discrete and continuous.
The basis definitions apply to both types of group, but the discussion
of a number of properties depends sensitively on the discrete or con-
tinuous nature of the group. In this course, we will focus our attention
on discrete groups first, to establish a conceptual base, and consider
continuous groups later in the course.
2.4.1 Finite Groups

One of the most fundamental properties of a group G is number of
elements contained in the group. This is termed the order of G and is
denoted by |G|. The group Z of integers under addition, has infinite
order and the order of S3 , the group of permutations of three objects,
is 6. We will be concerned initially with finite groups which, apart
from their applicability to a range of physical problems, have a number
interesting arithmetic properties.
Finite groups also have properties which are not shared by either
infinite or continuous groups. For example, if an element g of a finite
group G is multiplied by itself enough times, the unit e is eventually re-
covered. Clearly, multiplying any element g by itself a number of times
greater than |G| must eventually lead to a recurrence of the product,
since the number of distinct products is bounded from above by |G|.
To show this explicitly, we denote a recurring product by a and write
a = gp = gq ,
where p = q + n. Then, by using the associativity of the composition

law, g q+n = g q g n = g n g q , so
gp = gq gn = gngq = gq ,
and, from the definition of the identity and its uniqueness, we conclude
that
gn = e .
Thus, the set of elements g, g 2 , g 3 , . . . represents a recurring sequence.

The order of an element g, denoted by |g|, is the smallest value of k
such that g k = e. The period of such an element g is the collection of
elements {e, g, g 2 , . . . , g k−1 }.
Example 2.5. Using S3 as an example, |a| = |b| = |c| = 2 and

|d| = |f | = 3. The corresponding periods are {e, a}, {e, b}, {e, c},
and {e, d, f = d2 }.
Theorem 2.4. (Rearrangement Theorem) If {e, g1 , g2 , . . . , gn } are

the elements of a group G, and if gk is an arbitrary group element,
then the set of elements
Ggk = {egk , g1 gk , g2 gk , . . . , gn gk }
contains each group element once and only once.
Proof. The set Ggk contains |G| elements. Suppose two elements of
Ggk are equal: gi gk = gj gk . By the Cancellation Theorem, we must have
that gi = gj . Hence, each group element appears once and only once in
Ggk , so the sets G and Ggk are identical apart from a rearrangement
of the order of the elements if gk is not the identity.
2.4.2 Multiplication Tables

One application of this theorem is in the representation of the compo-
sition law for a finite group as a multiplication table. Such a table is a
square array with the rows and columns labelled by the elements of the
group and the entries corresponding to the products, i.e., the element
gij in the ith row and jth column is the product of the element gi la-
belling that row and the element gj labelling that column: gij = gi gj .
To see how the construction of multiplication tables proceeds by utiliz-
ing only the abstract group properties, consider the simplest nontrivial
group, that with two distinct elements {e, a}. We clearly must have the
products e2 = e and ea = ae = a. The Rearrangement Theorem then
requires that a2 = e. The multiplication table for this group is shown
below:
e a
e e a
a a e
Note that the entries of this table are symmetric about the main diag-
onal, which implies that this group is Abelian.
Now consider the group with three distinct elements: {e, a, b}. The
only products which we must determine explicitly are ab, ba, a2 , and b2
since all other products involve the unit e. The product ab cannot equal
a or b, since that would imply that either b = e or a = e, respectively.
Thus, ab = e. The Cancellation Theorem then requires that a2 = e,
b2 = a, and ba = e. The multiplication table for this group is shown
below:
e a b
e e a b
a a b e
b b e a
Because the entries of this table are symmetric about the main diagonal,
this group is also Abelian. Our procedure shows that every group
with two or three elements must have the multiplication tables just
calculated, i.e., the algebraic structures of group with two and three
elements are unique! Thus, we can speak of the group with two elements
and the group with three elements. A similar procedure for groups
with four elements {e, a, b, c} yields two distinct multiplication tables
(Problem Set 2). As a final example, the multiplication table for S3 is
shown below:
e a b c d f
e e a b c d f
a a e d f b c
b b f e d c a
c c d f e a b
d d c a b f e
f f b c a e d
As is immediately evident from this table, S3 not Abelian.
2.5 Subgroups and Cosets

If, from a group G, we select a subset H of elements which themselves
form a group under the same composition law, H is said to be a sub-
group of G. According to this definition, the unit element {e} forms a
subgroup of G, and G is a subgroup of itself. These are termed improper
subgroups. The determination of proper subgroups is one of the cen-
tral concerns of group theory. In physical applications, subgroups arise
in the description of symmetry-breaking, where a term is added to a
Hamiltonian or a Lagrangian which lowers the symmetry to a subgroup
of the original symmetry operations.
Example 2.6. The group S3 has a number of proper subgroups: {e, a},
{e, b}, {e, c}, and {e, d, f }. The identification of these subgroups is
most easily carried out by referring to the symmetry operations of an
equilateral triangle (Fig. 2.1).
If H = {e, h1 , h2 , . . . , hr } is a subgroup of a group G, and g is an

element of G, then the set
Hg = {eg, h1 g, h2 g, . . . , hr g}
is a right coset of H. Similarly, the set
gH = {ge, gh1 , gh2 , . . . , ghr }
is a left coset of H. A coset need not be a subgroup; it will be a subgroup
only if g is an element of H.
Theorem 2.5. Two cosets of a subgroup either contain exactly the

same elements or else have no common elements.
Proof. These cosets either have no common elements or have at

least one common element. We will show that if there is a single in
common, then all elements are common to both subgroups. Let Hg1
and Hg2 be two right cosets. If one common element of these cosets is
hi g1 = hj g2 , then
g2 g1−1 = h−1
j hi
so g2 g1−1 is in H. But also contained in H are the elements

Hg2 g1−1 = {eg2 g1−1 , h1 g2 g1−1 , h2 g2 g1−1 , . . . , hr g2 g1−1 }
since, according to the Rearrangement Theorem, each element of H
appears once and only once in this sequence. Therefore, the elements
of Hg1 are identical to those of
(Hg2 g1−1 )g1 = Hg2 (g1−1 g1 ) = Hg2
so these two cosets have only common elements.
Example 2.7. Consider again the group S3 and its subgroup H = {e, a}
(Example 2.6). The right cosets of this subgroup are
{e, a}e = {e, a}, {e, a}a = {a, e}, {e, a}b = {b, d}
{e, a}c = {c, f }, {e, a}d = {d, b}, {e, a}f = {f, c}
We see that there are three distinct right cosets of {e, a},
{e, a}, {b, d}, {c, f }
of which only the first is a subgroup (why?). Similarly, there are three
left cosets of {e, a}:
{e, a}, {c, d}, {b, f }
Notice that the left and right cosets are not the same.
Theorem 2.6 (Lagrange’s theorem). The order of a subgroup H of

a finite group G is a divisor of the order of G, i.e., |H| divides |G|.
Proof. Cosets either have all elements in common or they are dis-
tinct (Theorem 2.5). This fact, combined with the Rearrangement The-
orem, means that every element of the group must appear in exactly
one distinct coset. Thus, since each coset clearly has the same number
of elements, the number of distinct cosets, which is called the index
of the subgroup, multiplied by the number of elements in the coset, is
equal to the order of the group. Hence, since the order of the coset and
the subgroup are equal, the order of the group divided by the order of
the subgroup is equal to the number of distinct cosets, i.e., an integer.
Example 2.8. The subgroup {e, a} of S3 is of order 2 and the subgroup

{e, d, f } is of order 3. Both 2 and 3 are divisors of |S3 | = 6.
Lagrange’s theorem identifies the allowable orders of the subgroups

of a given group. But the converse of Lagrange’s theorem is not gener-
ally valid, i.e., the orders of the subgroups of a group G need not span
the divisors of G.
2.6 The Quotient Group

2.6.1 Conjugacy Classes
Two elements a and b of a group G are said to be conjugate if there is
an element g in the group, called the conjugating element, such that
a = gbg −1 . Conjugation is an example of what is called an equivalence
relation, which is denoted by “≡,” and is defined by three conditions:
1. a ≡ a (reflexive).
2. If a ≡ b, then b ≡ a (symmetric).
3. If a ≡ b and b ≡ c, then a ≡ c (transitive).
To show that conjugacy corresponds to an equivalence relation we
consider each of these conditions in turn. By choosing g = e as the
conjugating element, we have that a = eae−1 = a, so a ≡ a. If a ≡ b,
then a = gbg −1 , which we can rewrite as
g −1 ag = g −1 a(g −1 )−1 = b
so b ≡ a, with g −1 as the conjugating element. Finally, to show tran-
sitivity, the relations a ≡ b and b ≡ c imply that there are elements g1
and g2 such that b = g1 ag1−1 and c = g2 bg2−1 . Hence,
c = g2 bg2−1 = g2 g1 ag1−1 g2−1 = (g2 g1 )a(g2 g1 )−1
so c is conjugate to a with the conjugating element g1 g2 . Thus, conju-
gation fulfills the three conditions of an equivalency class.
One important consequence of equivalence is that it permits the
assembly of classes, i.e., sets of equivalent quantities. In particular,
a conjugacy class is the totality of elements which can be obtained
from a given group element by conjugation. Group elements in the
same conjugacy class have several common properties. For example,
all elements of the same class have the same order. To see this, we
begin with the definition of the order n of an element a as the smallest
integer such that an = e. An arbitrary conjugate b of a is b = gag −1 .
Hence,
bn = (gag −1 )(gag −1 ) · · · (gag −1 ) = gan g −1 = geg −1 = e
| {z }
n factors
so b has the same order as a.
Example 2.9. The group S3 has three classes: {e}, {a, b, c}, and {d, f }.
As we discussed in Example 2.5, the order of a, b, and c is two, and the
order of d and f is 3. The order of the unit element is 1 and is always
in a class by itself. Notice that each class corresponds to a distinct kind
of symmetry operation on an equilateral triangle. The operations a, b,
and c correspond to reflections, while d and f correspond to rotations.
In terms of operations in S3 , the elements d and f correspond to cyclic
permutations of the reference order, e.g., 1 → 2, 2 → 3, and 3 → 1,
while a, b, and c correspond to permutations which are not cyclic.
2.6.2 Self-Conjugate Subgroups

A subgroup H of G is self-conjugate if the elements gHg −1 are identical
with those of H for all elements g of G. The terms invariant subgroup
and normal subgroup are also used. A group with no self-conjugate
proper subgroups is called simple. If gHg −1 = H for all g in G, then
given an element h1 in H, for any a, we can find an element h2 in H such
that ah1 a−1 = h2 , which implies that ah1 = h2 a, or that aH = Ha.
This last equality yields another definition of a self-conjugate subgroup
as one whose left and right cosets are equal. From the definition of self-
conjugacy and of classes, we can furthermore conclude that a subgroup
H of G is self-conjugate if and only if it contains elements of G in
complete classes, i.e., H contains either all or none of the elements of
classes of G.
The cosets of a self-conjugate subgroup are themselves endowed with
a group structure, with multiplication corresponding to an element-by-
element composition of two cosets and discounting duplicate products.
We show first that the multiplication of the elements of two right cosets
of a conjugate subgroup yields another right coset. Let H be a self-
conjugate subgroup of G and consider the two right cosets Ha and Hb.
Then, the multiplication of Ha and Hb produces products of the form
hi ahj b = hi (ahj )b
The product ahj can be written as hk a for some hk in H, since H is

assumed to be self-conjugate. Thus, we have
hi (ahj )b = hi (hk a)b = (hi hk )(ab)
which is clearly an element of a right coset of H.
Example 2.10. Consider the subgroup {e, d, f } of S3 . Right-multiplying

this subgroup by each element of S3 yields the right cosets of this sub-
group:
{e, d, f }e = {e, d, f }, {e, d, f }a = {a, c, b}, {e, d, f }b = {b, a, c}
{e, d, f }c = {c, b, a}, {e, d, f }d = {d, f, e}, {e, d, f }f = {f, e, d}
Similarly, left-multiplying by each element of S3 produces the left cosets

of this subgroup:
e{e, d, f } = {e, d, f }, a{e, d, f } = {a, b, c}, b{e, d, f } = {b, c, a}
c{e, d, f } = {c, a, b}, d{e, d, f } = {d, f, e}, f {e, d, f } = {f, e, d}
Thus, since the right and left cosets of {e, d, f } are the same, these
elements form a self-conjugate subgroup of S3 whose distinct cosets
are {e, d, f } and {a, b, c}. Multiplying these subgroups together and
neglecting duplicate elements yields
{e, d, f }{e, d, f } = {e, d, f }, {e, d, f }{a, b, c} = {a, b, c}
{a, b, c}{e, d, f } = {a, b, c}, {a, b, c}{a, b, c} = {e, d, f }
The quotient group (also called the factor group) of a self-conjugate

subgroup is the collection of cosets, each being considered an element.
The order of the factor group is equal to the index of the self-conjugate
subgroup. With the notation used above, the quotient group is denoted
by G/H.
Example 2.11. The cosets of the self-conjugate subgroup {e, d, f } of

S3 are {e, d, f } and {a, b, c}, so the order of the factor group is two. If
we use the notation
E = {e, d, f }, A = {a, b, c} (2.2)
for the elements of the factor group, we can use the results of Example
2.8 to construct the multiplication table for this group (shown below)
from which see that E is the identity of the factor group, and E and
E A
E E A
A A E
A are their own inverses. Note that this multiplication table has the
identical structure as the two-element group {e, a} discussed in Sec. 2.4.
2.7 Summary
In this chapter, we have covered only the most basic properties of
groups. One of the remarkable aspects of this subject, already evident
in some of the discussion here, is that the four properties that define a
group, have such an enormous implication for the properties of groups,
quite apart from their implications for physical applications, which will
be explored throughout this course. A comprehensive discussion of the
mathematical theory of groups, including many wider issues in both
pure and applied mathematics, may be found in the book by Gallian.5
5
J.A. Gallian, Contemporary Abstract Algebra 4th edn. (Houghton Mifflin,
Boston, 1998).
Chapter 3
Representations of Groups
How can it be that mathematics, being after all a product of human

thought which is independent of experience, is so admirably appropriate
to the objects of reality?
—Albert Einstein
The structure of abstract groups developed in Chapter 2 forms the

basis for the application of group theory to physical problems. Typi-
cally in such applications, the group elements correspond to symmetry
operations which are carried out on spatial coordinates. When these
operations are represented as linear transformations with respect to a
coordinate system, the resulting matrices, together with the usual rule
for matrix multiplication, form a group that is equivalent to the group
of symmetry operations in a sense to be made precise later in this chap-
ter. In essence, these matrices form what is called a representation of
the symmetry group with each element corresponding to a particular
matrix.
For applications to quantum mechanics, as we have seen in Sec-
tion 1.2, the symmetry operations are performed on the Hamiltonian,
whose invariance properties determine the symmetry group. The wave-
functions, which do not all share the symmetry of the Hamiltonian,
will be seen to determine the representations of the symmetry group in
the sense described above. These representations will, in turn, provide
a classification scheme for the eigenfunctions of the Hamiltonian, in
33
34 Representations of Groups
analogous fashion to the identification of even and odd eigenfunctions

in Section 1.2. The strength of the group-theoretic formalism that we
will develop is that this procedure can be carried out in a systematic
fashion for a Hamiltonian having any symmetry without undue com-
putational effort.
In this chapter, we will set out the basic definitions that enable us to
construct a mathematical definition of what we mean by a representa-
tion and discuss the basic types of representation. In the next chapter
we will develop a number of remarkable properties of representations
that lie at the heart of applications of discrete group theory to quantum
mechanics.
3.1 Homomorphisms and Isomorphisms

Consider two finite groups G and G0 with elements {e, a, b, . . .} and
{e0 , a0 , b0 , . . .} and which need not be of the same order. Suppose there
is a mapping φ between the elements of G and G0 which preserves their
composition rules, i.e., if a0 = φ(a) and b0 = φ(b), then
φ(ab) = φ(a)φ(b) = a0 b0
If the order of the two groups is the same, then this mapping is said to
be an isomorphism and the two groups are isomorphic to one another.
This is denoted by G ≈ G0 . If the order of the two groups is not
the same, then the mapping is a homomorphism and the two groups
are said to be homomorphic. Thus, an isomorphism is a one-to-one
correspondence between two groups, while a homomorphism is a many-
to-one correspondence. An isomorphism preserves the structure of the
original group, but a homomorphism causes some of the structure of the
original group to be lost. Both properties are reflected in the behavior
of multiplication tables under these mappings. Homomorphisms and
isomorphisms are not limited to finite groups nor even to groups with
discrete elements.
Example 3.1. We saw in Sec. 2.2 that S3 is isomorphic to the planar

symmetry operations of an equilateral triangle, since there is a one-to-
one correspondence between the elements of the two groups and they
Representations of Groups 35
have the same multiplication table. On the other hand, consider the
correspondence between the elements of S3 and the elements of the
quotient group of S3 discussed in Examples 2.9 and 2.11):
{e, d, f } 7→ {E}, {a, b, c} 7→ {A} (3.1)
i.e. the mapping φ is defined by
φ(e) = E φ(d) = E φ(f ) = E

(3.2)
φ(a) = A φ(b) = A φ(c) = A
This is a homomorphism because three elements of S3 correspond to a

single element of the quotient group. To see that this mapping preserves
multiplication, we rearrange the multiplication table of S3 (Example
2.2) as follows:
e d f a b c
e e d f a b c
d d f e c a b E A
f f e d b c a 7→ E E A
a a b c e d f A A E
b b c a f e d
c c a b d f e
where the mapping of the multiplication table onto the elements {E, A}
is precisely that of a two-element group (cf. Example 2.9). This homo-
morphism clearly causes some of the structure of the original group to
be lost. For example, S3 is non-Abelian group, but the two-element
group is Abelian.
3.2 Representations
A representation of dimension n of an abstract group G is a homomor-
phism or isomorphism between the elements of G and the group of
nonsingular n × n matrices (i.e. n × n matrices with non-zero deter-
minant) with complex entries and with ordinary matrix multiplication
as the composition law (Example 2.4). An isomorphic representation
y
Figure 3.1: The coordinate system used to generate a two-dimensional rep-

resentation of the symmetry group of the equilateral triangle. The origin of
the coordinate system coincides with the geometric center of the triangle.
is called a faithful representation and a homomorphic representation is

called an unfaithful representation.
According to this definition, if elements a and b of G are assigned
matrices D(a) and D(b), then D(a)D(b) = D(ab). The nonsingular
nature of the matrices is required because inverses must be contained
in the set (Example 2.4). Representations can also be comprised of
numbers; the dimensionality of such representations is unity.
Example 3.2. Consider the following matrix representation of S3 based

on the correspondence with planar symmetry operations of an equilat-
eral triangle:
Ã ! Ã √ ! Ã √ !
1 0 1 − 3 1 3
e= , a = 12 √ , b = 12 √
0 1 − 3 −1 3 −1
Ã ! Ã √ ! Ã √ !(3.3)
−1 0 −1 − 3 −1 3
c= , d = 12 √ , f = 12 √
0 1 3 −1 − 3 −1
These matrices were generated by regarding each of the symmetry op-

erations as a linear transformation in the coordinate system shown in
Fig. 3.1. Matrices a, b, and c correspond to reflections, so their deter-
minant is −1, while matrices d and f correspond to rotations, so their
determinant is 1. These matrices form a faithful representation of S3 .
Consider now the following mapping between the elements of S3

and the set {1, −1}:
{e, f } 7→ {1}, {a, b, c} 7→ {−1} (3.4)
This is essentially a mapping between the elements of S3 and the de-

terminant of their matrix representation discussed above. Thus, the
identity matrix e and the rotations d and f have determinants of 1,
while the reflections a, b, and c have determinants of −1. The physical
interpretation of this homomorphism is therefore as a mapping from
the individual elements of S3 to their parity, i.e., whether they change
the orientation of the coordinate system (−1) or not (1).1 Since the
determinant provides less information about a transformation than its
matrix representation, it is clear that some information about the group
structure of S3 is not preserved by this homomorphism.
Finally, we note that the mapping of all elements to unity,
{e, a, b, c, d, f } 7→ 1
is a representation of any group, though clearly an unfaithful one. This

is called the identical representation. In the present case, the identical
representation corresponds to a mapping from the group element to
the absolute value of the determinant. Since all of the transformations
preserve the lengths of vectors, any product of these transformations
does so as well.
Representations of groups are important in quantum mechanics for

several reasons. First, the eigenfunctions of a Hamiltonian will trans-
form under the symmetry operations of that Hamiltonian according to
a particular representation of that group. Second, quantum mechanical
operators are often written in terms of their matrix elements, so it is
convenient to write symmetry operations in the same kind of matrix
representation. Moreover, the evaluation of these matrix elements may
sometimes be simplified by identifying the appropriate selection rules
1
In terms of the operations of S3 , even parity corresponds to an even number
of pairwise interchanges, while odd parity corresponds to an odd number of such
interchanges.
(Section 1.2). Finally, the algebra of matrices is generally simpler to

carry out than abstract symmetry operations. Thus, in the next section,
we discuss some of the important properties of matrix representations
of groups.
3.3 Reducible and Irreducible Represen-

tations
The definition of a representation provides for considerable flexibility
in constructing matrix representations, which is manifested in several
ways, but also indicates that representations are not unique. We con-
sider some examples.
Given a matrix representation
n o
D(e), D(a), D(b), . . .
of an abstract group with elements {e, a, b, . . .}, we can obtain a new set
of matrices which also form a representation by performing a transfor-
mation known variously as a similarity, equivalence, or canonical trans-
formation (cf. Sec. 2.6):
n o
BD(e)B −1 , BD(a)B −1 , BD(b)B −1 , . . . (3.5)
Such transformations arise quite naturally, for example, in carrying out

a change of basis for a set of matrices. Thus, suppose one begins with
the matrix equation b = Aa relating two vectors a and b through a
transformation A. If we now wish to express this equation in another
basis which is obtained from the original basis by applying a transfor-
mation B, we can write
Bb = BAa = BAB −1 Ba
so in the new basis, our original equation becomes
b0 = A0 a0
where b0 = Bb, a0 = Ba, and A0 = BAB −1 . A similarity transfor-

mation can therefore be interpreted as a sequence of transformations
involving first a transformation to the original basis (B −1 ), then per-

forming the transformation A, and finally transforming back to the
new basis (B). Referring back to the discussion in Section 2.6 on con-
jugacy classes, we see that group elements in the same conjugacy class
represent the same type of transformation (e.g., reflection or rotation)
which can be transformed into one another by particular symmetry
operations.
Suppose we have representations of dimensions m and n. We can
construct a representation of dimension m+n by forming block-diagonal
matrices:
(" # " # " # )
D(e) 0 D(a) 0 D(b) 0
, , ,... (3.6)
0 D0 (e) 0 D0 (a) 0 D0 (b)
where {D(e), D(a), D(b), . . .} is an n-dimensional representation and

{D0 (e), D0 (a), D0 (b), . . .} an m-dimensional representation of the group
G, and the symbol 0 is an n×m or an m×n zero matrix, as required by
its position in the supermatrix. Each of the m+n-dimensional matrices
formed in this manner is called a direct sum of the n- and m-dimensional
component matrices. The direct sum is denoted by “⊕” to distinguish
it from the ordinary addition of two matrices. Thus, we can write the
representation in (3.6) as
n o
D(e) ⊕ D0 (e), D(a) ⊕ D0 (a), D(b) ⊕ D0 (b), · · ·
The two representations that form this direct sum can be either distinct
or identical and, of course, the block-diagonal form can be continued
indefinitely simply by incorporating additional representations in diag-
onal blocks. However, in all such constructions, we are not actually
generating anything intrinsically new; we are simply reproducing the
properties of known representations. Thus, although representations
are a convenient way of associating matrices with group elements, the
freedom we have in constructing representations, exemplified in (3.5)
and (3.6), does not readily demonstrate that these matrices embody
any intrinsic characteristics of the group they represent. Accordingly,
we now describe a way of classifying equivalent representations and
then introduce a refinement of our definition of a representation.
To overcome the problem of nonuniqueness posed by representations

that are related by similarity transformations we consider the sum of
the diagonal elements of an n × n matrix A, called the trace of A and
by “tr”:
X
n
tr(A) = Aii
i=1
The utility of the trace stems from its invariance under similarity trans-
formations, i.e.,
tr(A) = tr(BAB −1 )
The importance of this invariance, the proof of which is discussed in

Problem Set 4, is that, although there is an infinite variety of represen-
tations related by similarity transformations, each such representation
has the same set of traces associated with each of its elements.
But working with the trace alone does not alleviate the nonunique-
ness of representations posed by (3.6). To address this issue, we in-
troduce the concept of an irreducible representation. Representations
such as those in (3.6) are termed reducible because they are the direct
sum of two (or more) representations. We could, of course, perform
a similarity transformation to obtain a representation that is not in
block form, but the representation so obtained is still deemed to be
reducible because it was obtained from matrices which originally were
in block form. Based on these considerations, we define reducible and
irreducible representations as follows:
Definition. If the same similarity transformation brings all of the ma-

trices of a representation into the same block form (by which we mean
matrices of the same dimension in the same positions), then this repre-
sentation is said to be reducible. Otherwise, the representation is said
to be irreducible.
Thus, irreducible representations cannot be expressed in terms of

representations of lower dimensionality. One-dimensional representa-
tions are, by definition, always irreducible. Determining the irreducible
representations of groups is one of the central issues to be covered in

the following chapters.
Example 3.4. All of the representations of S3 discussed in Example

3.2 are irreducible. This is clear for the identical representation and for
the representation in (3.4), since they are composed of numbers. But
we can use these representations to construct the following manifestly
reducible representation of S3 :
Ã ! Ã ! Ã !
1 0 1 0 1 0
e= , a= , b=
0 1 0 −1 0 −1
Ã ! Ã ! Ã !
1 0 1 0 1 0
c= , d= , f=
0 −1 0 1 0 1
The representation in (3.3) is irreducible. There is no similarity
transformation that will bring all of the matrices into block-diagonal
form which, for the case here, means simple diagonalization. The easiest
way to see this is from the point of view of the commutability of two
matrices. If two matrices can be brought into diagonal form by the same
similarity transformation, then they commute. As diagonal matrices,
they certainly commute, so they must also commute in their original
form. But a glance at the multiplication table for these matrices (recall
that they are a faithful representation of S3 ) in Example 2.2 shows that
they do not all commute. Hence, they cannot all be simultaneously
diagonalized, so this representation is irreducible.
3.4 Unitary Representations

Representations of groups are useful because of orthogonality theorems
which we will prove in the next chapter. As background to that dis-
cussion, we will prove in this section an important result about the
unitarity of representations. But we first review some general proper-
ties of matrices.
We begin by considering the transformation of an n × n matrix A
with entries Aij , i, j = 1, 2, . . . , n, under the action of various opera-
tions. The complex conjugate of A, denoted by A∗ , has entries which

are the complex conjugates of the corresponding entries of A:
(A∗ )ij = (Aij )∗ (3.7)
The transpose of A, denoted by At , has its rows and columns inter-

changed with respect to those of A:
(At )ij = Aji (3.8)
When applied to vectors, the transpose transforms a row vector into a

column vector and vice versa. The transpose of a product of matrices
A, B, C, . . . is
(ABC · · ·)t = · · · C t B t A t (3.9)
i.e., the order of matrix multiplication is reversed. This can be proven

easily from the definition (3.8). Finally, the adjoint or Hermitian conju-
gate of A, denoted by A† , is the transposed conjugate of A, i.e.
(A† )ij = (Aji )∗ (3.10)
In common with the transpose, the application of the Hermitian conju-

gate to a product of matrices A, B, C, . . . can be expressed as a product
of Hermitian conjugates of the individual matrices, but with the order
reversed:
(ABC · · ·)† = · · · C † B † A † (3.11)
3.4.1 Hermitian and Orthogonal Matrices

A matrix A is Hermitian if
A† = A (3.12)
Hermitian matrices and Hermitian operators are familiar from quan-

tum mechanics, where their properties of having real eigenvalues and
orthogonal eigenvectors are of fundamental importance. A matrix A is
orthogonal if its transpose is its inverse:
At A = AAt = I (3.13)
where I is the n × n unit matrix. In terms of matrix components, this

condition reads
X
n X
n
aki akj = aik ajk = δij (3.14)
k=1 k=1
where
(
0, if i 6= j;
δij = (3.15)
1, if i = j
is the Kronecker delta. Thus, the rows of an orthogonal matrix are
mutually orthogonal, as are the columns. The consequences of the
orthogonality of a transformation matrix can be seen by examining the
effect of applying an orthogonal matrix A to two n-dimensional vectors
u and v, yielding vectors u0 and v 0 :
u0 = Au, v 0 = Av
We now take the scalar, or ‘dot,’ product between u0 and v 0 :
(u0 , v 0 ) = (u0 )t v 0 = (Au)t Av = ut At Av = ut v = (u, v) (3.16)
where we have used (3.11) and the fact that A is orthogonal. This
shows that the relative orientations and the lengths of vectors are pre-
served by orthogonal transformations. Such transformations are either
rigid rotations, which preserve the “handedness” (i.e., left or right)
of a coordinate system, and are called proper rotations, or reflections,
which reverse the “handedness” of a coordinate system, and are called
improper “rotations.”
3.4.2 Unitary Matrices

A third type of matrix, called unitary, has the property that
A† A = AA† = I (3.17)
By writing this condition in terms of matrix components,

X
n X
n
a∗ki akj = aik a∗jk = δij (3.18)
k=1 k=1
we see that, in common with orthogonal matrices, the rows and columns
of a unitary matrix are orthogonal, but with respect to a different scalar
product. For two vectors u and v, this scalar product is defined as
(u, v) = u† v (3.19)
This generalizes the familiar dot product to complex vectors in n di-

mensions. We can now show, by proceeding as above, that unitary
transformations leave the scalar product invariant:
(u0 , v 0 ) = (u0 )† v 0 = (Au)† Av = u† A† Av = u† v = (u, v) (3.20)
The property of unitarity, when applied to operators, is of immense

importance in quantum mechanics because it enables changes of bases
to be performed while preserving the orthogonality of bases and, thus,
the overlap between wavefunctions. In this sense, unitary matrices
are associated with proper and improper “rotations,” in analogy with
orthogonal matrices.
3.4.3 Diagonalization of Hermitian Matrices∗

Let H be an n × n Hermitian matrix. The eigenvalue equation for this
matrix is
Ha = λa (3.21)
By writing this equation as
(H − λI)a = 0 (3.22)
the eigenvalue equation in (3.21) has nontrivial solutions for a if and

only if the determinant of the matrix of coefficients in (3.22) vanishes:
det(H − λI) = 0 (3.23)
The expansion of the determinant leads to an nth-order polynomial in

λ whose solution yields the n (not necessarily distinct) eigenvalues of
H: λ1 , λ2 , . . . , λn .
We now show that the eigenvectors of H which correspond to dis-
tinct eigenvalues are orthogonal. Consider the eigenvalue equations for
two eigenvectors a and b corresponding to distinct eigenvalues λ and

µ, respectively:
Ha = λa (3.24)
Hb = µb (3.25)
We now take the scalar product between b and (3.24) and that between
(3.25) and a:
b† (Ha) = λb† a (3.26)

(b† H † )a = µb† a (3.27)
Subtracting (3.27) from (3.26), and using the fact that H is Hermitian
yields
(λ − µ)b† a = b† Ha − b† H † a = 0 (3.28)
which, since λ 6= µ, implies that b† a = 0, i.e., that a and b are or-

thogonal. If λ and µ are not distinct, we must use a Gram–Schmidt
procedure to explicitly construct an orthogonal set of eigenvectors as-
sociated with the degenerate eigenvalue. Thus, the eigenvectors of a
Hermitian matrix can always be chosen to form an orthogonal set.
Consider the matrix U whose columns are the eigenvectors of H:
U = (a1 , a2 , . . . , an )
We can then write (3.21) in a form that subsumes all the eigenvectors
of H as follows:
HU = U D (3.29)
where D is the diagonal matrix whose entries are the eigenvalues of H:

 
λ1 0 ··· 0
 
 0 λ2 ··· 0 
 
D=
 .. .. .. ..


 . . . . 
 
0 0 · · · λd
Since the rows of U are composed of the (orthogonal) eigenvectors of

H, it has the property that (cf. 3.18)
U †U = U U † = I
i.e., U −1 = U † , so U is unitary. Hence, we can rewrite (3.29) as
U −1 HU = U † HU = D
We have proven the following theorem:
Theorem 3.1. Any Hermitian matrix can be diagonalized by an ap-

propriate unitary transformation.
This theorem will be used in the next section to prove an important

result concerning the existence of unitary group representations.
3.4.4 Transformation to Unitary Representations

We have seen in Section 3.3 that there is considerable flexibility in
constructing group representations. In this section, we take a first step
in restricting this freedom by showing that any representation can be
expressed entirely in terms of unitary matrices. Quite apart from the
convenient properties of unitary matrices discussed in Section 3.4.2,
this theorem allows to think of group representations as proper and
improper complex “rotations.”
Theorem 3.2. Every representation can be brought into unitary form

by a similarity transformation.
Proof. Let {A1 , A2 , . . . , A|G| } be a d-dimensional representation of

a group G, i.e., the Aα are a set of |G| d × d matrices with nonvanishing
determinants. From these matrices we form a matrix H given by the
sum
|G|
X
H= Aα A†α
α=1
This matrix is Hermitian because, using the property (3.11),

X X
H† = (Aα A†α )† = Aα A†α = H
α α
According to Theorem 3.1, any Hermitian matrix can be diagonalized

by some unitary transformation U . Denoting the diagonalized form of
H by D, we have D = U † HU , which enables us to write D as
X X X
D= U † Aα A†α U = (U † Aα U )(U † A†α U ) = (U † Aα U )(U † Aα U )†
α α α
By introducing the notation Ãα = U † Aα U , we can write the last equa-

tion in a more concise form as
X
D= Ãα Ã†α (3.30)
α
The diagonal elements of D are real, because

XX
Dkk = (Ãα )kj (Ã† α )jk
α j
XX
= (Ãα )kj (Ãα )∗kj
α j
X X ¯¯ ¯2
¯
= ¯(Ãα )kj ¯
α j
for k = 1, 2, . . . , d, and positive, because the summation over j includes

a diagonal element of the identity, which is a d × d unit matrix, and
hence is equal to unity. Thus, the diagonal matrix D1/2 ,
 1/2 
D11 0 ··· 0
 
 1/2 
 0 D22 ··· 0 
D1/2 =



 .. .. ... .. 
 . . . 
 
1/2
0 0 · · · Ddd
and D−1/2 , which is given by an analogous expression, both have posi-

tive entries.
We now form the matrices

Bα = D−1/2 Ãα D1/2
from which we obtain the corresponding Hermitian conjugates:
Bα† = (D−1/2 Ãα D1/2 )† = D1/2 Ã† α D−1/2
We will now demonstrate that the Bα are unitary by first showing that
the product Bα Bα† is equal to the identity matrix. The product Bα Bα†
is given by
³ ´³ ´
Bα Bα† = D−1/2 Ãα D1/2 D1/2 Ã† α D−1/2
= D−1/2 Ãα DÃ† α D−1/2

The definition of D in (3.30) and the associativity of matrix multipli-
cation allow us to write this expression as
X
Bα Bα† = D−1/2 Ãα Ãβ Ã† β Ã† α D−1/2
j
X
= D−1/2 (Ãα Ãβ )(Ãα Ãβ )† D−1/2
j
Since the Aα are a representation of G, then so are the Ãα (Problem 3,

Problem Set 4). Hence, the product Ãα Ãβ is another matrix Ãγ in this
representation. Moreover, according to the Rearrangement Theorem,
the sum over all β means that the set of Ãγ obtained from these prod-
ucts contains the matrix corresponding to each group element once and
only once. Thus,
X
Bα Bα† = D−1/2 Ãγ Ã†γ D−1/2 = I
γ
| {z }
D
where I is the d × d unit matrix. This result can also be used to show
that Bα† Bα = I. Thus, the Bα , which are obtained from the original
representation by a similarity transformation,
Bα = D−1/2 U −1 Aα U D1/2 = (U D1/2 )−1 Aα (U D1/2 )
form a unitary representation of G. Hence, without any loss of gener-
ality, we may always assume that a representation is unitary.
3.5 Summary
The main concepts introduced in this chapter are faithful and unfaithful
representations, based on isomorphic and homomorphic mappings, re-
spectively, reducible and irreducible representations, and the fact that
we may confine ourselves to unitary representations of groups. In the
next chapter we will focus on irreducible representations, both faithful
and unfaithful, since these cannot be decomposed into representations
of lower dimension and are, therefore, “intrinsic” to a symmetry group,
since all reducible representations will be shown to be composed of
direct sums of irreducible representations. Irreducible representations
occupy a special place in group theory because they can be classified for
a given symmetry group solely according to their traces and dimension.
Chapter 4
Properties of Irreducible
Representations
Algebra is generous; she often gives more than is asked of her.

—Jean d’Alembert
We have seen in the preceding chapter that a reducible representa-

tion can, through a similarity transformation, be brought into block-
diagonal form wherein each block is an irreducible representation. Thus,
irreducible representations are the basic components from which all
representations can be constructed. But the identification of whether a
representation is reducible or irreducible is a time-consuming task if it
relies solely on methods of linear algebra.1 In this chapter, we lay the
foundation for a more systematic approach to this question by deriving
the fundamental theorem of representation theory, called the Great Or-
thogonality Theorem. The utility of this theorem, and its central role
in the applications of group theory to physical problems, stem from the
fact that it leads to simple criteria for determining irreducibility and
provides a direct way of identifying the number of inequivalent repre-
sentations for a given group. This theorem is based on two lemmas of
Schur, which are the subjects of the first two sections of this chapter.
1
K. Hoffman and R. Kunze, Linear Algebra 2nd edn (Prentice–Hall, Englewood
Cliffs, New Jersey, 1971), Ch. 6,7.
51
52 Properties of Irreducible Representations
4.1 Schur’s First Lemma

Schur’s two lemmas are concerned with the properties of matrices that
commute with all of the matrices of a irreducible representations. The
first lemma addresses the properties of matrices which commute with
a given irreducible representation:
Theorem 4.1 (Schur’s First Lemma). A non-zero matrix which com-

mutes with all of the matrices of an irreducible representation is a
constant multiple of the unit matrix.
Proof. Let {A1 , A2 , . . . , A|G| } be the matrices of a d-dimensional

irreducible representation of a group G, i.e., the Aα are d × d matrices
which cannot all be brought into block-diagonal form by the same sim-
ilarity transformation. According to Theorem 3.2, we can take these
matrices to be unitary without any loss of generality. Suppose there is
a matrix M that commutes with all of the Aα :
M A α = Aα M (4.1)
for α = 1, 2, . . . , |G|. By taking the adjoint of each of these equations,
we obtain
A†α M † = M † A†α . (4.2)
Since the Aα are unitary, A†α = A−1
α , so multiplying (4.2) from the left
and right by Aα yields
M † A α = Aα M † , (4.3)
which demonstrates that, if M commutes with every matrix of a repre-
sentation, then so does M † . Therefore, given the commutation relations
in (4.1) and (4.3) any linear combination of M and M † also commute
with these matrices:
(aM + bM † )Aα = Aα (aM + bM † ) ,
where a and b are any complex constants. In particular, the linear
combinations
H1 = M + M † , H2 = i(M − M † )
Properties of Irreducible Representations 53
yield Hermitian matrices: Hi = Hi† for i = 1, 2. We will now show

that a Hermitian matrix which commutes with all the matrices of an
irreducible representation is a constant multiple of the unit matrix. It
then follows that M is also such a matrix, since
M = 12 (H1 − iH2 ) (4.4)
The commutation between a general Hermitian matrix H and the
Aα is expressed as
HAα = Aα H . (4.5)
Since H is Hermitian, there is a unitary matrix U which transforms H
into a diagonal matrix D (Theorem 3.1):
D = U −1 HU .
We now perform the same similarity transformation on (4.5):
U −1 HAi U = U −1 HU U −1 Ai U
= U −1 Ai HU = U −1 Ai U U −1 HU
By defining Ãα = U −1 Aα U , the transformed commutation relation (4.5)
reads
DÃα = Ãα D . (4.6)
Using the fact that D is a diagonal matrix, i.e., that its matrix elements
are Dij = Dii δij , where δij is the Kronecker delta, the (m, n)th matrix
element of the left-hand side of this equation is
X X
(DÃα )mn = Dmk (Ãα )kn = Dmm δmk (Ãα )kn = Dmm (Aα )mn .
k k
Similarly, the corresponding matrix element on the right-hand side is

X X
(Ãα D)mn = (Ãα )mk Dkn = (Ãα )mk Dnn δkn = (Ãα )mn Dnn .
k k
Thus, after a simple rearrangement, the (m, n)th matrix element of

(4.6) is
(Ãα )mn (Dmm − Dnn ) = 0 . (4.7)
There are three cases that we must consider to understand the impli-
cations of this equation.
Case I. Suppose that all of the diagonal elements of D are dis-
tinct: Dmm 6= Dnn if m 6= n. Then, (4.7) implies that
(Ãα )mn = 0, m 6= n ,
i.e., the off-diagonal elements of Ãα must vanish, these are diagonal ma-
trices and, therefore, according to the discussion in Section 3.3, they
form a reducible representation composed of d one-dimensional rep-
resentations. Since the Ãi are obtained from the Ai by a similarity
transformation, the Ai themselves form a reducible representation.
Case II. If all of the diagonal elements of D are equal, i.e. Dmm =
Dnn for all m and n, then D is proportional to the unit matrix. The
(Ãα )mn are not required to vanish for any m and n. Thus, only this
case is consistent with the requirement that the Aα form an irreducible
representation. If D is proportional to the unit matrix, then so is
H = U DU −1 and, according to (4.4), the matrix M is as well.
Case III. Suppose that the first p diagonal entries of D are equal,
but the remaining entries are distinct from these and from each other:
D11 = D22 = · · · = Dpp , Dmm 6= Dnn otherwise. The (Ãα )mn must
vanish for any pair of unequal diagonal entries. These correspond to
the cases where both m and n lie in the range 1, 2, . . . , p and where m
and n are equal and both greater than p, so all the Ãi all have the
following general form:
Ã !
B1 0
Ãi = ,
0 B2
where B1 is a p × p matrix and B2 is a (p − d) × (p − d) diagonal matrix.
Thus, the Ãi are block diagonal matrices and are, therefore, reducible.
We have shown that if a matrix that not a multiple of the unit
matrix commutes with all of the matrices of a representation, then
that representation is necessarily reducible (Cases I and III). Thus, if
a non-zero matrix commutes with all of the matrices of an irreducible
representation (Case III), that matrix must be a multiple of the unit
matrix. This proves Schur’s lemma.
4.2 Schur’s Second Lemma

Schur’s first lemma is concerned with the commutation of a matrix with
a given irreducible representation. The second lemma generalizes this
to the case of commutation with two distinct irreducible representations
which may have different dimensionalities. Its statement is as follows:
Theorem 4.2 (Schur’s Second Lemma). Let {A1 , A2 , . . . , A|G| } and

{A01 , A02 , . . . , A0|G| } be two irreducible representations of a group G of
dimensionalities d and d0 , respectively. If there is a matrix M such that
M Aα = A0α M
for α = 1, 2, . . . , |G|, then if d = d0 , either M = 0 or the two represen-

tations differ by a similarity transformation. If d 6= d0 , then M = 0.
Proof. Given the commutation relation between M and the two

irreducible representations,
M Aα = A0α M , (4.8)
we begin by taking the adjoint:
A†α M † = M † A0†
α. (4.9)
Since, according to Theorem 3.2, the Aα may be assumed to be unitary,

A†α = A−1
α , so (4.9) becomes
A−1 † † 0−1
α M = M Aα . (4.10)
By multiplying this equation from the left by M ,
M A−1 † † 0−1
α M = M M Aα ,
and utilizing the commutation relation (4.8) to write
M A−1 0−1
α = Aα M ,
we obtain
A0−1 † † 0−1
α M M = M M Aα .
Thus, the d0 × d0 matrix M M † commutes with all the matrices of an

irreducible representation. According to Schur’s First Lemma, M M †
must therefore be a constant multiple of the unit matrix,
M M † = cI , (4.11)
where c is a constant. We now consider individual cases.
Case I. d = d0 . If c 6= 0, Eq. (4.11) implies that2
1
M −1 = M † .
c
Thus, we can rearrange (4.8) as
Aα = M −1 A0α M ,
so our two representations are related by a similarity transformation
and are, therefore, equivalent.
If c = 0, then M M † = 0. The (i, j)th matrix element of this product
is
X X
(M M † )ij = Mik (M † )kj = ∗
Mik Mjk = 0.
k k
By setting i = j, we obtain
X X
∗
Mik Mik = |Mik |2 = 0 ,
k k
which implies that Mik = 0 for all i and k, i.e., that M is the zero
matrix. This completes the first part of the proof.
Case II. d 6= d0 . We take d < d0 . Then M is a rectangular matrix
with d columns and d0 rows:
 
M11 · · · M1d
 
 M21 ··· M2d 
 
M =
 .. ... ..
.

 . . 
 
Md0 1 · · · Md0 d
2
By multiplying (4.10) from the right by M and following analogous steps as
above, one can show that M † M = cI, so that the matrix c−1 M † is both the left
and right inverse of M .
We can make a d0 × d0 matrix N from M by adding d0 − d columns of

zeros:
 
M11 ··· M1d 0 ··· 0
 
 M21 ··· M2d 0 ··· 0
 
N =
 .. .. .. .. . .
 ≡ (M, 0) .
.. 
 . . . . . .
 
Md0 1 · · · Md0 d 0 ··· 0
Taking the adjoint of this matrix yields
 ∗ 
M11 M21 · · · Md∗0 1
 
 M∗ M22 ∗
· · · Md∗0 2 
 12 
 
 . .. ... .. 
 .. . . 
  Ã !
  M†
N† = 
 M1d∗ ∗
M2d ···

Md∗0 d  = .
  0
 
 0 0 ··· 0 
 
 
 .. .. ... .. 
 . . . 
 
0 0 ··· 0
Note that this construction maintains the product M M † :

Ã !
† M†
N N = (M, 0) = M M † = cI .
0
The determinant of N is clearly zero. Thus,
0
det(N N † ) = det(N ) det(N † ) = cd = 0
so c = 0, which means that M M † = 0. Proceeding as in Case I, we

conclude that this implies M = 0. This completes the second part of
the proof.
4.3 The Great Orthogonality Theorem

Schur’s lemmas provide restrictions on the form of matrices which com-
mute with all of the matrices of irreducible representations. But the
group property enables the construction of many matrices which sat-

isfy the relations in Schur’s First and Second Lemmas. The interplay
between these two facts provides the basis for proving the Great Or-
thogonality Theorem. The statement of this theorem is as follows:
Theorem 4.3 (Great Orthogonality Theorem). Let {A1 , A2 , . . . , A|G| }

and {A01 , A02 , . . . , A0|G| } be two inequivalent irreducible representations
of a group G with elements {g1 , g2 , . . . , g|G| } and which have dimen-
sionalities d and d0 , respectively. The matrices Aα and A0α in the two
representations correspond to the element gα in G. Then
X
(Aα )∗ij (A0α )i0 j 0 = 0
α
for all matrix elements. For the elements of a single unitary irreducible
representation, we have
X |G|
(Aα )∗ij (Aα )i0 j 0 = δi,i0 δj,j 0 ,
α d
where d is the dimension of the representation.
Proof. Consider the matrix

X
M= A0α XA−1
α , (4.12)
α
where X is an arbitrary matrix with d0 rows and d columns, so that M

is a d0 × d0 matrix. We will show that for any matrix X, M satisfies a
commutation relation of the type discussed in Schur’s Lemmas.
We now multiply M from the left by the matrix A0β corresponding
to some matrix in the the “primed” representation:
X
A0β M = A0β A0α XA−1
α
α
X
−1
= A0β A0α XA−1
α Aβ Aβ
α
X
= A0β A0α X(Aβ Aα )−1 Aβ . (4.13)
α
Since the Aα and A0α form representations of G, the products Aα Aβ

and A0α A0β yield matrices Aγ and A0γ , respectively, both corresponding
to the same element in G because representations preserve the group
composition rule. Hence, by the Rearrangement Theorem (Theorem
2.1), we can write the summation over α on the right-hand side of this
equation as
X X
A0β A0α X(Aβ Aα )−1 = A0γ XA−1
γ = M .
α γ
Substituting this result into (4.13) yields
A0β M = M Aβ . (4.14)
Depending on the nature of the two representations, this is precisely the

situation addressed by Schur’s First and Second Lemmas. We consider
the cases of equivalent and inequivalent representations separately.
Case I. d 6= d0 or, if d = d0 , the representations are inequivalent (i.e.,

not related by a similarity transformation). Schur’s Second Lemma
then implies that M must be the zero matrix, i.e., that each matrix
element of M is zero. From the definition (4.12), we see that this
requires
XX
Mii0 = (A0α )ij Xjj 0 (A−1
α )j 0 i0 = 0 . (4.15)
α jj 0
By writing this sum as (note that because all sums are finite, their
order can be changed at will)
X ·X ¸
Xjj 0 (Aα )0ij (A−1
α )j 0 i0 = 0 , (4.16)
jj 0 α
we see that, since X is arbitrary, each of its entries may be varied

arbitrarily and independently without affecting the vanishing of the
sum. The only way to ensure this is to require that the coefficients of
the Xjj 0 vanish:
X
(A0α )ij (A−1
α )j 0 i0 = 0 .
α
For unitary representations, (A−1 ∗

α )j 0 i0 = (Aα )i0 j 0 , so this equation re-
duces to
X
(A0α )ij (Aα )∗i0 j 0 = 0 ,
α
which proves the first part of the theorem.
Case II. d = d0 and the representations are equivalent. According

to Schur’s First Lemma, M = cI, so,
X
cI = Aα XA−1
α . (4.17)
α
Taking the trace of both sides of this equation,

µX ¶ X X
tr(cI) = tr Aα XA−1
α = tr(Aα XA−1
α ) = tr(X) ,
| {z } α α α
cd | {z }
|G| tr(X)
yields an expression for c:
|G|
c= tr(X) .
d
Substituting this into Eq. (4.17) and expressing the resulting equation
in terms of matrix elements, yields
·X ¸
X |G| X
X jj 0 (Aα )ij (A−1
α )j 0 i0 = δi,i0 Xjj ,
jj 0 α d j
or, after a simple rearrangement,

" #
X X |G|
Xjj 0 (Aα )ij (A−1
α )j 0 i0 − δi,i0 δj,j 0 = 0 .
jj 0 α d
This equation must remain valid under any independent variation of

the matrix elements of X. Thus, we must require that the coefficient
of Xjj 0 vanishes identically:
X |G|
(Aα )ij (A−1
α )j 0 i0 = δi,i0 δj,j 0 .
α d
Since the representation is unitary, this is equivalent to

X |G|
(Aα )ij (Aα )∗i0 j 0 = δi,i0 δj,j 0 .
α d
This proves the second part of the theorem.
4.4 Some Immediate Consequences of the

Great Orthogonality Theorem
The Great Orthogonality Theorem establishes a relation between ma-
trix elements of the irreducible representations of a group. Suppose we
denote the αth matrix in the kth irreducible representation by Akα and
the (i, j)th element of this matrix by (Akα )ij . We can then combine the
two statements of the Great Orthogonality Theorem as
X 0 |G|
(Akα )ij (Akα )∗i0 j 0 = δi,i0 δj,j 0 δk,k0 (4.18)
α d
This expression helps us to understand the motivation for the name

“Orthogonality Theorem” by inviting us to consider the matrix ele-
ments of irreducible representations as entries in |G|-component vec-
tors, i.e., vectors in a space of dimensionality |G|:
h i
V kij = (Ak1 )ij , (Ak2 )ij , . . . , (Ak|G| )ij
According to the statement of the Great Orthogonality Theorem, two

such vectors are orthogonal if they differ in any one of the indices i, j,
or k, since (4.18) requires that
0 |G|
V kij · V ki0 j 0 = δi,i0 δj,j 0 δk,k0
d
But, in a |G|-dimensional space there are at most |G| mutually or-
thogonal vectors. To see the consequences of this, suppose we have
irreducible representations of dimensionalities d1 , d2 , . . ., where the dk
are positive integers. For the k representations, there are dk choices

for each of i and j, i.e., there are d2k matrix elements in each matrix
of the representation. Summing over all irreducible representations, we
obtain the inequality
X
d2k ≤ |G| (4.19)
k
Thus, the order of the group acts as an upper bound both for the
number and the dimensionalities of the irreducible representations. In
particular, a finite group can have only a finite number of irreducible
representations. We will see later that the equality in (4.19) always
holds.
Example 4.1. For the group S3 , we have that |G| = 6 and we have
already identified two one-dimensional irreducible representations and
one two-dimensional irreducible representation (Example 3.2). Thus,
using (4.19), we have
X
d2k = 12 + 12 + 22 = 6
k
so the Great Orthogonality Theorem tells us that there are no addi-

tional distinct irreducible representations.
For the two element group, we have found two one-dimensional rep-
resentations, {1, 1} and {1, −1} (Example 3.3). According to the in-
equality in (4.19),
X
d2k = 1 + 1 = 2
k
so these are the only two irreducible representations of this group.
4.5 Summary
The central result of this chapter is the statement and proof of the
Great Orthogonality Theorem. Essentially all of the applications in
the next several chapters are consequences of this theorem. The impor-
tant advance provided this theorem is that it provides an orthogonality
relation between the entries of the matrices of the irreducible repre-

sentations of a group. While this can be used to test whether a given
representation is reducible or irreducible (Problem Set 6), its main role
will be in a somewhat “reduced” form, such as that used in Sec. 4.4 to
place bounds on the number of irreducible representations of a finite
group. One of the most important aspects of the Great Orthogonality
Theorem for applications to physical problems is in the construction
of “character tables,” i.e., tables of traces of matrices of an irreducible
representation. This is taken up in the next chapter.
Chapter 5
Characters and Character

Tables
In great mathematics there is a very high degree of unexpectedness, com-

bined with inevitability and economy.
—Godfrey H. Hardy1
In the preceding chapter, we proved the Great Orthogonality Theorem,

which is a statement about the orthogonality between the matrix ele-
ments corresponding to different irreducible representations of a group.
For many applications of group theory, however, the full matrix rep-
resentations of a group are not required, but only the traces within
classes of group elements—called “characters.” A typical application
involves determining whether a given representation is reducible or irre-
ducible and, if it is reducible, to identify the irreducible representations
contained within that representation.
In this chapter, we develop the mathematical machinery that is used
to assemble the characters of the irreducible representations of a group
in what are called “character tables.” The compilation of character ta-
bles requires two types of input: the order of the group and the number
of classes it contains. These quantities provide stringent restrictions
1
G.H. Hardy, A Mathematician’s Apology (Cambridge University Press, London,
1941)
65
66 Characters and Character Tables
on the number of irreducible representations and their dimensionali-

ties. Moreover, orthogonality relations derived from the Great Orthog-
onality Theorem will be shown to provide constraints on characters of
different irreducible representations, which considerably simplifies the
construction of character tables.
5.1 Orthogonality Relations

The Great Orthogonality Theorem,
X 0 |G|
(Akα )ij (Akα )∗i0 j 0 = δi,i0 δj,j 0 δk,k0 (5.1)
α dk
is a relationship between the matrix elements of the irreducible repre-
sentations of a group G. In this section, we show how this statement
can be manipulated into an expression solely in terms of the traces of
the matrices in these representations. This will open the way to estab-
lishing a sum rule between the number of irreducible representations
and the number of classes in a group.
We begin by setting j = i and j 0 = i0 in (5.1),
X 0 |G|
(Akα )ii (Akα )∗i0 i0 = δi,i0 δk,k0 , (5.2)
α dk
where we have used the fact that δi,i0 δi,i0 = δi,i0 . Summing over i and i0
on the left-hand side of this equation yields
" #" #
XX X X X
k0 k0
(Akα )ii (Aα )i0 i0 = (Akα )ii (Aα )∗i0 i0
i,i0 α α i i0
| {z }| {z }
0
tr(Akα ) tr(Akα )∗
X 0
= tr(Akα )tr(Akα )∗ ,
α
0
and, by summing over i and i on the right-hand side of (5.2), we obtain
|G| XX |G| X
δk,k0 δi,i0 = δk,k0 1 = |G|δk,k0 .
dk i i0
dk i
| {z }
dk
Characters and Character Tables 67
We have thereby reduced the Great Orthogonality Theorem to

X 0
tr(Akα )tr(Akα ∗ ) = |G|δk,k0 . (5.3)
α
This expression can be written in a more useful form by observing

that matrices corresponding to elements in the same conjugacy class
have the same trace. To see this, recall the definition in Section 2.6
of the conjugacy of two elements a and b group G. There must be
an element g in G such that a = gbg −1 . Any representation {Aα },
reducible or irreducible, must preserve this relation:
Aa = Ag Ab Ag−1 .
This representation must also have the property that Ag−1 = A−1
g . Thus
(Problem 2, Problem Set 4),
tr(Aa ) = tr(Ag Ab A−1 −1
g ) = tr(Ag Ag Ab ) = tr(Ab ) .
We can now introduce the notation χkα for the trace corresponding to
all of the elements of the αth class of the kth irreducible representation.
This is called the character of the class. If there are nα elements in this
class, then we can write the relation (5.3) in terms of characters as a
sum over conjugacy classes
C
X 0
nα χkα χkα ∗ = |G|δk,k0 , (5.4)
α=1
where C is the number of conjugacy classes. In arriving at this relation,

we have proven the following theorem:
Theorem 5.1 (Orthogonality Theorem for Characters). The char-
acters of the irreducible representations of a group obey the relation
X 0
nα χkα χαk ∗ = |G|δk,k0 .
α
This orthogonality theorem can be used to deduce a relationship

between the number classes of a group and the number of irreducible
representations. By rearranging (5.4) as
X ·µ nα ¶1/2 ¸·µ
nα
¶1/2
0
¸
χkα χkα ∗ = δk,k0
α |G| |G|
and introducing the vectors

√ √ √
e k = |G|−1/2 ( n1 χk1 , n2 χk2 , . . . , nC χkC ) ,
χ
we can write the orthogonality relation for characters as
0
e k ·χ
χ e k = δk,k0 .
The χ e k reside in a space whose dimension is the number of classes C in

the group. Thus, the maximum number of a set of mutually orthogonal
vectors in this space is C. But these vectors are labelled by an index k
corresponding to the irreducible representations of the group. Hence,
the number of irreducible representations must be less than or equal to
the number of classes.
It is also possible2 to obtain an orthogonality relation with the roles
of the irreducible representations and classes reversed in comparison to
that in Theorem 5.1:
X |G|
χkα χk∗
β = δα,β . (5.5)
k nα
By following analogous reasoning as above, we can deduce that this or-
thogonality relation implies that the number of irreducible representa-
tions must be greater than or equal to the number of classes. Combined
with the statement of Theorem 5.1, we have the following theorem:
Theorem 5.2. The number of irreducible representations of a group is

equal to the number of conjugacy classes of that group.
Example 5.1. For Abelian subgroups each element is in a class by

itself (Problem 6, Problem Set 3). Thus, the number of classes is equal
to the order of the group, so, according to Theorem 5.2, the number
of irreducible representations must also equal the order of the group.
When combined with the restriction imposed by Eqn. (4.19), which we
can now write as
|G|
X
d2k = |G| ,
k=1
2
M. Hamermesh, Group Theory and its Application to Physical Problems (Dover,
1989, New York) pp. 106–110.
we have an alternative way (cf. Problem 4, Problem Set 5) of seeing

that all of the the irreducible representations of an Abelian group are
one-dimensional, i.e., dk = 1, for k = 1, 2, . . . , |G|.
Example 5.2. For the group S3 , there are three classes: {e}, {a, b, c},
and {d, f } (Example 2.9). Thus, there are three irreducible represen-
tations which, as we have seen, consist of two one-dimensional repre-
sentations and one two-dimensional representation.
5.2 The Decomposition Theorem

One of the main uses of characters is in the decomposition of a given
reducible representation into its constituent irreducible representations.
The procedure by which this is accomplished is analogous to projecting
a vector onto a set of complete orthogonal basis vectors. The theorem
which provides the foundation for carrying this out with characters is
the following:
Theorem 5.3 (Decomposition Theorem). The character χα for the

αth class of any representation can be written uniquely in terms of the
corresponding characters of the irreducible representations of the group
as
X
χα = ak χkα ,
k
where
1 X
ak = nα χk∗
α χα .
|G| α
Proof. For a reducible representation, the same similarity transfor-

mation brings all of the matrices into the same block-diagonal form. In
this form, the matrix Aα can be written as the direct sum of matrices
Akj of irreducible representations:
Aα = Akα1 ⊕ Akα2 ⊕ · · · ⊕ Akαn ,

where α = 1, 2, . . . , |G| and k1 , k2 , . . . kn label irreducible representa-

tions. Given this, and the fact that similarity transformations leave
the trace invariant, we can write the character χi of this reducible rep-
resentation corresponding to the ith class as
X
χα = ak χkα , (5.6)
k
where the ak must be nonnegative integers. We now multiply both

0
sides of this equation by nα χαk ∗ , sum over α, and use the orthogonality
relation (5.4):
X 0 X X 0
nα χkα ∗ χα = ak nα χkα χkα ∗ = |G|ak0
α k α
| {z }
|G|δk,k0
Thus,
1 X 0
ak 0 = nα χαk ∗ χα , (5.7)
|G| α
so ak0 is the projection of the reducible representation onto the k 0 th

irreducible representation. Note that, because the number of irreducible
representations equals the number of classes, the orthogonal vectors of
characters span the space whose dimensionality is the number of classes,
so this decomposition is unique.
The Decomposition Theorem reduces the task of determining the ir-

reducible representations contained within a reducible representation to
one of vector algebra. Unless a particular application requires the ma-
trix forms of the representations, there is no need to block-diagonalize
a representation to identify its irreducible components.
We can follow a procedure analogous to that used to prove the De-
composition Theorem to derive a simple criterion to identify whether
a representation is reducible or irreducible. We begin with the decom-
position (5.6) and take its complex conjugate:
X 0
χ∗α = ak0 χkα ∗ , (5.8)
k0
where we have used the fact that the ak are integers, so a∗k = ak . We
now take the product of (5.6) and (5.8), multiply by nα , sum over α,
and invoke (5.4):
X X X 0 X
nα χα χ∗α = ak ak 0 nα χkα χαk ∗ = |G| a2k .
α k,k0 i k
| {z }
|G|δk,k0
Thus,
X X
nα |χ2α | = |G| a2k . (5.9)
α k
If the representation in question is irreducible, then all of the ak are zero,

except for the one corresponding to that irreducible representation,
which is equal to unity. If the representation is reducible, then there
will be at least two of the ak which are positive integers. We can
summarize these observations with a simple criterion for reducibility.
If the representation is irreducible, then
X
nα |χα |2 = |G| , (5.10)
α
and if the representation is reducible,

X
nα |χα |2 > |G| . (5.11)
α
Example 5.3. Consider the following representation of S3 :

Ã ! Ã √ ! Ã √ !
1 0 1 − 3 1 3
e= , a= 21
√ , b= 2 √
1
,
0 1 − 3 −1 3 −1
Ã ! Ã √ ! Ã √ !
−1 0 −1 3 −1 − 3
c= , d= 1
2 √ , f= 1
2 √ .
0 1 − 3 −1 3 −1
There are three classes of this group, {e}, {a, b, c}, and {d, f }, so we
have n1 = 1, n2 = 3, and n3 = 2, respectively. The corresponding
characters are
χ1 = 2, χ2 = 0, χ3 = −1 .
Forming the sum in (5.9), we obtain
X
3
nα |χα |2 = (1 × 4) + (3 × 0) + (2 × 1) = 6 ,
α=1
which is equal to the order of the group. Therefore, this representation

is irreducible, as we have already demonstrated in Example 3.4 and in
Problem 1, Problem Set 6.
Example 5.4. Another representation of S3 is

Ã ! Ã √ !
1 0 −1 − 3
e=d=f = , a=b=c= 1
2 √ .
0 1 − 3 1
The characters corresponding to the three classes are now
χ1 = 2, χ2 = 0, χ3 = 2 .
Forming the sum in (5.9), we find
X
3
n1 |χi |2 = (1 × 4) + (3 × 0) + (2 × 4) = 12 ,
i=1
which is greater than the order of the group, so this representation is

reducible (cf. Problem 2, Problem Set 6). To determine the irreducible
constituents of this representation, we use the decomposition theorem.
There are three irreducible representations of S3 : the one-dimensional
identical representation, with characters
χ11 = 1, χ12 = 1, χ13 = 1 ,
the one-dimensional “parity” representation, with characters
χ21 = 1, χ22 = −1, χ23 = 1 ,
and the two-dimensional “coordinate” representation discussed above

in Example 5.3, with characters
χ31 = 2, χ32 = 0, χ33 = −1 .

We now calculate the ak using the expression in Equation (5.7). These

determine the “projections” of the characters of the reducible represen-
tation onto the characters of the irreducible representation. We obtain
h i
a1 = 1
6
(1 × 1 × 2) + (3 × 1 × 0) + (2 × 1 × 2) = 1 ,
h i
a2 = 1
6
(1 × 1 × 2) + (3 × −1 × 0) + (2 × 1 × 2) = 1 ,
h i
a3 = 1
6
(1 × 2 × 2) + (3 × 0 × 0) + (2 × −1 × 2) = 0 .
Thus, this reducible representation is composed of the identical repre-

sentation and the “parity” representation, with no contribution from
the “coordinate” representation. The block-diagonal form of this rep-
resentation is, therefore,
Ã ! Ã !
1 0 1
1 0
e=d=f = , a=b=c= 2
,
0 1 0 −1
which is the result obtained in Problem 5, Problem Set 5 by applying
matrix methods.
5.3 The Regular Representation

Our construction of irreducible representations has thus far proceeded
in an essentially ad hoc fashion, relying in large part on physical argu-
ments. We have not yet developed a systematic procedure for construct-
ing all of the irreducible representations of a group. In this section, we
introduce a method, based on what is called the “regular” represen-
tation, which enables us to accomplish this. However, our purpose
for introducing such a methodology is not the determination of irre-
ducible representations as such, since even for relatively simple groups,
the approach we describe would present a computationally demanding
process, but as a theoretical tool for proving a theorem. Moreover, we
will find that, for applications of group theory to quantum mechanics,
the irreducible representations of the group of operations that leave
Hamiltonian invariant will emerge naturally without having to rely on
any auxiliary constructions.
The regular representation is a reducible representation that is ob-

tained directly from the multiplication table of a group. As we will show
below, this representation contains every irreducible representation of
a group at least once. The construction of the regular representation
is based on arranging the multiplication table of a group so that the
unit element appears along the main diagonal of the table. Within such
an arrangement the columns (or rows) of the table are labelled by the
group elements, arranged in any order, and the corresponding order of
the inverses labels the rows (or columns).
As an example, consider the multiplication table for S3 (Section 2.4)
arranged in the way just described:
e a b c d f
−1
e=e e a b c d f
a = a−1 a e d f b c
b = b−1 b f e d c a
c = c−1 c d f e a b
f = d−1 f b c a e d
d = f −1 d c a b f e
The matrices of the regular representation are obtained by regarding

the multiplication table as an |G| × |G| array from which the matrix
representation for each group element is assembled by putting a ‘1’
where that element appears in the multiplication table and zero else-
where. For example, the matrices corresponding to the unit e and the
element a are
   
1 0 0 0 0 0 0 1 0 0 0 0
   

0 1 0 0 0 0


1 0 0 0 0 0

   
   
0 0 1 0 0 0 0 0 0 0 0 1
e→


, a→



0 0 0 1 0 0 0 0 0 0 1 0
   
   
   
0 0 0 0 1 0 0 0 0 1 0 0
   
0 0 0 0 0 1 0 0 1 0 0 0
with analogous matrices for the other group elements.

Our first task is to show that the regular ‘representation’ is indeed

a representation of the group. First of all, it is clear that the mapping
we have described is one-to-one. For any two elements g1 and g2 of
this group, we denote the matrices in the regular representation that
correspond to these elements as Areg (g1 ) and Areg (g2 ). Thus, to show
that these matrices form a representation of S3 , we need to verify that
Areg (g1 g2 ) = Areg (g1 )Areg (g2 ) ,
i.e., that the multiplication table is preserved by this representation.

We consider this relation expressed in terms of matrix elements:
h i Xh i h i
Areg (g1 g2 ) = Areg (g1 ) Areg (g2 ) . (5.12)
ij ik kj
k
From the way the regular representation has been constructed, the ith
row index of these matrix elements can be labelled the inverse of the
ith group element gi−1 and the jth column can be labelled by the jth
group element gj :

h i h i  1, if gi−1 gj = g1 g2 ;
Areg (g1 g2 ) = Areg (g1 g2 ) =
ij gi−1 ,gj 
0; otherwise

h i h i  1, if gi−1 gk = g1 ;
Areg (g1 ) = Areg (g1 ) =
ik gi−1 ,gk 
0; otherwise

h i h i  1, if gk−1 gj = g2 ;
Areg (g2 ) = Areg (g2 ) =
kj gk−1 ,gj 
0; otherwise
Therefore, in the sum over k in (5.12), we have nonzero entries only
when
g1 g2 = (gi−1 gk )(gk−1 gj ) = gi−1 gj ,
which gives precisely the nonzero matrix elements of Areg (g1 g2 ). Hence,
the matrices Areg (g1 ) preserve the group multiplication table and thereby
form a faithful representation of the group.
Our main purpose in introducing the regular representation is to

prove the following theorem:
Theorem 5.4. The dimensionalities dk of the irreducible representa-

tions of a group are related to the order |G| of the group by
X
d2k = |G| .
k
This theorem shows that the inequality (4.19), which was deduced di-
rectly from the Great Orthogonality Theorem is, in fact, an equality.
Proof. We first show, using Eqn. (5.9), that the regular represen-
tation is reducible. To evaluate the sums on the left-hand side of this
equation, we note that, from the construction of the regular repre-
sentation, the characters χreg,i vanish for every class except for that
corresponding to the unit element. Denoting this character by χreg,e ,
we see that its value must be equal to the order of the group:
χreg,e = |G| .
Thus,
X
nα |χα |2 = χ2reg,e = |G|2 ,
α
which, for |G| > 1 is greater than |G|. Thus, for groups other than the
single-element group {e}, the regular representation is reducible.
We will now use the Decomposition Theorem to identify the irre-
ducible constituents of the regular representation. Thus, the characters
χreg,α for the αth class in the regular representation can be written as
X
χreg,α = ak χkα .
k
According to the Decomposition Theorem, the ak are given by

1 X
ak = nα χk∗
α χreg,α .
|G| α
We again use the fact that χreg,e = |G|, with all other characters vanish-
ing. The corresponding value of χke is determined by taking the trace of
the identity matrix whose dimensionality is that of the kth irreducible
representation: χke = dk . Therefore, the Decomposition Theorem yields
1
ak = × dk × |G| = dk ,
|G|
i.e., the kth irreducible representation appears dk times in the regular
representation: each one-dimensional irreducible representation appears
once, each two-dimensional irreducible representation appears twice,
and so on. Since the dimensionality of the regular representation is |G|,
and since ak is the number of times the kth irreducible representation
appears in the regular representation, we have the constraint
X
ak dk = |G| ,
k
i.e.,
X
d2k = |G| .
k
This sum rule, and that equating the number of classes to the num-
ber of irreducible representations (Theorem 5.2), relate a property of
the abstract group (its order and the number of classes) to a property
of the irreducible representations (their number and dimensionality).
The application of these rules and the orthogonality theorems for char-
acters is the basis for constructing character tables. This is described
in the next section.
5.4 Character Tables

Character tables are central to many applications of group theory to
physical problems, especially those involving the decomposition of re-
ducible representations into their irreducible components. Many text-
books on group theory contain compilations of character tables for the
most common groups. In this section, we will describe the construction

of character tables for S3 . We will utilize two types of information: sum
rules for the number and dimensionalities of the irreducible represen-
tations, and orthogonality relations for the characters. Additionally,
the group multiplication table can be used to establish relationships
for one-dimensional representations. By convention, characters tables
are displayed with the columns labelled by the classes and the rows by
the irreducible representations.
The first step in the construction of this character table is to note
that, since |S3 | = 6 and there are three classes (Example 2.9), there are
3 irreducible representations whose dimensionalities must satisfy
d21 + d22 + d23 = 6 .
The unique solution of this equation (with only positive integers) is
d1 = 1, d2 = 1, and d3 = 2, so there are two one-dimensional irreducible
representations and one two-dimensional irreducible representation.
In the character table for any group, several entries can be made im-
mediately. The identical representation, where all elements are equal to
unity, is always a one-dimensional irreducible representation. Similarly,
the characters corresponding to the unit element are equal to the di-
mensionality of that representation, since they are calculated from the
trace of the identity matrix with that dimensionality. Thus, denoting
by α, β, γ, and δ quantities that are to be determined, the character
table for S3 is:
S3 {e} {a, b, c} {d, f }
Γ1 1 1 1
Γ2 1 α β
Γ3 2 γ δ
where the Γi are a standard label for the irreducible representations.

The remaining entries are determined from the orthogonality re-
lations for characters and, for one-dimensional irreducible representa-
tions, from the multiplication table of the group. The orthogonality
relation in Theorem 5.1, which is an orthogonality relation for the rows
of a character table, yield
1 + 3α + 2β = 0 , (5.13)
1 + 3α2 + 2β 2 = 6 . (5.14)
The group multiplication table requires that
a2 = e, b2 = e, c2 = e, d2 = f .
Since the one-dimensional representations must obey the multiplication

table, these products imply that
α2 = 1, β2 = β .
Substituting these relations into (5.14), yields 4 + 2β = 6, i.e.,
β=1
Upon substitution of this value into (5.13), we obtain 3 + 3α = 0, i.e.,
α = −1
From the orthogonality relation (5.5), which is an orthogonality relation

between the columns of a character table, we obtain
1 + α + 2γ = 0
1 + β + 2δ = 0
Substituting the values obtained for α and β into these equations yields
γ = 0, δ = −1
The complete character table for S3 is therefore given by
S3 {e} {a, b, c} {d, f }

Γ1 1 1 1
Γ2 1 −1 1
Γ3 2 0 −1
When character tables are compiled for the most common groups,
a notation is used which reflects the fact that the group elements cor-
respond to transformations on physical objects. The notation for the
classes of S3 are as follows:
• {e} → E. The identity.
• {a, b, c} → 3σv . Reflection through vertical planes, where ‘verti-

cal’ refers to the fact that these planes contain the axis of highest
rotational symmetry, in this case, the z-axis. The ‘3’ refers to
there being three elements in this class.
• {d, f } → 2C3 . Rotation by 23 π radians, with the ‘2’ again referring

to the there being two elements in this class. The notation C32
is for rotations by 43 π radians, so the ‘class’ notation is meant
only to indicate the type of operation. In general, Cn refers to
rotations through 2π/n radians.
Several notations are used for irreducible representations. One of

the most common is to use A for one-dimensional representations, E
for two-dimensional representations, and T for three-dimensional rep-
resentations, with subscripts used to distinguish multiple occurrences
of irreducible representations of the same dimensionality. The notation
Γ is often used to indicate a generic (usually irreducible) representa-
tion, with subscripts and superscripts employed to distinguish between
different representations. With the first of these conventions, the char-
acter table for S3 , which is known as the group C3v when interpreted
as the planar symmetry operations of an equilateral triangle, is
C3v E 3σv 2C3

A1 1 1 1
A2 1 −1 1
E 2 0 −1
5.5 Summary
This chapter has been devoted to characters and character tables. The
utility of characters in applications stems from the following:
1. The character is a property of the class of an element.
2. Characters are unaffected by similarity transformations, so equiv-

alent representations—reducible or irreducible—have the same
characters.
3. As shown in Equations (5.10) and (5.11), the characters of a repre-

sentation indicate, through a straightforward calculation, whether
that representation is reducible or irreducible.
4. Characters of irreducible representations obey orthogonality the-

orems which, when interpreted in the context of character ta-
bles, correspond to the orthogonality relations of their rows and
columns.
5. According to the Decomposition Theorem, once the character ta-

ble of a group is known, the characters of any representation can
be decomposed into its irreducible components.
Chapter 6
Groups and Representations

in Quantum Mechanics
The universe is an enormous direct product of representations of sym-

metry groups.
—Steven Weinberg1
This chapter is devoted to applying the mathematical theory of groups

and representations which we have developed in the preceding chapters
to the quantum mechanical description of physical systems. The power
of applying group theory to quantum mechanics is that it provides a
framework for making exact statements about a physical system with
a knowledge only of the symmetry operations which leave its Hamil-
tonian invariant, the so-called “group of the Hamiltonian.” Moreover,
when we apply the machinery of groups to quantum mechanics, we find
that representations—and irreducible representations in particular—
arise quite naturally, as do related concepts such as the importance of
unitarity of representations and the connection between the symmetry
of a physical system and the degeneracy of its eigenstates. We will
follow the general sequence of the discussion in Sections 1.2 and 1.3,
1
Steven Weinberg, Sheldon Glashow, and Abdus Salam were awarded the 1979
Nobel Prize in Physics for their incorporation of the weak and electromagnetic
interactions into a single theory.
83
84 Groups and Representations in Quantum Mechanics
beginning with the group of the Hamiltonian, using this to establish the
symmetry properties of the eigenfunctions, and concluding with a dis-
cussion of selection rules, which demonstrates the power and economy
of using character tables. As a demonstration of the usefulness of these
constructions, we will prove Bloch’s theorem, the fundamental princi-
ple behind the properties of wavefunctions in periodic systems such as
electrons and phonons (the quanta of lattice vibrations) in single crys-
tals. The application of group theory to selection rules necessitates the
introduction of the “direct product” of matrices and groups, though
here, too, quantum mechanics provides a motivation for this concept.
6.1 The Group of the Hamiltonian

Recall the definition of a similarity transformation introduced in Section
3.3. Two matrices, or operators, A and B are related by a similarity
transformation generated by a matrix (or operator) R if
B = RAR−1 .
The quantity B is therefore the expression of A under the transforma-

tion R. Consider now a Hamiltonian H and its transformation by an
operation R
RHR−1 .
The Hamiltonian is said to be invariant under R if
H = RHR−1 , (6.1)
or, equivalently,
RH = HR . (6.2)
Thus the order in which H and the R are applied is immaterial, so H

and R commute: [H, R] = 0. In this case, R is said to be a symmetry
operation of the Hamiltonian.
Consider set of all symmetry operations of the Hamiltonian, which
we will denote by {Rα }. We now show that these operations form a
Groups and Representations in Quantum Mechanics 85
group. To demonstrate closure, we observe that if Rα and Rβ are two

operations which satisfy (6.1), then
Rα HRα−1 = Rα (Rβ HRβ−1 )Rα−1 = (Rα Rβ )H(Rα Rβ )−1 = H .
Thus, the product Rα Rβ = Rγ is also a symmetry operation of the
Hamiltonian. Associativity is clearly obeyed since these operations
represent transformations of coordinates and other variables of the
Hamiltonian.2 The unit element E corresponds to performing no op-
eration at all and the inverse Rα−1 of a symmetry operation Rα is the
application of the reverse operation to “undo” the original transfor-
mation. Thus, the set {Rα } forms a group, called the group of the
Hamiltonian.
6.2 Eigenfunctions and Representations

There are a number of consequences of the discussion in the preced-
ing section for the representations of the group of the Hamiltonian.
Consider an eigenfunction ϕ of a Hamiltonian H corresponding to the
eigenvalue E:
Hϕ = Eϕ .
We now apply a symmetry operation Rα to both sides of this equation,
Rα Hϕ = ERα ϕ ,
and use (6.2) to write
Rα Hϕ = HRα ϕ .
Thus, we have
H(Rα ϕ) = E(Rα ϕ) .
If the eigenvalue is nondegenerate, then Rα ϕ differs from ϕ by at most
a phase factor:
Rα ϕ = eiφα ϕ .
2
The associativity of linear operations is discussed by Wigner in Group Theory
(Academic, New York, 1959), p. 5.
The application of a second operation Rβ then produces

Rβ (Rα ϕ) = eiφβ eiφα ϕ . (6.3)
The left-hand side of this equation can also be written as
(Rβ Rα )ϕ = eiφβα ϕ , (6.4)
Equating the right-hand sides of Eqs. (6.3) and (6.4), yields
eiφβα = eiφβ eiφα ,
i.e., these phases preserve the multiplication table of the symmetry op-
erations. Thus, the repeated application of all of the Rα to ϕ generates
a one-dimensional representation of the group of the Hamiltonian.
The other case to consider occurs if the application of all of the
symmetry operations to ϕ produces ` distinct eigenfunctions. These
eigenfunctions are said to be `-fold degenerate. If these are the only
eigenfunctions which have energy E, this is said to be a normal degen-
eracy. If, however, there are other degenerate eigenfunctions which are
not captured by this procedure, this is said to be an accidental degen-
eracy. The term “accidental” refers to the fact that the degeneracy is
not due to symmetry. But an “accidental” degeneracy can also occur
because a symmetry is “hidden,” i.e., not immediately apparent, so the
group of the Hamiltonian is not complete. One well-known example of
this is the level degeneracy of the hydrogen atom.
For a normal degeneracy, there are orthonormal eigenfunctions ϕi ,
i = 1, 2, . . . , ` which, upon application of one of the symmetry op-
erations Rα are transformed into linear combinations of one another.
Thus, if we denote by ϕ the `-dimensional row vector
ϕ = (ϕ1 , ϕ2 , . . . , ϕ` ) ,
we can write
Rα ϕ = ϕΓ(Rα ) ,
where Γ(Rα ) is an ` × ` matrix. In terms of components, this equation
reads
X̀
Rα ϕ i = ϕk [Γ(Rα )]ki (6.5)
k=1
The successive application of operations Rα and Rβ then yields
X̀ X̀
Rβ Rα φi = Rβ ϕk [Γ(Rα )]ki = (Rβ ϕk )[Γ(Rα )]ki .
k=1 k=1
The operation Rβ ϕk can be written as in (6.5):
X̀
Rβ ϕ k = ϕj [Γ(Rβ )]jk .
j=1
Thus,
X̀ X̀
Rβ Rα φi = ϕj [Γ(Rβ )]jk [Γ(Rα )]ki
k=1 j=1
X̀ ½ X̀ ¾
= ϕj [Γ(Rβ )]jk [Γ(Rα )]ki . (6.6)
j=1 k=1
Alternatively, we can write

X̀
Rβ R α ϕ i = ϕj [Γ(Rβ Rα )]ji . (6.7)
j=1
By comparing (6.6) and (6.7) and using the orthonormality of the wave-
functions, we conclude that
Γ(Rβ Rα ) = Γ(Rβ )Γ(Rα ) ,
so the Γ(Ri ) form an `-dimensional representation of the group of the

Hamiltonian. Since the eigenfunctions can be made orthonormal, this
representation can always be taken to be unitary (Problem Set 8). We
will now show that this representation is also irreducible. We first
consider the effect of replacing the ϕi by a linear combination of these
functions, ψ = ϕU . Then the effect of operating with R on the ψ is
Rψ = RϕU = ϕΓU = ψU −1 ΓU ,
i.e., the representation with the transformed wavefunctions is related

by a similarity transformation to that with the original eigenfunctions,
i.e., the two representations are equivalent. Suppose that this represen-
tation is reducible. Then there is a unitary transformation of the ϕj
such that there are two or more subsets of the ψi that transform only
among one another under the symmetry operations of the Hamiltonian.
This implies that the application of the Ri to any eigenfunction gen-
erates eigenfunctions only in the same subset. The degeneracy of the
eigenfunctions in the other subset is therefore accidental, in contradic-
tion to our original assertion that the degeneracy is normal. Hence, the
representation obtained for a normal degeneracy is irreducible and the
corresponding eigenfunctions are said to generate, or form a basis for
this representation.
We can summarize the results of this section as follows:
• To each eigenvalue of a Hamiltonian there corresponds a unique
irreducible representation of the group of that Hamiltonian.
• The degeneracy of an eigenvalue is the dimensionality of this ir-
reducible representation. Thus, the dimensionalities of the irre-
ducible representations of a group are the possible degeneracies
of Hamiltonians with that symmetry group.
• Group theory provides “good quantum numbers,” i.e., labels cor-
responding irreducible representations to which eigenfunctions
belong.
• Although these statements have been shown for finite groups,
they are also valid for continuous groups.
6.3 Group Theory in Quantum Mechanics

The fact that eigenfunctions corresponding to an `-fold degenerate
eigenvalue form a basis for an `-dimensional irreducible representation
of the group of the Hamiltonian is one of the fundamental principles
behind the application of group theory to quantum mechanics. In this
section, we briefly describe the two main types of such applications,
namely, where group theory is used to obtain exact results, and where
it is used in conjunction with perturbation theory to obtain approximate
results.
6.3.1 Exact Results
One of the most elegant applications of group theory to quantum me-

chanics involves using the group of the Hamiltonian to determine the
(normal) degeneracies of the eigenstates, which are just the dimen-
sions of the irreducible representations. Because such a classification is
derived from the symmetry properties of the Hamiltonian, it can be ac-
complished without having to solve the Schrödinger equation. Among
the most historically important of such applications is the classifica-
tion of atomic spectral lines. The atomic Hamiltonian is comprised
of the sum of the kinetic energies of the electrons and their Coulomb
interactions, so an exact solution is impractical, even for few-electron
atoms such as He. Nevertheless, the spherical symmetry of the Hamil-
tonian enables the identification of the irreducible representations of
atomic states from which are derived the angular momentum addition
rules and multiplet structures. This will be explored further when we
discuss continuous groups. Another exact result is Bloch’s theorem,
which is the basis for many aspects of condensed matter physics. This
theorem uses the translational invariance of perfect periodic crystals
to determine the form of the eigenfunctions. As discussed in the next
section, Bloch’s theorem can be reduced to a statement about the (one-
dimensional) irreducible representations and basis functions of cyclic
groups.
The lowering of the symmetry of a Hamiltonian by a perturbation
can also be examined with group theory. In particular, the question of
whether the allowed degeneracies are affected by such a perturbation
can be addressed by examining the irreducible representations of the
groups of the original and perturbed Hamiltonians. Group theory can
address not only whether degeneracies can change (from the irreducible
representations of the two groups), but how irreducible representations
of the original group are related to those of the perturbed group. Typi-
cally, when the symmetry of a system is lowered, the dimensionalities of
the irreducible representations can also be lowered, resulting in a “split-
ting” of the original irreducible representations into lower-dimensional
irreducible representations of the group of the perturbed system.
Finally, on a somewhat more practical level, group theory can be
used to construct symmetrized linear combinations of basis functions
to diagonalize a Hamiltonian. Examples where this arises is the low-

ering of the symmetry of a system by a perturbation, where the basis
functions are the eigenfunctions of the original Hamiltonian, the bond-
ing within molecules, where the basis functions are localized around
the atomic sites within the molecule, and vibrations in molecules and
solids, where the basis functions describe the displacements of atoms.
These applications are discussed by Tinkham.3
6.3.2 Approximate Results

The most common application of group theory in approximate calcula-
tions involves the calculation of matrix elements in perturbation theory.
A typical example is involved adding to a Hamiltonian H0 and pertur-
bation H0 due to an electromagnetic field which causes transitions be-
tween the eigenstates of the original Hamiltonian. The transition rate
W is calculated from first-order time-dependent perturbation theory,
with the result known as Fermi’s Golden Rule:4
2π
W = %if |(i|H0 |f )|2 ,
h̄
where %if is called the “joint density of states,” which is a measure of the
number of initial and final states which are available for the excitation,
and (i|H0 |f ) is a matrix element of H0 between the initial and final
states. The application of group theory to this problem, which is the
subject of Section 6.6, involves determining when this matrix element
vanishes by reasons of symmetry.
6.4 Bloch’s Theorem∗

Bloch’s theorem is of central importance to many aspects of electrons,
phonons, and other excitations in crystalline solids. One of the main
results of this theorem, namely, the form of the eigenfunctions, can be
derived solely from group theory. We will work in one spatial dimension,
3
M. Tinkham, Group Theory and Quantum Mechanics (McGraw–Hill, New York,
1964)
4
L.I. Schiff, Quantum Mechanics 2nd edn (McGraw–Hill, New York, 1955)
but the discussion can be extended easily to higher dimensions. We

consider a one-dimensional crystal where the distance between nearest
neighbors is a and the number of repeat units is N (a large number for
a macroscopic solid). Since this system is finite, it has no translational
symmetry. However, by imposing a type of boundary condition known
as periodic, whereby the N th unit is identified with the first unit—
effectively forming a circle from this solid—we now have N discrete
symmetries. The Schrödinger equation for a particle of mass m moving
in the periodic potential of this system is
· ¸
h̄2 d2
− + V (x) ϕ = Eϕ ,
2m dx2
where V (x + a) = V (x).
6.4.1 The Group of the Hamiltonian

The translation of an eigenfunction by a will be denoted by Ra :
Ra ϕ(x) = ϕ(x + a) .
The basic properties of translations originate with the observation that

a translation through na,
Rna ϕ(x) = ϕ(x + na) ,
can be written as the n-fold product of Ra :
Ran ϕ(x) = Ra Ra · · · Ra ϕ(x) = ϕ(x + na) .

| {z }
n factors
Moreover, because of the periodic boundary conditions, we identify the
N th unit with the first, so
RaN = R0 ,
which means that no translation is carried out at all. Thus, the col-
lection of all the translations can be written as the powers of a single
element, Ra :
{Ra , Ra2 , . . . , RaN = E} , (6.8)

where E is the identity. This shows that the group of the Hamiltonian
is a cyclic group of order N . In particular, since cyclic groups are
Abelian, there are N one-dimensional irreducible representations of this
group, i.e., each eigenvalue is nondegenerate and labelled by one of these
irreducible representations.
6.4.2 Character Table and Irreducible Represen-

tations
Having identified the algebraic structure of the group of the Hamilto-
nian, we now construct the character table. Since RaN = E, and since
all irreducible representations are one-dimensional, the character for Ra
in each of these representations, χ(n) (Ra ) must obey this product:
h iN
χ(n) (Ra ) = 1.
The solutions to this equation are the N th roots of unity (cf. Problem
3, Problem Set 5):
χ(n) (Ra ) = e2πin/N , n = 0, 1, 2, . . . N − 1 .
The character table is constructed by choosing one of these values for

each irreducible representation and then determining the remaining en-
tries from the multiplication table of the group (since each irreducible
representation is one-dimensional). The resulting character table is:
{E} {Ra } {Ra2 } · · · {RaN −1 }

Γ1 1 1 1 ··· 1
N −1
Γ2 1 ω ω2 ··· ω
Γ3 1 ω2 ω4 · · · ω 2(N −1)
.. .. .. .. .. ..
. . . . . .
ΓN 1 ω N −1 ω 2N −2 ··· ω (N −1)2
where ω = e2πi/N . If we denote the eigenfunction corresponding to the

nth irreducible representation by ϕn , then applying Ra yields
Ra ϕn (x) = ω n−1 ϕn (x) = ϕn (x + a) .

Since the characters of this group are pure phases, the moduli of the
eigenfunctions are periodic functions:
|ϕn (x + a)|2 = |ϕn (x)|2 .
Thus, the most general form of the ϕn is
ϕn (x) = eiφn (x) un (x) , (6.9)
where φn (x) is a phase function, which we will determine below, and

the un have the periodicity of the lattice: un (x + a) = un (x). By com-
bining this form of the wavefunction with the transformation properties
required by the character table, we can write
Ram ϕn (x) = ω m(n−1) ϕn (x) = ω m(n−1) eiφn (x) un (x) .
Alternatively, by applying the same translation operation directly to

(6.9) yields
Ram ϕn (x) = ϕn (x + ma) = eiφn (x+ma) un (x) .
By equating these two ways of writing Ram ϕn (x), we find that their
phase changes must be equal. This, in turn, requires that the phase
function satisfies
2πm(n − 1)
φn (x + ma) = φn (x) + . (6.10)
N
Thus, φn is a linear function of m and, therefore, also of x + ma, since
φn is a function of only a single variable:
φn (x) = Ax + B ,
where A and B are constants to be determined. Upon substitution of

this expression into both sides of (6.10),
2πm(n − 1)
A(x + ma) + B = Ax + B + ,
N
and cancelling common factors, we obtain
φn (x) = kn x + B ,
where
2π(n − 1) 2π(n − 1)
kn = =
Na L
and L = N a is the size system. The wavefunction in (6.9) thereby

reduces to
ϕn (x) = eikn x un (x) ,
where we have absorbed the constant phase due to B into the definition
of un (x). This is called a Bloch function: a function un (x) with the
periodicity of the lattice modulated by a plane wave.5 This is one of
the two main results of Bloch’s theorem, the other being the existence
of energy gaps, which is beyond the scope of the discussion here.
6.5 Direct Products

The direct product provides a way of enlarging the number of elements
in a group while retaining the group properties. Direct products oc-
cur in several contexts. For example, if a Hamiltonian or Lagrangian
contains different types of coordinates, such as spatial coordinates for
different particles, or spatial and spin coordinates, then the symmetry
operations on the different coordinates commute with each other. If
there is a coupling between such degrees of freedom, such as particle
interactions or a spin-orbit interaction, then the direct product is re-
quired to determine the appropriate irreducible representations of the
resulting eigenstates. In this section, we develop the group theory as-
sociated with direct products and their representations. We will then
apply these concepts to selection rules in the following section.
5
A related issue which can be addressed by group theory is the nature of the
quantity h̄kn . Although it has units of momentum, it does not represent a true
momentum, but is called the “crystal momentum.” The true momentum h̄k la-
bels the irreducible representations of the translation group, which is a continuous
group and will be discussed in the next chapter. The discrete translations of a pe-
riodic potential form a subgroup of the full translation group, so the corresponding
irreducible representations cannot be labelled by momentum.
6.5.1 Direct Product of Groups

Consider two groups
Ga = {e, a2 , . . . , a|Ga | }, Gb = {e, b2 , . . . , b|Gb | } ,
such that all elements in Ga commute with all elements in Gb :
ai bj = bj ai ,
for i = 1, 2, . . . , |Ga | and j = 1, 2, . . . , |Gb |. We have defined a1 = e and
b1 = e. The direct product of Ga and Gb , denoted by Ga ⊗ Gb , is the set
containing all elements ai bj :
Ga ⊗ Gb = {e, a2 , . . . , a|Ga | , b2 , . . . , b|Gb | , . . . , ai bj , . . .} . (6.11)
As shown in Problem 3 of Problem Set 8, the direct product is a group
of order |Ga ||Gb |.
Example 6.1. Consider the symmetry operations on an equilateral
triangle that has a thickness, i.e., the triangle has become a “wedge.”
Thus, in addition to the original symmetry operations of the planar
equilateral triangle, there is now also a reflection plane σh . There are
now six vertices, which are labelled as in Example 2.1, except that
we now distinguish between points which lie above, {1+ , 2+ , 3+ }, and
below, {1− , 2− , 3− }, the reflection plane. The original six operations
do not transform points above and below the reflection plane into one
another. The reflection plane, on the other hand, only transforms cor-
responding points above and below the plane into one another. Hence,
the 6 operations of a planar triangle commute with σh .
The symmetry group of the equilateral wedge consists of the original
6 operations of a planar triangle, the horizontal reflection plane, and
their products. Since the set with elements {E, σh } forms a group (and
each element commutes with the symmetry operations of an equilateral
triangle), the appropriate group for the wedge is thereby obtained by
taking the direct product
{E, σv,1 , σv,2 , σv,3 , C3 , C32 } ⊗ {E, σh } .
The 12 elements of this group are
{E, σv,1 , σv,2 , σv,3 , C3 , C32 , σh , σh σv,1 , σh σv,2 , σh σv,3 , σh C3 , σh C32 } .
6.5.2 Direct Product of Matrices

The determination of the irreducible representations and the character
table of a direct product group does not require a separate new calcu-
lation of the type discussed in the preceding chapter. Instead, we can
utilize the irreducible representations of the two groups used to form
the direct to obtain these quantities. To carry out these operations
necessitates introducing the direct product of matrices.
The direct product C of two matrices A and B, written as A ⊗ B =
C, is defined in terms of matrix elements by
aij bkl = cik;jl . (6.12)
Note that the row and column labels of the matrix elements of C are
composite labels: the row label, ik, is obtained from the row labels of
the matrix elements of A and B and the column label, jl, is obtained
from the corresponding column labels. The matrices need not have the
same dimension and, in fact, need not even be square. However, since
we will apply direct products to construct group representations, we
will confine our discussion to square matrices. In this case, if A is an
n × n matrix and B is an m × m matrix, C is an mn × mn matrix.
Example 6.2. For matrices A and B given by

 
Ã ! b11 b12 b13
a11 a12  
A= , B=
 b21 b22 b23 
 ,
a21 a22
b31 b32 b33
the direct product C = A ⊗ B is
 
a11 b11 a11 b12 a11 b13 a12 b11 a12 b12 a12 b13
 

 a11 b21 a11 b22 a11 b23 a12 b21 a12 b22 a12 b23 

 
 
 a11 b31 a11 b32 a11 b33 a12 b31 a12 b32 a12 b33 
 
A⊗B =
a b
 .
 21 11 a21 b12 a21 b13 a22 b11 a22 b12 a22 b13 

 
 
 a21 b21 a21 b22 a21 b23 a22 b21 a22 b22 a22 b23 
 
 
a21 b31 a21 b32 a21 b33 a22 b31 a22 b32 a22 b33
Another way of writing the direct product that more clearly displays
its structure is
Ã !
a11 B a12 B
A⊗B = .
a21 B a22 B
The notion of a direct product arises quite naturally in quantum

mechanics if we consider the transformation properties of a product of
two eigenfunctions. Suppose we have two eigenfunctions ϕi and ϕi0 of
a Hamiltonian H which is invariant under some group of operations.
As in Section 6.2, the action of these operations on the eigenfunctions
of H is
X̀
Rϕi = ϕj Γji (R) ,
j=1
0
X
`
Rϕ =i0 ϕj 0 Γj 0 i0 (R) .
j 0 =1
The question we now ask is: how does the product ϕi ϕi0 transform under
the symmetry operations of the Hamiltonian? Given the transformation
properties of ϕi and ϕi0 noted above, we first observe that
R(ϕi ϕi0 ) = R(ϕi )R(ϕi0 ) .
In other words, since R represents a coordinate transformation, its ac-

tion on any function of the coordinates is to transform each occurrence
of the coordinates. Thus,
0
X̀ X
`
R(ϕi ϕ ) =
i0 ϕj ϕj 0 Γji (R)Γj 0 i0 (R)
j=1 j 0 =1
0
X̀ X
`
= ϕj ϕj 0 Γjj 0 ;ii0 (R) ,
j=1 j 0 =1
so ϕi ϕi0 transforms as the direct product of the irreducible representa-

tions associated with ϕi and ϕi0 .
6.5.3 Representations of Direct Product Groups

Determining the representations of direct products and the construction
of their character tables are based on the following theorem:
Theorem 6.1. The direct product of the representations of two groups

is a representation of the direct product of these groups.
Proof. A typical product of elements in the direct product group in

(6.11) is
(ap bq )(ap0 bq0 ) = (ap ap0 )(bq bq0 ) = ar br0 .
A representation of the direct product group must preserve the mul-
tiplication table. We will use the notation that the matrix A(ap bq )
corresponds to the element ap bq . Thus, we must require that
A(ap bq )A(ap0 bq0 ) = A(ar br0 ) .
By using the definition of the direct product of two matrices in Equation
(6.12), we can write this equation in terms of matrix elements as
h i X
A(ap bq )A(ap0 bq0 ) = A(ap bq )ik;mn A(ap0 bq0 )mn;jl
m,n | {z }| {z }
ik;jl
A(ap )im A(bq )kn (A(ap0 )mj A(bq0 )nl
µX ¶µX ¶
= A(ap )im A(ap0 )mj A(bq )]kn A(bq0 )nl
m n
| {z }| {z }
A(ap ap0 )ij A(bp bp0 )kl
= A(ar )ij A(br0 )kl
= A(ar br0 )ik;jl .

Thus, the direct product of the representations preserves the multipli-
cation table of the direct product group and, hence, is a representation
of this group.
In fact, as shown in Problem 4 of Problem Set 8, the direct product

of irreducible representations of two groups is an irreducible represen-
tation of the direct product of those groups. An additional convenient
feature of direct product groups is that the characters of its represen-

tations can be computed directly from the characters of the represen-
tations of the two groups forming the direct product. This statement
is based on the following theorem:
Theorem 6.2. If χ(ap ) and χ(bq ) are the characters of representations

of two groups Ga and Gb , the characters χ(ap bq ) of the representation
formed from the matrix direct product of these representations is
χ(ap bq ) = χ(ap )χ(bq ) .
Proof. From the definition of the direct product, a representation

of the direct product group is
A(ap bq )ij;kl = A(ap )ik A(bq )jl .
Taking the trace of both sides of this expression yields

X µX ¶µX ¶
A(ap bq )ij;ij = A(ap )ii A(bq )jl .
i,j i j
| {z } | {z }| {z }
χ(ap bq ) χ(ap ) χ(bq )
Thus,
χ(ap bq ) = χ(ap )χ(bq ) ,
which proves the theorem.
Since the characters are associated with a given class, the characters
for the classes of the direct product are computed from the characters
of the classes of the original groups whose elements contribute to each
class of the direct product. Moreover, the number of classes in the direct
product group is the product of the numbers of classes in the original
groups. This can be seen immediately from the equivalence classes in
the direct product group. Using the fact that elements belonging to
the different groups commute,
(ai bj )−1 (ak bl )(ai bj )−1 = (a−1 −1

i ak ai )(bj bl bj ) .
Thus, equivalence classes in the direct product group must be formed

from elements in equivalence classes in the original groups.
Example 6.3. Consider the direct product group of the equilateral

wedge in Example 6.1. The classes of S3 are (Example 2.9), in the
notation of Example 5.5,
{E}, {σv,1 , σv,2 , σv,3 }, {C3 , C32 } ,
and the classes of the group {E, σh } are
{E}, {σh } .
There are, therefore, six classes in the direct product group, which are
obtained by taking the products of elements in the original classes, as
discussed above:
{E}, {C3 , C32 }, {σv,1 , σv,2 , σv,3 } ,
{σh }, σh {C3 , C32 }, σh {σv,1 , σv,2 , σv,3 } .
The structure of the character table of the direct product group can
now be determined quite easily. We denote the character for the αth
class of the jth irreducible representation of group Ga by χjα (ap ). Simi-
larly, we denote the the character for the βth class of the lth irreducible
representation of group Ga by χlβ (bq ). Since the direct products of irre-
ducible representations of Ga and Gb are irreducible representations of
Ga ⊗ Gb (Problem 4, Problem Set 8), and since the classes of Ga ⊗ Gb
are formed from products of classes of Ga and Gb , the character table
of the direct product group has the form
χjl j l
αβ (ap bq ) = χα (ap )χβ (bq ) .
In other words, with the character tables regarded as square matrices,

the character table of the direct product group Ga × Gb is constructed
as a direct product of the character tables of Ga and Gb !
Example 6.4. For the direct product group in Example 6.3, the char-
acter tables of the original groups are
E 3σv 2C3
A1 1 1 1
A2 1 −1 1
E 2 0 −1
and
E σh
A1 1 1
A2 1 −1
The character table of the direct product group is, therefore, the
direct product of these tables (cf. Example 6.1):
E 3σv 2C3 σh 3σh σv 2σh C3

A1+ 1 1 1 1 1 1
A2+ 1 −1 1 1 −1 1
E+ 2 0 −1 2 0 −1
A1− 1 1 1 −1 −1 −1
A2− 1 −1 1 −1 1 −1
E− 2 0 −1 −2 0 1
where the superscript on the irreducible representation refers to the

parity under reflection through σh .
6.6 Selection Rules

One common application of direct products and their representations
is in the determination of selection rules. In this section, we will apply
the techniques developed in this chapter to determine the conditions
where symmetry requires that a matrix element vanishes.
6.6.1 Matrix Elements

As discussed in Section 6.3.2, the determination of selection rules is
based on using group theory to ascertain when the matrix element
Z
0
Mif = (i|H |f ) = ϕi (x)∗ H0 ϕf (x) dx (6.13)
vanishes by reasons of symmetry. In this matrix element, the initial

state transforms according to an irreducible representation Γ(i) and
the final state transforms according to an irreducible representation
Γ(f ) . It only remains to determine the transformation properties of
H0 . We do this by applying each of the operations of the group of
the original Hamiltonian H0 to the perturbation H0 . If we retain only
the distinct results of these operations we obtain, by construction, a
representation of the group of the Hamiltonian, which we denote by Γ0 .
This representation may be either reducible or irreducible, depending
on H0 and on the symmetry of H0 . If H0 has the same symmetry as H0 ,
then this procedure generates the identical representation. At the other
extreme, if H0 has none of the symmetry properties of H0 , then this
procedure generates a reducible representation whose dimensionality is
equal to the order of the group.
We now consider the symmetry properties under transformation of
the product H(x)ϕf (x). From the discussion in Section 6.5.2, we con-
clude that this quantity transforms as the direct product Γ0 ⊗ Γ(f ) .
Since quantities that transform to different irreducible irreducible rep-
resentations are orthogonal (Problem 6, Problem Set 8), the matrix
element (6.13) vanishes if this direct product is either not equal to Γ(i)
or, if it is reducible, does not include Γ(i) in its decomposition. We can
summarize this result in the following theorem:
Theorem 6.3. The matrix element

Z
(i|H0 |f ) = ϕi (x)∗ H0 ϕf (x) dx
vanishes if the irreducible representation Γ(i) corresponding to ϕi is not

included in the direct product Γ0 ⊗ Γ(f ) of the representations Γ0 and
Γ(f ) corresponding to H0 and ϕf , respectively.
It is important to note that this selection rule only provides a con-

dition that guarantees that the matrix element will vanish. It does not
guarantee that the matrix element will not vanish even if the conditions
of the theorem are fulfilled.
6.6.2 Dipole Selection Rules

As a scenario which illustrates the power of group theoretical methods,
suppose that H0 transforms as a vector, i.e., as (x, y, z). This situation
arises when the transitions described by Fermi’s Golden Rule (Section
6.3.2) are caused by an electromagnetic field. The form of H0 in the
presence of an electromagnetic potential A is obtained by making the
replacement6
p → p − eA
for the momentum in the Hamiltonian. For weak fields, this leads to a
perturbation of the form
e
H0 = p·A (6.14)
m
Since the electromagnetic is typically uniform, we can write the matrix
element Mif as
Mif ∼ (i|p|f ) · A
so the transformation properties of p = (px , py , pz ), which are clearly

those of a vector, determine the selection rules for electromagnetic tran-
sitions. These are called the dipole selection rules. The examination of
many properties of materials rely on the evaluation of dipole matrix
elements.
Example 6.6. Suppose the group of the Hamiltonian corresponds to

the symmetry operations of an equilateral triangle, i.e., C3v , the char-
acter table for which is (Example 5.5)
6
H. Goldstein, Classical Mechanics (Addison–Wesley, Reading, MA, 1950)
C3v E 3σv 2C3

A1 1 1 1
A2 1 −1 1
E 2 0 −1
To determine the dipole selection rules for this system, we must first
determine the transformation properties of a vector r = (x, y, z). We
take the x- and y-axes in the plane of the equilateral triangle and the
z-axis normal to this plane to form a right-handed coordinate system.
Applying each symmetry operation to r produces a reducible repre-
sentation because these operations are either rotations or reflections
through vertical planes. Thus, the z coordinate is invariant under ev-
ery symmetry operation of this group which, together with the fact that
an (x, y) basis generates the two-dimensional irreducible representation
E, yields
Γ0 = A1 ⊕ E
We must now calculate the characters associated with the direct

products of between Γ0 and each irreducible representation to determine
the allowed final states given the transformation properties of the initial
states. The characters for these direct products are shown below
Γ0 = A1 ⊕ E
C3v E 3σv 2C3
A1 1 1 1
A2 1 −1 1
E 2 0 −1
0
A1 ⊗ Γ 3 1 0
A2 ⊗ Γ0 3 −1 0
E ⊗ Γ0 6 0 0
Using the decomposition theorem, we find
A1 ⊗ Γ0 = A1 ⊕ E
A2 ⊗ Γ0 = A2 ⊕ E
E ⊗ Γ0 = A1 ⊕ A2 ⊕ 2E
Thus, if the initial state transforms as the identical representation A1 ,

the matrix element vanishes if the final state transforms as A2 . If the
initial state transforms as the “parity” representation A2 , the matrix
element vanishes if the final state transforms as A1 . Finally, there is no
symmetry restriction if the initial state transforms as the “coordinate”
representation E.
6.7 Summary
This chapter has demonstrated how the mathematics of groups and
their representations are used in quantum mechanics and, indeed, how
many of the structures introduced in the preceding chapters appear
quite naturally in this context. Apart from exact results, such as
Bloch’s theorem, we have focussed on the derivation of selection rules
induced by perturbations, and derived the principles behind dipole se-
lection rules. A detailed discussion of other applications of discrete
groups to quantum mechanical problems is described in the book by
Tinkham. Many of the proofs concerning the relation between quan-
tum mechanics and representations of the group of the Hamiltonian are
discussed by Wigner.
Chapter 7
Continuous Groups, Lie

Groups, and Lie Algebras
Zeno was concerned with three problems . . . These are the problem of
the infinitesimal, the infinite, and continuity . . .
—Bertrand Russell
The groups we have considered so far have been, in all but a few cases,
discrete and finite. Most of the central theorems for these groups and
their representations have relied on carrying out sums over the group
elements, often in conjunction with the Rearrangement Theorem (The-
orem 2.1). These results provide the basis for the application of groups
and representations to physical problems through the construction and
manipulation of character tables and the associated computations that
require direct sums, direct products, orthogonality and decomposition.
But the notion of symmetry transformations that are based on con-
tinuous quantities also occur naturally in physical applications. For
example, the Hamiltonian of a system with spherical symmetry (e.g.,
atoms and, in particular, the hydrogen atom) is invariant under all
three-dimensional rotations. To address the consequences of this in-
variance within the framework of group theory necessitates confronting
several issues that arise from the continuum of rotation angles. These
include defining what we mean by a “multiplication table,” determin-
ing how summations over group elements are carried out, and deriving
107
108 Continuous Groups, Lie Groups, and Lie Algebras
the appropriate re-statement of the Rearrangement Theorem to enable

the Great Orthogonality Theorem and its consequences to be obtained
for continuous groups. More generally, the existence of a continuum
of group elements, when combined with the requirement of analyticity,
introduces new structures associated with constructing differentials and
integrals of group elements. In effect, this represents an amalgamation
of group theory and analysis, so such groups are the natural objects
for describing the symmetry of analytic structures such as differential
equations and those that arise in differential geometry. In fact, the
introduction of analytic groups by Sophus Lie late in the 19th century
was motivated by the search for symmetries of differential equations.
In this chapter we begin our discussion about the modifications to
our development of groups and representations that are necessitated by
having a continuum of elements. We begin in the first section with the
definition of a continuous group and specialize to the most common
type of continuous group, the Lie group. We then introduce the idea
of an infinitesimal generator of a transformation, from which every
element can be obtained by repeated application. These generators
embody much of the structure of the group and, because there are a
finite number of these entities, are simpler to work with than the full
group. This leads naturally to the Lie algebra associated with a Lie
group. All of these concepts are illustrated with the groups of proper
rotations in two and three dimensions. The representation of these
groups, their character tables, and basis functions will be discussed in
the next chapter.
7.1 Continuous Groups

Consider a set of elements R that depend on a number of real continuous
parameters, R(a) ≡ R(a1 , a2 , . . . , ar ). These elements are said to form
a continuous group if they fulfill the requirements of a group (Section
2.1) and if there is some notion of ‘proximity’ or ‘continuity’ imposed
on the elements of the group in the sense that a small change in one
of the factors of a product produces a correspondingly small change in
their product. If the group elements depend on r parameters, this is
called an r-parameter continuous group.
Continuous Groups, Lie Groups, and Lie Algebras 109
In general terms, the requirements that a continuous set of elements

form a group are the same as those for discrete elements, namely, clo-
sure under multiplication, associativity, the existence of a unit, and
an inverse for every element. Consider first the multiplication of two
elements R(a) and R(b) to yield the product R(c):
R(c) = R(a)R(b) .
Then c must be a continuous real function f of a and b:
c = f (a, b) .
This defines the structure of the group in the same way as the multi-
plication table does for discrete groups. The associativity of the com-
position law,
h i i
R(a) R(b)R(c) = [R(a)R(b) R(c) ,
| {z } | {z }
R[f (b, c)] R[f (b, c)]
requires that
f [a, f (b, c)] = f [f (a, b), c] .
The existence of an identity element, which we denote by R(a0 ),
R(a0 )R(a) = R(a)R(a0 ) = R(a) ,
is expressed in terms of f as
f (a0 , a) = f (a, a0 ) = a .
The inverse of each element R(a), denoted by R(a0 ), produces
R(a0 )R(a) = R(a)R(a0 ) = R(a0 ) .
Therefore,
f (a0 , a) = f (a, a0 ) = a0 .
If f is an analytic function, i.e., a function with a convergent Tay-

lor series expansion within the domain defined by the parameters, the
resulting group is called an r-parameter Lie group, named after Sophus

Lie, a Norwegian mathematician who provided the foundations for such
groups.
Our interest in physical applications centers around transformations
on d-dimensional spaces. Examples include Euclidean spaces, where the
variables are spatial coordinates, Minkowski spaces, where the variables
are space-time coordinates, and spaces associated with internal degrees
of freedom, such as spin or isospin. In all cases, these are mappings of
the space onto itself and have the general form
x0i = fi (x1 , x2 , . . . , xd ; a1 , a2 , . . . , ar ), i = 1, 2, . . . , d .
If the fi are analytic, then this defines an r-parameter Lie group of

transformations.
Example 7.1 Consider the one-dimensional transformations
x0 = ax (7.1)
where a is an non-zero real number. This transformation corresponds

to stretching the real line by a factor a. The product of two such
operations, x00 = ax0 and x0 = bx is
x00 = ax0 = abx .
By writing x00 = cx, we have that
c = ab , (7.2)
so the multiplication of two transformations is described by an analytic

function that yields another transformation of the form in (7.1). This
operation is clearly associative, as well as Abelian, since the product
transformation corresponds to the multiplication of real numbers. This
product can also be used to determine the inverse of these transfor-
mations. By setting c = 1 in (7.2), so that x00 = x, the inverse of
(7.1) is seen to correspond to the transformation with a0 = a−1 , which
explains the requirement that a 6= 0. Finally, the identity is deter-
mined from x0 = x, which clearly corresponds to the transformation
with a = 1. Hence, the transformations defined in (7.1) form a one-

parameter Abelian Lie group.
Example 7.2 Now consider the one-dimensional transformations
x 0 = a 1 x + a2 , (7.3)
where again a1 is an non-zero real number. These transformations cor-

responds to the stretching of the real line by a factor a1 , as in the
preceding Example, and a translation by a2 . The product of two oper-
ations is
x00 = a1 x0 + a2 = a1 (b1 x + b2 ) + a2 = a1 b1 x + a1 b2 + a2 .
By writing x00 = c1 x + c2 , we have that
c 1 = a1 b 1 , c2 = a1 b2 + a2 ,
so the multiplication of two transformations is described by an analytic

function and yields another transformation of the form in (7.1). How-
ever, although this multiplication is associative, it is not Abelian, as
can be seen from the fact that the indices do not enter symmetrically
in c2 . By setting, c1 = c2 = 1, the inverse of (7.3) is the transformation
x a2
x0 = − .
a1 a1
The identity is again determined from x0 = x, which requires that
a1 = 1 and a2 = 0. Hence, the transformations in (7.3) form a two-
parameter (non-Abelian) Lie group.
7.2 Linear Transformation Groups

An important class of transformations is the group of linear transfor-
mations in d dimensions. These can be represented by d × d matrices.
For example, the most general such transformation in two dimensions
is x0 = Ax or, in matrix form,
Ã ! Ã !Ã !
x0 a11 a12 x
= , (7.4)
y0 a21 a22 y
where det(A) = a11 a22 − a12 a21 6= 0 (Example 2.4). With no further
restriction, and with the composition of two elements given by the usual
rules of matrix multiplication, these matrices form a four-parameter Lie
group. This Lie group is called the general linear group in two dimensions
and is denoted by GL(2,R), where the ‘R’ signifies that the entries
are real; the corresponding group with complex entries is denoted by
GL(2,C). In n dimensions, these transformation groups are denoted by
GL(n,R), or, with complex entries, by GL(n,C).
7.2.1 Orthogonal Groups

Many transformations in physical applications are required to preserve
length in the appropriate space. If that space is ordinary Euclidean
n-dimensional space, the restriction that lengths be preserved means
that
x02 02 02
1 + x2 + · · · + xn = x1 + x2 + · · · + xn .
2 2 2
(7.5)
The corresponding groups, which are subgroups of the general linear

group, are called orthogonal, and are denoted by O(n).
Consider the orthogonal group in two-dimensions, i.e., O(2), where
the coordinates are x and y. By substituting the general transformation
(7.4) into (7.5), we require that
x02 + y 02 = (a11 x + a12 y)2 + (a21 x + a22 y)2
= (a211 + a221 )x2 + 2(a11 a12 + a21 a22 )xy + (a212 + a222 )y 2 .
For the right-hand side of this equation to be equal to x2 + y 2 for all x

and y, we must set
a211 + a221 = 1, a11 a12 + a21 a22 = 0, a212 + a222 = 1 .
Thus, we have three conditions imposed on four parameters, leaving one

free parameter. These conditions can be used to establish the following
relation:
(a11 a22 − a12 a21 )2 = 1 .

Recognizing the quantity in parentheses as the determinant of the trans-

formation, this condition implies that
det(A) = ±1 .
If det(A) = 1, then the parity of the coordinate system is not changed

by the transformation; this corresponds to a proper rotation. If det(A) =
−1, then the parity of the coordinate system is changed by the transfor-
mation; this corresponds to an improper rotation. As we have already
seen, both types of transformations are important in physical applica-
tions, but we will first examine the proper rotations in two-dimensions.
This group is called the special orthogonal group in two dimensions and
is denoted by SO(2), where “special” signifies the restriction to proper
rotations. The parametrization of this group that we will use is
Ã !
cos ϕ − sin ϕ
R(ϕ) = , (7.6)
sin ϕ cos ϕ
where ϕ, the single parameter in this Lie group, is the rotation angle of
the transformation. As can easily be checked using the trigonometric
identities for the sum of two angles,
R(ϕ1 + ϕ2 ) = R(ϕ1 )R(ϕ2 ) , (7.7)
so this group is clearly Abelian.
7.3 Infinitesimal Generators

A construction of immense utility in the study of Lie groups, which was
introduced and extensively studied by Lie, is the infinitesimal generator.
The idea behind this is that instead of having to consider the group as
a whole, for many purposes it is sufficient to consider an infinitesimal
transformation around the identity. Any finite transformation can then
be constructed by the repeated application, or “integration,” of this
infinitesimal transformation.
7.3.1 Matrix Form of Generators

For SO(2), we first expand R(ϕ) in a Taylor series around the identity
(ϕ = 0):
¯ ¯
dR ¯¯ 1 d2 R ¯¯
R(ϕ) = R(0) + ¯ ϕ+ 2 ¯ ϕ2 + · · · . (7.8)
dϕ ϕ=0 2 dϕ ϕ=0
The coefficients in this series can be determined directly from (7.6), but
a more elegant solution may be found by first differentiating (7.7) with
respect to ϕ1 ,
d dR(ϕ1 )
R(ϕ1 + ϕ2 ) = R(ϕ2 ) , (7.9)
dϕ1 dϕ1
then setting ϕ1 = 0. Using the chain rule, the left-hand side of this
equation is
· ¸¯
dR(ϕ1 + ϕ2 ) d(ϕ1 + ϕ2 ) ¯¯ dR(ϕ2 )
¯ = ,
d(ϕ1 + ϕ2 ) dϕ1 ϕ1 =0 dϕ2
so Eq. (7.9) becomes
dR(ϕ)
= XR(ϕ) , (7.10)
dϕ
where
¯ Ã !
dR(ϕ1 ) ¯¯ 0 −1
= ≡X. (7.11)
dϕ1 ¯ϕ1 =0 1 0
Equations (7.10) and (7.11) allow us to determine all of the expan-
sions coefficients in (7.9). By setting ϕ = 0 in (7.10) and observing
that R(0) = I, where I is the 2 × 2 unit matrix,
Ã !
1 0
I= ,
0 1
we obtain
¯
dR(ϕ) ¯¯
=X. (7.12)
dϕ ¯ϕ=0
To determine the higher-order derivatives of R, we differentiate (7.10)

n times, and set ϕ = 0:
¯ ¯
dn R(ϕ) ¯¯ dn−1 R(ϕ) ¯¯
= X .
dϕn ¯ϕ=0 dϕn−1 ¯ϕ=0
This yields, in conjunction with (7.12),
¯
dn R(ϕ) ¯¯
= Xn .
dϕn ¯ϕ=0
Substituting this expression into the Taylor series in (7.8) allows us to
write
R(ϕ) = I + Xϕ + 12 X 2 ϕ2 + · · ·
∞
X 1
= (Xϕ)n
n=0 n!
≡ eϕX ,
where X 0 = I and the exponential of a matrix is defined by the Taylor
series expansion of the exponential. Thus, every rotation by a finite
angle can be obtain from the exponentiation of the matrix X, which
is called the infinitesimal generator of rotations. Since X 2 = I, it is a
straightforward matter to show directly from the Taylor series of the
exponential (Problem 4, Problem Set 9) that
Ã !
cos ϕ − sin ϕ
eϕX = I cos ϕ + X sin ϕ = .
sin ϕ cos ϕ
7.3.2 Operator Form of Generators

An alternative way of representing infinitesimal generators through
which connections with quantum mechanics can be directly made is
in terms of differential operators. To derive the operator associated
with infinitesimal rotations, we expand (7.6) to first order in dϕ to
obtain the transformation
x0 = x cos ϕ − y sin ϕ = x − y dϕ ,
y 0 = x sin ϕ + y cos ϕ = x dϕ + y .
An arbitrary differentiable function F (x, y) then transforms as
F (x0 , y 0 ) = F (x − y dϕ, x dϕ + y) .
Retaining terms to first order in dϕ on the right-hand side of this equa-

tion yields
µ ¶
0 0 ∂F ∂F
F (x , y ) = F (x, y) + −y +x dϕ .
∂x ∂y
Since F is an arbitrary function, we can associate infinitesimal rotations

with the operator
∂ ∂
X=x −y .
∂y ∂x
As we will see in the next section, this operator is proportional to the

z-component of the angular momentum operator.
The group SO(2) is simple enough that the full benefits of an in-
finitesimal generator are not readily apparent. We will see in the next
section, where we discuss SO(3), that the infinitesimal generators em-
body much of the structure of the full group.
7.4 SO(3)
The orthogonal group in three dimensions is comprised of the trans-
formations that leave the quantity x2 + y 2 + z 2 invariant. The group
GL(3,R) has 9 parameters, but the invariance of the length produces six
independent conditions, leaving three free parameters, so O(3) forms a
three-parameter Lie group. If we restrict ourselves to transformations
with unit determinant, we obtain the group of proper rotations in three
dimensions, SO(3).
There are three common ways to parametrize these rotations:
• Successive rotations about three mutually orthogonal fixed axes.
• Successive about the z-axis, about the new y-axis, and then about
the new z-axis. These are called Euler angles.
• The axis-angle representation, defined in terms of an axis whose

direction is specified by a unit vector (two parameters) and a
rotation about that axis (one parameter).
In this section, we will use the first of these parametrizations to

demonstrate some of the properties of SO(3). In the next chapter,
where we will develop the orthogonality relations for this group, the
axis-angle representation will prove more convenient.
7.4.1 Rotation Matrices

Consider first rotations about the z-axis by an angle ϕ3 :
 
cos ϕ3 − sin ϕ3 0
 
R3 (ϕ3 ) = 
 sin ϕ3 cos ϕ3 0
 .
0 0 1
The corresponding infinitesimal generator is calculated as in (7.11):

 
¯
0 −1 0
dR3 ¯¯  
X3 = ¯ =
1 0 0
.
dϕ3 ϕ3 =0
0 0 0
These results are essentially identical to those for SO(2). However,

for SO(3), we have rotations about two other axes to consider. For
rotations about the x-axes by an angle ϕ1 , the rotation matrix is
 
1 0 0
 
R1 (ϕ1 ) = 
0 cos ϕ1 − sin ϕ1 

0 sin ϕ1 cos ϕ1
and the corresponding generator is

 
¯
0 0 0
dR1 ¯¯  
X1 = ¯ =
0 0 −1 

dϕ1 ϕ1 =0
0 1 0
Finally, for rotations about the y-axis by an angle ϕ2 , we have

 
cos ϕ2 0 sin ϕ2
 
R2 (ϕ2 ) = 
 0 1 0 

− sin ϕ2 0 cos ϕ2
and the generator is
 
¯
0 0 1
dR2 ¯¯  
X2 = ¯ =
 0 0 0

dϕ2 ϕ2 =0
−1 0 0
As can be easily verified, the matrices Ri (ϕi ) do not commute, nor
do the Xi . However, the Xi have an additional useful property, namely
closure under commutation. As an example, consider the products
X1 X2 and X2 X1 :
    
0 0 0 0 0 1 0 0 0
    
X1 X2 = 
0 0 −1  
 0 0 0 
 = 1 0 0

0 1 0 −1 0 0 0 0 0
    
0 0 1 0 0 0 0 1 0
    
X2 X1 = 
 0 0 0 
0 0 −1  
 = 0 0 0

−1 0 0 0 1 0 0 0 0
Thus, the commutator of X1 and X2 , denoted by [X1 , X2 ] is given by
 
0 −1 0
 
[X1 , X2 ] ≡ X1 X2 − X2 X1 = 
1 0 0
 = X3
0 0 0
Similarly, we have
[X2 , X3 ] = X1 , [X3 , X1 ] = X2
The commutation relations among all of the Xi can be succinctly sum-

marized by introducing the anti-symmetric symbol εijk , which takes the
value 1 for a symmetric permutation of distinct i, j, and k, the value

−1 for an antisymmetric permutation, and is zero otherwise (i.e., if two
or more of i, j and k are equal). We can then write
[Xi , Xj ] = εijk Xk (7.13)
We will discuss the physical interpretation of these generators once we

obtain their operator form in the next section.
7.4.2 Operators for Infinitesimal Rotations

As was the case in Section 7.3, an alternative to the matrix represen-
tation of infinitesimal generators is in terms of differential operators.
Proceeding as in that section, we first write the general rotation as an
expansion to first order in each of the ϕi about the identity. This yields
the transformation matrix
    
x0 1 −ϕ3 ϕ2 x
 0   
 y  =  ϕ3 1 −ϕ1   
   y 
z0 −ϕ2 ϕ1 1 z
Substituting this coordinate transformation into a differentiable func-
tion F (x, y, z),
F (x0 , y 0 , z 0 ) = F (x − ϕ3 y + ϕ2 z, y + ϕ3 x − ϕ1 z, z − ϕ2 x + ϕ1 y)
and expanding the right-hand side to first order in the ϕi yields the
following expression:
F (x0 , y 0 , z 0 ) = F (x, y, z)
µ ¶ µ ¶ µ ¶
∂F ∂F ∂F ∂F ∂F ∂F
+ y− z ϕ1 + z− x ϕ2 + x− y ϕ3
∂z ∂y ∂x ∂z ∂y ∂x
Since F is an arbitrary differentiable function, we can identify the gen-
erators Xi of rotations about the coordinate axes from the coefficients
of the ϕi , i.e., with the differential operators
∂ ∂
X1 = y −z
∂z ∂y
∂ ∂
X2 = z −x (7.14)
∂x ∂z
∂ ∂
X3 = x −y
∂y ∂x
Notice that X3 is the operator obtained for SO(2) in Section 7.3. We
can now assign a physical interpretation to these operators by compar-
ing them with the vectors components of the angular operators in the
coordinate representation, obtained from the definition
L = r × p = r × (−ih̄∇)
Carrying out the cross-product yields the standard expressions

µ ¶
∂ ∂
L1 = −ih̄ y −z
∂z ∂y
µ ¶
∂ ∂
L2 = −ih̄ z −x (7.15)
∂x ∂z
µ ¶
∂ ∂
L3 = −ih̄ x −y
∂y ∂x
for the x, y, and z components of L, respectively. Thus, Li = −ih̄Xi ,
for i = 1, 2, 3, and (7.13) becomes
[Li , Lj ] = ih̄εijk Lk
which are the usual angular momentum commutation relations. There-

fore, we can associate the vector components of the angular momentum
operator with the generators of infinitesimal rotations about the cor-
responding axes. An analogous association exists between the vector
components of the coordinate representation of the linear momentum
operator and differential translation operations along the corresponding
directions.
7.4.3 The Algebra of Infinitesimal Generators

The commutation relations in (7.13) define a “product” of two gener-
ators which yields the third generator. Thus, the set of generators is
closed under this operation. Triple products, which determine whether

or not this composition law is associative, can be written in a concise
form using only the definition of the commutator, i.e., in the form of
an identity, without any explicit reference to the quantities involved.
Beginning with the triple product
h i
A, [B, C] = A[B, C] − [B, C]A
= ABC − ACB − BCA + CBA
We now add and subtract the quantities BAC and CAB on the right-
hand side of this equation and rearrange the resulting expression into
commutators to obtain
h i
A, [B, C] = ABC − ACB − BCA + CBA
+BAC − BAC + CAB − CAB
= −C(AB − BA) + (AB − BA)C
+B(AC − CA) − (AC − CA)B

h i h i
= − [A, B], C + [C, A], B
A simple rearrangement yields the Jacobi identity:

h i h i h i
A, [B, C] + B, [C, A] + C, [A, B] = 0
Notice that this identity has been obtained using only the definition of
the commutator.
For the infinitesimal generators of the rotation group, with the com-
mutator in (7.13), each of the terms in the Jacobi identity vanishes.
Thus,
h i h i
A, [B, C] = [A, B], C]
so the product of these generators is associative. In the more general

case, however, products of quantities defined in terms of a commutator
are not associative. The Lie algebra associated with the Lie group from
which the generators are obtained consists of quantities A, B, C, . . .

defined by
X
3 X
3 X
3
A= ak Xk , B= bk Xk , C= ck Xk , etc.
k=1 k=1 k=1
where the ak , bk , ck , . . . are real coefficients and from which linear com-
binations αA + βB with real α and β can be formed. The product is
given by
[A, B] = −[B, A]
and the Jacobi identity is, of course, satisfied.

The formal definition of a Lie algebra, which is an abstraction of
the properties just discussed, is as follows.
Definition. A Lie algebra is a vector space L over some field F 1

(typically the real or complex numbers) together with a binary opera-
tion [·, ·] : L × L → L, called the Lie bracket, which has the following
properties:
1. Bilinearity.
[ax + by, z] = a[x, z] + b[y, z]

[z, ax + by] = a[z, x] + b[z, y]
for all a and b in F and x, y, and z in L.
2. Jacobi identity.
h i h h i
[x, y], z + [z, x], y] + [y, z], x = 0
for all x, y, and z in L.

1
A field is an algebraic system of elements in which the operations of addition,
subtraction, multiplication, and division (except by zero) may be performed without
leaving the system (closure) and the associative, commutative, and distributive
rules, familiar from the arithmetic of ordinary numbers, hold. Examples of fields
are the rational numbers, the real numbers, and the complex numbers. The smallest
field has only two elements: {0, 1}. The concept of a field is useful for defining vectors
and matrices, whose components can be elements of any field.
3. Antisymmetry.
[x, y] = −[y, x]
for all x and y in L.
7.5 Summary
In this chapter, we have described the properties of Lie groups in
terms of specific examples, especially SO(2) and SO(3). With this
background, we can generalize our discussion to any Lie group. An
r-parameter Lie group of transformations on an n-dimensional space is
x0i = fi (x1 , x2 , . . . , xn ; a1 , a2 , . . . , ar )
where i = 1, 2, . . . , n. If only one of the r parameters ai is changed
from zero, while all the other parameters are held fixed, we obtain the
infinitesimal transformations Xi associated with this Lie group. These
can be expressed as differential operators by examining the effect of
these infinitesimal coordinate transformations on an arbitrary differen-
tiable function F :
Xn
∂F
dF = dxj
j=1 ∂xj
µ r ¯ ¶
X
n
∂F X ∂fj ¯¯
= ¯ dai
j=1 ∂xj i=1 ∂ai a=0
µX ¯ ¶
X
r n
∂fj ¯¯ ∂
= dai ¯ F
i=1 j=1 ∂ai a=0 ∂xj
We identify the differential operators Xi as the coefficient of dai in this

differential:
¯
Xn
∂fj ¯¯ ∂
Xi = ¯
j=1 ∂ai a=0 ∂xj
for r = 1, 2, . . . , r. These operators satisfy commutation relations of

the form
[Xi , Xj ] = ckij Xk
where the ckij are called structure constants and are a property of the
group. The commutator satisfies the Jacobi identity,
h i h i h i
Xi , [Xj , Xk ] + Xj , [Xk , Xi ] + Xk , [Xi , Xj ] = 0
which places a constraint on the structure constants. The commutator

and the Jacobi identity, together with the ability to form real linear
combinations of the Xi endows these generators with the structure of
an algebra, called the Lie algebra associated with the Lie group.
Chapter 8
Irreducible Representations
of SO(2) and SO(3)
The shortest path between two truths in the real domain passes through
the complex domain.
—Jacques Hadamard1
Some of the most useful aspects of group theory for applications to

physical problems stem from the orthogonality relations of characters
of irreducible representations. The widespread impact of these relations
stems from their role in constructing and resolving new representations
from direct products of irreducible representations. Direct products are
especially important in applications involving continuous groups, with
the construction of higher dimensional irreducible representations, the
derivation of angular momentum coupling rules, and the characteriza-
tion of families of elementary particles all relying on the formation and
decomposition of direct products.
Although the notion of an irreducible representation can be carried
over directly from our development of discrete groups through Schur’s
first lemma, a transcription of Schur’s second lemma and the Great
Orthogonality Theorem to the language of continuous groups requires
a separate discussion. This is because proving the latter two theorems
1
Quoted in The Mathematical Intelligencer 13(1), 1991.
125
126 Irreducible Representations of SO(2) and SO(3)
necessitates performing summations over group elements and invoking

the Rearrangement Theorem (Theorem 2.1). This theorem guarantees
the following equality
X X
f (g) = f (g 0 g) , (8.1)
g g
where the summation is over elements g in a group G, g 0 is any other el-

ement in G, and f is some function of the group elements. The crucial
point is that the same quantities appear on both sides of the equa-
tion; the only difference is the order of their appearance. To proceed
with the proofs of these theorems for continuous groups requires an
equality analogous to (8.1):
Z Z
f (R) dR = f (R0 R) dR , (8.2)
where R and R0 are the elements of a continuous group and f is some

function of these elements. To appreciate the issues involved, we write
the integral on the left-hand side of (8.2) as an integral over the pa-
rameters
Z Z
f (R) dR = f (R)g(R) da , (8.3)
where g(R) is the density of group elements in parameter space in the

neighborhood of R. The equality in (8.2) will hold provided that the
density of group elements is arranged so that the density of the points
R0 R is the same as that of the points R. Our task is to find the form of
g(R) which ensures this. A related concept that will arise is the notion
of the “order” of the continuous group as the volume of its elements in
the space defined by the parameters of the group.
This chapter is devoted to the characters and irreducible represen-
tations of SO(2) and SO(3). For SO(2), we will show that the density of
group elements is uniform across parameter space, so the density func-
tion reduces to a constant. But, for SO(3), we will need to carry out
the determination of the density function in (8.3) explicitly. This will
illustrate the general procedure which is applicable to any group. For
both SO(2) and SO(3), we will derive the basis functions for their irre-
ducible representations which will be used to obtain the corresponding
characters and to demonstrate their orthogonality
Irreducible Representations of SO(2) and SO(3) 127
8.1 Orthogonality of Characters for SO(2)

The structure of SO(2) is simple enough that many of the results ob-
tained for discrete groups can be taken over directly with little or no
modification. The basis of this claim is that the Rearrangement Theo-
rem for this group is, apart from the replacement of the sum by an in-
tegral, a direct transcription of that for discrete groups which, together
with this group being Abelian, renders the calculation of characters a
straightforward exercise.
8.1.1 The Rearrangement Theorem

We first show that the rearrangement theorem for this group is
Z 2π Z 2π
0
R(ϕ )R(ϕ) dϕ = R(ϕ) dϕ .
0 0
This implies that the weight function appearing in (8.3) is unity, i.e.,
the density of group elements is uniform in the space of the parameter
ϕ. Using the fact that R(ϕ0 )R(ϕ) = R(ϕ0 + ϕ), we have
Z 2π Z 2π
R(ϕ0 )R(ϕ) dϕ = R(ϕ0 + ϕ) dϕ .
0 0
We now introduce a new integration variable θ = ϕ0 + ϕ. Since ϕ0 is

fixed, we have that dϕ = dθ. Then, making the appropriate changes
in the upper and lower limits of integration, and using the fact that
R(ϕ + 2π) = R(ϕ), yields
Z 2π Z ϕ0 +2π
R(ϕ0 + ϕ) dϕ = R(θ) dθ
0 ϕ0
Z 2π Z ϕ0 +2π
= R(θ) dθ + R(θ) dθ
ϕ0 2π
Z 2π Z ϕ0
= R(θ) dθ + R(θ) dθ
ϕ0 0
Z 2π
= R(θ) dθ ,
0
which verifies our assertion.

8.1.2 Characters of Irreducible Representations

We can now use Schur’s first lemma for SO(2). Since SO(2) is an
Abelian group, this first lemma requires all of the irreducible represen-
tations to be one-dimensional (cf. Problem 4, Problem Set 5). Thus,
every element is in a class by itself and the characters must satisfy the
same multiplication rules as the elements of the group:
χ(ϕ)χ(ϕ0 ) = χ(ϕ + ϕ0 ) . (8.4)
The character corresponding to the unit element, χ(0), which must

map onto the identity for ordinary multiplication, is clearly unity for
all irreducible representations:
χ(0) = 1 . (8.5)
Finally, we require the irreducible representations to be single-valued,

i.e., an increase in the rotation angle by 2π does not change the effect
of the rotation. Thus,
χ(ϕ + 2π) = χ(ϕ) . (8.6)
The three conditions in (8.4), (8.5), and (8.6) are sufficient to determine
the characters of all of the irreducible representations of SO(2).
We will proceed by writing Eq. (8.4) as a differential equation and
using (8.5) as an “initial condition” and (8.6) as a “boundary condi-
tion.” In (8.4), we set ϕ0 = dϕ,
χ(ϕ)χ(dϕ) = χ(ϕ + dϕ) ,
and expand both sides of this equation to first order in dϕ:

" ¯ #
dχ ¯¯ dχ
χ(ϕ) χ(0) + ¯ dϕ = χ(ϕ) + dϕ .
dϕ ϕ=0 dϕ
Then, using (8.5) and cancelling common terms, this equation reduces
to a first-order ordinary differential equation for χ(ϕ):
dχ
= χ00 χ(ϕ) ,
dϕ
where χ00 = χ0 (0) is to be determined. The general solution to this

equation is
0
χ(ϕ) = A eχ0 ϕ ,
where A is a constant of integration which is also to be determined.

In fact, by setting ϕ = 0 and invoking (8.5), we see that A = 1. The
requirement (8.6) of single-valuedness, when applied to this solution,
yields the condition that
0 0
eχ0 (ϕ+2π) = eχ0 ϕ ,
or,
0
e2πχ0 = 1 .
The most general solution of this equation is χ00 = im, where i2 = −1

and m is any integer. This produces an infinite sequence of characters
of the irreducible representations of SO(2):
χ(m) (ϕ) = eimϕ , m = . . . , −2, −1, 0, 1, 2, . . . (8.7)
The identical representation corresponds to m = 0. In contrast to the

case of finite groups, we see that SO(2) has an infinite set of irreducible
representations, albeit one that is countably infinite.
8.1.3 Orthogonality Relations

Having determined the characters for SO(2), we can now examine the
validity of the orthogonality theorems for characters which were dis-
cussed for discrete groups in Theorem 5.1. We proceed heuristically
and begin by observing that the exponential functions in (8.7) are or-
thogonal over the interval 0 ≤ ϕ < 2π:
Z 2π 0
ei(m −m)ϕ dϕ = 2πδm,m0 .
0
By writing this relation as

Z 2π 0
χ(m)∗ (ϕ)χ(m ) (ϕ) dϕ = 2πδm,m0 , (8.8)
0
we obtain an orthogonality relation of the form in Eq. (5.4), once we

identify the “order” of SO(2) as the quantity
Z 2π
dϕ = 2π .
0
This is the “volume” of the group in the space of the parameter ϕ,

which lies in the range 0 ≤ ϕ < 2π, given that the density function is
unity, according to the discussion in thew preceding section. Note that
the integration over ϕ is effectively a sum over classes.
Example 8.1. Consider the representation of SO(2) derived in Section

7.2:
Ã !
cos ϕ − sin ϕ
R(ϕ) = . (8.9)
sin ϕ cos ϕ
Since SO(2) is an Abelian group, this representation must be reducible.

We can decompose this representation into its irreducible components
by using either the analogue of the Decomposition Theorem (Section
5.3) for continuous groups or, more directly, by using identities between
complex exponential and trigonometric functions:
χ(ϕ) ≡ tr[R(ϕ)]
= 2 cos ϕ
= eiϕ + e−iϕ .
A comparison with (8.7) yields
χ(ϕ) = χ(1) (ϕ) + χ(−1) (ϕ) ,
so the representation in (8.9) is a direct sum of the irreducible repre-

sentations corresponding to m = 1 and m = −1.2
2
This example illustrates the importance of the field used in the entries of the
matrices for SO(2). If we are restricted to real entries, then the representation in
(8.9) is irreducible. But, if the entries are complex, then this example shows that
this representation is reducible.
8.2 Basis Functions for Irreducible Rep-

resentations
We were able to determine the characters for all of the irreducible rep-
resentations of SO(2) without any knowledge of the representations
themselves. But this is not the typical case for continuous groups. We
will see, for example, when determining the characters for SO(3) that
we will be required to construct explicit representations of rotations
corresponding to different classes. The action of these rotations on the
basis functions will determine the representation of that class and the
character will be calculated directly from this representation. As an
introduction to that discussion, in this section we will determine the
basis functions of the irreducible representations of SO(2).
We begin by calculating the eigenvalues of the matrix in (8.9) from
det(R − λI) = 0:
¯ ¯
¯ cos ϕ − λ − sin ϕ ¯¯
¯
¯ ¯ = (cos ϕ − λ)2 + sin2 ϕ
¯ sin ϕ cos ϕ − λ ¯
= λ2 − 2λ cos ϕ + 1 = 0 .
Solving for λ yields
λ = cos ϕ ± i sin ϕ = e±iϕ . (8.10)
The corresponding eigenvectors are proportional to x ± iy. Thus, op-

erating on these eigenvectors with R(ϕ) (see below) generates the irre-
ducible representations corresponding to m = 1 and m = −1 in (8.7),
i.e., the characters χ(1) (ϕ) and χ(−1) (ϕ).
Obtaining the basis functions for the other irreducible representa-
tions of SO(2) is now a matter of taking appropriate direct products,
since
0 0
χ(m) (ϕ)χ(m ) (ϕ) = χ(m+m ) (ϕ) .
In particular, the m-fold products (x ± iy)m generate irreducible repre-

sentations for the m-fold direct product, as discussed in Sec. 6.5. This
can be verified directly from the transformation (8.9) applied to x and

y:
x0 = x cos ϕ − y sin ϕ ,
y 0 = x sin ϕ + y cos ϕ .
Then,
h im
(x0 ± iy 0 )m = x cos ϕ − y sin ϕ ± i(x sin ϕ + y cos ϕ)
h im
= x(cos ϕ ± i sin ϕ) ± iy(cos ϕ ± i sin ϕ)
h im
= (x ± iy) e±iϕ
= (x ± iy)m e±imϕ .
Therefore, we can now complete the character table for SO(2), including
the basis functions which generate the irreducible representations:
SO(2) E R(ϕ)
Γ±m : (x ± iy)m 1 e±imϕ
We note for future reference that the basis functions (x ± iy)m could
have been derived in a completely different manner. Consider Laplace’s
equation in two dimensions:
∂2u ∂2u
+ = 0.
∂x2 ∂y 2
This equation is invariant under all the elements of SO(2), as can be
easily verified. The general solution to this equation is
u(x, y) = F (x + iy) + G(x − iy) ,
where F and G are arbitrary functions. Thus, if we are interested

in solutions which are homogeneous polynomials of degree m, we can
choose in turn solutions with F (s) = sm and G(s) = 0 and then with
F (s) = 0 and G(s) = sm . We thereby obtain the expressions
u(x, y) = (x ± iy)m (8.11)
as solutions of Laplace’s equations which are also the basis functions of

the irreducible representations of SO(2). These functions are the ana-
logues in two dimensions of spherical harmonics, which are the solutions
of Laplace’s equations in three dimensions. These will be discussed later
in this chapter.
8.3 Axis–Angle Representation of Proper

Rotations in Three Dimensions
The three most common parametrizations of proper rotations were dis-
cussed in Section 7.4. For the purposes of obtaining the orthogonal-
ity relations for the characters of SO(3), the representation in terms
of a fixed axis about which a rotation is carried out—the axis–angle
representation—is the most convenient. We begin this section by show-
ing how this representation emerges naturally from the basic properties
of orthogonal matrices.
8.3.1 Eigenvalues of Orthogonal Matrices

Let A be any proper rotation matrix in three dimensions. Denoting the
eigenvalues of A by λ1 , λ2 , and λ3 , and the corresponding eigenvalues
by u1 , u2 , and u3 , we then have
Aui = λi ui
for i = 1, 2, 3. We can also form the adjoint of each equation:
u†i At = λ∗ u†i .
These eigenvalue equations imply
u†i ui = u†i At Aui = |λ2i |u†i ui ,

which shows that |λ2i | = 1, i.e., that the modulus of every eigenvalue
of an orthogonal matrix is unity [cf. (8.10)]. The most general form
of such a quantity is a complex number of the form eiϕ for some angle
ϕ. But these eigenvalues are also the roots of the characteristic equa-
tion det(A − λI) = 0 so, according to the Fundamental Theorem of
Algebra,3 if they are complex, they must occur in complex conjugate
pairs (because the coefficients of this polynomial, which are obtained
from the entries of A, are real). Hence, the most general form of the
eigenvalues of an orthogonal matrix in three dimensions is
λ1 = 1, λ2 = eiϕ , λ3 = e−iϕ . (8.12)
The eigenvector corresponding to λ1 = 1, which is unaffected by the

action of A, thereby defines the axis about which the rotation is taken.
The quantity ϕ appearing in λ2 and λ3 defines the angle of rotation
about this axis.
8.3.2 The Axis and Angle of an Orthogonal Matrix

In this section, we show how the axis and angle of an orthogonal matrix
can be determined from its matrix elements. We take the axis of the
rotation to be a unit vector n, which is the eigenvector corresponding
to the eigenvalue of unity:
An = n . (8.13)
This equation and the orthogonality of A (AAt = At A = 1) enables us

to write
At n = At An = n . (8.14)
Subtracting (8.14) from (8.13) yields
(A − At )n = 0 .
3
K. Hoffman and R. Kunze, Linear Algebra 2nd edn (Prentice–Hall, Englewood
Cliffs, NJ, 1971), p. 138.
In terms of the matrix elements aij of A and the components ni of n,

we then have
(a12 − a21 )n2 + (a13 − a31 )n3 = 0 ,
(a21 − a12 )n1 + (a23 − a32 )n3 = 0 ,
(a31 − a13 )n1 + (a32 − a23 )n2 = 0 .
Notice that these equations involve only the off-diagonal elements of A.

The solution of these equations yield the relations
n2 a31 − a13 n3 a12 − a21
= , = , (8.15)
n1 a23 − a32 n1 a23 − a32
which, when combined with the normalization condition
n·n = n21 + n22 + n23 = 1
determines n uniquely.
The angle of the rotation can be determined from the invariance of
the trace of A under similarity transformations. Noting that the trace
is the sum of the eigenvalues, and using (8.12), we have
a11 + a22 + a33 = 1 + eiϕ + e−iϕ = 1 + 2 cos ϕ , (8.16)
so ϕ is determined only by the diagonal elements of A.
8.3.3 Normal Form of an Orthogonal Matrix

We conclude this section by deriving the form of a rotation matrix in an
orthogonal coordinate system which naturally manifests the axis and
angle. The diagonal form of a rotation matrix is clearly given by
 
1 0 0
 
Λ=
0 eiϕ 0 
.
0 0 eiϕ
The eigenvector n corresponding to λ1 = 1 is the axis of the rotation
and can always be chosen to be real. However, the eigenvectors of λ2 =
eiϕ and λ3 = e−iϕ are inherently complex quantities. An orthonormal

set can be chosen as
√ √
n2 = 12 2(0, 1, i), n2 = 12 2(0, 1, −i) ,
respectively. Since we are interested in transformations of real coor-

dinates, we must perform a unitary transformation from this complex
basis to a real orthogonal basis, in which case our rotation matrix Λ will
no longer be diagonal. The required unitary matrix which accomplishes
this is
 
1 0 0
 √ √ 
U =
0
1
2 1
i 2
 .
 2
√
2
√ 
0 1
2
2 −2i 2
1
Thus,
 
1 0 0
 
R = U −1 ΛU = 
0 cos ϕ − sin ϕ 
. (8.17)
0 sin ϕ cos ϕ
When expressed in this basis, the rotation matrix clearly displays the
axis of rotation through the entry R11 = 1, and the angle of rotation
through a 2×2 rotational submatrix in a plane perpendicular to this
axis.
8.3.4 Parameter Space for SO(3)

The axis-angle representation of three-dimensional rotations provides
a convenient parametrization of all elements of SO(3). We have seen
that every element of SO(3) can be represented by a unit vector corre-
sponding to the rotation axis and a scalar corresponding to the rotation
angle. Thus, consider the space defined by the three quantities
(n1 ϕ, n2 ϕ, n3 ϕ) , (8.18)
where n21 + n22 + n23 = 1. Every direction is represented by a point on

the unit sphere. Thus, defining an azimuthal angle φ and a polar angle
B D
A
E
C
Figure 8.1: Two-dimensional representation of the parameter space of SO(3)

as the interior of a sphere of radius π. The point A represents a rotation
whose axis is along the direction OA and whose angle is the length of OA.
The points at A, B and C correspond to rotations with the same angle but
about axis along different directions. This defines the classes of SO(3). The
diametrically opposite points at D and E correspond to the same operation.
θ according to the usual conventions in spherical polar coordinates, the

parameter space of SO(3) can be represented as
(ϕ cos φ sin θ, ϕ sin φ sin θ, ϕ cos θ) , (8.19)
where
0 ≤ ϕ ≤ π, 0 ≤ φ ≤ 2π, 0 ≤ θ ≤ π.
We can now see directly that this parameter space corresponds to the
interior of a sphere of radius π (Fig. 8.1). For every point within the
sphere, there is a unique assignment to an element of SO(3): the direc-
tion from the radius to the point corresponds to the direction of the
rotation axis and the distance from the point to the origin represents
the rotation angle. Two diametrically opposed points on the surface of
the sphere (ϕ = π) correspond to the same rotation, since a rotation
by π about n is the same as a rotation by −π about this axis which,
in turn, is the same as a rotation by π about −n (whatever the sense
of rotation).
Another useful feature of the axis-angle parametrization is the rep-

resentation of classes of SO(3). Consider two elements of SO(3) which
have the same angle of rotation ϕ but about different axes n and n0 . We
denote these operations by R(n, ϕ) and R(n0 , ϕ). Let U (n, n0 ) denote
the rotation of n into n0 . The inverse of this operation then rotates n0
into n. The relationship between R(n, ϕ), R(n0 , ϕ), and U (n, n0 ) is,
therefore,
h i−1
R(n, ϕ) = U (n, n0 ) R(n0 , ϕ)U (n, n0 ) ,
i.e., R(n, ϕ) and R(n0 , ϕ) are related by a similarity transformation

and, therefore, belong to the same equivalence class. Referring to
Fig. 8.1, equivalence classes of SO(3) correspond to operations which
lie on the same radius. Thus, a summation over the classes of SO(3)
is equivalent to a sum over spherical shells.
8.4 Orthogonality Relations for SO(3)

The axis-angle representation of rotations provides, in addition to a
conceptual simplicity of elements of SO(3) in parameter space, a natural
framework within which to discuss the integration over the elements
of SO(3) and thereby to obtain the Rearrangement Theorem for this
group. In this section, we derive the density function g in (8.3) for
this group and then use this to identify the appropriate form of the
orthogonality relations for characters
8.4.1 The Density Function

As discussed in the introduction, one of the basic quantities of interest
for continuous groups is the density of group elements as a function
of position in parameter space. To determine this function for SO(3),
we first consider the elements in the neighborhood of the identity and
then examine the behavior of these points under an arbitrary element
of SO(3). Referring to the discussion in Section 7.4.2, these elements
correspond to rotations by infinitesimal angles ϕ1 , ϕ2 , and ϕ3 about
each of the three coordinate axes. The rotation matrix associated with
this transformation is
 
1 −ϕ3 ϕ2
 
δR = 
 ϕ3 1 −ϕ1 
 .
−ϕ2 ϕ1 1
The identity of SO(3) corresponds to the origin in the three-dimensional
parameter space, ϕ1 = ϕ2 = ϕ3 = 0, and is indicated by the point
O in Fig. 8.1. For infinitesimal rotation angles, the parameter space
spanned by δR is associated with an infinitesimal volume element in
the neighborhood of the origin.
We now follow the infinitesimal transformation δR by a finite trans-
formation R(n, ϕ), i.e., we form the product R δR. This generates a
volume element in the neighborhood of R and the product R δR can be
viewed as transformation of the volume near the origin to that near R.
The Jacobian of this transformation is the relative change of volume
near the origin to that near R or, equivalently, is the relative change
of the density of operations near the origin to that near R. According
to the discussion in the introduction, this is the information required
from the density function for SO(3).
We have already seen that equivalence classes of SO(3) are com-
prised of all rotations with the same rotation angle, regardless of the
direction of the rotation axis. Thus, the density function is expected
to depend only on ϕ. Referring to Fig. 8.1, this means that the density
of elements depends only on the “radial” distance from the origin, not
on the direction, so we can choose R in accordance with this at our
convenience. Therefore, in constructing the matrix R δR, we will use
for R a matrix of the form in (8.17). Thus,
  
1 0 0 1 −ϕ3 ϕ2
  
R δR = 
0 cos ϕ − sin ϕ  
  ϕ3 1 −ϕ1 

0 sin ϕ cos ϕ −ϕ2 ϕ1 1
 
1 −ϕ3 ϕ2
 
= 
 ϕ3 cos ϕ + ϕ2 sin ϕ cos ϕ − ϕ1 sin ϕ −ϕ1 cos ϕ − sin ϕ  .
ϕ3 sin ϕ − ϕ2 cos ϕ sin ϕ − ϕ1 cos ϕ −ϕ1 sin ϕ + cos ϕ
We can now use (8.15) and (8.16) to determine the axis n0 and angle
ϕ0 of this product. The angle is determined from
1 + 2 cos ϕ0 = 1 + 2 cos ϕ − 2ϕ1 sin ϕ ,
which, upon cancelling common factors, becomes
cos ϕ0 = cos ϕ − ϕ1 sin ϕ .
Using the standard trigonometric formula for the cosine of a sum, we
find, to first order in ϕ1 , that
ϕ0 = ϕ + ϕ1 .
The unnormalized components of n0 are determined from (8.15) to be
n01 = −2ϕ1 cos ϕ − 2 sin ϕ ,
n02 = ϕ3 sin ϕ − ϕ2 (1 + cos ϕ) ,
n03 = −ϕ2 sin ϕ − ϕ3 (1 + cos ϕ) .

To normalize the axis, we first determine the length based on these
components. To first order in the ϕi , we find
|n0 | = 2ϕ1 cos ϕ + 2 sin ϕ .
Thus, the components of the normalized rotation axis of R δR are
n01 = 1 ,
1 + cos ϕ
n02 = − 12 ϕ3 + 12 ϕ2 ,
sin ϕ
1 + cos ϕ
n03 = 12 ϕ2 + 12 ϕ3 .
sin ϕ
Expressed in terms of the parametrization in (8.18), R δR is given by
(n01 ϕ0 , n02 ϕ0 , n03 ϕ0 ) =
( Ã ! Ã !)
1 + cos ϕ 1 1 + cos ϕ
ϕ+ ϕ1 , 12 ϕ − ϕ3 + ϕ2 , 2 ϕ ϕ2 + ϕ3 .
sin ϕ sin ϕ
This defines the transformation from the neighborhood of the origin to

the neighborhood near R δR. The Jacobian J of this transformation,
obtained from
¯ ¯
¯ ∂(n0 ϕ0 ) ¯
¯ i ¯
J = det ¯ ¯, (8.20)
¯ ∂ϕj ¯
determines how the density of elements of SO(3) near the origin is

transformed to the density of points near R. By taking the derivatives
in (8.20) to obtain the entries (i, j) in the Jacobian matrix, we obtain
¯ ¯
¯1 0 0 ¯
¯ ¯
¯ ¯
¯ 1 + cos ϕ ¯
¯ ¯
−2ϕ1 ϕ2
J = ¯¯ ¯
0 ϕ
2 sin ϕ ¯= .
¯ ¯ 2(1 − cos ϕ)
¯ ¯
¯ 1 + cos ϕ ¯¯
¯0 1
ϕ ϕ
¯ 2
2 sin ϕ ¯
Notice that
lim J = 1 ,
ϕ→0
so that the normalization of the volume in parameter space is such

that the volume near the unit element is unity. Hence, the density
of elements in parameter space is the reciprocal of J, so the density
function g in (8.3) is
2
g(ϕ) = (1 − cos ϕ) . (8.21)
ϕ2
8.4.2 Integrals in Parameter Space

The density function in (8.21) now permits us to carry out integral over
the group. Thus, for a function F (ϕ, Ω), where Ω denotes the angular
variables in the parametrization in (8.19), we have
ZZ
g(ϕ)F (ϕ, Ω)ϕ2 dϕ dΩ ,
where we have used the usual volume element for spherical polar coor-
dinates. Using the density function in (8.21), this integral becomes
ZZ
2(1 − cos ϕ)F (ϕ, Ω)dϕ dΩ .
We can now establish the orthogonality relation for characters. If

we denote the characters for two irreducible representations of SO(3)
by χµ (ϕ) and χν (ϕ), then we have
ZZ ZZ
2(1 − cos ϕ)χ (ϕ)χ (ϕ)dϕ dΩ = δµ,ν
µ ν
2(1 − cos ϕ)dϕ dΩ .
The integral on the right-hand side of this equation, which has the
value 8π 2 , corresponds to the volume of SO(3) in parameter space. The
integral over the angular variables on the left-hand side yields 2 × 4π,
so cancelling common factors, we obtain
Z π
(1 − cos ϕ)χµ (ϕ)χν (ϕ) dϕ = πδµ,ν . (8.22)
0
This is the orthogonality relation for characters of SO(3).
8.5 Irreducible Representations and Char-

acters for SO(3)
For SO(2), we were able to determine the characters of the irreducible
representations directly, i.e., without having to determine the basis
functions of these representations. The structure of SO(3), however,
does not allow for such a simple procedure, so we must determine the
basis functions from the outset.
8.5.1 Spherical Harmonics

We proceed as in Section 8.2 by determining the homogeneous polyno-
mial solutions of Laplace’s equation, now in three dimensions:
∂ 2u ∂ 2u ∂2u
+ + = 0.
∂x2 ∂y 2 ∂z 2
We seek solutions of the form

X
u(x, y, z) = cab (x + iy)a (x − iy)b z `−a−b ,
a,b
which are homogeneous polynomials of degree `. In spherical polar

coordinates,
x = r cos φ sin θ, y = r sin φ sin θ, z = r cos θ ,
where 0 ≤ φ < 2π and 0 ≤ θ ≤ π, these polynomial solutions transform

to
X
u(r, θ, φ) = cab r` sina+b θ cos`−a−b θ ei(a−b)φ . (8.23)
a,b
Alternatively, Laplace’s equation in spherical polar coordinates is

µ ¶ µ ¶
1 ∂ 2 ∂u 1 ∂ ∂u 1 ∂ 2u
r + sin θ + = 0.
r2 ∂r ∂r r2 sin θ ∂θ ∂θ r2 sin2 θ ∂φ2
When the method of separation of variables is used to find solutions

of this equation of the form u(r, θ, φ) = R(r)Θ(θ)Φ(φ), the stipulation
that the solution be single-valued with respect changes in φ by 2π,
u(r, θ, φ + 2π) = u(r, θ, φ) ,
requires that
Φ(φ) ∝ eimφ ,
where m is an integer. Comparing this expression with the correspond-

ing factor in (8.23), we see that a − b = m. Since the ranges of both
a and b are between 0 and `, we see that there are 2` + 1 values of
m consistent with homogeneous polynomial solutions of degree `. The
corresponding values of m are −` ≤ m ≤ `. The 2` + 1 independent
homogeneous polynomials of degree ` are called the spherical harmonics
and denoted by Y`m (θ, φ). Their functional form is
Y`m (θ, φ) ∝ Pm` (θ) eimφ , (8.24)
where Pm` (θ) is a Legendre function. In the following discussion, we will

utilize only the exponential factor in the spherical harmonics.
8.5.2 Characters of Irreducible Representations

The Y`m (θ, φ) form a (2` + 1)-dimensional representation of SO(3).
Thus, for a general rotation R, we have
X̀
R Y`m (θ, φ) = Y`m0 (θ, φ) .Γ`m0 m (R)
m0 =−`
To determine the character of this representation, it is convenient to

again invoke the fact that the classes of SO(3) are determined only by
the rotation angle, not by the direction of the rotation axis. Thus, we
can choose a rotation axis at our convenience and we therefore focus on
rotations through an angle ϕ about the z-axis. In this case, the form
of (8.24) allows us to write
Rz (ϕ)Y`m (θ, φ) = Y`m (θ, φ − ϕ) = e−imϕ Y`m (θ, φ) .
Thus, the corresponding transformation matrix is given by
 
e−i`ϕ 0 ··· 0
 
 0 e−i(`−1)ϕ ··· 0 
 
Γ [Rz (ϕ)] = 
`
 .. .. ... ..
.
 (8.25)
 . . . 
 
0 0 · · · ei`ϕ
The character χ(`) (ϕ) of this class is obtained by taking the trace of
this matrix:
χ(`) (ϕ) = e−i`ϕ + e−i(`−1)ϕ + · · · + ei`ϕ
µ ¶
−i`ϕ
=e 1+e +e iϕ 2iϕ
+ ··· + e 2`iϕ
1 − e−(2`+1)iϕ
= e−i`ϕ
1 − eiϕ
e(`+1/2)iϕ − e−(`+1/2)iϕ
=
eiϕ/2 − e−iϕ/2
sin [(` + 12 )ϕ]
= .
sin ( 12 ϕ)
The orthogonality integral for these characters takes the form

Z π sin [(` + 12 )ϕ] sin [(`0 + 12 )ϕ]
(1 − cos ϕ) dϕ .
0 sin2 ( 12 ϕ)
Using the trigonometric identity
2 sin2 ( 12 ϕ) = 1 − cos ϕ
enables us to write the orthogonality integral as

Z π
sin [(` + 12 )ϕ] sin [(`0 + 12 )ϕ] dϕ = 12 πδ`,`0 ,
0
where the right-hand side of this equation follows either from (8.22) or
from the orthogonality of the sine functions over (0, π).
It is possible to show directly, using Schur’s first lemma, that the
spherical harmonics form a basis for (2` + 1)-dimensional irreducible
representations of SO(3). However, this requires invoking properties of
the Legendre functions in (8.24). If we confine ourselves to the matrices
in (8.25) then we can show that a matrix that commutes with all such
rotation matrices must reduce to a diagonal matrix. If we then consider
rotations about any other direction, which requires some knowledge of
the Legendre functions, we can then show that this constant matrix
must, in fact, be a constant multiple of the unit matrix. Hence, accord-
ing to Schur’s first lemma, these representations are irreducible. We can
now construct the character table for SO(3) with the basis functions
which generate the irreducible representations:
SO(3) E R(ϕ)
sin [(` + 12 )ϕ]
Γ` : Y`m (θ, φ) 1
sin ( 12 ϕ)
8.6 Summary
In this chapter, we have shown how the orthogonality relations devel-
oped for finite groups must be adapted for continuous groups, using
SO(2) and SO(3) as examples. For SO(2), which is a one-parameter

Abelian group, this proved to be a straightforward matter. However,
the corresponding calculations for SO(3) required us to determine ex-
plicitly the density function to produce the appropriate form of the
orthogonality relations. We found that the there are an infinite se-
quence of irreducible representations of dimensionality 2` + 1, where
` ≥ 0. Because of the connection between SO(3) and angular mo-
mentum, the structure of these irreducible representations has several
physical consequences:
• For systems that possess spherical symmetry, the energy eigen-

states have degeneracies of 2` + 1. The fact that there is a greater
degeneracy for the hydrogen atom is due to a “hidden” SO(4)
symmetry.4
• The formation and decomposition of direct products of the irre-

ducible representations of SO(3) forms the basis of angular mo-
mentum coupling rules (Problem 6, Problem Sets 10) and the
classification of atomic spectra.5
• When atoms are placed within crystals, the original spherical

symmetry is lowered to the symmetry of the crystal. This causes
levels which were degenerate in the spherically-symmetric envi-
ronment to split. Such “crystal-field” effects are important for
many aspects for electrons in crystalline solids.6
4
H.F. Jones, Groups, Representations and Physics (Institute of Physics, Bristol,
1998), pp. 124–127.
5
E.P. Wigner, Group Theory and its Application to the Quantum Mechanics of
Atomic Spectra (Academic, New York, 1959), pp. 177–194.
6
M. Tinkham, Group Theory and Quantum Mechanics (McGraw–Hill, New York,
1964), pp. 65–80.
Chapter 9
Unitary Groups and SU(N)∗
The irreducible representations of SO(3) are appropriate for describing

the degeneracies of states of quantum mechanical systems which have
rotational symmetry in three dimensions. But there are many systems
for which operations on classical coordinates must be supplemented
by operations on “internal” degrees of freedom which have no classical
analogue. For example, the Stern–Gerlach experiment showed that
electrons are endowed with an internal degree of freedom called “spin”
which has the properties of an angular momentum. The two spin states
are therefore inconsistent with the dimensionalities of the irreducible
representations of SO(3), so another group—SU(2)—must be used to
describe these states. Since, as we will show in Section 9.2, SU(2) is
locally isomorphic to SO(3), we can define a total spin S in an abstract
three-dimensional space, analogous to the total angular momentum in
real space. In particle physics, unitary symmetry was used to describe
the approximate symmetry (called isospin) of neutrons and protons
and, more recently, to describe particle spectra within the framework
of the quark model.
In this chapter, we introduce unitary groups and their irreducible
representations in a similar manner to which we developed SO(3). We
begin by defining unitarity in terms of the invariance of an appropriate
quantity and proceed to discuss the construction of irreducible repre-
sentations of these groups in N dimensions. Higher-dimensional irre-
ducible representations will be obtained with the aid of Young tableaux,
which is a diagrammatic technique for determining the dimensionali-
147
148 Unitary Groups and SU(N)
ties and the basis functions of irreducible representations derived from

direct products.
9.1 SU(2)
As with orthogonal matrices, the unitary groups can be defined in terms
of quantities which are left invariant. Consider a general complex trans-
formation in two dimensions, x0 = Ax which, in matrix form, reads:
Ã ! Ã !Ã !
x0 a b x
=
y0 c d y
where a, b, c, and d are complex, so there are eight free parameters.

The determinant of this matrix is nonzero to permit the construction
of inverses.
9.1.1 Unitary Transformations

Suppose we require the quantity |x|2 + |y|2 to be an invariant of such a
transformation. Then,
|x0 |2 + |y 0 |2 = |ax + by|2 + |cx + dy|2
= (ax + by)(a∗ x∗ + b∗ y ∗ ) + (cx + dy)(c∗ x∗ + d∗ y ∗ )
= (|a|2 + |c|2 )|x|2 + (ab∗ + cd∗ )xy ∗ + (a∗ b + c∗ d)x∗ y
+ (|b|2 + |d|2 )|y|2
= |x|2 + |y|2
Since x and y are independent variables, this invariance necessitates

setting the following conditions on the matrix elements:
|a|2 + |c|2 = 1, |b|2 + |d|2 = 1, ab∗ + cd∗ = 0
These four conditions (the last equation provides two conditions be-
cause it involves complex quantities) means that the original eight free
Unitary Groups and SU(N) 149
parameters are reduced to four. These conditions are the same as those
obtained by requiring the A† A = 1, so the determinant of the result-
ing matrix has modulus unity. These transformations are analogous
to orthogonal transformations of real coordinates and, indeed, orthog-
onal transformations are also unitary. The group comprised of unitary
matrices is denoted by U(2) and by U(N) for the N -dimensional case.
9.1.2 Special Unitary Transformations

If, in addition to the conditions above, we require that the determinant
of the transformation is unity, the transformation matrix must have the
form
Ã ! Ã !Ã !
x0 a b x
0
= ∗ ∗
, |a|2 + |b|2 = 1 (9.1)
y −b a y
There are now three free parameters and the group of these matrices is
denoted by SU(2) where, as in our discussion of orthogonal groups, the
‘S’ signifies ‘special’ because of the requirement of a unit determinant.
9.2 Relation between SU(2) and SO(3)

9.2.1 Pauli Matrices
If the matrix elements of the general unitary matrix in (9.1) are ex-
pressed in terms of their real and imaginary parts, we can decompose
this matrix into the components of a “basis.” Thus, with a = ar + iai
and b = br + ibi , we have
Ã !
ar + iai br + ibi
U =
−br + ibi ar − iai
Ã ! Ã ! Ã ! Ã !
1 0 1 0 0 1 0 1
= ar + iai + br +ibi
0 1 0 −1 −1 0 1 0
| {z }
Ã !
0 −i
ibr
i 0
Thus, any 2 × 2 unitary matrix can be represented as a linear combi-

nation of the unit matrix and the matrices
Ã ! Ã ! Ã !
1 0 0 −i 0 1
σx = , σy = , σz =
0 −1 i 0 1 0
These three (Hermitian) matrices are known as the Pauli matrices. They
satisfy the following multiplication rules:
σi2 = I (i = x, y, z)
(9.2)
σi σj = −σj σi = iεijk σk ({i, j, k} = x, y, z)
where I is the 2 × 2 unit matrix. These multiplication rules can be
used to obtain a concise expression for the product of two matrices
written as a · σ and b · σ, where a = (ax , ay , az ), b = (bx , by , bz ), and
σ = (σx , σy , σz ):
(a·σ)(b·σ) = (a·b)I + i(a × b)·σ (9.3)
9.2.2 Infinitesimal Generators

Moreover, if we define matrices Xi = − 12 iσi , for i = 1, 2, 3, then the sec-
ond of the multiplication rules in (9.2) yield the following commutation
relations:
[Xi , Xj ] = εijk Xk
These are identical to commutators of the infinitesimal generators of

SO(3) in (7.13). Thus, locally at least, there is an isomorphism between
SO(3) and SU(2). Motivated by the discussion in Section 7.3, consider
the matrix
U = exp ( − 12 iϕn·σ)
where ϕn is the axis-angle representation of a rotation (Section (8.3).

Since the exponential of a matrix is defined by its Taylor series expan-
sion, we have
∞
X (−i)n
U= ( 12 ϕ)n (n·σ)n
k=0 n!
From Equation (9.3), (n·σ)2 = I, so

∞
X ∞
X
(−1)n (−1)n 1 2n+1
U =I ( 12 ϕ)2n − i(n·σ) ( 2 ϕ)
k=0 (2n)! k=0 (2n + 1)!
= cos ( 12 ϕ)I − i(n·σ) sin ( 12 ϕ)

 
cos ( 12 ϕ) − inz sin ( 12 ϕ) −(ny + inx ) sin ( 12 ϕ)
=


 (9.4)
(ny − inx ) sin ( 12 ϕ) cos ( 12 ϕ) + inz sin ( 12 ϕ)
This matrix is manifestly of the unitary form in (9.1) with unit deter-
minant. The Pauli matrices are, therefore, the infinitesimal generators
of SU(2) and form a representation of its Lie algebra.
9.2.3 Local and Global Mappings between SU(2)

and SO(3)
The matrix in (9.4) is parametrized in the same way as rotations in
SO(3), namely, in terms of a rotation angle ϕ and a rotation axis n.
But, although the mapping between SU(2) and SO(3) is locally an iso-
morphism, since their algebras are isomorphic, globally this relationship
is a homomorphism. The reason for this stems from the periodicity of
the two groups: SO(3) has a periodicity of 2π, while SU(2) has a peri-
odicity of 4π. In particular U (0, n) = I, but U (2π, n) = −I, so both
of these elements are associated with the identity of SO(3). Moreover,
these elements form an invariant subgroup of SU(2) (Section 2.4) which
is isomorphic to the group Z2 = {1, −1} under ordinary multiplication.
In general, using the trigonometric identities,
h i
cos 1
2
(ϕ + 2π) = − cos ( 12 ϕ)
h i
sin 1
2
(ϕ + 2π) = − sin ( 12 ϕ)
we find that
U (ϕ + 2π, n) = −U (ϕ, n)
Thus, if we form the cosets of the subgroup {U (0, n), U (2π, n)}, we
obtain
n o n o
U (0, n), U (2π, n) U (ϕ, n) = U (ϕ, n), U (ϕ + 2π, n)
Thus, the factor group SU(2)/Z2 is isomorphic to SO(3):
SU(2)/Z2 = SO(3)
In fact, this double-valuedness extends to characters as well. Taking

the trace of the matrix in 9.4) yields
2 cos ( 12 ϕ)
If we compare this expression with that for χ(`) (ϕ) for SO(3) with ` = 12 ,
we find
sin ϕ
χ(1/2) (ϕ) = = 2 cos ( 12 ϕ)
sin ( 12 ϕ)
so the two-dimensional (irreducible) representation of SU(2) generated

by the Pauli matrices corresponds to a representation of SO(3) with a
half-integer index. The integer values of ` can be traced to the require-
ment of single-valuedness of the spherical harmonics, so the double-
valued correspondence between SU(2) and SO(3) results in this half-
integer index.
9.3 Irreducible Representations of SU(2)

When we constructed the irreducible representations of SO(2) and
SO(3), we used as basis functions obtained from the coordinates {x, y}
and {x, y, z}, respectively, and to obtain higher-order irreducible rep-
resentations from direct products. The basic procedure is much the
same for unitary groups, except that we can no longer rely on basis
states expressed in terms of coordinates. In this section, we carry out
the required calculations for SU(2) and then generalize the method for
SU(N) in the next section.
9.3.1 Basis States

By associating the Pauli matrices with angular momentum operators
through Ji = 12 h̄σi , we choose as our basis states the vectors
Ã ! Ã !
1 0
u1 = , u2 =
0 1
There are several physical interpretations of these states. For exam-

ple, they can represent the two possible energy eigenstates of a spin- 12
particle, such an electron or proton. Another possibility is that u1 and
u2 represent the isospin eigenstates of an isospin- 12 particle, such as a
proton or a neutron. The fact that the proton and neutron are not ex-
actly degenerate means that isospin symmetry is only an approximate
symmetry. A third interpretation of u1 and u2 is as “up” and “down”
quarks which make up nucleons. We will discuss further refinements of
the quark model in the context of SU(N) later in this chapter.
9.3.2 Multiparticle Systems and Direct Products

When using basis states of SU(2) to construct multiparticle states
through direct products, we must respect the indistinguishability of
the particles. Thus, measurable properties of a quantum system can-
not depend on the labelling of the particles, though wavefunctions, of
course, need not obey this invariance. Consider a two-particle system,
with particle ‘1’ in state i and particle ‘2’ in state j. The corresponding
wavefunction is ψi,j (1, 2). We require that
|ψi,j (1, 2)|2 = |ψi,j (2, 1)|2
which implies that
ψi,j (2, 1) = eiθ ψi,j (1, 2)
for some phase angle θ. Since a two-fold exchange restores the original
labelling,
ψi,j (1, 2) = eiθ ψi,j (2, 1) = e2iθ ψi,j (1, 2)

we must have that e2iθ = 1, or that θ = 0 or θ = π. In the first case,

the wavefunction is symmetric under the interchange of particles,
ψi,j (2, 1) = ψi,j (1, 2)
while in the latter case, the wavefunction is antisymmetric under the
interchange of particles,
ψi,j (2, 1) = −ψi,j (1, 2)
Consider now a two-particle system each of which occupy one of the
states of SU(2). The basis of these two-particle states is comprised of
{u1 u1 , u1 u2 , u2 u1 , u2 u2 }, where we have adopted the convention that the
order of the states corresponds to the order of the particle coordinates,
e.g., u1 u1 ≡ u1 (1)u1 (2). But not all of these states are symmetric or
antisymmetric under the interchange of particles. Hence, we construct
the new basis
n o
u1 u1 , u1 u2 + u2 u1 , u2 u2 , u1 u2 − u2 u1 (9.5)
| {z } | {z }
symmetric antisymmetric
We can compare this result with that obtained from the two-fold direct
product representation of SU(2):
h i2
χ(1/2) (ϕ)χ(1/2) (ϕ) = 2 cos ( 12 )
³ ´2
= eiϕ/2 + e−iϕ/2
³ ´
= eiϕ/2 + 1 + e−iϕ/2 + 1
= χ(1) (ϕ) + χ(0) (ϕ)

we see that the three symmetric wavefunctions for a basis for the ` = 1
irreducible representation of SO(3) and the antisymmetric wavefunc-
tions transforms as the identical representation (` = 0) of SO(3). If we
think of these as spin- 12 particles, the symmetric state corresponds to a
total spin S = 1, while the antisymmetric state corresponds to S = 0.
We could proceed in this way to construct states for larger numbers of
particles, but in the next section we introduce a technique which is far
more efficient and which can be applied to other SU(N) groups, where
the direct method described in this section becomes cumbersome.
9.3.3 Young Tableaux
Determining the dimensionalities of the irreducible representations of

direct products of basis states of SU(N) is a problem which is encoun-
tered in several applications in physics and group theory. Young tableaux
provide a diagrammatic method for carrying this out in a straightfor-
ward manner. In this section, we repeat the calculation in the preceding
section to illustrate the method, and in the next section, we describe
the general procedure for applying Young tableaux to SU(N).
The basic unit of a Young tableau is a ‘box’, shown below
which denotes a basis state. If there is no entry in the box, then this
tableau represents any state. An entry, signified by a number denotes
one of the basis states in some reference order. Thus, for SU(2), we
have
u1 = 1 u2 = 2
The utility of Young tableaux centers around the construction of

direct products. For the two-fold direct products of SU(2) in (9.5),
there are two types of states, symmetric and antisymmetric. The Young
tableau for a generic two-particle symmetric state is
and the two-particle antisymmetric state is
The Young tableaux for three symmetric states in (9.5) are

1 1 1 2 2 2
and that for the antisymmetric state is
1
2
In the framework of Young tableaux, the two-fold direct product is

written as
× = +
The three-fold direct product illustrates the conventions used in the

construction of Young tableaux and their labelling. The generic tableaux
are
× × = + +
The rules for constructing the “standard” arrangement of Young tableaux

are as follows
• The rows are constructed from left to right
• The columns are constructed from top to bottom
• No row is longer than any row above it
• No column is longer than any column to the left of it
Thus, with these conventions, a typical tableau is shown below:

The states for the three-fold direct product are as follows. There
are four symmetric states:
1 1 1 1 1 2 1 2 2 2 2 2
which correspond to a four-dimensional irreducible representation, and

two “mixed” states:
1 1 1 2
2 2
which correspond to a two-dimensional irreducible representation. There

are no totally antisymmetric three-particle states because we have only
two distinct basis states. Thus, the rules for entering states into Young
tableaux are:
• The numbers within rows are nondecreasing from left to right.
• The numbers within columns are increasing from top to bottom.
The two sets of rules for constructing Young tableaux of generic
states and identifying particular states enables the calculation of the
dimensionalities in a straightforward manner, often by identifying ap-
propriate combinatorial rules.
9.4 Young Tableaux for SU(N)

The groups SU(N) have acquired an importance in particle physics
because of the quark model. This necessitates calculating direct prod-
ucts of basis states to determine the characteristics of particle spectra.
This, in turn, requires that we adapt the methodology of the Young

tableaux developed in the preceding section to SU(N), which turns out
to be straightforward given the rules stated in the preceding section.
There is no change to the construction of the generic tableaux; the only
changes are in the labelling of the tableaux. Consider, for example the
case of a two-fold direct product of SU(3). There are six symmetric
states
1 1 1 2 1 3 2 2 2 3 3 3
and three antisymmetric states
1 1 2
2 3 3
As is evident from these constructions, the number of states asso-

ciated with a tableau of a particular topology increases sharply with
the number of basis states. The rules in the preceding section allow
the number of such symmetric and antisymmetric states to be calcu-
lated for SU(N). There 12 N (N + 1) symmetric states and 12 N (N − 1)
antisymmetric states.
The only other modification to our discussion of SU(2) is that for
larger numbers of basis states, tableaux which make no contribution
to SU(2), may make a contribution to SU(N). Consider, for example,
the antisymmetric three-particle state. This state vanishes for SU(2)
because there are only two basis states, but for SU(3), we have
1
2
3
In fact, this is a direct consequence of the rule for labelling Young

tableaux, and we see that, for SU(N), any column with more than N
boxes makes no contribution.
9.5 Summary
In this chapter, we have extended our discussion of orthogonal groups
to unitary groups. These groups play an especially important role in
quantum mechanics because of their property of conserving probability
density. We have constructed direct products of basis states, which are
required in a number of applications of these groups. The use of Young
tableaux was shown to be an especially convenient way to determine
the dimensionalities of higher-dimensional irreducible representations
of unitary groups and their basis functions.
Group Theory
Problem Set 1 October 12, 2001
Note: Problems marked with an asterisk are for Rapid Feedback; problems marked with a
double asterisk are optional.
1. Show that the wave equation for the propagation of an impulse at the speed of light c,
1 ∂2u ∂2u ∂2u ∂2u

= + 2 + 2,
c2 ∂t2 ∂x2 ∂y ∂z
is covariant under the Lorentz transformation

µ ¶
0 0 0 0 v
x = γ(x − vt), y = y, z = z, t = γ t − 2x ,
c
where γ = (1 − v 2 /c2 )−1/2 .
2.∗ The Schrödinger equation for a free particle of mass m is
∂ϕ h̄2 ∂ 2 ϕ
ih̄ =− .
∂t 2m ∂x2
Show that this equation is invariant to the global change of phase of the wavefunction:
ϕ → ϕ0 = eiα ϕ ,
where α is any real number. This is an example of an internal symmetry transformation,

since it does not involve the space-time coordinates.
According to Noether’s theorem,
R ∞ this symmetry implies the existence of a conservation
law. Show that the quantity −∞ |ϕ(x, t)|2 dx is independent of time for solutions of the
free-particle Schrödinger equation.
3.∗ Consider the following sets of elements and composition laws. Determine whether they
are groups and, if not, identify which group property is violated.
(a) The rational numbers, excluding zero, under multiplication.

(b) The non-negative integers under addition.
(c) The even integers under addition.
(d) The nth roots of unity, i.e., e2πmi/n , for m = 0, 1, . . . , n − 1, under multiplication.
(e) The set of integers under ordinary subtraction.
4.∗∗ The general form of the Liouville equation is
· ¸
d dy £ ¤
p(x) + q(x) + λr(x) y = 0
dx dx
where p, q and r are real-valued functions of x with p and r taking only positive values.
The quantity λ is called the eigenvalue and the function y, called the eigenfunction, is
assumed to be defined over an interval [a, b]. We take the boundary conditions to be
y(a) = y(b) = 0
but the result derived below is also valid for more general boundary conditions. No-
tice that the Liouville equations contains the one-dimensional Schrödinger equation as a
special case.
Let u(x; λ) and v(x; λ) be the fundamental solutions of the Liouville equation, i.e. u
and v are two linearly-independent solutions in terms of which all other solutions may
be expressed (for a given value λ). Then there are constants A and B which allow any
solution y to be expressed as a linear combination of this fundamental set:
y(x; λ) = Au(x; λ) + Bv(x; λ)
These constants are determined by requiring y(x; λ) to satisfy the boundary conditions:
y(a; λ) = Au(a; λ) + Bv(a; λ) = 0
y(b; λ) = Au(b; λ) + Bv(b; λ) = 0
Use this to show that the solution y(x; λ) is unique, i.e., that there is one and only one
solution corresponding to an eigenvalue of the Liouville equation.
Group Theory
Solutions to Problem Set 1 October 6, 2000
1. To express the the wave equation for the propagation of an im-

pulse at the speed of light c,
1 ∂2u ∂2u ∂2u ∂2u

= + + , (1)
c2 ∂t2 ∂x2 ∂y 2 ∂z 2
under the Lorentz transformation
µ ¶
0 0 0 0 v
x = γ(x − vt), y = y, z = z, t = γ t − 2x , (2)
c
where γ = (1 − v 2 /c2 )−1/2 , we need to obtain expressions for the
second derivatives in the primed variables. With u0 (x0 , y 0 , z 0 ) =
u(x, y, t), we have
∂u ∂u0 ∂x0 ∂u0 ∂t0 ∂u0 v ∂u0

= + = γ − γ , (3)
∂x ∂x0 ∂x ∂t0 ∂x ∂x0 c2 ∂t0
2 0 2 2 0
∂2u 2∂ u 2v ∂ u
= γ + γ , (4)
∂x2 ∂x02 c4 ∂t02
∂2u ∂ 2 u0
= , (5)
∂y 2 ∂y 02
∂2u ∂ 2 u0
= , (6)
∂z 2 ∂z 02
∂u ∂u0 ∂t0 ∂u0 ∂x0 ∂u0 ∂u0
= 0 + 0 = γ 0 − γv 0 , (7)
∂t ∂t ∂t ∂x ∂t ∂t ∂x
2 0 2 0
∂2u 2∂ u 2 2∂ u
= γ + γ v . (8)
∂t2 ∂t02 ∂x02
Substituting these expressions into the wave equation yields
γ 2 ∂ 2 u0 γ 2 v 2 ∂ 2 u0 2 0
2∂ u
2 2 0
2v ∂ u ∂ 2 u 0 ∂ 2 u0
+ = γ + γ + + 02 , (9)
c2 ∂t02 c2 ∂x02 ∂x02 c4 ∂t02 ∂y 02 ∂z
2
which, upon rearrangement, becomes

µ ¶ µ ¶
γ2 v 2 ∂ 2 u0 v 2 ∂ 2 u 0 ∂ 2 u0 ∂ 2 u 0
1 − = γ 2
1 − + 02 + 02 . (10)
c2 c2 ∂t02 c2 ∂x02 ∂y ∂z
Invoking the definition of γ, we obtain
1 ∂ 2 u0 ∂ 2 u0 ∂ 2 u 0 ∂ 2 u0
= + 02 + 02 , (11)
c2 ∂t02 ∂x02 ∂y ∂z
which confirms the covariance of the wave equation under the
Lorentz transformation.
2. We begin with the Schrödinger equation for a free particle of mass

m:
∂ϕ h̄2 ∂ 2 ϕ
ih̄ =− . (12)
∂t 2m ∂x2
Performing the transformation
ϕ → ϕ0 = eiα ϕ , (13)
where α is any real number, we find
∂ϕ0 h̄2 iα ∂ 2 ϕ0
ih̄eiα =− e , (14)
∂t 2m ∂x2
or, upon cancelling the common factor eiα ,
∂ϕ0 h̄2 ∂ 2 ϕ0
ih̄ =− , (15)
∂t 2m ∂x2
which establishes the covariance of the Schrödinger equation un-
der this transformation.
We can derive the corresponding quantity multiplying Eq. (12)

by the complex conjugate ϕ∗ and subtracting the product of ϕ
and the complex conjugate of Eq. (12):
µ ¶ µ ¶
∗ ∂ϕ ∂ϕ∗ h̄2 2
∗∂ ϕ ∂ 2 ϕ∗
ih̄ ϕ +ϕ =− ϕ −ϕ 2 . (16)
∂t ∂t 2m ∂x2 ∂x
3
The left-hand side of this equation can be written as

µ ¶
∗ ∂ϕ ∂ϕ∗ ∂ ∂
ih̄ ϕ +ϕ = ih̄ (ϕϕ∗ ) = ih̄ |ϕ|2 , (17)
∂t ∂t ∂t ∂t
and the right-hand side can be written as
µ ¶ µ ¶
h̄2 ∂2ϕ ∂ 2 ϕ∗ h̄2 ∂ ∂ϕ ∂ϕ∗
− ϕ∗ 2 − ϕ 2 =− ϕ∗ −ϕ . (18)
2m ∂x ∂x 2m ∂x ∂x ∂x
We now consider the solution to Eq. (12) corresponding to a wave

packet, whereby by ϕ and its derivatives vanish as x → ±∞.
Then, integrating Eq. (16) over the real line, and using Eqns. (17)
and (18), we obtain
· µ ¶¸
∂ Z∞ h̄2 Z ∞ ∂ ∂ϕ ∂ϕ∗
ih̄ |ϕ(x, t)|2 dx = − ϕ∗ −ϕ dx
∂t −∞ 2m −∞ ∂x ∂x ∂x
µ ¶¯
h̄2 ∂ϕ ∂ϕ∗ ¯¯∞
=− ϕ∗ −ϕ
2m ∂x ∂x ¯−∞
= 0. (19)
∞ R
Thus, the quantity −∞ |ϕ(x, t)|2 dx is independent of time for so-
lutions of the free-particle Schrödinger equation which correspond
to wave packets.
3. (a) The multiplication of two rational numbers, m/n and p/q,

where m, n, p and q are integers, yields another rational number,
mp/nq, so closure is obeyed. The unit is 1, multiplication is an
associative operation, and the inverse of m/n is n/m, which is a
rational number. The set excludes zero, so the problem of finding
the inverse of zero does not arise. Hence, the rational numbers,
excluding zero, under multiplication form a group.
(b) The sum of two non-negative integers is a non-negative in-

teger, thus ensuring closure, addition is associative, the unit is
zero, but the inverse under addition of a negative integer n is −n,
4
which is a negative integer and, therefore, excluded from the set.

Hence, the non-negative integers under addition do not form a
group.
(c) The sum of two even integers 2m and 2n, where m and n are
any two integers, is 2(m + n), which is an even integer, so closure
is obeyed. Addition is associative, the unit is zero, which is an
even integer, and the inverse of 2n is −2n, which is also an even
integer. Hence, the even integers under addition form a group.
(d) The multiplication of two elements amounts to the addition of

the integers 0, 1, . . . , n − 1, modulo n, i.e., the addition of any two
elements and, if the sum lies out side of this range, subtract n to
bring it into the range. Thus, the multiplication of two nth roots
of unity is again an nth root of unity, multiplication is associative,
and the unit is 1. The inverse of e2πmi/n is therefore
e−2πmi/n = e2πi(n−m)/n (20)
Thus, the nth roots of unity form a group for any value of n.
(e) For the set of integers under ordinary subtraction, the differ-
ence between two integers n and m is another integer p, n−m = p,
the identity is 0, since, n − 0 = 0, and every integer is its own
inverse, since n − n = 0. However, subtraction is not associative
because
(n − m) − p 6= n − (m − p) = n − m + p
Hence, the integers under ordinary subtraction do not form a

group.
4. Let u(x; λ) and v(x; λ) be the fundamental solutions of the Li-

ouville equation with the boundary conditions y(a) = y(b) = 0.
Then there are constants A and B which allow any solution y to
be expressed as a linear combination of this fundamental set:
y(x; λ) = Au(x; λ) + Bv(x; λ) (21)

5
These constants are determined by requiring y(x; λ) to satisfy the

boundary conditions given above. Applying these boundary con-
ditions to the expression in (21) leads to the following equations:
y(a; λ) = Au(a; λ) + Bv(a; λ) = 0

(22)
y(b; λ) = Au(b; λ) + Bv(b; λ) = 0
Equations (22) are two simultaneous equations for the unknown

quantities A and B. To determine the conditions which guarantee
that this system of equations has a nontrivial solution, we write
these equations in matrix form:
Ã !Ã ! Ã !
u(a; λ) v(a; λ) A 0
= (23)
u(b; λ) v(b; λ) B 0
Thus, we see that Equations (22) can be solved for nonzero values
of A and B only if the determinant of the matrix of coefficients in
(23) vanishes. Otherwise, the only solution is A = B = 0, which
yields the trivial solution y = 0. The condition for a nontrivial
solution of (22) is, therefore, given by
¯ ¯
¯ u(a; λ) v(a; λ) ¯¯
¯
¯ ¯ = u(a; λ)v(b; λ) − u(b; λ)v(a; λ) = 0 (24)
¯ u(b; λ) v(b; λ) ¯
This guarantees that the solution for A and B is unique. Hence,

the eigenvalues are non-degenerate.
Group Theory
Note: Problems marked with an asterisk are for Rapid Feedback.
1.∗ Show that, by requiring the existence of an identity in a group G, it is sufficient to require
only a left identity, ea = a, or only a right identity ae = a, for every element a in G,
since these two quantities must be equal.
2.∗ Similarly, show that it is sufficient to require only a left inverse, a−1 a = e, or only a right
inverse aa−1 = e, for every element a in G, since these two quantities must also be equal.
3. Show that for any group G, (ab)−1 = b−1 a−1 .
4.∗ For the elements g1 , g2 , . . . , gn of a group, determine the inverse of the n-fold product
g1 g2 · · · gn .
5.∗ Show that a group is Abelian if and only if (ab)−1 = a−1 b−1 . You need to show that
this condition is both necessary and sufficient for the group to be Abelian.
6. By explicit construction of multiplication tables, show that there are two distinct struc-
tures for groups of order 4. Are either of these groups Abelian?
7.∗ Consider the group of order 3 discussed in Section 2.4. Suppose we regard the rows of
the multiplication table as individual permutations of the elements {e, a, b} of this group.
We label the permutations πg by the group element corresponding to that row:
Ã ! Ã ! Ã !
e a b e a b e a b
πe = , πa = , πb =
e a b a b e b e a
(a) Show that, under the composition law for permutations discussed in Section 2.3,
the multiplication table of the 3-element group is preserved by this association, e.g.,
πa πb = πe .
(b) Show that for every element g in {e, a, b},
Ã !
e a b
πg =
g ga gb
Hence, show that the πg have the same multiplication table as the 3-element group.
(c) Determine the relationship between this group and S3 . This is an example of Cayley’s
theorem.
(d) To which of the operations on an equilateral triangle in Fig. 2.1 do these group
elements correspond?
Group Theory
Solutions to Problem Set 2 October 26, 2001
1. Suppose that e is the right identity of a group G,
ge = g (1)
for all g in G, and that e0 is the left identity,
e0 g = g (2)
for all g in G. The choice g = e0 in the first of these equations

and g = e in the second, yields
e0 e = e0 (3)
and
e0 e = e (4)
respectively. These equations imply that
e0 = e (5)
so the left and right identities are equal. Hence, we need specify
only the left or right identity in a group in the knowledge that
this is the identity of the group.
2. Suppose that a is the right inverse of any element g in a group G,
ga = e (6)
and a0 is the left inverse of g,
a0 g = e (7)
Multiplying the first of these equations from the left by a0 and

invoking the second equation yields
a0 = a0 (ga) = (a0 g)a = a (8)

2
so the left and right inverses of an element are equal. The same
result could have been obtained by multiplying the second equa-
tion from the right by a and invoking the first equation.
3. To show that for any group G, (ab)−1 = b−1 a−1 , we begin with
the properties of the inverse. We must have that
(ab)(ab)−1 = e
Left-multiplying both sides of this equation first by a−1 and then

by b−1 yields
(ab)−1 = b−1 a−1
4. For elements g1 , g2 , . . . , gn of a group G, we require the inverse of

the n-fold product g1 g2 · · · gn . We proceed as in Problem 2 using
the definition of the inverse to write
(g1 g2 · · · gn )(g1 g2 · · · gn )−1 = e
We now follow the same procedure as in Problem 2 and left-

multiply both sides of this equation in turn by g1−1 , g2−1 , . . . , gn−1
to obtain
(g1 g2 · · · gn )−1 = gn−1 · · · g2−1 g1−1
5. We must prove two statements here: that for an Abelian group

G, (ab)−1 = a−1 b−1 , for all a and b in G, and that this equality
implies that G is Abelian. If G is Abelian, then using the result
3
of Problem 3 and the commutativity of the composition law, we

find
(ab)−1 = b−1 a−1 = a−1 b−1
Now, suppose that there is a group G (which we must not assume

is Abelian, such that
(ab)−1 = a−1 b−1
for all a and b in G. We now right multiply both sides of this

equation first by b and then by a to obtain
(ab)−1 ba = e
Then, left-multiplying both sides of this equation by (ab) yields
ba = ab
so G is Abelian. Hence, we have shown that G is an Abelian

group if and only if, for elements a and b in G, (ab)−1 = a−1 b−1 .
6. To construct the multiplication table of a four-element group

{e, a, b, c} we proceed as in Section 2.4 of the course notes. The
properties of the unit of the group enable us to make the following
entries into the multiplication table:
e a b c
e e a b c
a a
b b
c c
We now consider the product aa. This cannot equal a, since that
would imply that a = e, but it can equal any of the other el-
ements, including the identity. However, this leads only to two
distinct choices for the product, since the apparent difference be-
tween aa = b and aa = c disappears under the interchange of the
4
e a b c e a b c
e e a b c e e a b c
a a e a a b (1)
b b b b
c c c c
labelling of b and c. Thus, at this stage, we have two distinct

structures for the multiplication table:
We now determine the remaining entries for these two groups.
For the table on the left, we consider the product ab. From the
Rearrangement Theorem, this cannot equal a or or e, nor can it
equal b (since that would imply a = e). Therefore, ab = c, from
which it follows that ac = b. According to the Rearrangement
Theorem, the multiplication table becomes
e a b c
e e a b c
a a e c b (2)
b b c
c c b
For the remaining entries of this table, we observe that b2 = a

and b2 = e are equally valid assignments. These leads to two
multiplication tables:
e a b c e a b c
e e a b c e e a b c
a a e c b a a e c b (3)
b b c e a b b c a e
c c b a e c c b e a
Note that these tables are distinct in that there is no relabelling

of the elements which transforms one into the other.
We now return to the other multiplication table on the right in
(1). The Rearrangement Theorem requires that the second row
must be completed as follows:
5
e a b c
e e a b c
a a b c e (4)
b b c
c c e
Again invoking the Rearrangement Theorem, we must have that

this multiplication table can be completed only as:
e a b c
e e a b c
a a b c e (5)
b b c e a
c c e a b
Notice that all of the multiplication tables in (3) and (5) are
Abelian and that the table in (5) is cyclic, i.e., all of the group
elements can be obtained by taking successive products of any
non-unit element.
We now appear to have three distinct multiplication tables for
groups of order 4: the two tables in (3) and the one in (5). How-
ever, if we reorder the elements in the second table in (3) to
{e, b, a, c} and reassemble the multiplication table (using the same
products), we obtain
e b a c
e e b a c
c b a c e (6)
b a c e b
a c e b a
which, under the relabelling a 7→ b and b 7→ a, is identical to (5).

Hence, there are only two distinct structures of groups with four
elements:
6
e a b c e a b c
e e a b c e e a b c
a a e c b a a b c e (7)
b b c e a b b c e a
c c b a e c c e a b
7. (a) All of the products involving the identity are self-evident. The
only products that must be calculated explicitly are a2 , ab, ba,
and b2 . These are given by
Ã !Ã ! Ã !
e a b e a b e a b
πa π a = = = πb
a b e a b e b e a
Ã !Ã ! Ã !
e a b e a b e a b
πa πb = = = πe
a b e b e a e a b
Ã !Ã ! Ã !
e a b e a b e a b
πb πa = = = πe
b e a a b e e a b
Ã !Ã ! Ã !
e a b e a b e a b
πb πb = = = πa
b e a b e a a b e
Thus, the association g → πg , for g = e, a, b preserves the prod-
ucts of the three-element group.
(b) With the construction

Ã !
e a b
πg = (9)
g ga gb
for g = e, a, b, we can use the rows of the multiplication table on
p. 19 to obtain
Ã ! Ã !
e a b e a b
πe = =
ee ea eb e a b
Ã ! Ã !
e a b e a b
πa = =
ae aa ab a b e
7
Ã ! Ã !
e a b e a b
πb = = (10)
be ba bb b e a
Thus, the association g → πg is one-to-one and preserves the

products of the 3-element group. Hence, these groups are equiv-
alent.
(c) The elements of the three-element group correspond to the

cyclic permutations of S3 . In other words, given a reference order
{a, b, c}, the cyclic permutations are a 7→ b, b 7→ c, and c 7→ a,
yielding {b, c, a}, and then b 7→ c, c 7→ a, and a 7→ b, yielding
{c, a, b}.
(d) These elements correspond to the rotations of an equilateral

triangle, i.e., the elements {e, d, f } in Fig. 2.1.
Group Theory
1.∗ List all of the subgroups of any group whose order is a prime number.
2.∗ Show that a group whose order is a prime number is necessarily cyclic, i.e., all of the
elements can be generated from the powers of any non-unit element.
3. Suppose that, for a group G, |G| = pq, where p and q are both prime. Show that every
proper subgroup of G is cyclic.
4.∗ Let g be an element of a finite group G. Show that g |G| = e.
5. In a quotient group G/H, which set always corresponds to the unit “element”?
6. Show that, for an Abelian group, every element is in a class by itself.
7. Show that every subgroup with index 2 is self-conjugate.

Hint: The conjugating element is either in the subgroup or not. Consider the two cases
separately.
8.∗ Consider the following cyclic group of order 4, G = {a, a2 , a3 , a4 = e} (cf. Problem 6,
Problem Set 2). Show, by direct multiplication or otherwise, that the subgroup H =
{e, a2 } is self-conjugate and identify the elements in the factor group G/H.
9.∗ Suppose that there is an isomorphism φ from a group G onto a group G0 . Show that the
identity e of G is mapped onto the identity e0 of G0 : e0 = φ(e).
Hint: Use the fact that e = ee must be preserved by φ and that φ(g) = e0 φ(g) for all g
in G.
Group Theory
Solutions to Problem Set 3 November 2, 2001
1. According to Lagrange’s theorem, the order of a subgroup H of

a group G must be a divisor of |G|. Since the divisors of a prime
number are only the number itself and unity, the subgroups of
a group of prime order must be either the unit element alone,
H = {e}, or the group G itself, H = G, both of which are im-
proper subgroups. Therefore, a group of prime order has no proper
subgroups.
2. From a group G of prime order, select any element g, which is

not the unit element, and form its period:
g, g 2 , g 3 , . . . , g n = e ,
where n is the order of g (Sec. 2.4). The period must include
every element in G, because otherwise we would have constructed
a subgroup whose order is neither unity nor |G|. This contradicts
the conclusion of Problem 1. Hence, a group of prime order is
necessarily cyclic (but a cyclic group need not necessarily be of
prime order).
3. For a group G with |G| = pq, where p and q are both prime, we
know from Lagrange’s theorem that the only proper subgroups
have order p and q. Since these subgroups are of prime order, the
conclusion of Problem 2 requires these subgroups to be cyclic.
4. Since the period of an element g of a group G forms a subgroup of

G (this is straightforward to verify), Lagrange’s theorem requires
that |g| must be a divisor of |G|, i.e., G = k|g| for some integer
k. Hence,
g |G| = g k|g| = (g |g| )k = ek = e .
2
5. The identity e of a group G has the property that for every el-
ement g in G, ag = ge = g. We also have that different cosets
either have no common elements or have only common elements.
Thus, in the factor group G/H of G generated by a subgroup H,
the set which contains the unit element corresponds to the unit
element of the factor group, since
{e, h1 , h2 , . . .}{a, b, c, . . .} = {a, b, c, . . .} .
6. The class of an element a in a group G is defined as the set of

elements gag −1 for all elements g in G. If G is Abelian, then we
have
gag −1 = gg −1 a = a
for all g in G. Hence, in an Abelian group, every element is in a

class by itself.
7. Let H be a subgroup of a group of G of index 2, i.e., H has

two left cosets and two right cosets. If H is self-conjugate, then
gHg −1 = H for any g in G. Therefore, to show that H is self-
conjugate, we must show that gH = Hg for any g in G, i.e., that
the left and right cosets are the same. Since H has index 2, and
H is itself a right coset, all of the elements in Hg must either be
in H or in the other coset of H, which we will call A. There two
possibilities: either g is in H or g is not in H. If g is an element
of H, then, according to the Rearrangement Theorem,
Hg = gH = H .
If g is not in H, then it is in A, which is a right coset of H. Two

(left or right) cosets of a subgroup have either all elements in
common or no elements in common. Thus, since the unit element
3
must be contained in H, the set Hg will contain g which, by

hypothesis, is in A. We conclude that
Hg = gH = A .
Therefore,
Hg = gH
for all g in G and H is, therefore, a self-conjugate subgroup.
8. The subgroup H = {e, a2 } of the group G = {e, a, a2 , a3 , a4 = e}

has index 2. Therefore, according to Problem 7, H must be self-
conjugate. Therefore, the elements of the factor group G/H are
the subgroup H, which corresponds to the unit element, so we call
it E, and the set consisting of the elements A = {a, a3 }: G/H =
{E, A}.
9. Let φ be an isomorphism between a group G and a group G0 ,

i.e. φ is a one-to-one mapping between all the elements g of G
and g 0 of G0 . From the group properties we have that the identity
e of G must obey the relation
e = ee .
Since φ preserves all products, this relation must in particular be

preserved by φ:
φ(e) = φ(e)φ(e) .
The group properties require that, for any element g of G,
φ(g) = e0 φ(g) ,
where e0 is the identity of G0 . Setting g = e and comparing with

the preceding equation yields the equality
φ(e)φ(e) = e0 φ(e) ,
4
which, by cancellation, implies
e0 = φ(e) .
Thus, an isomorphism maps the identity in G onto the identity

in G0 .
Group Theory
1.∗ Given a set of matrices D(g) that form a representation a group G, show that the matrices
which are obtainable by a similarity transformation U D(g)U −1 are also a representation
of G.
2.∗ Show that the trace of three matrices A, B, and C satisfies the following relation:
tr(ABC) = tr(CAB) = tr(BCA)
3. Generalize the result in Problem 4 to show that the trace of an n-fold product of matrices
is invariant under cyclic permutations of the product.
4.∗ Show that the trace of an arbitrary matrix A is invariant under a similarity transformation
U AU −1 .
5. Consider the following representation of S3 :

Ã ! Ã √ ! Ã √ !
1 0 1 − 3 1 3
e= , a = 12 √ , b= 1
2 √
0 1 − 3 −1 3 −1
Ã ! Ã √ ! Ã √ !
−1 0 −1 − 3 −1 3
1 1
c= , d= 2 √ , f= 2 √
0 1 3 −1 − 3 −1
How can these matrices be permuted to provide an equally faithful representation of S3 ?

Relate your result to the class identified with each element.
6.∗ Consider the planar symmetry operations of an equilateral triangle. Using the matrices
in Example 3.2 determined from transformations of the coordinates in Fig. 3.1, construct
a three-dimensional representation of S3 in the (x, y, z) coordinate system, where the z-
axis emanates from the geometric center of the triangle. Is this representation reducible
or irreducible? If it is reducible determine the irreducible representations which form the
direct sum of this representation.
7. Show that two matrices are simultaneously diagonalizable if and only if they commute.
Hint: Two matrices A and B are simultaneously diagonalizable if the same similarity
transformation brings both matrices into a form where they have only diagonal entries.
Proving that simultaneous diagonalizability implies commutativity is straightforward. To
prove the converse, suppose that there is a similarity transformation which brings one
of the matrices into diagonal form. By writing out the matrix elements of the products
and using the fact that A and B commute, show that the same similarity transformation
must also diagonalize the other matrix.
8.∗ What does the result of Problem 7 imply about the dimensionalities of the irreducible
representations of Abelian groups?
9.∗ Verify that the matrices

Ã ! Ã √ !
1 0 −1 3
1
e= , a= 2 √
0 1 3 1
form a representation for the two-element group {e, a}. Is this representation reducible
or irreducible? If it is reducible determine the one-dimensional representations which
form the direct sum of this representation.
10.∗ Prove the relations in Eqns (3.9) and (3.11).

Group Theory
1. Let D0 (g) = U D(g)U −1 , where D(g) is a representation of a group

G with elements g. To show that D0 (g) is also a representation of
G, it is sufficient to show that this representation preserves the
multiplication table of G. Thus, let a and b be any two elements
of G with matrix representations D(a) and D(b). The product ab
is represented by
D(ab) = D(a)D(b) .
Therefore,
D0 (ab) = U D(ab)U −1
= U D(a)D(b)U −1
= U D(a)U −1 U D(b)U 0
= D0 (a)D0 (b) ,
so multiplication is preserved and D0 (g) is therefore also a repre-

sentation of G.
2. The trace of a matrix is the sum of its diagonal elements. There-

fore, the trace of the product of three matrices A, B, and C is
given by
X
tr(ABC) = Aij Bjk Cki .
ijk
By using the fact that i, j, and k are dummy summation indices

with the same range, this sum can be written in the equivalent
forms
X X X
Aij Bjk Cki = Cki Aij Bjk = Bjk Cki Aij .
ijk ijk ijk
2
But the second and third of these are

X
Cki Aij Bjk = tr(CAB)
ijk
and
X
Bjk Cki Aij = tr(BCA) ,
ijk
respectively. Thus, we obtain the relation
tr(ABC) = tr(CAB) = tr(BCA) .
3. The trace of an n-fold product, A1 A2 · · · An is

X
tr(A1 A2 · · · An ) = (A1 )i1 i2 (A2 )i2 i3 · · · (An )in i1 .
i1 ,i2 ,...in
Proceeding as in Problem 2, we observe that the ik (k = 1, . . . , n)

are dummy summation indices all of which have the same range.
Thus, any cyclic permutation of the matrices in the product leaves
the sum and, hence, the trace invariant.
4. From Problem 2, we have that
tr(U AU −1 ) = tr(U −1 U A) = tr(A) ,
so a similarity transformation leaves the trace of a matrix invari-

ant.
3
5. Given a faithful representation of a group, similarity transfor-

mations of the matrices provide equally faithful representations.
Since we wish to obtain permutations of a particular matrix repre-
sentation, we base our similarity transformations on the non-unit
elements in the group. Thus, consider the following similarity
transformations:
a{e, a, b, c, d, f }a−1 = {e, a, c, b, f, d} ,
b{e, a, b, c, d, f }b−1 = {e, c, b, a, f, d} ,
c{e, a, b, c, d, f }c−1 = {e, b, a, c, f, d} , (1)
d{e, a, b, c, d, f }d−1 = {e, b, c, a, d, f } ,
e{e, a, b, c, d, f }e−1 = {e, c, a, b, d, f } .
Thus, the following permutations of the elements {e, a, b, c, d, f }

provide equally faithful representations:
{e, a, c, b, f, d} , {e, c, b, a, f, d} ,
{e, b, a, c, f, d} , {e, b, c, a, d, f } ,
{e, c, a, b, d, f } .
Notice that only elements within the same class can be permuted.
For S3 , the classes are {e}, {a, b, c}, {d, f }.
6. In the basis (x, y, z) where x and y are given in Fig. 3.1 and the
z-axis emanates from the origin of this coordinate system (the
geometric center of the triangle), all of the symmetry operations of
the equilateral triangle leave the z-axis invariant. This is because
the z-axis is either an axis of rotation (for operations d and f ) or
lies within the reflection plane (for operations a, b, and c). Hence,
4
the matrices of these operations are given by

   √ 
1 0 0 1 − 3 0
   √ 
e=
0 1 0,
 a = 12 
− 3 −1 0 
,
0 0 1 0 0 2
 √   
1 3 0 −1 0 0
 √   
b = 12 
 3 −1 0
, c=
 0 1 0,
0 0 2 0 0 1
 √   √ 
−1 − 3 0 −1 3 0
√   √ 
d = 12 
 3 −1 0  1  
 , f = 2  − 3 −1 0  .
0 0 2 0 0 2
This representation is seen to be reducible and that it is the direct
sum of the representation in Example 3.2 (which, as discussed in
Example 3.4, is irreducible) and the identical representation.
7. We must show (i) that two matrices which are simultaneously di-
agonalizable commute and (ii) that two matrices which commute
are simultaneously diagonalizable. Showing (i) is straightforward.
For two d × d matrices A and B which are simultaneously diago-
nalizable, there is a matrix U such that
U AU −1 = DA and U BU −1 = DB ,
where DA and DB are diagonal forms of these matrices. Clearly,

therefore, we have that
DA DB = DB DA .
Hence, transforming back to the original basis,
(U −1 DA U ) (U −1 DB U ) = (U −1 DB U ) (U −1 DA U ) ,
| {z }| {z } | {z }| {z }
A B B A
5
so A and B commute.
Now suppose that A and B commute and there is a transforma-

tion that brings one of these matrices, say A, into the diagonal
form DA :
U AU −1 = DA .
Then, with
U BU −1 = B 0 ,
the commutation relation AB = BA transforms to
DA B 0 = B 0 DA .
The (i, j)th matrix element of these products is
X
(DA B 0 )ij = (DA )ik (B 0 )kj = (DA )ii (B 0 )ij
k
X
= (B 0 DA )ij = (B 0 )ik (DA )kj = (B 0 )ij (DA )jj .
k
After a simple rearrangement, we have

(B 0 )ij [(DA )ii − (DA )jj ] = 0 .
There are three cases to consider:
Case I. All of the diagonal entries of DA are distinct. Then,

(DA )ii − (DA )jj 6= 0 if i 6= j ,
so all of the off-diagonal matrix elements of B 0 vanish, i.e., B 0 is a
diagonal matrix. Thus, the same similarity transformation which
diagonalizes A also diagonalizes B.
Case II. All of the diagonal entries of DA are the same. In this
case DA is proportional to the unit matrix, DA = cI, for some
complex constant c. Hence, this matrix is always diagonal,
U (cI)U −1 = cI
6
and, in particular, it is diagonal when B is diagonal.
Case III. Some of the diagonal entries are the same and some
are distinct. If we arrange the elements of DA such that the first
p elements are the same, (DA )11 = (DA )22 = · · · = (DA )pp , then
DA has the general form
Ã !
cIp 0
DA = 0
,
0 DA
where Ip is the p × p unit matrix and c is a complex constant.

From Cases I and II, we deduce that B must be of the form
Ã !
Bp 0
B= 0
,
0 DB
0
where Bp is some p × p matrix and DB is a diagonal matrix. Let
Vp be the matrix which diagonalizes B:
Vp Bp Vp−1 = DB
00
.
Then the matrix

Ã !
Vp 0
V =
0 Id−p
diagonalizes B while leaving DA unchanged. Here, Id−p is the

(d − p) × (d − p) unit matrix.
Hence, in all three cases, we have shown that the same transfor-
mation which diagonalizes A also diagonalizes B.
8. The matrices of any representation {A1 , A2 , . . . , An } of an Abelian

group G commute:
Ai Aj = Aj Ai
7
for all i and j. Hence, according to Problem 7, these matrices can

all be simultaneously diagonalized. Since this is true of all repre-
sentations of G, we conclude that all irreducible representations of
Abelian groups are one-dimensional, i.e., they are numbers with
ordinary multiplication as the composition law.
9. To verify that the matrices

Ã ! Ã √ !
1 0 −1 3
e= , a= 1
2 √ (2)
0 1 3 1
form a representation for the two-element group {e, a}, we need

to demonstrate that the multiplication table for this group,
e a
e e a
a a e
is fulfilled by these matrices. The products e2 = e, ea = a, and

ae = a can be verified by inspection. The product a2 is
Ã √ !Ã √ ! Ã !
−1 3 −1 3 1 0
a =4 √
2 1
√ = = e,
3 1 3 1 0 1
so the matrices in (2) form a representation of the two-element

group.
Since these matrices commute, they can be diagonalized simulta-

neously (Problem 7). Since the matrix is the unit matrix, we can
determine the diagonal form of a, simply by finding its eigenval-
ues. The characteristic equation of a is
¯ 1 √ ¯
¯− − λ 1
3 ¯¯
¯ 2
det(a − λI) = ¯ 1 √ 2
¯
¯ 3 1
− λ¯
2 2
= −( 12 − λ)( 12 + λ) − 3
4
= λ2 − 1 .
8
which yields λ = ±1. Therefore, diagonal form of a is

Ã !
1 0
a= , (3)
0 −1
so this representation is the direct sum of the identical represen-
tation {1, 1}, and the “parity” representation {1, −1}. Note that,
according to Problem 8, every representation of the two-element
group with dimensionality greater than two must be reducible.
10. The relations in (3.9) and (3.11) can be proven simultaneously,

since they differ only by complex conjugation, which preserves the
order of matrices. The (i, j)th matrix element of n-fold product
of matrices A1 , A2 , . . . , An is
X
(A1 A2 · · · An )ij = (A1 )ik1 (A2 )k1 k2 · · · (An )kn−1 j .
k1 ,k2 ,...,kn−1
The corresponding matrix element of the transpose of this prod-

uct is
[(A1 A2 · · · An )t ]ij = (A1 A2 · · · An )ji .
Thus, since the ki are dummy indices,

X
[(A1 A2 · · · An )t ]ij = (A1 )jk1 (A2 )k1 k2 · · · (An )kn−1 i
k1 ,k2 ,...,kn−1
X
= (At1 )k1 j (At2 )k2 k1 · · · (Atn )ikn−1
k1 ,k2 ,...,kn−1
X
= (Atn )ikn−1 (Atn−1 )kn−1 kn−2 · · · (At2 )k2 k1 (At1 )k1 j
k1 ,k2 ,...,kn−1
We conclude that
(A1 A2 · · · An )t = Atn Atn−1 · · · At1

9
and, similarly, that
(A1 A2 · · · An )† = A†n A†n−1 · · · A†1

Group Theory
Problem Set 5 November 6, 2001
1. In proving Theorem 3.2, we established the relation Bi Bi† = I. Using the definitions in
that proof, show that this result implies that Bi† Bi = I as well.
Hint: Show that Bi Bi† = I implies that Ãi DÃ†i = D.
2.∗ Consider the three-element group G = {e, a, b} (Sec. 2.4).
(a) Show that this group is Abelian and cyclic (cf. Problem 2, Problem Set 3).
(b) Consider a one-dimensional representation based on choosing a = z, where z is a

complex number. Show that for this to produce a representation of G, we must
require that z 3 = 1.
(c) Use the result of (b) to obtain three representations of G. Given what you know
about the irreducible representations of Abelian groups (Problem 8, Problem Set
4), are there any other irreducible representations of G?
3.∗ Generalize the result of Problem 2 to any cylic group of order n.
4.∗ Use Schur’s First Lemma to prove that all the irreducible representations of an Abelian
group are one-dimensional.
5.∗ Consider the following matrices:

Ã ! Ã √ ! Ã √ !
1 0 −1 − 3 −1 − 3
1 1
e= , a= 2 √ , b= 2 √
0 1 − 3 1 − 3 1
Ã √ ! Ã ! Ã !
−1 − 3 1 0 1 0
1
c= 2 √ , d= , f=
− 3 1 0 1 0 1
Verify that these matrices form a representation of S3 . Use Schur’s first Lemma to
determine if this representation reducible or irreducible. If reducible, determine the
irreducible representations that are obtained from the diagonal form of these matrices.
Group Theory
1. In proving Theorem 3.2, we established that Bi Bi† = I, where
Bi = D−1/2 Ãi D1/2
To show that this result implies that Bi† Bi = I, we first use the
definitions of Bi and Bi† to write
Bi† Bi = D1/2 Ã†i D−1 Ãi D1/2
We can find an expression for D−1 by first rearranging
Bi Bi† = D−1/2 Ãi DÃ†i D−1/2 = I
as
Ãi DÃ†i = D
Then, taking the inverse of both sides of this equation yields
D−1 = Ã†−1
i D−1 Ã−1
i
Therefore,
Bi† Bi = D1/2 Ã†i D−1 Ãi D1/2

= D1/2 Ã†i (Ã†−1
i D−1 Ã−1
i )Ãi D
1/2
= I
2. (a) The multiplication table for the three-element group is shown

below (Sec. 2.4):
2
e a b
e e a b
a a b e
b b e a
We can see immediately that a2 = b and that ab = ba = a3 = e,

Thus, the three-element group can be written as {a, a2 , a3 = e},
i.e., it is a cyclic group (and, therefore, Abelian).
(b) By choosing a one-dimensional representation a = z, for some

complex number z, the multiplication table requires that a3 = e,
which means that z 3 = 1.
(c) There are three solutions to z 3 = 1: z = 1, e2πi/3 , ande4πi/3 .

The three irreducible representations are obtained by choosing
a = 1, a = e2πi/3 , and a = e4πi/3 . Denoting these representations
by Γ1 , Γ2 , and Γ3 , we obtain
e a b
Γ1 1 1 1
Γ2 1 e2πi/3 e4πi/3
Γ2 1 e4πi/3 e2πi/3
3. The preceding Problem can be generalized to any cyclic group

of order n. The elements of this group are {g, g 2 , . . . , g n = e}.
By writing g = z, we require that z n = 1. The solutions to this
equation are the nth roots of unity:
z = e2mπi/n , m = 0, 1, 2, . . . , n − 1
Accordingly, there are n irreducible representations based on the

n choices z = e2mπi/n together with the requirements of the group
multiplication table.
3
4. Suppose that we have a representation of an Abelian group of

dimensionality d is greater than one. Suppose furthermore that
these matrices are not all unit matrices (for, if they were, the rep-
resentation would already be reducible to the d-fold direct sum of
the identical representation.) Then, since the group is Abelian,
and the representation must reflect this fact, any non-unit ma-
trix in the representation commutes with all the other matrices
in the representation. According to Schur’s First Lemma, this
renders the representation reducible. Hence, all the irreducible
representations of an Abelian group are one-dimensional.
5. For the following matrices,

Ã ! Ã √ !
1 0 −1 − 3
e=d=f = , a=b=c= 1
2 √
0 1 − 3 1
to be a representation of S3 , their products must preserve the

multiplication table of this group, which was discussed in Sec. 2.4
and is displayed below:
e a b c d f
e e a b c d f
a a e d f b c
b b f e d c a
c c d f e a b
d d c a b f e
f f b c a e d
To determine the multiplication table of this representation, we

use the notation E for the unit matrix, corresponding to the el-
ements e, d, and f , and A for the matrix corresponding to the
elements a, b, and c. Then, by observing that A2 = E (as is
required by the group multiplication table) the multiplication ta-
ble of this representation is straightforward to calculate, and is
shown below:
4
e a b c d f
e E A A A E E
a A E E E A A
b A E E E A A
c A E E E A A
d E A A A E E
f E A A A E E
If we now take the multiplication table of S3 and perform the

mapping {e, d, f } 7→ E and {a, b, c} 7→ A, we get the same table
as that just obtained by calculating the matrix products directly.
Hence, these matrices form a representation of S3 .
From Schur’s First Lemma, we see that the matrix
Ã √ !
−1 − 3
1
2 √
− 3 1
commutes with all the matrices of the representation. Since this

is not a unit matrix, the representation must be reducible.
The diagonal form of these matrices must have entries of one-
dimensional irreducible representations. Two one-dimensional ir-
reducible representations of S3 (we will see later that these are
the only irreducible representations of S3 ) are (Example 3.2) the
identical representation,
Ae = 1, Aa = 1, Ab = 1,
Ac = 1, Ad = 1, Af = 1
and the ‘parity’ representation,
Ae = 1, Aa = −1, Ab = −1,
Ac = −1, Ad = 1, Af = 1
Since the diagonal forms of the matrices are obtained by perform-

ing a similarity transformation on the original matrices, which
5
preserves the trace, they must take the form

Ã ! Ã !
1 0 1 0
e=d=f = , a=b=c=
0 1 0 −1
i.e., this reducible representation contains both the identical and

parity representations.
Group Theory
1.∗ Verify the Great Orthogonality Theorem for the following irreducible representation of
S3 : Ã ! Ã √ ! Ã √ !
1 0 1 − 3 1 3
e= , a = 12 √ , b = 12 √
0 1 − 3 −1 3 −1
Ã ! Ã √ ! Ã √ !
−1 0 −1 3 −1 − 3
1 1
c= , d= 2 √ , f= 2 √
0 1 − 3 −1 3 −1
2.∗ Does the following representation of the three-element group {e, a, b}:
Ã ! Ã √ ! Ã √ !
1 0 −1 3 −1 − 3
e= , a = 12 √ , b = 12 √
0 1 − 3 −1 3 −1
satisfy the Great Orthogonality Theorem? Explain your answer.
3.∗ Specialize the Great Orthogonality Theorem to Abelian groups. When viewed as the
components of a vector in a |G|-dimensional space, what does the Great Orthogonal-
ity Theorem state about the relationship between different irreducible representations?
What bound does this place on the number of irreducible representations of an Abelian
group?
4.∗ Consider the irreducible representations of the three-element calculated in Problem 2 of

Problem Set 5.
(a) Verify that the Great Orthogonality Theorem, in the reduced form obtained in
Problem 3, is satisfied for these representations.
(b) In view of the discussion in Sec. 4.4, would you expect to find any other irreducible
representations of this group?
(c) Would you expect your answer in (b) to apply to cyclic groups of any order?
5.∗ Consider any Abelian group. By using the notion of the order of an element (Sec. 2.4),
determine the magnitude of every element in a representation. Is this consistent with the
Great Orthogonality Theorem?
Group Theory
1. The Great Orthogonality Theorem states that, for the matrix

elements of the same irreducible representation {A1 , A2 , . . . , A|G| }
of a group G,
X |G|
(Aα )ij (Aα )∗i0 j 0 = δi,i0 δj,j 0 .
α d
Thus, we first form the vectors V ij whose components are the

(i, j)th elements taken from each matrix in the representation in
some fixed order. The Great Orthogonality Theorem can then be
expressed more concisely as
|G|
V ij · V ∗i0 j 0 = δi,i0 δj,j 0 .
d
For the given representation of S3 ,
Ã ! Ã √ ! Ã √ !
1 0 1 − 3 1 3
e= , a= 1
2 √ , b= 1
2 √ ,
0 1 − 3 −1 3 −1
Ã ! Ã √ ! Ã √ !
−1 0 −1 3 −1 − 3
c= , d= 1
2 √ , f= 1
2 √ ,
0 1 − 3 −1 3 −1
these vectors are:

³ ´
V 11 = 1, 12 , 12 , −1, − 12 , − 12 ,
³ √ √ √ √ ´
V 12 = 0, − 12 3, 12 3, 0, 12 3, − 12 3 ,
³ √ √ √ √ ´
V 21 = 0, − 12 3, 12 3, 0, − 12 3, 12 3 ,
³ ´
V 22 = 1, − 12 , − 12 , 1, − 12 , − 12 .
2
Note that, since all of the entries are real, complex conjugation is
not required for substitution into the Great Orthogonality Theo-
rem. For i = j and i0 = j 0 , with |G| = 6 and d = 2, we have
V 11 · V 11 = 1 + 14 + 14 + 1 + 14 + 1
4
= 3,
V 12 · V 12 = 0 + 34 + 34 + 0 + 34 + 3
4
= 3,
V 21 · V 21 = 0 + 34 + 34 + 0 + 34 + 3
4
= 3.
V 22 · V 22 = 1 + 14 + 14 + 1 + 14 + 1
4
= 3,
all of which are in accord with the Great Orthogonality Theorem.

For i 6= j and/or i0 6= j 0 , we have
√ √ √ √
V 11 · V 12 = 0 − 14 3 + 14 3 + 0 − 14 3 + 14 3 = 0 ,
√ √ √ √
V 11 · V 21 = 0 − 1
4
3+ 1
4
3+0+ 1
4
3− 1
4
3 = 0,
V 11 · V 22 = 1 − 14 − 14 − 1 + 14 + 1
4
= 0,
V 12 · V 21 = 0 + 34 + 34 + 0 − 34 − 3
4
= 0,
√ √ √ √
V 12 · V 22 = 0 + 1
4
3− 1
4
3+0− 1
4
3+ 1
4
3 = 0,
√ √ √ √
V 21 · V 22 = 0 + 1
4
3− 1
4
3+0+ 1
4
3− 1
4
3 = 0,
which is also in accord with the Great Orthogonality Theorem.
2. For the following two-dimensional representation of the three-

element group,
Ã ! Ã √ ! Ã √ !
1 0 −1 3 −1 − 3
e= , a= 21
√ , b= 2 √
1
,
0 1 − 3 −1 3 −1
we again form the vectors V ij whose components are the (i, j)th
elements of each matrix in the representation:
³ ´
V 11 = 1, − 12 , − 12 ,
3
³ √ √ ´
V 12 = 0, 12 3, − 12 3 ,
³ √ √ ´
V 21 = 0, − 12 3, 12 3 ,
³ ´
V 22 = 1, − 12 , − 12 .
Calculating the summation in the Great Orthogonality Theorem,

first with i = j and i0 = j 0 , we have
V 11 · V 11 = 1 + 14 + 1
4
= 32 ,
V 12 · V 12 = 0 + 34 + 3
4
= 32 ,
V 21 · V 12 = 0 + 34 + 3
4
= 32 ,
V 11 · V 11 = 1 + 14 + 1
4
= 32 ,
all of which are in accord with the Great Orthogonality Theorem

with |G| = 3 and d = 2. Performing the analogous summations
with i 6= j and/or i0 6= j 0 , yields
√ √
V 11 · V 12 = 0 − 14 3 + 14 3 = 0 ,
√ √
V 11 · V 21 = 0 + 14 3 − 14 3 = 0 ,
V 11 · V 22 = 1 + 14 + 1
4
= 32 ,
V 12 · V 21 = 0 − 34 − 34 = − 32 ,
√ √
V 12 · V 22 = 0 − 14 3 + 14 3 = 0 ,
√ √
V 21 · V 22 = 0 + 14 3 − 14 3 = 0 ,
which is not consistent with the Great Orthogonality Theorem,

since all of these quantities must vanish. If there is even a single
violation of the Great Orthogonality Theorem, as is the case here,
the representation is necessarily reducible.
4
3. All of the irreducible representations of an Abelian group are one-

dimensional (e.g., Problem 4, Problem Set 5). Hence, for Abelian
groups, the Great Orthogonality Theorem reduces to
X 0
Akα Akα ∗ = |G|δk,k0 .
α
If we view the irreducible representations as |G|-dimensional vec-

tors Ak with entries Akα ,
Ak = (Ak1 , Ak2 , . . . Ak|G| ) ,
then the Great Orthogonality Theorem can be written as a “dot”

product:
0
Ak ·Ak ∗ = |G|δk,k0 .
This states that the irreducible representations of an Abelian

group are orthogonal vectors in this |G|-dimensional space. Since
there can be at most |G| such vectors, the number of irreducible
representations of an Abelian group is less than or equal to the
order of the group.
4. (a) From Problem 2 of Problem Set 5, the irreducible representa-

tions of the three element group are:
e a b
Γ1 1 1 1
Γ2 1 e2πi/3 e4πi/3
Γ2 1 e4πi/3 e2πi/3
In the notation of Problem 3, we have
A1 = (1, 1, 1), A2 = (1, e2πi/3 , e4πi/3 ), A3 = (1, e4πi/3 , e2πi/3 ) .
Note that some of these entries are complex. Thus, the distinct
inner products between these vectors are
A1 ·A1∗ = 1 + 1 + 1 = 3 ,
5
A2 ·A2∗ = 1 + 1 + 1 = 3 ,
A3 ·A3∗ = 1 + 1 + 1 = 3 ,
A1 ·A2∗ = 1 + e−2πi/3 + e−4πi/3 = 0 ,
A1 ·A3∗ = 1 + e−4πi/3 + e−2πi/3 = 0 ,
A2 ·A3∗ = 1 + e−2πi/3 + e2πi/3 = 0 ,
all of which are consistent with the Great Orthogonality Theorem.
(b) In view of the fact that there are 3 mutually orthogonal vec-
tors, there can be no additional irreducible representations of this
group.
(c) For cyclic groups of order |G|, we determined that the irre-
ducible representations were based on the |G|th roots of unity
(Problem 3, Problem Set 5). Since this produces |G| distinct irre-
ducible representations, our procedure yields all of the irreducible
representations of any cyclic group.
5. Every irreducible representation of an Abelian group is one-dimen-

sional. Moreover, since every one of these representations is either
a homomorphism or isomorphism of the group, with the operation
in the representation being ordinary multiplication, the identity
always corresponds to unity (Problem 9, Problem Set 3). Now,
the order n of a group element g is the smallest integer for which
gn = e .
For every element in any group 1 ≤ n ≤ |G|. This relationship

must be preserved by the irreducible representation. Thus, if Akg
is the entry corresponding to the element g in the kth irreducible
representation, then
(Akg )n = 1 ,
6
i.e., Akg is the nth root of unity:
Akg = e2mπi/n , m = 0, 1, . . . , n − 1 .
The modulus of each of these quantities is clearly unity, so the

modulus of every entry in the irreducible representations of an
Abelian group is unity.
This is consistent with the Great Orthogonality Theorem when

applied to a given representation (cf. Problem 3):
X ∗ X ¯¯ ¯¯2
Akα Akα = ¯Akα ¯ = |G| . (1)
α α
Group Theory
1.∗ Identify the 12 symmetry operations of a regular hexagon.
2. Show that elements in the same class of a group must have the same order.
3.∗ Identify the 6 classes of this group.
Hint: You do not need to compute the conjugacy classes explicitly. Refer to the discus-
sion for the group S3 in Example 2.9 and use the fact that elements in the same class
have the same order.
4.∗ How many irreducible representations are there and what are their dimensions?
5.∗ Construct the character table of this group by following the procedure outlined below:
(a) Enter the characters for the identical and “parity” representations. As in the case
of S3 , the characters for the parity representation are either +1 or −1, depending
on whether or not the the operation preserves the “handedness” of the coordinate
system.
(b) Enter the characters for the “coordinate” representation obtained from the action
on (x, y) for each group operation. Note that the character is the same for elements
in the same class.
(c) Use the products C3 C32 = E and C33 = E to identify the characters for all one-
dimensional irreducible representations for the appropriate classes. The meaning
of the notation Cnm for rotations is discussed in Section 5.4.
(d) Use the result of (c) and the products C6 C3 = C2 to deduce that the characters
for the class of C6 and those for the class of C2 are the same. Then, use the
orthogonality of the columns of the character table to compute these characters.
(e) Use the appropriate orthogonality relations for characters to compute the remaining
entries of the character table.
Group Theory
1. A regular hexagon is shown below:
6 1
5 2
4 3
The following notation will be used for the symmetry operations

of this hexagon:
Ã !
1 2 3 4 5 6
,
a1 a2 a3 a4 a5 a6
where the first row corresponds to the reference order of the ver-
tices shown in the diagram and the ai denote the number at the
ith vertex after the transformation of the hexagon.
The symmetry operations of this hexagon consist of the identity,
rotations by angles of 13 nπ radians, where n = 1, 2, 3, 4, 5, three
mirror planes which pass through opposite faces of the hexagon,
and three mirror planes which pass through opposite vertices of
the hexagon. For the identity and the rotations, the effect on the
hexagon is
2
6 1 1 2 2 3
5 2 6 3 1 4
4 3 5 4 6 5
3 4 4 5 5 6
2 5 3 6 4 1
1 6 2 1 3 2
These operations correspond to

Ã !
1 2 3 4 5 6
E= ,
1 2 3 4 5 6
Ã !
1 2 3 4 5 6
C6 = ,
2 3 4 5 6 1
Ã !
1 2 3 4 5 6
C62 = C3 = ,
3 4 5 6 1 2
Ã !
1 2 3 4 5 6
C63 = C2 = ,
4 5 6 1 2 3
Ã !
1 2 3 4 5 6
C64 = C32 = ,
5 6 1 2 3 4
Ã !
1 2 3 4 5 6
C65 = .
6 1 2 3 4 5
The three mirror planes which pass through opposite faces of the
hexagon are
3
1 6 3 2 5 4
2 5 4 1 6 3
3 4 5 6 1 2
which correspond to
Ã !
1 2 3 4 5 6
σv,1 = ,
6 5 4 3 2 1
Ã !
1 2 3 4 5 6
σv,2 = ,
2 1 6 5 4 3
Ã !
1 2 3 4 5 6
σv,3 = .
4 3 2 1 6 5
Finally, the three mirror planes which pass through opposite ver-
tices of the hexagon are
2 1 4 3 6 5
3 6 5 2 1 4
4 5 6 1 2 3

Ã !
1 2 3 4 5 6
σd,1 = ,
1 6 5 4 3 2
Ã !
1 2 3 4 5 6
σd,2 = ,
3 2 1 6 5 4
4
Ã !
1 2 3 4 5 6
σd,3 = .
5 4 3 2 1 6
That these 12 elements do, in fact, form a group is straightforward

to verify. The standard notation for this group is C6v .
2. The order n of an element a of a group is defined as the smallest

integer such that an = e. If group elements a and b are in the
same class, then there is an element g in the group such that
b = g −1 ag .
The m-fold product of b is then given by
bm = (g −1 ag)(g −1 ag) · · · (g −1 ag) = g −1 am g .

| {z }
m factors
If this is equal to the unit element e, we must have
g −1 am g = e ,
or,
am = e .
The smallest value of m for which this equality can be satisfied

is, by definition, n, the order of a. Hence, two elements in the
same class have the same order.
3. For two elements a and b of a group to be in the same class,

there must be another group element such that b = g −1 ag. If the
group elements are coordinate transformations, then elements in
the same class correspond to the same type of operation, but in
coordinate systems related by symmetry operations. This fact,
together with the result of Problem 2, allows us to determine the
classes of the group of the hexagon.
5
The identity, as always, is in a class by itself. Although all of the

rotations are the same type of operation, not all of these rotations
have the same orders: C6 and C65 have order 6, C3 and C32 have
order 3, and C2 has order 2. Thus, the 5 rotations belong to three
different classes.
The two types of mirror planes, σv,i and σd,i , must belong to differ-
ent classes since there is no group operation which will transform
any of the σv,i to any of the σd,i . To do so would require a rotation
by an odd multiple of 16 π, which is not a group element. All of
the σv,i are in the same class and all of the σd,i are in the same
class, since each is the same type of operation, but in coordinate
systems related by symmetry operations (one of the rotations)
and, of course, they all have order 2, since each reflection plane
is its own inverse.
Hence, there are six classes in this group are
E ≡ {E} ,
2C6 ≡ {C6 , C65 } ,
2C3 ≡ {C3 , C32 } ,
C2 ≡ {C2 } ,
3σv ≡ {σv,1 , σv,2 , σv,3 } ,
3σd ≡ {σd,1 , σd,2 , σd,3 } .
4. As there are 6 classes, there are 6 irreducible representations, the

dimensions of which must satisfy the sum rule
X
6
d2k = 12 ,
k=1
6
since |C6v | = 12. The only positive integer solutions of this equa-
tion are
d1 = 1, d2 = 1, d3 = 1, d4 = 1, d5 = 2, d6 = 2 ,
i.e., there are 4 one-dimensional irreducible representations and 2

two-dimensional irreducible representations.
5. (a) For the identical representation, all of the characters are 1.

For the parity representation, the character is 1 for operations
which preserve the parity of the coordinate system (“proper” ro-
tations) and −1 for operations which change the parity of the
coordinate system (“improper” rotations). Additionally, we can
enter immediately the column of characters for the class of the
unit element. These are equal to the dimensionality of each ir-
reducible representation, since the unit element is the identity
matrix with that dimensionality. Thus, we have the following
entries for the character table of C6v :
C6v E 2C6 2C3 C2 3σv 3σd

Γ1 1 1 1 1 1 1
Γ01 1 1 1 1 −1 −1
Γ001 1
Γ000
1 1
Γ2 2
Γ02 2
(b) The characters for one of the two-dimensional representations

of C6v can be obtained by constructing matrices for operations
in analogy with the procedure discussed in Section 3.2 for the
equilateral triangle. One important difference here is that we
require such a construction only for one element in each class
(since the all matrices in a given class have the same trace). We
will determine the representations of operations in each class in
an (x, y) coordinate system shown below:
7
Thus, a rotation by an angle φ, denoted by R(φ), is given by the

two-dimensional rotational matrix:
Ã !
cos φ sin φ
R(φ) = .
− sin φ cos φ
The corresponding character χ(φ) is, therefore, simply the sum

of the diagonal elements of this matrix:
χ(φ) = 2 cos φ .
We can now calculate the characters for each of the classes com-
posed of rotations:
χ(2C6 ) = χ( 13 π) = 1 ,
χ(2C3 ) = χ( 23 π) = −1 ,
χ(C2 ) = χ(π) = −2 .
For the two classes of mirror planes, we need only determine the
character of one element in each class, which may be chosen at
our convenience. Thus, for example, since the representation of
8
σv,1 can be determined directly by inspection:

Ã !
−1 0
,
0 1
we can obtain the character of the corresponding class as
χ(3σv ) = 0 .
Similarly, the representation of σd,2 can also be determined di-
rectly by inspection:
Ã !
1 0
,
0 −1
which yields the character
χ(3σd ) = 0 .
We can now add the entries for this two-dimensional irreducible

representations to the character table of C6v :

Γ1 1 1 1 1 1 1
Γ01 1 1 1 1 −1 −1
Γ001 1
Γ000
1 1
Γ2 2 1 −1 −2 0 0
Γ02 2
(c) The one-dimensional irreducible representations must obey

the multiplication table, since they themselves are representations
of the group. In particular, given the products
C3 C32 = E, C33 = E ,
if we denote by α the character of the class 2C3 = {C3 , C32 }, then
these products require that
α2 = 1, α3 = 1 ,
9
respectively. Thus, we deduce that α = 1 for all of the one-

dimensional irreducible representations. With these additions to
the character table, we have

Γ1 1 1 1 1 1 1
Γ01 1 1 1 1 −1 −1
Γ001 1 1
Γ000
1 1 1
Γ2 2 1 −1 −2 0 0
Γ02 2
(d) Since the character for all one-dimensional irreducible rep-

resentations for the class 2C3 = {C3 , C32 } is unity, the product
C6 C3 = C2 requires that the characters for the classes of C6 and
C2 are the same in these representations. Since C22 = E, this char-
acter must be 1 or −1. Suppose we choose χ(2C6 ) = χ(C2 ) = 1.
Then, the orthogonality of the columns of the character table
requires that the character for the classes E and 2C6 are orthog-
onal. If we denote by β the character for the class 2C6 of the
representation Γ02 , we require
(1 × 1) + (1 × 1) + (1 × 1) + (1 × 1) + (2 × 1) + (2 × β) = 0 ,
i.e., β = −3. But this value violates the requirement that
X
nα |χα |2 = |G| . (1)
α
Thus, we must choose χ(2C6 ) = χ(C2 ) = −1, and our character

table becomes
Γ1 1 1 1 1 1 1
Γ01 1 1 1 1 −1 −1
Γ001 1 −1 1 −1
Γ000
1 1 −1 1 −1
Γ2 2 1 −1 −2 0 0
Γ02 2
10
(e) The characters for the classes 2C6 , 2C3 , and C2 of the Γ02
representation can now be determined by requiring the columns
corresponding to these classes to be orthogonal to the column
corresponding to the class of the identity. When this is done, we
find that the values obtained saturate the sum rule in (1), so the
characters corresponding to both classes of mirror planes in this
representation must vanish. This enables to complete the entries
for the Γ02 representation:

Γ1 1 1 1 1 1 1
Γ01 1 1 1 1 −1 −1
Γ001 1 −1 1 −1
Γ000
1 1 −1 1 −1
Γ2 2 1 −1 −2 0 0
Γ02 2 −1 1 2 0 0
The remaining entries are straightforward to calculate. The fact

that each mirror reflection has order 2 means that these entries
must be either +1 or −1. The requirement of orthogonality of
columns leaves only one choice:

Γ1 1 1 1 1 1 1
Γ01 1 1 1 1 −1 −1
Γ001 1 −1 1 −1 1 −1
Γ000
1 1 −1 1 −1 −1 1
Γ2 2 1 −1 −2 0 0
Γ02 2 −1 1 2 0 0
which completes the character table for C6v .

Group Theory
1. Show that if two matrices A and B are orthogonal, then their direct product A ⊗ B is
also an orthogonal matrix.
2. Show that the trace of the direct product of two matrices A and B is the product of
the traces of A and B:
tr(A ⊗ B) = tr(A) tr(B)
3.∗ Show that the direct product of groups Ga and Gb with elements Ga = {e, a2 , . . . , a|Ga | }
and Gb = {e, b2 , . . . , b|Gb | }, such that ai bj = bj ai for all i and j, is a group. What is
the order of this group?
4.∗ Use the Great Orthogonality Theorem to show that the direct product of irreducible
representations of two groups is an irreducible representation of the direct product of
those groups.
5.∗ For an n-fold degenerate set of eigenfunctions ϕi , i, 1, 2, . . . , n, we showed show that

the matrices Γ(Rα ) generated by the group of the Hamiltonian,
X
n
R α ϕi = ϕj Γji (Rα )
j=1
form a representation of that group. Show that if the ϕj are chosen to be an orthonormal
set of functions, then this representation is unitary.
6.∗ The set of distinct functions obtained from a given function ϕi by operations in the
group of the Hamiltonian, ϕj = Rα ϕi , are called partners. Use the Great Orthogonality
Theorem to show that two functions which belong to different irreducible representa-
tions or are different partners in the same unitary representation are orthogonal.
7. Consider a particle of mass m confined to a square in two dimensions whose vertices

are located at (1, 1), (1, −1), (−1, −1), and (−1, 1). The potential is taken to be zero
within the square and infinite at the edges of the square. The eigenfunctions ϕ are of
the form ( )( )
cos(kp x) cos(kq y)
ϕp,q (x, y) ∝
sin(kp x) sin(kq y)
where kp = 12 pπ, kq = 12 qπ, and p and q are positive integers. The notation above
means that cos(kp x) is taken if p is odd, sin(kp x) is taken if p is even, and similarly for
the other factor. The corresponding eigenvalues are
h̄2 π 2 2
Ep,q = (p + q 2 )
8m
(a) Determine the eight planar symmetry operations of a square. These operations form
the group of the Hamiltonian for this problem. Assemble the symmetry operations
into equivalence classes.
(b) Determine the number of irreducible representations and their dimensions for this
group. Do these dimensions appear to be broadly consistent with the degeneracies
of the energy eigenvalues?
(c) Determine the action of each group operation on (x, y).

Hint: This can be done by inspection.
(d) Determine the characters corresponding to the identical, parity, and coordinate
representations. Using appropriate orthogonality relations, complete the character
table for this group.
(e) For which irreducible representations do the eigenfunctions ϕ1,1 (x, y) and ϕ2,2 (x, y)
form bases?
(f) For which irreducible transformation do the eigenfunctions ϕ1,2 (x, y) and ϕ2,1 (x, y)
form a basis?
(g) What is the degeneracy corresponding to (p = 6, q = 7) and (p = 2, q = 9)? Is this

a normal or accidental degeneracy?
(h) Are there eigenfunctions which form a basis for each of the irreducible representa-
tions of this group?
8.∗ Consider the regular hexagon in Problem Set 7. Suppose there is a vector perturbation,
i.e., a perturbation that transforms as (x, y, z). Determine the selection rule associated
with an initial state that transforms according to the “parity” representation.
Hint: The reasoning for determining the irreducible representations associated with
(x, y, z) is analogous to that used in Section 6.6.2 for the equilateral triangle.
Group Theory
Solutions to Problem Set 8 December 7, 2001
1. A matrix A is said to be orthogonal if its matrix elements aij

satisfy the following relations:
X X
aij aik = δj,k , aij akj = δij , (1)
i j
i.e., the rows and columns are orthogonal vectors. This ensures
that At A = AAt = I.
The direct product C of two matrices A and B, denoted by C =
A ⊗ B, is given in terms of matrix elements by
cik;jl = aij akl .
If A and B are orthogonal matrices, then we can show that C is

also an orthogonal matrix by verifying the relations in Eq. (1).
The first of these relations is
X
cik;jl cik;j 0 l0
ik
X µX ¶µ X ¶
= aij akl aij 0 akl0 = aij aij 0 akl akl0 = δj,j 0 δl,l0 ,
ik i k
where the last step follows from the first of Eqs. (1). The second
orthogonality relation is
X
cik;jl ci0 k0 ;jl
jl
X µX ¶µ X ¶
= aij akl ai0 j ak0 l = aij ai0 j akl ak0 l = δi,i0 δk,k0
jl j l
where the last step follows from the second of Eqs. (1). Thus, we
have shown that the direct product of two orthogonal matrices is
also an orthogonal matrix.
2
2. The direct product of two matrices A and B with matrix elements

aij and bij is
cik,jl = aij bkl .
The trace of the direct product A ⊗ B is obtained by setting j = i

and l = k and summing over i and k:
X X X X
tr(A ⊗ B) = cik,ik = aii bkk = aii bkk = tr(A) tr(B) ,
ik ik i k
which is the product of the traces of A and B.
3. We have two groups Ga and Gb with elements
Ga = {ea , a2 , a3 , . . . , a|Ga | }
and
Gb = {eb , b2 , b3 , . . . , b|Gb | } ,
such that ai bj = bj ai for all i and j. We are using a notation

where it is understood that a1 = ea and b1 = eb . The direct
product Ga ⊗ Gb of these groups is the set obtained by forming
the product of every element of Ga with every element of Gb :
Ga ⊗ Gb = {e, a2 , a3 , . . . , ana , b2 , b3 , . . . , bnb , . . . , ai bj , . . .} .
To show that Ga ⊗ Gb is a group, we must demonstrate that these

elements fulfill each of the four requirements in Sec. 2.1.
Closure. The product of two elements ai bj and ai0 bj 0 is given by
(ai bj )(ai0 bj 0 ) = (ai ai0 )(bj bj 0 ) = ak bl ,
where the first step follows from the commutativity of elements

between the two groups and the second step from the group prop-
erty of Ga and Gb .
3
Associativity. The associativity of the composition law follows

from
h ih i
(ai bi0 aj bj 0 )ak bk0 = (ai aj )ak (bi0 bj 0 )bk0
h ih i
= ai (aj ak ) bi0 (bj 0 bk0 )
= ai bi0 (aj bj 0 ak bk0 ) ,
since associativity holds for Ga and Gb separately.

Unit Element. The unit element e for the direct product group is
ea eb = eb ea , since
(ai bj )(ea eb ) = (ai ea )(bj eb ) = (ea ai )(eb bj ) = (ea eb )(ai bj ) .
Inverse. Finally, the inverse of each element ai bj is a−1 −1

i bj because
(ai bj )(a−1 −1 −1 −1
i bj ) = (ai ai )(bj bj ) = ea eb
and
(a−1 −1 −1 −1
i bj )(ai bj ) = (ai ai )(bj bj ) = ea eb .
Thus, we have shown that the direct product of two groups is

itself a group. Since the elements of this group are obtained by
taking all products of elements from Ga and Gb , the order of this
group is |Ga ||Gb |.
4. Suppose we have an irreducible representation for each of two

groups Ga and Gb . We denote these representations, which may
be of different dimensions, by A(ai ) and A(bj ), and their matrix
elements by A(ai )ij and A(bj )ij . Since these representations are
irreducible, they satisfy the Great Orthogonality Theorem:
X |Ga |
A(ai )∗ij A(ai )i0 j 0 = δi,i0 δj,j 0 ,
ai da
X |Gb |
A(bj )∗ij A(bj )i0 j 0 = δi,i0 δj,j 0 ,
bj db
4
where da and db are the dimensions of the irreducible representa-

tions of Ga and Gb , respectively. A representation of the direct
product of two groups, denoted by A(ai bj ), is obtained from the
direct product of representations of each group:
A(ai bj )ik;jl = A(ai )ij A(bj )kl .
The sum in the Great Orthogonality Theorem for the direct prod-
uct representation is
XX
A(ai bj )∗ik;jl A(ai bj )i0 k0 ;j 0 l0
ai bj
XX
= A(ai )∗ij A(bj )∗kl A(ai )i0 j 0 A(bj )k0 l0
ai bj
·X ¸·X ¸
= A(ai )∗ij A(ai )i0 j 0 A(bj )∗kl A(bj )k0 l0
ai bj
| {z }| {z }
|Ga | |Gb |
δi,i0 δj,j 0 δk,k0 δl,l0
da db
µ ¶
|Ga ||Gb |
= δi,i0 δk,k0 δj,j 0 δl,l0 .
da db
This shows that this direct product representation is, in fact,

irreducible. It has dimensionality da db and the order of the direct
product is, of course, |Ga | × |Gb |.
5. If the ϕi are orthonormal, and if this property is required to be

preserved by the group of the Hamiltonian (as it must, to conserve
probability), then, in Dirac notation, we have
Z Z
∗
(i, j) ≡ ϕi (x) ϕj (x) dx = [Rϕi (x)]∗ Rϕj (x) dx
= (i|R† R|j) = δi,j .

5
Therefore,
X
(i|R† R|j) = (k, l)Γ(R)∗ki Γ(R)lj
k,l
X
= Γ(R)∗ki Γ(R)kj
k
Xh i
= Γ(R)† Γ(R)kj
ik
k
h i
= Γ(R)† Γ(R) ,
ij
i.e., when written in matrix notation,
Γ(R)† Γ(R) = I .
Thus, the matrix representation is unitary.
6. We again use Dirac notation to signify basis functions ϕi and

ϕj corresponding to irreducible representations n and n0 , respec-
tively: |n, i) and |n0 , j). Then, the operations R in the group of
the Hamiltonian applied to these functions yield
X
R|n, i) = Γ(n) (R)ki |n, k) ,
k
X 0
R|n0 , j) = Γ(n ) (R)lj |n0 , l) .
l
Since the operators and their representations are unitary,

X 0
(n0 , j|R† = (n0 , j|R−1 = Γ(n ) (R)∗lj (n0 , l| ,
l
we have
(n0 , j|R−1 R|n, i) = (n0 , j|n, i)

X 0
= Γ(n ) (R)∗kj Γ(n) (R)li (n0 , k|n, l) .
kl
6
If we now sum both sides of this equation over the elements of

the group of the Hamiltonian, and invoke the Great Orthogonality
Theorem, we obtain
X
(n0 , j|n, i) = |G|(n0 , j|n, i)
R
X·X ¸
(n0 )
= Γ (R)∗kj Γ(n) (R)li (n0 , k|n, l)
kl R
| {z }
|G|
δn,n0 δk,l δi,j
dn
= |G|δn,n0 δi,j (n0 , k|n, k) ,
where |G| is the order of the group of the Hamiltonian and dn is

the dimension of the nth irreducible representation. Therefore,
(n0 , j|n, i) = δn,n0 δi,j ,
since (n, k|n, k) = 1.
7. (a) A square is shown below:
4 1
3 2
In analogy with the procedure described in Problem Set 7, we

will use the following notation for the symmetry operations of
7
this hexagon:
Ã !
1 2 3 4
,
a1 a2 a3 a4
where the ai denote the number at the ith vertex after the trans-
formation of the hexagon given in the indicated reference order.
Thus, the identity operation, which identifies the reference order
of the vertices, corresponds to
Ã !
1 2 3 4
.
1 2 3 4
The symmetry operations on this square consist of the identity,

rotations by angles of 12 nπ radians, for n = 1, 2, 3, two mirror
planes which pass through opposite faces of the square, and two
mirror planes which pass through opposite vertices of the square.
For the rotations, the effect on the square is
3 4 2 3 1 2
2 1 1 4 4 3

Ã !
1 2 3 4
C4 = ,
4 1 2 3
Ã !
1 2 3 4
C42 = C2 = ,
3 4 1 2
Ã !
1 2 3 4
C43 = .
2 3 4 1
8
The two mirror planes which pass through opposite faces of the
square are
1 4 3 2
2 3 4 1
which correspond to
Ã !
1 2 3 4
σv,1 = ,
4 3 2 1
Ã !
1 2 3 4
σv,2 = .
2 1 4 3
Finally, the two mirror planes which pass through opposite ver-
tices of the square are
2 1 4 3
3 4 1 2

Ã !
0
1 2 3 4
σv,1 = ,
1 4 3 2
Ã !
0
1 2 3 4
σv,2 = .
3 2 1 4
9
Elements in the same equivalence class must have the same order
and correspond to the same “type” of operation. Thus, there are
five equivalence classes of this group:
{E}, {C2 = C42 }, {2C4 }, {2σv }, {2σv0 } .
Note that, as in the case of the regular hexagon (Problem Set

7), all of the rotations need not belong to the same class, despite
being the same “type” of operation because they must also have
the same order.
(b) The order of this group is 8 and there are 5 equivalence classes.
Thus, there must be five irreducible representations whose dimen-
sionalities must satisfy
d21 + d22 + d23 + d24 + d25 = 8 .
The only solution of this equation (with positive integer values

for the dk ) is
d1 = 1, d2 = 1, d3 = 1, d4 = 1, d5 = 2 .
These dimensionalities imply that the energy levels for a Hamilto-

nian with this symmetry are either nondegenerate or are two-fold
degenerate. From the expression given for the energy eigenval-
ues, we see immediately that the energy eigenvalues with p = q
are non-degenerate, and those with p 6= q are two-fold degen-
erate (but see below). Thus, the dimensions of the irreducible
representations are consistent with these degeneracies.
(c) The simplest way to obtain a two-dimensional representation

of this group is to consider the action of each group element on
some generic point (x, y). Then the action on this point of each
of the operations given above can be determined by inspection.
We begin with the figure below:
10
From the diagrammatic representation of each symmetry opera-

tion, we will be able to determine the corresponding representa-
tion, simply by inspection. The action on this point by the three
rotations acn be represented as
These rotations are thus seen to transform the point (x, y) into
(−y, x), (−x, −y), and (y, −x), respectively. The two reflections
that pass through the center of faces are
so they transform the (x, y) into (−x, y) and (x, −y), respectively.
Finally, for the two reflection planes which pass through vertices,
11
which transform the point (x, y) into (y, x) and (−y, −x), respec-
tively. These transformations enable us to construct the char-
acters corresponding to the “coordinate” representation. Then,
together with the identical and parity representations, we have
the following entries of the character table for this group:
E C2 2C4 2σv 2σv0

Γ1 1 1 1 1 1
Γ01 1 1 1 −1 −1
Γ001 1
Γ000
1 1
Γ2 2 −2 0 0 0
The group multiplication table and the orthogonality of columns

allows us to immediately complete the entries for the classes {C2 }
and {2C4 }:
E C2 2C4 2σv 2σv0

Γ1 1 1 1 1 1
Γ01 1 1 1 −1 −1
Γ001 1 1 −1
Γ000
1 1 1 −1
Γ2 2 −2 0 0 0
The remaining four entries can be determined from the orthog-

onality of either rows or columns and again invoking the group
multiplication table:
12
E C2 2C4 2σv 2σv0

Γ1 1 1 1 1 1
Γ01 1 1 1 −1 −1
Γ001 1 1 −1 1 −1
Γ000
1 1 1 −1 −1 1
Γ2 2 −2 0 0 0
(e) The eigenfunctions ϕ1,1 (x, y) and ϕ2,2 (x, y) are given by
ϕ1,1 (x, y) ∝ cos( 12 πx) cos( 12 πy)
and
ϕ2,2 (x, y) ∝ sin(πx) sin(πy) .
Since ϕ1,1 (x, y) is invariant under the interchange of x and y and
under changes in their signs, it transforms according to the iden-
tical representation. However, although ϕ2,2 (x, y) is invariant un-
der the interchange of x and y, each sine factor changes sign if
their argument changes sign. Thus, this eigenfunction transforms
according to the parity representation.
(f) The (degenerate) eigenfunctions ϕ1,2 (x, y) and ϕ2,1 (x, y) are
Ã ! " #
ϕ1,2 cos( 12 πx) sin(πy)
∝ .
ϕ2,1 sin(πx) cos( 12 πy)
The transformation properties of these eigenfunctions can be de-
termined from the results of part (c). This yields the following
matrix representation of each symmetry operation:
Ã ! Ã ! Ã !
1 0 0 1 −1 0
E= , C4 = , C42 = ,
0 1 −1 0 0 −1
Ã ! Ã ! Ã !
0 −1 1 0 −1 0
C43 = , σv,1 = , σv,2 = ,
1 0 0 −1 0 1
Ã ! Ã !
0
0 1 0
0 −1
σv,1 = , σv,2 = .
1 0 −1 0
13
This produces the following characters:
{E} = 2, {C2 } = −2, {2C4 } = 0, {2σv } = 0, {2σv0 } = 0 ,
which are the characters of the two-dimensional irreducible repre-

sentation Γ2 , which is the “coordinate” irreducible representation.
(g) We have that the energies E6,7 and E2,9 are given by
h̄2 π 2 2 h̄2 π 2
E6,7 = E7,6 = (6 + 72 ) = 85
8m 8m
and
h̄2 π 2 2 2 h̄2 π 2
E2,9 = E9,2 = (2 + 9 ) = 85 ,
8m 8m
so this energy is fourfold degenerate. However, since the group
operations have the effect of interchanging x and y with possible
changes of sign, the eigenfunctions ϕ6,7 and ϕ7,6 are transformed
only between one another, and the eigenfunctions ϕ2,9 and ϕ9,2
are transformed only between one another. In other words, this
fourfold degeneracy is accidental, resulting only from the numer-
ical coincidence of the energies of two twofold-degenerate states.
(h) We have already determined that ϕp,p with p even transforms

according to the identical representation, while if p is odd, ϕp,p
transforms according to the parity representation. Moreover, the
pair of eigenfunctions ϕp,q where p is even and q is odd transforms
according to the coordinate representation.
Consider now the case where the eigenfunctions are of the form
ϕp,q where both p and q are even. The matrices corresponding to
14
the symmetry operations are

Ã ! Ã ! Ã !
1 0 0 1 1 0
E= , C4 = , C42 = ,
0 1 1 0 0 1
Ã ! Ã ! Ã !
0 1 1 0 1 0
C43 = , σv,1 = , σv,2 = ,
1 0 0 1 0 1
Ã ! Ã !
0
0 1 0
0 1
σv,1 = , σv,2 = .
1 0 1 0
The corresponding characters are
{E} = 2, {C2 } = 2, {2C4 } = 0, {2σv } = 2, {2σv0 } = 0 .
This representation must be reducible, since its characters do not

correspond to those of any of the irreducible representations in
the table determined in Part (d). A straightforward application
of the Decomposition Theorem (or simple inspection) shows that
this representation is the direct sum of the Γ1 and Γ001 irreducible
representations. This means that there is a linear combination of
these eigenfunctions that diagonalizes the matrices corresponding
to each symmetry operation of this group.
For the eigenfunctions of the form ϕp,q where both p and q are
odd, the matrices corresponding to the symmetry operations are
Ã ! Ã ! Ã !
1 0 0 −1 1 0
E= , C4 = , C42 = ,
0 1 −1 0 0 1
Ã ! Ã ! Ã !
0 −1 −1 0 −1 0
C43 = , σv,1 = , σv,2 = ,
−1 0 0 −1 0 −1
Ã ! Ã !
0
0 1 0
0 1
σv,1 = , σv,2 = .
1 0 1 0
The characters are now
{E} = 2, {C2 } = 2, {2C4 } = 0, {2σv } = −2, {2σv0 } = 0 .

15
which correspond to a reducible representation composed of the

direct sum of the Γ01 and Γ000
1 irreducible representations. Thus,
all of the irreducible representations occur in the eigenfunctions
of the two-dimensional square well.
8. The character table of the regular hexagon is reproduced below:

Γ1 1 1 1 1 1 1
Γ01 1 1 1 1 −1 −1
Γ001 1 −1 1 −1 1 −1
Γ000
1 1 −1 1 −1 −1 1
Γ2 2 1 −1 −2 0 0
Γ02 2 −1 1 2 0 0
A transformation properties of a vector perturbation can be de-

duced in a manner analogous to that for the equilateral trian-
gle (Section 6.6.2). Applying each symmetry operation to r =
(x, y, z) produces a reducible representation because these oper-
ations are either rotations or reflections through vertical planes.
Thus, the z axis is invariant under every symmetry operation of
this group which. Together with the fact that an (x, y) basis gen-
erates the two-dimensional irreducible representation Γ2 [Problem
5(b), Problem Set 7], yields
Γ0 = Γ1 ⊕ Γ2 .
The corresponding characters are

Γ1 ⊕ Γ2 3 2 0 −1 1 1
to determine the selection rule for an initial state that transforms

according to the parity representation (Γ01 , we must calculated
Γ01 ⊗ Γ0 = Γ01 ⊗ (Γ1 ⊕ Γ2 ) .
The characters associated with this operation are

16

Γ01 ⊗ (Γ1 ⊕ Γ2 ) 3 2 0 −1 −1 −1
Finally, either by inspection, or by applying the decomposition

theorem, we find that
Γ01 ⊗ (Γ1 ⊕ Γ2 ) = Γ01 ⊕ Γ2 ,
so transitions between states that transform according to the par-

ity representation and any states other than those that transform
as the parity or coordinate representations are forbidden by sym-
metry.
Group Theory
Problem Set 9 December 4, 2001
1.∗ Consider the group O(n), the elements of which preserve the Euclidean length in n
dimensions:
x02 02 02
1 + x2 + · · · + xn = x1 + x2 + · · · + xn .
2 2 2
Show that these transformations have 12 n(n − 1) free parameters.
2. The condition that the Euclidean length is preserved in two dimensions, x02 + y 02 =
x2 + y 2 , was shown in lectures to require that
a211 + a221 = 1, a11 a12 + a21 a22 = 0, a212 + a222 = 1 .
Show that these requirements imply that
(a11 a22 − a12 a21 )2 = 1 .
3. Rotations in two dimensions can be parametrized by

Ã !
cos ϕ − sin ϕ
R(ϕ) = .
sin ϕ cos ϕ
Show that
R(ϕ1 + ϕ2 ) = R(ϕ1 )R(ϕ2 )
and, hence, deduce that this group is Abelian.
4.∗ We showed in lectures that a rotation R(ϕ) by an angle ϕ in two dimensions can be
written as
R(ϕ) = eϕX ,
where Ã !
0 −1
X= .
1 0
Verify that
eϕX = I cos ϕ + X sin ϕ ,
where I is the two-dimensional unit matrix. This shows that eϕX is the rotation matrix
in two dimensions.
5.∗ Consider the two-parameter group
x0 = ax + b
Determine the infinitesimal operators of this group.
6.∗ Consider the group C∞v which contains, in addition to all two-dimensional rotations,
a reflection plane, denoted by σv in, say, the x-z plane. Is this group Abelian? What
are the equivalence classes of this group?
Hint: Denoting reflection in the x–z plane by S, show that SR(ϕ)S −1 = R(−ϕ).
7. By extending the procedure used in lectures for SO(3), show that the infinitesimal
generators of SO(4), the group of proper rotations in four dimensions which leave the
quantity x2 + y 2 + z 2 + w2 invariant, are
∂ ∂ ∂ ∂ ∂ ∂
A1 = z −y , A2 = x −z , A3 = y −x
∂y ∂z ∂z ∂x ∂x ∂y
∂ ∂ ∂ ∂ ∂ ∂
B1 = x −w , B2 = y −w , B3 = z −w
∂w ∂x ∂w ∂y ∂w ∂z
8. Show that the commutators of the generators obtained in Problem 7 are
[Ai , Aj ] = εijk Ak , [Bi , Bj ] = εijk Ak , [Ai , Bj ] = εijk Bk
9. Show that by making the linear transformation of the generators in Problem 7 to
Ji = 12 (Ai + Bi ), Ki = 12 (Ai − Bi )
the commutators become
[Ji , Jj ] = εijk Jk , [Ki , Kj ] = εijk Kk , [Ji , Kj ] = 0
This shows that locally SO(4)=SO(3)⊗SO(3).

Group Theory
1. The Lie group GL(n,R) has n2 parameters, because the transfor-

mations can be represented as n × n matrices (with real entries).
The requirement that the Euclidean length dimensions be pre-
served by such a transformation leads to the requirement that,
x02 02 02
1 + x2 + · · · + xn = x1 + x2 + · · · + xn .
2 2 2
Proceeding as in Sec. 7.2, we note that there are n conditions

from the requirement that the coefficients of xi , i = 1, 2, . . . , n
be equal to unity. Then, there are 12 n(n − 1) conditions from the
requirement that the coefficients of the unique products xi xj , i 6=
j vanish. Thus, beginning with n free parameters for GL(n,R),
there are
n2 − n − 12 n(n − 1) = n2 − n − 12 n2 + 12 n = 12 n(n − 1)
free parameters for O(n).
2. Beginning with the three conditions
a211 + a221 = 1, a11 a12 + a21 a22 = 0, a212 + a222 = 1 ,
we take the product of the first by the third equations and sub-
tract the square of the second equation to obtain
(a211 + a221 )(a212 + a222 ) − (a11 a12 + a21 a22 )2

= a211 a212 + a211 a222 + a221 a212 + a221 a222 − a211 a212
−2a11 a12 a21 a22 − a221 a222
= a211 a222 + a221 a212 − 2a11 a12 a21 a22
= (a11 a22 − a12 a21 )2
= 1.
2
Thus, the three constraints for orthogonal groups in two dimen-

sions imply that the square of the determinant of such transfor-
mation must be equal to unity.
3. Forming the product of the the matrices corresponding to R(ϕ1 )

and R(ϕ2 ) yields
Ã !Ã !
cos ϕ1 − sin ϕ1 cos ϕ2 − sin ϕ2
sin ϕ1 cos ϕ1 sin ϕ2 cos ϕ2
Ã !
cos ϕ1 cos ϕ2 − sin ϕ1 sin ϕ2 − cos ϕ1 sin ϕ2 − sin ϕ1 cos ϕ2
= .
sin ϕ1 cos ϕ2 + cos ϕ1 sin ϕ2 − sin ϕ1 sin ϕ2 + cos ϕ1 cos ϕ2
By invoking the standard trigonometric identities for the sines

and cosines of the sum and difference of two angles,
cos(x ± y) = cos x cos y ∓ sin x sin y ,

sin(x ± y) = sin x cos y ± cos x sin y ,
we can write
Ã !Ã !
cos ϕ1 − sin ϕ1 cos ϕ2 − sin ϕ2
sin ϕ1 cos ϕ1 sin ϕ2 cos ϕ2
" #
cos(ϕ1 + ϕ2 ) − sin(ϕ1 + ϕ2 )
= .
sin(ϕ1 + ϕ2 ) cos(ϕ1 + ϕ2 )
Thus,
R(ϕ1 + ϕ2 ) = R(ϕ1 )R(ϕ2 ) .

3
4. The expression
R(ϕ) = eϕX ,
where
Ã !
0 −1
X= ,
1 0
is defined by its Taylor series:
∞
X 1
eϕX = (ϕX)n . (1)
n=0 n!
Successive powers of X yield

Ã ! Ã !
0 −1 2
−1 0
X= , X = ,
1 0 0 −1
Ã ! Ã !
0 1 1 0
X3 = , X4 = ,
−1 0 0 1
whereupon this sequence is repeated. We can write this sequence
in matrix form as X 2 = −I, X 3 = −X, X 4 = I, . . ., where I is
the 2 × 2 unit matrix. The powers of X are therefore given by

 I, n even
X 2n =

−I, n odd
for even powers and

 X, n even
X 2n+1 =

−X, n odd
for odd powers Thus, the Taylor series in (1) may be written as
∞
X ∞
X
(−1)n (−1)n 2n+1
eϕX = ϕ2n I + ϕ X
n=0 (2n)! n=0 (2n + 1)!
| {z } | {z }
cos ϕ sin ϕ
4
= I cos ϕ + X sin ϕ
Ã !
cos ϕ − sin ϕ
= ,
sin ϕ cos ϕ
which is the rotation matrix in two dimensions.
5. The two parameter group
x0 = ax + b
was discussed in Example 7.1. The identity was found to cor-

respond to the parameters a = 1 and b = 0. The infinitesimal
transformations are therefore given by
x0 = (1 + da)x + db = x + x da + db .
If we substitute this into some function f (x) and expand to first

order in the parameters a and b, we obtain
∂f ∂f
f (x0 ) = f (x + x da + db) = f (x) + x da + db ,
∂x ∂x
from which we identify the infinitesimal operators
∂ ∂
X1 = x , X2 = .
∂x ∂x
6. The group C∞v contains all two-dimensional rotations and a ver-

tical reflection plane, denoted by σv , in the x-z plane. Since this
reflection changes the parity of the coordinate system, it changes
the sense of the rotation angle ϕ. Thus, a rotation by ϕ in the
original coordinate system corresponds to a rotation by −ϕ in the
5
transformed coordinate system. Denoting the reflection operator

by S, we then must have that
SR(ϕ)S −1 = R(−ϕ) . (2)
Since S = S −1 , we can see this explicitly for the two-dimensional
rotation matrix R(ϕ):
Ã !Ã !Ã ! Ã !
1 0 cos ϕ − sin ϕ 1 0 cos ϕ sin ϕ
= ,
0 −1 sin ϕ cos ϕ 0 −1 − sin ϕ cos ϕ
where the matrix on the right-hand side of this equation is R(−ϕ).
Equation (2) shows that (i) the group is no longer Abelian, and
(ii) the equivalence classes correspond to rotations by ϕ and −ϕ.
7. Proceeding as in Section 7.4, the infinitesimal rotations in four

dimensions which leave the quantity x2 + y 2 + z 2 + w2 invariant
are
    
x0 1 ϕ1 ϕ2 ϕ3 x
    
 0   
y   −ϕ1 1 ϕ4 ϕ5  y
    
 =  .
 0 
z   −ϕ2 −ϕ4 1 ϕ6   
 z 
    
0
w −ϕ3 −ϕ5 −ϕ6 1 w
Substituting this coordinate transformation into a differentiable
function F (x, y, z, w),
F (x0 , y 0 , z 0 , w0 )
= F (x + ϕ1 y + ϕ2 z + ϕ3 w, y − ϕ1 x − ϕ4 z + ϕ5 w,
z − ϕ2 x + ϕ4 y + ϕ6 w, w − ϕ3 x − ϕ5 y − ϕ6 z) .
and expanding to first order in the ϕi , yields
µ ¶
0 0 0 0 ∂F ∂F
F (x , y , z , w ) = F (x, y, z, w) + ϕ1 y −x
∂x ∂y
6
µ ¶ µ ¶
∂F ∂F ∂F ∂F
= ϕ2 z −x + ϕ3 w −x
∂x ∂z ∂x ∂w
µ ¶ µ ¶
∂F ∂F ∂F ∂F
= ϕ4 y −z + ϕ5 w −y
∂z ∂y ∂y ∂w
µ ¶
∂F ∂F
= ϕ6 w −z .
∂z ∂w
From these equations and, if necessary, a change in sign of the
corresponding ϕi , we can identify the following differential oper-
ators
∂ ∂ ∂ ∂ ∂ ∂
A1 = z −y , A2 = x −z , A3 = y −x ,
∂y ∂z ∂z ∂x ∂x ∂y
∂ ∂ ∂ ∂ ∂ ∂
B1 = x − t , B2 = y − t , B3 = z − t .
∂t ∂x ∂t ∂y ∂t ∂z
8. With the infinitesimal generators calculated in Problem 7, we de-

termine the commutators in the standard fashion. For the com-
mutators between the Ai , we have
[A1 , A2 ]f = A1 (A2 f ) − A2 (A1 f )

µ ¶µ ¶ µ ¶µ ¶
∂ ∂ ∂f ∂f ∂ ∂ ∂f ∂f
= z −y x −z − x −z z −y
∂y ∂z ∂z ∂x ∂z ∂x ∂y ∂z
∂2f ∂2f ∂2f ∂f ∂2f

= xz − z2 − xy 2 + y + yz
∂y∂z ∂y∂x ∂z ∂x ∂z∂x
∂f ∂2f ∂ 2f ∂2f ∂2f

−x − xz + xy 2 + z 2 + yz
∂y ∂z∂y ∂z ∂x∂y ∂x∂z
∂f ∂f
=y − −x
∂x ∂y
= A3 f ,
7
[A1 , A3 ]f = A1 (A3 f ) − A3 (A1 f )

µ ¶µ ¶ µ ¶µ ¶
∂ ∂ ∂f ∂f ∂ ∂ ∂f ∂f
= z −y y −x − y −x z −y
∂y ∂z ∂x ∂y ∂x ∂y ∂y ∂z
∂f ∂ 2f ∂2f ∂ 2f ∂ 2f
=z + yz − xz 2 − y 2 + xy
∂x ∂y∂z ∂y ∂z∂x ∂z∂y
∂2f ∂2f ∂ 2f ∂f ∂2f

−yz + y2 + xz 2 − x − xy
∂x∂y ∂x∂z ∂y ∂z ∂y∂z
∂f ∂f
=z −x
∂x ∂z
= −A2 f ,
[A2 , A3 ]f = A2 (A3 f ) − A3 (A2 f )

µ ¶µ ¶ µ ¶µ ¶
∂ ∂ ∂f ∂f ∂ ∂ ∂f ∂f
= x −z y −x − y −x x −z
∂z ∂x ∂x ∂y ∂x ∂y ∂z ∂x
∂ 2f ∂ 2f ∂2f ∂f ∂2f
= xy − x2 − yz 2 + z + xz
∂z∂x ∂z∂y ∂x ∂y ∂x∂y
∂f ∂2f ∂2f ∂2f ∂2f

−y − xy + yz 2 + x2 − xz
∂z ∂x∂z ∂x ∂y∂z ∂y∂x
∂f ∂f
=z −y
∂y ∂z
= A1 f .
Thus, we can summarize these results as
[Ai , Aj ] = εijk Ak .
Similarly, for the Bi , we calculate the pertinent commutators as
[B1 , B2 ]f = B1 (B2 f ) − B2 (B1 f )

8
µ ¶µ ¶ µ ¶µ ¶
∂ ∂ ∂f ∂f ∂ ∂ ∂f ∂f
= x −w y −w − y −w x −w
∂w ∂x ∂w ∂y ∂w ∂y ∂w ∂x
∂ 2f ∂f ∂2f ∂ 2f 2
2 ∂ f
= xy − x − xw − yw + w
∂w2 ∂y ∂w∂y ∂x∂w ∂x∂y
∂2f ∂f ∂ 2f ∂ 2f 2
2 ∂ f
−xy + y + yw + xw − w
∂w2 ∂x ∂w∂x ∂y∂t ∂y∂x
∂f ∂f
=y −x
∂x ∂y
= A3 f ,
[B1 , B3 ]f = B1 (B3 f ) − B3 (B1 f )

µ ¶µ ¶ µ ¶µ ¶
∂ ∂ ∂f ∂f ∂ ∂ ∂f ∂f
= x −w z −w − z −w x −w
∂w ∂x ∂w ∂z ∂w ∂z ∂w ∂x
∂2f ∂f ∂2f ∂ 2f 2
2 ∂ f
= xz − x − xw − zw + t
∂w2 ∂z ∂w∂z ∂x∂w ∂x∂z
∂2f ∂f ∂2f ∂ 2f 2
2 ∂ f
−xz + z + zw + xt − w
∂w2 ∂x ∂w∂x ∂z∂w ∂z∂x
∂f ∂f
=z −x
∂x ∂z
= −A2 f ,
[B2 , B3 ]f = B2 (B3 f ) − B3 (B2 f )

µ ¶µ ¶ µ ¶µ ¶
∂ ∂ ∂f ∂f ∂ ∂ ∂f ∂f
= y −w z −w − z −w y −w
∂w ∂y ∂w ∂z ∂w ∂z ∂w ∂y
∂2f ∂f ∂ 2f ∂2f 2
2 ∂ f
= yz − y − yw − zw + w
∂w2 ∂z ∂w∂z ∂y∂w ∂y∂z
9
∂2f ∂f ∂2f ∂ 2f 2
2 ∂ f
−yz + z + zw + yt − w
∂w2 ∂y ∂w∂y ∂z∂w ∂z∂y
∂f ∂f
=z −y
∂y ∂z
= A1 f .
These results can be summarized as
[Bi , Bj ] = εijk Ak .
Finally, for the commutators between the Ai and Bj , we note first

by inspection that
[Ai , Bi ] = 0 ,
for i = 1, 2, 3, since Ai and Bi involve mutually exclusive pairs of
variables. For the remaining commutator pairs, we have
[A1 , B2 ] = A1 (B2 f ) − B2 (A1 f )
µ ¶µ ¶ µ ¶µ ¶
∂ ∂ ∂f ∂f ∂ ∂ ∂f ∂f
= z −y y −w − y −w z −y
∂y ∂z ∂w ∂y ∂w ∂y ∂y ∂z
∂f ∂2f ∂2f ∂2f ∂ 2f

=z + yz − zw 2 − y 2 + yw
∂w ∂y∂w ∂y ∂z∂w ∂z∂y
∂2f ∂2f ∂2f ∂f ∂2f

−yz + y2 + zw 2 − w − yw
∂w∂y ∂w∂z ∂y ∂z ∂y∂z
∂f ∂f
=z −w
∂w ∂z
= B3 f ,
[A1 , B3 ] = A1 (B3 f ) − B3 (A1 f )

µ ¶µ ¶ µ ¶µ ¶
∂ ∂ ∂f ∂f ∂ ∂ ∂f ∂f
= z −y z −w − z −w z −y
∂y ∂z ∂w ∂z ∂w ∂z ∂y ∂z
10
∂2f ∂ 2f ∂f ∂ 2f ∂2
= z2 − zw −y − yz + yw 2
∂y∂w ∂y∂z ∂w ∂z∂w ∂z
∂2f ∂ 2f ∂f ∂ 2f ∂2f
−z 2 + yz +w + zw − yw 2
∂w∂y ∂w∂z ∂y ∂z∂y ∂z
∂f ∂f
=w −y
∂y ∂w
= −B2 f ,
[A2 , B3 ] = A2 (B3 f ) − B3 (A2 f )

µ ¶µ ¶ µ ¶µ ¶
∂ ∂ ∂f ∂f ∂ ∂ ∂f ∂f
= x −z z −w − z −w x −z
∂z ∂x ∂w ∂z ∂w ∂z ∂z ∂x
∂f ∂2f ∂2f ∂2f ∂ 2f
=x + xz − xw 2 − z 2 + zw
∂w ∂z∂w ∂z ∂x∂w ∂x∂z
∂2f ∂2f ∂f ∂ 2f ∂2f
−xz + z2 −w + xw 2 − zw
∂w∂z ∂w∂x ∂x ∂z ∂x∂z
∂f ∂f
=x −w
∂w ∂x
= B1 f .
Thus,
[Ai , Bj ] = εijk Bk .
9. Consider the following linear combinations of the operators in

Problem 7:
Ji = 12 (Ai + Bi ), Ki = 12 (Ai − Bi ) . (3)

11
We can now use the commutation relations derived in Problem 8

to derive the commutation relations for the Ji and Kj . For the
Ji , we have
[Ji , Jj ] = 14 [Ai + Bi , Aj + Bj ]
³ ´
1
= 4
[Ai , Aj ] + [Ai , Bj ] + [Bi , Aj ] + [Bi , Bj ]
= 14 (εijk Ak + εijk Bk + εijk Bk + εijk Ak )
= εijk 12 (Ak + Bk )
= εijk Jk ,
[Ki , Kj ] = 14 [Ai − Bi , Aj − Bj ]
³ ´
= 1
4
[Ai , Aj ] − [Ai , Bj ] − [Bi , Aj ] + [Bi , Bj ]
= 14 (εijk Ak − εijk Bk − εijk Bk + εijk Ak )
= εijk 12 (Ak − Bk )
= εijk Kk ,
[Ji , Kj ] = 14 [Ai + Bi , Aj − Bj ]
³ ´
= 1
4
[Ai , Aj ] − [Ai , Bj ] + [Bi , Aj ] − [Bi , Bj ]
= 14 (εijk Ak + εijk Bk − εijk Bk − εijk Ak )
= 0.
Group Theory
Problem Set 10 December 11, 2001
1.∗ Prove that a proper orthogonal transformation in an odd-dimensional space always

possesses an axis, i.e., a line whose point are left unchanged by the transformation.
2. Prove Euler’s theorem: The general displacement of a rigid body with one fixed point is
a rotation about an axis.
3.∗ The functions (x ± iy)m , where m is an integer generate irreducible representations

of SO(2). Suppose we now consider the group O(2), where we now allow improper
rotations. Use Schur’s lemma to show that these functions generate irreducible two-
dimensional representations of O(2) for m 6= 0, but a reducible representation for m = 0.
Hint: The general improper rotation in two dimensions is

Ã !
cos ϕ sin ϕ
sin ϕ − cos ϕ
4. Consider the rotation matrix obtained by rotating an initial set of axes counterclockwise
by φ about the z-axis, then rotated about the new x-axis counterclockwise by θ, and
finally rotated about the new z-axis counterclockwise by ψ. These are the Euler angles
and the corresponding rotation matrix is
 
cos ψ cos φ − cos θ sin φ sin ψ cos ψ sin φ + cos θ cos φ sin ψ sin ψ sin θ
 
 − sin ψ cos φ − cos θ sin φ cos ψ − sin ψ sin φ + cos θ cos φ cos ψ cos ψ sin θ 
sin θ sin φ − sin θ cos φ cos θ
Verify that the angle of rotation ϕ of this transformation is given by
¡ ¢ £ ¤ ¡ ¢
cos 12 ϕ = cos 12 (φ + ψ) cos 12 θ
5. Determine the axis of the transformation in Problem 4.
6.∗ Verify that the direct product of two irreducible representations of SO(3) has the fol-
lowing decomposition
`X
1 +`2
χ(`1 ) (ϕ)χ(`2 ) (ϕ) = χ(`) (ϕ)

`=|`1 −`2 |
This is called the Clebsch–Gordan series and provides a group-theoretic statement of
the addition of angular momenta.
7.∗ Determine the corresponding Clebsch-Gordan series for SO(2).
8.∗ Show that the requirement that xx∗ +yy ∗ is invariant under the complex transformation
Ã ! Ã !Ã !
x0 a b x
=
y0 c d y
together with the determinant of this transformation being unity means that the trans-
formation must have the form
Ã 0! Ã !Ã !
x a b x
=
y0 −b∗ a∗ y
where aa∗ + bb∗ = 1.

Group Theory
1. As shown in Section 8.3.1, the eigenvalues of an orthogonal ma-

trix have modulus unity. These eigenvalues are also the roots
of the polynomial equation det(A − λI) = 0, so the Fundamen-
tal Theorem of Algebra requires that, if these roots are com-
plex, they must occur in complex conjugate pairs. Thus, only in
an odd-dimensional space is there guaranteed to be a single real
eigenvalue of unity. The corresponding eigenvector is the axis of
rotation.
2. If the fixed point is taken as the origin of the set of axes of the
body, then the displacement of the rigid body involves no trans-
lation, but only a change of orientation, i.e., a rotation. Since, in
three dimensions, every rotation can be expressed in an axis-angle
representation, Euler’s theorem follows immediately.
3. The general improper transformation in two dimensions is

Ã ! Ã ! 
x0 cos ϕ sin ϕ x
=  .
y0 sin ϕ − cos ϕ y
Thus, for the functions (x ± iy)m we have
h im
(x0 ± iy 0 )m = x cos ϕ + y sin ϕ ± i(x sin ϕ − y cos ϕ)
h im
= x( cos ϕ ± i sin ϕ) ∓ iy( cos ϕ ± i sin ϕ)
= (x ∓ iy)m e±imϕ ,
so they generate the representation
" # Ã !" #
(x0 + iy 0 )m 0 eimϕ (x + iy)m
= .
(x0 − iy 0 )m e−imϕ 0 (x − iy)m
2
To determine whether or not this representation is reducible, we

apply Schur’s first lemma. Suppose a matrix A commutes with
all of the matrices of our two dimensional representation. Then,
we have
Ã !Ã ! Ã !Ã !
a11 a12 0 eimϕ 0 eimϕ a11 a12
= .
a21 a22 e−imϕ 0 e−imϕ 0 a21 a22
| {z } | {z }
   
a12 e−imϕ a11 eimϕ a21 eimϕ a22 eimϕ
   
a22 e−imϕ a21 eimϕ a11 e−imϕ a12 e−imϕ
Thus, if m 6= 0, we must require that a12 = a21 = 0 and that

a11 = a22 , i.e., A is multiple of the 2×2 unit matrix and, according
to Schur’s first lemma, this representation is irreducible. However,
of m = 0, we need only require that a12 = a21 and a11 = a22 , so
this is a reducible representation.
4. The rotation angle ϕ is calculated from the trace of the transfor-

mation matrix:
1 + 2 cos ϕ = cos ψ cos φ − cos θ sin φ sin ψ − sin ψ sin φ
+ cos θ cos φ cos ψ + cos θ
= (1 + cos θ)( cos φ cos ψ − sin φ sin ψ) + cos θ
= (1 + cos θ) cos(φ + ψ) + cos θ .
Using the triginometric identity
1 + 2 cos ϕ = 4 cos2 ( 12 ϕ) − 1 ,
we obtain
4 cos2 ( 12 ϕ) = (1 + cos θ)[1 + cos(φ + ψ)]
= 4 cos2 ( 12 θ) cos2 [ 12 (φ + ψ)] ,

3
or,
cos ( 12 ϕ) = cos ( 12 θ) cos [ 12 (φ + ψ)] .
5. The axis of the transformation in Problem 4 is determined from

the equations derived in Section 8.3.2:
n2 a31 − a13 n3 a12 − a21
= , = .
n1 a23 − a32 n1 a23 − a32
The denominator of these expressions is
a23 − a32 = sin θ cos ψ + sin θ cos φ = sin θ( cos ψ + cos φ) .
We also have
a31 − a13 = sin θ sin φ − sin θ sin ψ = sin θ(sin φ − sin ψ)
a12 − a21 = cos ψ sin φ + cos θ cos φ sin ψ
+ sin ψ cos φ + cos θ sin φ cos ψ
= (1 + cos θ)(cos φ sin ψ + sin φ cos ψ)
= (1 + cos θ) sin(φ + ψ) .
Thus, the (unnormalized) direction of the rotation axis is

( )
sin φ − sin ψ (1 + cos θ) sin(φ + ψ)
1, ,2 .
cos ψ + cos φ sin θ(cos φ + cos ψ)
6. There are a number of ways of decomposing the direct product

of irreducible representations of SO(3). The books by Tinkham
4
and Jones give two very different approaches. Below, we provide

a third method. We first calculate the direct product
Ã !Ã !
X̀ X
1
χ(`) (ϕ)χ(1) (ϕ) = e−imϕ e−im1 ϕ .
m=−` m1 =−1
By expanding the second summation and multiplying the first

summation with each of the exponentials, we obtain
Ã !Ã !
X̀ X
1 X̀ ³ ´
−imϕ −im1 ϕ
e e = e−imϕ eiϕ + 1 + e−iϕ
m=−` m1 =−1 m=−`
X̀ X̀ X̀
= e−i(m−1)ϕ + e−imϕ + e−i(m+1)ϕ .
m=−` m=−` m=−`
If, in the first summation on the right-hand side of this equation,

we change the summation variable to m0 = m − 1 and in the last
summation change the summation variable to m0 = m + 1, we
have
X̀ X̀
e−i(m−1)ϕ + e−i(m+1)ϕ
m=−` m=−`
X
`−1
0 X
`+1
0
= e−im ϕ + e−im ϕ
m0 =−`−1 m0 =−`+1
X
`+1
0 X
`−1
0
= e−im ϕ + e−im ϕ .
m0 =−(`+1) m0 =−(`−1)
In fact, for any positive integer k, we have

X̀ X̀
e−i(m−k)ϕ + e−i(m+k)ϕ
m=−` m=−`
X
`−k
0 X
`+k
0
= e−im ϕ + e−im ϕ
m0 =−`−k m0 =−`+k
X
`+k X
`−k
−im0 ϕ 0
= e + e−im ϕ . (1)
m0 =−(`+k) m0 =−(`−k)
5
Thus, we conclude that
χ(`) (ϕ)χ(1) (ϕ) = χ(`−1) (ϕ) + χ(`) (ϕ) + χ(`+1) (ϕ) .
Then, by using (1), we have, in the general case
0 X̀ h 0 0 0
i
χ(`) (ϕ)χ(` ) (ϕ) = e−imϕ ei` ϕ + ei(` −1)ϕ + · · · + e−i` ϕ
m=−`
0 0 0
= χ(`+` ) (ϕ) + χ(`+` −1) (ϕ) + · · · + χ(`−` ) .
Therefore,
0
X
`+`
(`) `0
χ (ϕ)χ (ϕ) = χ(m) (ϕ) ,
m=`−`0
where, from our procedure, it is clear that `0 ≤ `.
7. The corresponding Clebsch–Gordan series for SO(2) is very simple

because the group is Abelian. Since
χ(m) (ϕ) = eimϕ ,
then
χ(m1 ) (ϕ)χ(m2 ) (ϕ) = χ(m1 +m2 ) (ϕ) .
8. Given the complex transformation

Ã ! Ã !Ã !
x0 a b x
= , (2)
y0 c d y
6
then the invariance of the quantity xx∗ + yy ∗ yields

x0 x0∗ + y 0 y 0∗
= (ax + by)(a∗ x∗ + b∗ y ∗ ) + (cx + dy)(c∗ x∗ + d∗ y ∗ )
= (aa∗ + cc∗ )xx∗ + (ab∗ + cd∗ )xy ∗ + (a∗ b + c∗ d)x∗ y
+ (cc∗ + dd∗ )yy ∗ .

Maintaining equality for all independent variations of x and y
requires that
aa∗ + cc∗ = 1, ab∗ + cd∗ = 0, cc∗ + dd∗ = 1 . (3)
A fourth condition is that the determinant of the transformation
in (2) is unity:
ad − bc = 1 (4)
If we take the second of equations (3), multiply by a∗ , and then
use the first of these equations and Equation (4), we obtain
a∗ (ab∗ + cd∗ ) = aa∗ b∗ + a∗ cd∗
= (1 − cc∗ )b∗ + (1 + b∗ c∗ )c
= b∗ + c = 0
which yields
c = −b∗
The second of equations (4) then immediately yields
a = d∗ (5)
Thus, the transformation (2) must have the form
Ã ! Ã !Ã !
x0 a b x
=
y0 −b∗ a∗ y
where aa∗ + bb∗ = 1.

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Group Theory

First Term 2001 Office Hours:

1.1 Symmetry in Physics

1.1.1 What is a Symmetry?

after rotations of 12 π, π, and 32 π, and the circle is indistinguishable after

(a) (b) (c)

1.1.2 Symmetry in Physical Laws

equations and the Galilean invariance of Newtonian mechanics was, of

1.1.3 Noether’s Theorem

Noether’s Theorem. The covariance of the equations of motion with

In classical mechanics, the conservation of linear momentum results

1.1.4 Symmetry and Quantum Mechanics

and vibrational properties and especially their response to external

Figure 1.2: A section of a Penrose tile, which has a fivefold rotational

1.2 Examples from Quantum Mechanics

Thus, the Hamiltonian operator in (1.5) is itself invariant under inver-

This requires that A2 = 1, i.e., A = 1 or A = −1. Combining this result

ϕ(−x) = ϕ(x) (1.12)

1.2.2 Symmetries and Quantum Numbers

ϕ(x, t) = ei(kx−ωt) , (1.15)

where k and ω are related to the momentum and energy by p = h̄k

solutions to Eq. (1.14) correspond to the momentum and energy which,

1.2.3 Matrix Elements and Selection Rules

where the range of integration is symmetric about the origin. If H0

where A is a constant, i.e., H0 (x) is proportional to the coordinate x.

Elements of Abstract Group

Mathematics is a game played according to certain simple rules with

The importance of symmetry in physics, and for quantum mechanics

2.1 Groups: Definitions and Examples

Definition. A group G is a set of elements {a, b, c, . . .} together with

2. Associativity. The composition law is associative, i.e., for any

3. Identity. There exists an element, called the unit or identity and

4. Inverses. Every element a in G has an inverse, denoted by a−1 ,

4.0 Inverses. Every element a in G has a unique inverse, denoted by

The terms “multiplication,” “product,” and “unit” used in this def-

Example 2.1. Consider the set of integers,

. . . , −3, −2, −1, 0, 1, 2, 3, . . .

Since the order in which two integers are added is immaterial, Z is an

Example 2.2. The importance of the composition law for determining

and the inverse of (2.1) is

2.2 Permutation Groups

permutations and is carried out by rearranging the objects according to

Figure 2.1: The symmetry transformations of an equilateral triangle labelled

which is important, not any particular realization of the group. Further

2.3 Elementary Properties of Groups

Theorem 2.1. (Uniqueness of the identity) The identity element in

Proof. Suppose there are two identity elements e and e0 in G. Then,

for all a in G. Setting a = e0 in the first of these equations and a = e

This theorem enables us to speak of the identity e of a group. The

Theorem 2.2. (Cancellation) In a group G, the left and right cancel-

Proof. Suppose that ab = ac. Let a−1 be an inverse of a. Then, by

a−1 (ab) = a−1 (ac)

and invoking associativity,

(a−1 a)b = (a−1 a)c ,

so b = c. Similarly, beginning with ba = ca and right-multiplying by

Theorem 2.3. (Uniqueness of inverses) For each element a in a

Proof. Suppose that there are two inverses b and c of a. Then ab = e

As in the case of the identity of a group, we may now speak of the

by g n . Similarly g n g m = g n+m , which conforms to the usual rule of ex-