Physical Sciences P2 NSC-Marking Guideline Common Test June 2019

PHYSICAL SCIENCES P2 (CHEMISTRY)

COMMON TEST

JUNE 2019

MARKING GUIDELINE

NATIONAL
SENIOR CERTIFICATE

GRADE 11

TIME: 2 hours

MARKS: 100

This marking guideline consists of 7 pages.

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Physical Sciences P2 NSC-Marking Guideline Common Test June 2019
2

QUESTION 1

1.1. C 🗸🗸
1.2. B 🗸🗸
1.3. A 🗸🗸
1.4. D 🗸🗸
1.5. C 🗸🗸
1.6. B 🗸🗸
1.7. A 🗸🗸 7x2 = (14)

QUESTION 2

2.1.1 A🗸 and I🗸 (2)

2.1.2. (B and F) 🗸 🗸 OR (D and F) (2 or 0) (2)

2.1.3. G 🗸 (1)

2.1.4. G🗸 (1)

2.1.5. C 🗸 (1)

2.1.6. E 🗸 (1)

2.2 H2O has hydrogen bonding 🗸and H2S has dipole- dipole forces. 🗸 The intermolecular

forces in water are stronger 🗸Therefore more energy is required to break the IMF

in water. 🗸 (4)

2.3. H
x
●
H x ● C ●x H
●
x
H 🗸🗸 (2)

2.4.1 NON- POLAR🗸

-
CO2 is a symmetrical molecule with even distribution of electrons🗸

There is no net dipole moment/dipoles cancel out🗸/. There is no distinct opposite

positive and negative ends. (3)

2.4.2 London forces 🗸 (1)

[18]

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QUESTION 3

3.1. Capillarity / height 🗸 (1)

3.2. Nail polish remover🗸 (1)

3.3. It has the weakest intermolecular forces /cohesive forces 🗸 molecules

separate easily. 🗸 The adhesive forces are stronger than the cohesive
forces/IMF 🗸 (3)

3.4. Nail polish remover; water ; glycerine 🗸🗸 (2)

3.5 Glycerine🗸 (1)

[8]

QUESTION 4

4.1.1 Charle’s Law --🗸 The volume of an enclosed gas is directly proportional to its
Kelvin temperature provided the pressure is kept constant. 🗸🗸 (3)

4.1.2. Amount/mass of gas🗸 (1)

4.1.3. volume is directly proportional to Kelvin temperature/ Vα T🗸 / volume is linearly

proportional to Celsius temperature

ACCEPT As temperature increases, volume increases. (1)

4.1.4. P3 🗸 (1)
-
4.1.5 . From pV = nRT , gradient which is V/T is equal to nR/P. 🗸Since R and n are constant, 🗸

Gradient is inversely proportional to the pressure/ higher pressure represents smaller

gradient. 🗸 (3)

OR

From Boyles law --- at a constant temperature, 🗸 the gas with the highest volume will have
the lowest pressure🗸 pV = k🗸
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4
4.2.
OPTION 2
OPTION 1

Change in pressure = 100-55 = pV = nRT🗸

45kPa🗸 pV = nRT🗸 100 x 103 x 10 x 10-3 = n x 8.31 x 298🗸

n= 0.404mol ( original no. of

45 x 103 x 10 x 10-3 🗸= n x 8.31 x
moles of oxygen in vessel)
298🗸 n = 0.182mol🗸 pV = nRT
[20]
n = m/M🗸 55 x 103 x 10 x 10-3 = n x 8.31 x 298🗸

0.182 = m/32🗸 n= 0.222mol ( no of mol in vessel

after leak is repaired)
m = 5.824g 🗸 of O2 is lost
NB: ACCEPT p values in kPa with V values in dm3 no of moles of gas leaked
=0.404 – 0.222🗸
= 0.182mol🗸

n = m/M🗸

0.182 = m/32🗸

m = 5.824g 🗸 of O2 is lost
(8)

[17]

QUESTION 5

5.1 Simplest whole number ratio in which elements in a compound combine 🗸🗸 (2)

5.2.

Element Mass per 100 g n=m/M(mol) Simplest ratio

C 54.56 54.56/12 = 4.547🗸 4.547/2.2725 = 2
H 9.08🗸 9.08/1 = 9.08🗸 9.08/2.2725 = 4 🗸
O 36.36 36.36/16 = 2.2725🗸 2.2725/2.2725 = 1

Empirical formula is C2H4O🗸 (6)

5.3 n = True Mr/ Empirical Mr

= 132/44

= 3🗸

Molecular formula is C6 H12 O3🗸 (award both marks if answer correct without calculation) (2)
[10]

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QUESTION 6

6.1. The amount of substance having the same number of particles as there
are atoms in 12g of C-12. 🗸🗸/ Amount of substance having 6,02 x 1023
elementary particles. (2)

6.2.
n = V/Vm N = 2.8125 x 6.02 x 1023🗸

= 63/22.4 🗸 = 1.693 x 10 24 molecules🗸 of CO2

= 2.8125 mol
(4)

6.3
POSITIVE MARKING FROM 6.2

Fe : CO2

2:3 🗸

nFe = 2.8125 x2/3 (4)

= 1.875mol🗸
(2)

6.4.
Positive marking form 6.2/6.3
CO2 : Fe2O3 OR Fe : Fe2O3
3 :1 2 :1
nFe2O3 = 2.8125/3🗸 nFe2O3 = 1.875/2
= 0.9375 mol = 0.9375 mol

mFe2O3 = nM
= 0.9375 x 160🗸
(4)
= 150 g
[12]
% purity = 150/160 x 100🗸

= 93,75% 🗸

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QUESTION 7

7.1 Substance that is used up completely in a reaction. 🗸 🗸 (2)

7.2

Ratio 5 1 5 2
Moles Ca V2O5 CaO V

Initial 500🗸 175 🗸 0 0

Change 500🗸 100 500 200🗸

End 0 75 500 200

Ca V2O5

n = m/M n = m/M

= 20 000/40 = 31 850/182

= 500 mol = 175mol

nV formed = 200 mol

m = nxM

= 200 x 51🗸

= 10 200 g 🗸 (6)

7.3 % yield = 8670/10 200 x 100🗸

= 85 %🗸 (2)

[10]

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QUESTION 8

8.1 Amount of solute per litre of solution. 🗸 🗸 (2)

8.2. n = m/M

= 4.14/69 🗸
= 0.06mol 🗸 (2)

8.3 Positive marking from 8.2.

c=

n/V🗸 0.05

=0.06/V🗸

V = 1,20 dm3 🗸 (3)

8.4

Positive marking from 8.3

Positive marking from 8.2. and 8.3
c1V1 = c2V2 🗸
c = n/V🗸
0.05 x 1.20🗸 = c2 x 1.45🗸
=0.06🗸/1.45🗸
C2 = 0.04 mol.dm-3🗸
c= 0.04 mol.dm-3🗸

(4)

[11]

TOTAL MARKS : 100

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