Vidyamandir Classes: Innovating For Your Success

Solutions to Mock JEE Main - 17 |JEE-2022

PHYSICS
SECTION-1
1.(A) F  Adv / dx
dx 1 1 MV
 F  m  a  time  
dv A area A

2.(B) Applying conservation of momentum, m(uiˆ  2ujˆ)  3m(0)  4m(viˆ  vˆj )

 v  u / 4 and v  u / 2

hc 1 1  3  4 
3.(C)  13.6Z 2     13.6Z 2   ;   3  k 
 1 4  4  
 line of Paschen
hc 1 1 
 13.6Z 2   
   9 25 
9  25 3 9  25 33  52
  k  ;      
16 4 16 26
Am
4.(D)   0.5 { Am  20 volt, Ac  40 volt}
Ac

m(t )  Am sin m t {c  2106}

c(t )  Ac sin c t {m  210 103}
Cm (t )  ( Ac  Am sin m t )sin c t  Ac {1   sin mt}sin c t

1L 2 L
5.(C) R1  2
; R2 
a 3a 2
R1R2   L
Both are in parallel  Req   2 1 2
R1  R2 a (31  2 )
p
6.(A) I … (i)
4r 2
1
and I
0 E02 c … (ii)
2
From (i) and (ii)
p 1 2p 9  109  2  15
 0 E02 c  E0  ; E0   2  103 V/m
4r 2 2 4  0 r 2 c 15  15  106  3  108
RT V1 T 363
7.(C) v ;  1 ; V1   340  1.1 340   374 m/s
M V2 T2 300
8.(D) Fact. Due to decrease in intermolecular forces
300
9.(B) Time taken by trains to collide   2hrs
150
Speed of bird = 200 km/hr
Total distance travelled by bird  200  2  400 km

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10.(B) At minima, I  ( I 0  25I 0 )2  16 I 0

16 4
At maxima, I  ( I 0  25I 0 )2  36I 0   Ratio 
36 9
11.(C) The time spent in magnetic field (t) is independent of velocity of charge.
1  2m 
t 
4  qB 
12.(C) At second surface,
i  25
r  25
   i  r  50

13.(A) Workdone by gas = area enclosed in P-V diagram

 (2)2 lt-atm
14.(C) Taking torque at top pt, mg sin 30  L / 2  F cos30  L  F  mg / 2 3

15.(B) For permanent magnetic Y is good choice, As it has very high coercivity (comparitively)
a
16.(C) Let the origin be at the CM of the particles, let the initial positions of the particles be x 
2
a
and x   and let the instantaneous positions of the particles be x  r and x  r
2
Let the instantaneous velocity of each particle be v
a
Let the time after which the distance between the particles has reduced to be T
2
a
Then, for the particle that was initially at x  ,
2
Gm2 v dv Gm 4 v dv
 m  
 2r  2 dr r 2 dr
1/2
v r dr Gm  1 2   Gm  1 2  
 4 vdv  Gm   v2      v     
0 a /2 r 2 2 r a  2  r a 
[v is negative because the velocity is towards the –X direction]
1/2
dr  Gm  1 2   a /4 r Gm T
 
2a 0
      dr  dt
dt  2  r a  a /2 a  2r
a /4 r Gm
 a /2 a  2r
dr  
2a
T … (i)

r
Let us now evaluate the integral I   dr
a  2r
a sin 2 
Let r   dr  a sin  cos  d 
2
a a a  1 
Therefore, I  sin 2  d    1  cos  d      sin 
2 2 2 2 2 2 
a sin 2  2r  2r  2r  8r  a  2r 
Since r  ,   sin 1 and sin 2  2sin  cos   2  
 1  
2 a  a  a  a

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a  1 2r 2r  a  2r   a 2r r  a  2r 
So, I  sin   sin 1 
2 2  a a  2 2

a 2
Therefore, from equation (i),
a /4
2a  a 2r r  a  2r   2a  a    1  a  
T   sin 1       

Gm 2 2 a 2  Gm  2 2  4  2  2 2  
 a /2

a  a a     2  a 3
Hence, T    
Gm  8 4   8  Gm
17.(B) In y axis u y  v0 a y   E0 q / m
1 2v0 m
s y  0, u y t  a y t 2  0  t  2u y / a y 
2 E0 q
2v0 m 2v02 m
x coordinate at that time  vx  t   v0 
E0 q E0 q
18.(D) Pitch p  0.5 mm
Device has +ve zero error
p p 24 p 24
R  6 p  28  4  6p  ; 3mm   0.5  3.24 mm
50 50 50 50
19.(A) Centripetal acceleration is provided by friction force. Maximum friction force should be equal to or
greater that mv 2 / R.
mv 2 100
mg  ;  ;   1/ 10 ;   0.1
R 100  10
20.(C) Using parallel axis theorem for the side BC, the moment of inertia of the triangle about an axis
passing through A and perpendicular to the plane of the triangle,
  3a   3 2
2
1 2  1
I A  2  ma   ma  m     ma
2
 3   12  2   2

If the angular velocity of the triangle at any instant is , the velocity of the vertex B at that instant
is a
Therefore, the velocity of B is maximum at the instant the angular velocity is maximum, i.e. when the
side BC becomes horizontal
Let the angular velocity at this instant be MAX
Then, by conservation of energy
Gain in kinetic energy = Loss in potential energy
1
I A 2MAX  3mg  Loss in height of CM of triangle 
2
13 2 2  a a  3 2g
 ma  MAX  3mg     mga  2MAX 
2 2   3 2 3 2 3a
2 ga
2
Therefore, the maximum velocity of the vertex B is given by vMAX  2MAX a 2 
3

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SECTION-2
21.(7) In case 1, Ephoton  2eV ; metal surface  Ephoton  KEmax  1eV
12400
In case 2, Ephoton   8eV ; max.KE  8eV  1eV  7eV
1550
22.(3.33) Charge initially on capacitor 1  10C
Charge initially on capacitor 2  20C
Finally the potential difference across
both capacitor will be equal.
Let us assume that to be V.
1V  2V  10
V  10 / 3  3.33V

23.(70) When relative sliding stops, both move with same velocity.
Only friction acts in horizontal direction.
 for system no external force, we can apply conservation of momentum.
1 12  5  0  6  v
v  2 m/s
Now work done by friction on block = change in kinetic energy of block
1 1 1
w  m(22  122 )  (1)(4  144)  (140)  70J
2 2 2
8R 5R x 8
24.(1.60) x  ; y ;   1.6
2 2 y 5
25.(8) EMF induced  BLV  4  2  1  8V
BLV 8
Current produced    8A
R 1
loge 2
26.(175) t1/2 , half life  3s

Initially 200 nuclei were there
After 3 half-lives, 9 seconds,
1
No. of nuclei = 3  200  25
2
Therefore, the number of nuclei that decayed = 200 – 25 = 175
27.(5) Gold band is equal to 5% tolerance
28.(21) f 0  300 Hz
3rd overtone  7 f 0  2100 Hz
Q Q 300
29.(800) H  L QL   1600  800 J
TH TL 600
 work done  QH  QL  1600  800  800 J
30.(100) 1R  0.5  1.5
1R  1
1000
R  100
10

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Chemistry

SECTION-1
1.(B) Here cyclohexanone is formed as follows

2.(D) If the carbonyl compound is sterically crowded, then it will be reluctant to undergo addition reaction.
Moreover, attachment of bulkier alkyl group with the carbonyl carbon decreases the partial positive
charge resulting into the minimization of attack by R  from RMgBr. So, the order is

  
3.(B) CH3CH2COOH NH3 
 CH3CH2CO2 NH 4 
H O
CH3CH 2CONH 2
2
(P) (Q) (R)
KOH  Br

2
 CH3CH2 NH2  H2O

4.(A) (A) SiO 2 has three-dimensional network structure of Si  O bonds; while carbon dioxide
consists of discrete CO 2 molecules. SiO 2 is solid, whereas CO 2 is a gas
(B) Because of its great affinity for oxygen, Si always occurs as the oxide, silica (SiO 2 ) or in the
form of silicates, which are the compounds of SiO 2 with other metal oxides.
(C) SiO2  2Mg 
 Si  2MgO
(D) The reluctance of silicon to form p  p bonds to itself is clearly shown by the fact that
silicon does not exist in graphite-like structure, but only in diamond like structure.

h
5.(D)  , there is inverse relation between de-Broglie wavelength and momentum, hence the graph will
p
be rectangular hyperbola.

6.(D) To stop bleeding, FeCl3 is applied locally because FeCl3 causes denaturation of proteins present in
blood. It is a case of coagulation.
7.(A) i. Zn  2NaOH 
 Na 2 ZnO2  H2
ii. 4Au  8NaCN  O2  2H2O 
 4Na[Au(CN)2 ]  4NaOH
iii. Cu  4HNO3 
 Cu(NO3 )2  2NO2  2H2O
(conc.)

iv. Formation of passive layer of Fe2 O3 on the surface of Fe and NO 2 gas is evolved

8.(D) [Co(NH3 )6 ]3 is diamagnetic (t 62g e g 0 ) and is inner orbital complex.

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9.(A) When Ferric chloride reacts with potassium thiocyanate a blood red colour of Ferric thiocyanate is
formed
FeCl3  3KSCN 
 Fe(SCN)3  3KCl

10.(D) As Zn(OH) 2 , BeO, Al2O3 are amphoteric, so they can react with both HCl and NaOH.

11.(D) In SN 2 reaction, inversion takes place, so configuration get reversed.

12.(A)
5 4 3 2 1
CH3  C  CH  CH2  COOH
|
C  O  C2 H5
||
O
4-ethoxycarbonylpent-3-enoic acid
13.(D) The given value of  (spin only)
2.84  n(n  2) BM, So, n  2
Among the given configurations, d 4 system in strong field ligand will have 2-unpaired e in t 2g set
of orbitals as shown below.

14.(C) The process of moving sodium and potassium ions across the cell membrane is an active transport
process involving the hydrolysis of ATP to provide the necessary energy.

15.(D) Nitrogen, sulphur and halogens are tested in an organic compound by lassaigne’s test.
The organic compound is fused with sodium metal as to convert these elements into ionisable
inorganic substances.
Na  C  N 
 NaCN
2Na  S 
 Na 2S
2Na  X2   2NaX
The cyanide, sulphide or halide ions can be confirmed in aqueous solution by usual test.

16.(A) The second ionization energy of K is maximum, because the second electron is removed from fully
filled 3p6 subshell. The second ionization energies of group 2 elements decrease down the group.
Hence, second I.E. of Ca  second I.E. of Ba.

17.(A) All monosaccharides which differ in configuration at C1 and C 2 gives the same osazone. Since,
glucose and fructose differ from each other only in configuration at C1 and C 2 therefore, they give
the same osazone. All other options given in the questions do not satisfy this condition and hence, do
not from the same osazone.
18.(B) 2CO(g)  O2 (g)   2CO2 (g)
n g  2  (2  1)   1
H  E  n g RT or H  E  1RT
i.e. H  E

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19.(D) Sometimes, when maximum covalency is obtained, the halides become inert to water, thus SF6 (or
similarly CCl4 ) is stable. This is because SF6 is coordinately saturated and sterically hindered. Thus,
SF6 is inert to water, because of kinetic rather than thermodynamic factor.
A. PCl5  4H2O 
 H3PO4  5HCl
B. SiCl4  4H2O 
 Si(OH)4  4HCl
C. BCl3  3H2O 
 B(OH)3  3HCl

20.(B) One mole of water is converted to vapour at its boiling point which is 100°C and at 1 atm. For this
process G  0. As phase transformation of water is an equilibrium process and at equilibrium, free
energy change is always zero.

SECTION-2
21.(5) ATP has phosphate group, PO34
So x  4( 2)   3 or x   5

22.(16)

The number of chiral carbons in open-chain aldohexose (such as glucose) is four, therefore, the
number of stereoisomers  24  16.

23.(836)
Hrxn  Hf (N2O, g)  3Hf (CO2 ,g)  (2Hf NO2 , g)  3Hf (CO, g)
 81  3  ( 393)  2  34  3(110)
 81  1179  68  330   836kJ

24.(0) As 3f-orbital does not exist as value of cannot be equal to n, hence no electron can be
accommodated.

25.(400) As 500g of tooth-paste has  0.2g of F 

0.2g 106 g 
So, 106 g of toothpaste has  F  400g of F
500g
Hence, concentration in ppm is 400.

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26.(150) P1  1atm
40
P 2  1atm   0.40atm
100
V1  100cm3
V2  ?
At constant temperature, P1V1  P2 V2

P1V1 1atm 100cm3

So V2    250cm3
P2 0.40atm
Hence, the volume of bulb B  (250  100)cm3  150cm3

27.(4145.40)
Gº   2.303RT log K p   2.303  2  300log103

  2.303  2  300  ( 3)  4145.4cal mol1

28.(1.93)
To decompose 1 mole of H 2 O, we need two moles of electrons i.e. 2 faraday
To decompose 4 moles of H 2 O, we need 8 faraday.
8  96500
Now, Q  i  t  t  1.93 105 sec
4

29.(0.50) Number of mol of A reacted  1105  105

Number of molecule of A  105  6 1023
6  1018
Quantum efficiency   0.50
1.2  1019

30.(64) Temperature coefficient is 2 that means rate of reaction doubles at every 10°C rise in temperature.
k
Thus, 90C  26  64
k 30C

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Mathematics

SECTION-1
1.(C) p(10hr )  .1 p( s / 10hr )  .8
p(7hr )  .2 p(s / 7hr )  .6
p(4hr )  .7 p(s / 4hr )  .4
p( s)  .1 .8  .2  .6  .7  .4
.7  .4 28 28 7
p(4hr / s)    
.1 .8  .2  .6  .7  .4 8  12  28 48 12

1  1
2.(B) 0  1 1  0
1 1 1
1(1  1)   (  1)  1(  1)  0
2   2     1  0
 2  1    1,  1
a 2  b2  2
3.(C) b1 , b2 , b3
a, ar , ar 2 ........
1
a  ar  1  a 
(1  r )


 bk  2
a
 2
k 1 1 r
1
2
1 r2
1 1
r2   r  
2 2
1
b2  0  r    a  b1  2  2
2
4.(D) ( I  M ) 2  ( I  M )( I  M )  I  2M  M 2  ( I  2M )
( I  M )3  ( I  2M )( I  M )  I  3M  2M 2  ( I  3M )
( I  M )50  I  50M
det(( I  M )50  50M )  det( I )  1
5.(C) y2  4x ( x  3)2  y 2  9
1
y  mx  (3, 0), r  3
m
1
3m 
m 3
1  m2

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1
9m 2   6  9  9m 2
m2
1 1
2
3  m
m 3
1
m in first quadrant
3
x
y  3  3y  x  3
3
Tr 1 1
6.(B) 
Tr 3
 T1 , T2 , T3 …………G.P.
1
T7 
243
1
ar 6 
243
a 1
6
 5  a3
3 3
Sum of infinite series  T1T2  T2T3  T3T4 …………..
1
3 3
T1T2 3  27

1 r 2
1
1 8
9
7.(A) ~ ( p  (~ p  q )
 ~ p  (~ (~ p  q ))  ~ p  ( p  ~ q )
3
8.(B) y  sin 2
2
x  e sin 
dy 3cos 2 3
    (cos   sin )
dx e (cos   sin ) e
9.(C) (var ) New  k 2 (var )Old  4  5  20
3 3

 ( x  1)( x  2)( x  3) dx  x  6 x 2  11x  6 dx

3
10.(B)
0 0

1 2 3

  
A   ( x3  6 x 2  11x  6)dx  ( x3  6 x 2  11x  6)dx  ( x3  6 x 2  11x  6) dx
0 1 2

11
A
4

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2 2
11.(A) z2  z2
 x0
Hence z minimum ‘0’
12.(C) f ( x)  ( x  2) 2
 12  (2) 2    3
f ( x)  3( x  2) 2 ; f (6)  3  42  48
13.(B) tan 1 ( x)  t
t 2  4t  3  0
t  (, 1)  (3, )
  
tan 1 ( x)    , 1
 2 
x  (, tan1)
Largest integral x  1
14.(A) log x  t
12
 2 1
t  
 t
r
 1
Tr 1  12Cr (t 2 )12r     12Cr t 243r (1)r
 t
For constant term r  8 & coefficient 12 C8
12 1110  9
 45 11  495
24
dy dx
15.(B)  2
1 y2 x
1 
sin 1 ( y )    c  c 
x 2
  
sin 1 ( y )    
3 2 6
1
y
2
x5 x 4
16.(C) f ( x)   5
20 12
x 4 x3  x 1
f '( x)    x3   
4 3  4 3

f "( x)  x3  x 2  x 2 ( x  1)
x  1 point of inflection

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17.(C) f '( x)  x(1  y )

dy
 xdx
y 1
x2
ln( y  1)  c
2
(0, 0)
c0
x2 x2
y 1  e 2
 e 2
2
x2
 k  (ln 2  0)
2
x   2k
18.(D) For point of intersection
1  3  3  
2    1  2
5  5    1,   1
Point of intersection (4, 3, 5)
For greatest distance from origin perpendicular from meet plane at point of intersection
Hence equation r  (4iˆ  3 ˆj  5kˆ)  50

19.(D) Differentiable  continuous

Continuous at x  2  2a  b  0
Continuous at x  3
0  9 p  3q  1
Differentiable at x  2
a  2  2  5  a  1
Differentiable at x  3
23  5  2 p 3  q  6 p  q 1
4 5
a  1, b  2, p  , q  
9 3
20.(C) 2 a 2
 3b 2
 35
a  0, b  I
a  1, b 2  11  b  I
a  2, b  9  b  3 or  3
17
a  3, b2  bI
3
a  4, b 2  1  b  1

SECTION-2
21.(570) All even + 2 odd 1 even
10
C3  10
C2 10 C1
10  9  8 10  9
 10
6 2
120  450  570

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22.(12) Family of circle through (2, 2) and (9, 9), ( x  2)( x  9)  ( y  2)( y  9)   ( y  x )  0
Touches y  0 (x-axis)
( x  2)( x  9)  18   x  0
x 2  11x   x  36  0
x 2  (11   ) x  36  0 has repeated roots
D  0    1,   23
x  6 or x  6
Difference = 12
2 2
3a  4b  9 a  16 b  24a  b
2
23.(2)

But a  b  0, a  b k
3a  4b  5k
4a  3b  5k
10k  20  k  2  a  b
 /2
x
24.(8) 
0
2
cos 2 x dx
 /4  /2
x x

0
2
cos 2 x dx   cos 2 x dx
 /4 2
 /4  /4  /2  /2
x sin 2 x  sin 2 x  x sin 2 x  sin 2 x
2 2  0
  0
4
dx     
 2 2  /4  /4 4
dx
 /4  /2
 cos 2 x    cos 2 x 
   
16 8 0 16  8  /4
 1  1 
    
8 8  8 8
ae2 x  b cos x  c
25.(4) lim 1
x 0 x 2 sin x
x
ae2 x  b cos x  c 1
lim lim
x 0 x 2 x 0  sin x 
 
 x 
For limit to exist
a  0, b  c
c
 1  c  2, b  2
2
abc 4

26.(220) 4
Cr  4Cr 1  5Cr 1
4
Cr 1  5Cr 1  4Cr

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 8 Cr  4Cr 1  8C0  4C1  8C1  4C2  8C2  4C3  8C3  4C4

r 0

 8C8  4C1  8C7  4C2  8C6  4C3  8C5  4C4

12 1110
 12C9   220
6
27.(0) A2  4 A  4 I  0
A2  2 AI  2 A  4 I  0
( A  2I )2  0  A  2I  0
B  297 A  594I
 297( A  2I )

28.(16) 1  x 4  x5  a0 (1  x)0  a1 (1  x)  a2 (1  x) 2 ..........  a5 (1  x)5

Differentiate
4 x3  5 x 4  a1  2a2 (1  x)  3a3 (1  x) 2 ……….
12 x 2  20 x3  2a2  6a3 (1  x) ……….
Put x  1
12  20  2a2 ............  a2  16
29.(9)

c  5, a  2, b  1

30.(8) PQ is focal chord.

Quadrilateral PTQR is square

PQ  TR
Area  8
2

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