Pnas 0913721107
Pnas 0913721107
Pnas 0913721107
Contributed by Dennis V. Kent, November 30, 2009 (sent for review October 16, 2009)
Identifying locations for secure sequestration of CO2 in geological seafloor (16) may offer potential solutions to these additional
formations is one of our most pressing global scientific problems. issues that are more problematic on land. Deep-sea aquifers
Injection into basalt formations provides unique and significant are fully saturated with seawater and typically capped by imper-
advantages over other potential geological storage options, includ- meable sediments. The likelihood of postinjection leakage of
ing large potential storage volumes and permanent fixation of car- CO2 to the seafloor is therefore low, reducing the potential
bon by mineralization. The Central Atlantic Magmatic Prov- impact on natural and human ecosystems (8). Long after CO2
ince basalt flows along the eastern seaboard of the United States injection, the consequences of laterally displaced formation water
may provide large and secure storage reservoirs both onshore and to distant locations and ultimately into the ocean, whether by
offshore. Sites in the South Georgia basin, the New York Bight engineered or natural outflow systems, are benign. For more than
basin, and the Sandy Hook basin offer promising basalt-hosted a decade, subseabed CO2 sequestration has been successfully
conducted at >600 m depth in the Utsira Formation as part of
SUSTAINABILITY
reservoirs with considerable potential for CO2 sequestration due
the Norweigan Sleipner project (17). The Central Atlantic Mag-
SCIENCE
to their proximity to major metropolitan centers, and thus to large
industrial sources for CO2. Onshore sites are suggested for cost- matic Province (CAMP) basalt formations formed during rifting
effective characterization studies of these reservoirs, although of the Pangea supercontinent (18, 19) and are present near the
offshore sites may offer larger potential capacity and additional highly industrial US and western European coastlines. In this
long-term advantages for safe and secure CO2 sequestration. study, we further consider the viability of continental flood basalts
as potential targets for geological CO2 sequestration (9)—speci-
Eastern United States ∣ greenhouse gas ∣ Jurassic ∣ lavas ∣ rift fically identifying CAMP basalts in both onshore and near-shore
locations along the eastern North American seaboard.
I
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such as the CAMP and the Columbia River plateau basalts are flows, which are the thickest among known flood basalt provinces.
emplaced during phased eruptive events. This results in a stacked Three flow units have been identified in this area—upper, mid-
sequence of basalt flows with different thicknesses sometimes se- dle, and lower units of the Orange Mountain basalt (31). In Fig. 4,
Fig. 1. Distribution of rift basins in eastern North America and Morocco and the distribution of the CAMP flood basalt, modified from ref. 19. Dotted lines
represent major strike slip fault zones. Detail areas (Inset A and B) are discussed in the text.
SCIENCE
show considerable vesicular and rubbly pore space as compared to the dense, low-porosity flow interior. Scales are presented in original measurement units
(i.e., core depth in feet).
the middle/lower basalt units are shown as measured by in situ flow interiors—and reaches a porosity value of 20% in the log and
geophysical well logs near Martinsville, NJ (32). Porosity profiles 10% on core samples. Note, however, that core measurements do
are computed from density and neutron measurements as well as not sample the fracture porosity or large void space (secondary
from core samples. Cores were subsampled over the flow bound- porosity) in most formations and often underestimate the mea-
ary and measured using He-pyncnometry to obtain bulk and grain sured in situ porosity. The best estimate of porosity in the inter-
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density estimates for comparison with the logs. These data pro- flow zone is greater than the core estimates and likely averages
vide the minimum porosity of each sample, assuming that He 15%. The interpretation of these data suggests massive basalt
invades all of the connected pore space. Very little chemical alter- flow interiors bounded by fractured flow tops and porous inter-
ation is observed by above-baseline natural gamma ray measure- flow contact zones typically occur between the CAMP flows.
ments, and the borehole conditions were consistent through most
of this interval (32). Neutron porosity data are erroneously high Offshore Long Island Rift Basins
over the interval due to the presence of clay minerals that in- Along the eastern North American seaboard, the early Atlantic
crease the neutron count. Importantly, the interflow interval from rifting also generated a series of offshore basins filled with
830–880 ft indicates elevated porosity measurements— Mesozoic sediments, previously identified by seismic, gravity,
a factor of two or more greater than the overlying and underlying and magnetic surveying. Hutchinson et al. (33) mapped four
buried rift basins on the Long Island platform, extending from
the New York Bight to Nantucket, and each extending more than
1; 000 km2 in area and filled with >800 m of sediments (Fig. 5A).
Hutchinson and Grow (34) identified a postrift fault northwest of
the buried New York Bight basin, with no specific evidence of
recent activity, but suggest that this relic fault may be associated
with the origins of the Mesozoic rift basins along the coastline.
Maguire et al. (35) investigated a similar, smaller off-shore basin
near Sandy Hook, NJ. The Sandy Hook and New York Bight
basins have been proposed to be offshore extensions of the
basalt-hosting Hartford rift system and are thus potential loca-
tions of buried CAMP flow basalts. Maguire et al. (35) conducted
a modeling study of the Sandy Hook basin and predicted that
basalt exists under several hundred meters of flat-lying sediments.
These deposits have never been drilled or dated, however their
proposed existence explains seismic reflections observed across
the basin as well as gravity and magnetic anomalies in the region.
Maguire et al. (35) hypothesized that these buried basalt flows are
associated with the eastern extent of the CAMP intrusion and
synchronous with the Orange Mountain basalt flows. Similar
gravity and magnetic anomalies in the New York Bight basin
could be explained by buried basalt flows that exist under a thick
Fig. 3. Photograph of the highly fractured Preakness basalt in the Newark Triassic–Jurassic sediment pile, and associated faults, although
Basin. Photograph courtesy of author (PEO). the early seismic surveys did not adequately resolve these deep
Goldberg et al. PNAS ∣ January 26, 2010 ∣ vol. 107 ∣ no. 4 ∣ 1329
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Fig. 4. Geophysical log profiles through lower, middle, and upper flows of the Orange Mountain basalt. Density and porosity profiles indicate an increase
from ≈10% to 20% porosity over the 15-m (50-ft) thick flow-top boundary zone, which amounts to ≈2.25 × 106 m3 open pore volume per km2. Scales are
presented in original measurements units (i.e., log depth in feet and hole diameter in inches).
features (34, 35). Drilling in the Nantucket basin also sampled clay-rich sediments, both advantages for secure storage and rapid
basalt flows of the CAMP (36). carbonation of injected CO2 . For example, considering the small
CAMP extrusives both onshore and offshore were contem- Sandy Hook basin off of New Jersey and assuming that basalt
poraneous, formed episodically, and contain interflow zones like flow-top boundary zones have average bulk porosity of 15%
those observed in the Orange Mountain basalt, potentially pro- and extend over one-third of its area, we estimate that 7 km3
viding a buried storage reservoir with considerable flow-top of basalt flow-top volume and ≈1 km3 of potential pore volume
boundary porosity. In subocean locations, flow tops would be sea- could be available for CO2 storage in this basin alone. This
water filled and capped by dense basalt as well as fine-grained and amounts to a total volume of pore space for injection of up to
Fig. 5. Potential onshore and offshore sites for pilot drilling studies in CAMP basalt along eastern US coastal regions. Black squares indicate initial study areas.
Maps refer to inset box locations in Fig. 1. (A) Sites located in buried Mesozoic rift basins on the Long Island platform (shaded), modified from ref. 33 and nearby
onshore basins (cross-hatched): a, Newark basin; b, Hartford basin; c, Sandy Hook basin; d–e, New York Bight basin; f, Nantucket basin; g–h, Atlantis basin. (B)
Sites located across the extent of buried basalt (hachured) in the South Georgia Rift basin (shaded), modified from ref. 38: i, location proximal to Clubhouse
Crossroads basalt cores; j–k, sites more proximal to seaward-dipping reflectors.
SUSTAINABILITY
(41). These features may also be offshore basalts associated with
CAMP basalt reservoirs. Offshore areas would require high-
SCIENCE
the CAMP, but they have never been drilled or dated.
Based on the US Geological Survey cores in South Carolina, resolution survey mapping to identify, and avoid, neotectonic
the Clubhouse Crossroads basalt is a 250-m thick series of basalt faults that could be reactivated above basalt reservoirs. Several
flows that are chemically similar to CAMP basalts, underlain by suggested initial study locations, both onshore and offshore, in
rift basin sediments, and overlain by coastal plain deposits and, potential CAMP basalt reservoirs are indicated on Fig. 5.
like other CAMP flows, consist of multiple eruptive events (42); Because of their proximity to major metropolitan centers, and
similar properties of the basalt interiors and interflow zones can thus to large industrial sources of CO2 , these CAMP targets could
be anticipated at these sites. Given that the South Georgia Rift ultimately provide safe and secure sequestration of carbon at
basin far exceeds the known area of the other eastern US coastal several practical locations.
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