Material Safety Data Sheet Cover-Sheet – This page provides additional New Zealand

specific information for this product and must be read in conjunction with the Safety Data
Sheet (SDS) attached

Product Name: Endo-Frost

Manufacturer: Coltene

SDS Expiry: 20 February 2023

Supplier Details: Henry Schein New Zealand

23 William Pickering Drive, Albany
PO Box 101 140, North Shore, Auckland 0745
Ph. 0800 808 855
www.henryschein.co.nz

Emergency Contacts: Poisons/Hazardous Chemical Info Centre –

0800POISON/0800764766 (24 Hours)
Phone 111 for Fire, Ambulance or Police

HSNO Class/Category: 2

HSNO Group Standard: Compressed Gas Mixtures Flammable Group Standard 2017
HSR002532

Statements/Pictograms: As per attached Safety Data Sheet (SDS)

Date Prepared: This coversheet was prepared - May 2021

This SDS coversheet has been produced by Henry Schein NZ and has been prepared in accordance with NZ EPA advice on
making overseas SDS compliant to HSNO Act. The above information is based on the present state of our knowledge of
the product at the time of publication. It is given in good faith, no warranty is implied with respect to the quality or the
specifications of the product. Users must satisfy that the product is entirely suitable for their purpose. The SDS and this
coversheet may be revised from time to time, please ensure you have a current copy.
COLTENE/Whaledent GmbH & Co. KG Safety Data Sheet

according to Regulation (EC) No 1907/2006

Endo-Frost
Revision date: 20.02.2018 Print date: 20.02.2018 Page 1 of 7

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Endo-Frost
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
for dental use only
Uses advised against
No information available.
1.3. Details of the supplier of the safety data sheet
Company name: COLTENE/Whaledent GmbH & Co. KG
Street: Raiffeisenstraße 30
Place: D-89129 Langenau
Telephone: +49 (7345) 805 0
Telefax: +49 (7345) 805 201
e-mail: [email protected]
Internet: www.coltene.com
1.4. Emergency telephone +49 (0) 6132-84463 GBK GmbH Global Regulatory Compliance (24 h)
number:
Further Information
Aerosol

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Regulation (EC) No. 1272/2008
Hazard categories:
Aerosol: Aerosol 1
Hazard Statements:
Extremely flammable aerosol.
Pressurised container: May burst if heated.
2.2. Label elements
Regulation (EC) No. 1272/2008
Signal word: Danger

Pictograms:

Hazard statements
H222 Extremely flammable aerosol.
H229 Pressurised container: May burst if heated.
Precautionary statements
P102 Keep out of reach of children.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Do not pierce or burn, even after use.
P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
P501 Dispose of waste according to applicable legislation.

Revision No: 2.2 GB - EN

COLTENE/Whaledent GmbH & Co. KG Safety Data Sheet

according to Regulation (EC) No 1907/2006

Endo-Frost
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2.3. Other hazards

Caution! Container under pressure. Pressurized container: protect from sunlight and do not expose to
temperatures exceeding 50 °C. Do not pierce or burn, even after use.
Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No
smoking. Keep out of the reach of children.

The components in this formulation do not meet the criteria for classification as PBT or vPvB .

SECTION 3: Composition/information on ingredients

3.2. Mixtures

Hazardous components
CAS No Chemical name Quantity
EC No Index No REACH No
Classification according to Regulation (EC) No. 1272/2008 [CLP]
106-97-8 butane 30-50 %
203-448-7 601-004-00-0
Flam. Gas 1; H220
74-98-6 propane 30-50 %
200-827-9 601-003-00-5
Flam. Gas 1; H220
75-28-5 isobutane 10-20 %
200-857-2 601-004-00-0
Flam. Gas 1; H220
Full text of H and EUH statements: see section 16.
Further Information
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 °C. Do not
pierce or burn, even after use.
Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No
smoking. Keep out of the reach of children.
The components in this formulation do not meet the criteria for classification as PBT or vPvB .

SECTION 4: First aid measures

4.1. Description of first aid measures

After inhalation
Provide fresh air.
Get medical advice/attention if you feel unwell.
After contact with skin
After contact with skin, wash immediately with plenty of water and soap.
After contact with eyes
In case of contact with eyes, rinse immediately with plenty of flowing water for 10 to 15 minutes holding eyelids
apart. Subsequently consult an ophthalmologist.
After ingestion
Get medical advice/attention if you feel unwell.
4.2. Most important symptoms and effects, both acute and delayed
No information available.
4.3. Indication of any immediate medical attention and special treatment needed
No information available.

Revision No: 2.2 GB - EN

COLTENE/Whaledent GmbH & Co. KG Safety Data Sheet

according to Regulation (EC) No 1907/2006

Endo-Frost
Revision date: 20.02.2018 Print date: 20.02.2018 Page 3 of 7

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media
Carbon dioxide (CO2). Dry extinguishing powder. Sand.
Unsuitable extinguishing media
Water.
High power water jet.
5.2. Special hazards arising from the substance or mixture
Extremely flammable aerosol.
Caution! Container under pressure.
5.3. Advice for firefighters
In case of fire: Wear self-contained breathing apparatus.
Protective clothing.
Additional information
Co-ordinate fire-fighting measures to the fire surroundings.
Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Remove all sources of ignition. Ventilate affected area. Remove persons to safety.
6.2. Environmental precautions
Do not allow to enter into surface water or drains.
6.3. Methods and material for containment and cleaning up
Do not rinse down with water. Provide adequate ventilation.

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Advice on safe handling
for professional use only Keep out of the reach of children.
Observe instructions for use.
Advice on protection against fire and explosion
Do not spray on naked flames or any incandescent material.
Keep away from sources of ignition - No smoking.
Further information on handling
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 °C. Do not
pierce or burn, even after use.
7.2. Conditions for safe storage, including any incompatibilities
Further information on storage conditions
Keep container tightly closed in a cool place.
Protect from sunlight. Do no expose to temperatures exceeding 50°C/122°F.
7.3. Specific end use(s)
No information available.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Revision No: 2.2 GB - EN

COLTENE/Whaledent GmbH & Co. KG Safety Data Sheet

according to Regulation (EC) No 1907/2006

Endo-Frost
Revision date: 20.02.2018 Print date: 20.02.2018 Page 4 of 7

Exposure limits (EH40)

CAS No Substance ppm mg/m³ fibres/ml Category Origin

106-97-8 Butane 600 1450 TWA (8 h) WEL

750 1810 STEL (15 min) WEL

8.2. Exposure controls

Protective and hygiene measures
When using do not eat, drink or smoke.
Eye/face protection
Tightly sealed safety glasses.
Hand protection
Wear suitable gloves.
Skin protection
Lab apron.
Respiratory protection
Provide adequate ventilation.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state: liquid/ gaseous
Colour: colourless
Test method
pH-Value: not applicable
Changes in the physical state
Initial boiling point and boiling range: not applicable
Flash point: -97 °C
Explosive properties
In use may form flammable/explosive vapour-air mixture.
Lower explosion limits: 1.5 vol. %
Upper explosion limits: 10.9 vol. %
Ignition temperature: 365 °C
Vapour pressure: 5000 hPa
(at 20 °C)
Density (at 20 °C): 0.55 g/cm³
Water solubility: The study does not need to be conducted
because the substance is known to be
insoluble in water /Immiscible
Solvent content: 100%
9.2. Other information
Volatile organic compounds (VOC) content in percent by weight: 100%

SECTION 10: Stability and reactivity

10.2. Chemical stability

-----

Revision No: 2.2 GB - EN

COLTENE/Whaledent GmbH & Co. KG Safety Data Sheet

according to Regulation (EC) No 1907/2006

Endo-Frost
Revision date: 20.02.2018 Print date: 20.02.2018 Page 5 of 7

10.3. Possibility of hazardous reactions

-----
10.4. Conditions to avoid
heat.
10.5. Incompatible materials
-----
10.6. Hazardous decomposition products
-----
Further information
Heating causes rise in pressure with risk of bursting.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity
CAS No Chemical name
Exposure route Dose Species Source Method
106-97-8 butane
inhalative (4 h) gas LC50 658 ppm Rat GESTIS

Irritation and corrosivity

Classification according EC regulation 1272/2008 (CLP): Not an irritant.
Classification according to directive 67/548/EEC or 1999/45/EC: Not an irritant.
Sensitising effects
Classification according EC regulation 1272/2008 (CLP): no danger of sensitization.
Classification according to directive 67/548/EEC or 1999/45/EC: no danger of sensitization.
STOT-single exposure
---------
STOT-repeated exposure
---------
Further information
---------

SECTION 12: Ecological information

12.2. Persistence and degradability
------
12.3. Bioaccumulative potential
Partition coefficient n-octanol/water
CAS No Chemical name Log Pow
106-97-8 butane 2,89
74-98-6 propane 2,36
75-28-5 isobutane 2,8

12.4. Mobility in soil

------
12.5. Results of PBT and vPvB assessment
not applicable

Revision No: 2.2 GB - EN

COLTENE/Whaledent GmbH & Co. KG Safety Data Sheet

according to Regulation (EC) No 1907/2006

Endo-Frost
Revision date: 20.02.2018 Print date: 20.02.2018 Page 6 of 7

Further information
According to the criteria of the EC-classification and labelling "dangerous for the environment" (93/21/EEC) the
material/product is not to be classified as dangerous to the environment.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Advice on disposal
Dispose of waste according to applicable legislation.
Waste disposal number of waste from residues/unused products
150110 WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND
PROTECTIVE CLOTHING NOT OTHERWISE SPECIFIED; packaging (including separately
collected municipal packaging waste); packaging containing residues of or contaminated by
hazardous substances
Classified as hazardous waste.
Waste disposal number of contaminated packaging
150104 WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND
PROTECTIVE CLOTHING NOT OTHERWISE SPECIFIED; packaging (including separately
collected municipal packaging waste); metallic packaging
Contaminated packaging
Dispose of waste according to applicable legislation.

SECTION 14: Transport information

Land transport (ADR/RID)

14.1. UN number: UN 1950
14.2. UN proper shipping name: AEROSOLS
14.3. Transport hazard class(es): 2
14.4. Packing group: -
Hazard label: 2.1
Classification code: 5F
Special Provisions: 190 327 344 625
Limited quantity: 1 L (LQ2)
Excepted quantity: E0
Transport category: 2
Tunnel restriction code: D
Other applicable information (land transport)
Special provisions: 190 - 327 - 344 -625
E0
Transport category: 2
Marine transport (IMDG)
14.1. UN number: UN 1950
14.2. UN proper shipping name: AEROSOLS
14.3. Transport hazard class(es): 2.1
14.4. Packing group: -
Hazard label: 2.1
Marine pollutant: NO
Special Provisions: 63-190-277-327-344-959
Limited quantity: 1L
Excepted quantity: E0
EmS: F-D, S-U

Revision No: 2.2 GB - EN

COLTENE/Whaledent GmbH & Co. KG Safety Data Sheet

according to Regulation (EC) No 1907/2006

Endo-Frost
Revision date: 20.02.2018 Print date: 20.02.2018 Page 7 of 7

Other applicable information (marine transport)

E0
Flash Point -97° C
Air transport (ICAO-TI/IATA-DGR)
14.1. UN number: UN 1950
14.2. UN proper shipping name: AEROSOLS, flammable
14.3. Transport hazard class(es): 2.1
14.4. Packing group: -
Hazard label: 2.1
Special Provisions: A145 - A167 - A802
Limited quantity Passenger: 30 kg G
Passenger LQ: Y203
Excepted quantity: E0
IATA-packing instructions - Passenger: Y203 (LQ)
IATA-max. quantity - Passenger: 75 kg
IATA-packing instructions - Cargo: 203
IATA-max. quantity - Cargo: 150 kg
Other applicable information (air transport)
E0
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
not applicable

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulatory information
Restrictions on use (REACH, annex XVII):
Entry 28: butane; isobutane
National regulatory information
Additional information
VOC (CH) : 0.111 kg/Unit

SECTION 16: Other information

Abbreviations and acronyms

Land transport (ADR/RID)
Sea transport (IMDG)
Air transport (ICAO-TI / IATA-DGR)
Relevant H and EUH statements (number and full text)
H220 Extremely flammable gas.
H222 Extremely flammable aerosol.
H229 Pressurised container: May burst if heated.
Further Information
The above information describes exclusively the safety requirements of the product and is based on our
present-day knowledge. The information is intended to give you advice about the safe handling of the product
named in this safety data sheet, for storage, processing, transport and disposal.

(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety
data sheet.)

Revision No: 2.2 GB - EN