MATERIAL SAFETY DATA SHEET

Asia Pacific GHS Format

Print date: 20-Mar-2011 Revision Number: 5 Revision date: 20-Mar-2011

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY

Trade Name: LEXAN*

Product Name: 141R -GY1D175 -GE27

Product Description: Poly (bisphenol-A-carbonate) [CASRN 111211-39-3]

Product Type: Commercial Product

Recommended use: May be used to produce molded or extruded articles or as a component of other industrial
products.

Company: SABIC Innovative Plastics Japan LLC.

Tokyo Club Building, 2-6 3Chome Kasumigaseki, Chiyoda-Ku Tokyo, 100-0013 Japan
SABIC Innovative Plastics (China) Ltd.
16F, Plaza 66, No: 1266 Nanjing Rd. (W), Shanghai 200040 China
SABIC Innovative Plastics Korea, Ltd.
Donghoon Bldg, 20fl, 702-19, Yeoksam-Dong, Kangnam-Ku, Seoul, Korea
SABIC Innovative Plastics Singapore Pte Ltd
23, Benoi Road, 629895 Singapore
SABIC Innovative Plastics (Thailand) Co. Ltd
64/22 Moo 4 Tumbol Pluak Daeng, Amphur Pluak Daeng,Rayong 21140 Thailand
Sabic Innivative Plastics India Ltd.
Plastics Avenue, P.O. Jawaharnagar,District Vadodara 391320 India
SABIC Innovative Plastics Taiwan Holding Limited,
Room B,7F,No. 8,Min-Sheng E. Rd. Sec. 3,Taipei City 10480 Taiwan

Manufacturer: SABIC Innovative Plastics Singapore Pte Ltd

23, Benoi Road
Singapore 629895
Telephone: (65) 6 210 4273
Fax: (65) 6 210 4267

Emergency Telephone Number: Japan: +(81)-285-80-2300

China: +(86)-532-388-9090, 532-388-9191,20-8498-0148
Singapore: +(65)-6210 4199
Korea: +(82)-2-510-6546
Thailand: +(66)-22312323-4 ext. 46, +(66)-38927000 ext. 7026
India: +(91)-265 3068554

E-mail: [email protected]
Website Address: www.sabic-ip.com

2. HAZARDS IDENTIFICATION

Globally Harmonized System, UN(GHS) - Classification

GHS Category
Not hazardous • Not classified

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GHS-Labeling

GHS Labeling not required

Precautionary Statements

No GHS specific Precautionary Statements required - observe all other warnings and handling instructions in this MSDS.

Other hazards which do not result in classification:

SABIC Emergency Overview

• Pellets with slight or no odor
• Spilled material may create slipping hazard
• Can burn in a fire creating dense, toxic smoke
• Molten plastic can cause severe thermal burns
• Fumes produced during melt processing may cause eye, skin, and respiratory tract irritation. Severe over-exposure may result in
nausea, headache, chills, and fever. See below for additional effects.
• Secondary operations, such as grinding, sanding, or sawing can produce dust which may present an explosion or respiratory hazard.

Other Information: OSHA, IARC and/or NTP have listed carbon, titanium dioxide, crystalline silica (quartz),
respirable glass and certain heavy metals, present in some colorants and fillers, as
carcinogens. If these materials are present in this product at significant quantities, they are
shown in Section 2. These materials are essentially bound to the plastic matrix and are unlikely
to contribute to workplace exposure under recommended processing conditions.

Processing Issues: Processing vapors may cause irritation to the eyes, skin, and respiratory tract. In cases of
severe exposure, nausea and headache can also occur. Grease-like processing vapor
condensates on ventilation ductwork, molds, and other surfaces can cause irritation and injury
to skin.

Aggravated Medical Conditions: MEDICAL RESTRICTIONS: There are no known health effects aggravated by exposure to this
product. However, certain sensitive individuals and individuals with respiratory impairments
may be affected by exposure to components in the processing vapors.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Product Type Mixture

Hazardous Components
Chemical Name CAS Number Weight % EC-No.
Titanium dioxide 13463-67-7 0.1-1.0 -
Chromium antimony titanium oxide yellow 68186-90-3 0.1-1.0 051-003-00-9
024-017-00-8

If present, components listed above are physical or health hazards as defined in the Hazard Communication Standard. The quantities
represent typical or average values for the materials shown. Additional compositional data are provided in Section 15, REGULATORY
INFORMATION.

4. FIRST AID MEASURES

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 4. FIRST AID MEASURES
If Inhalation: Move to fresh air in case of accidental inhalation of fumes from overheating or combustion. If
symptoms persist, call a physician.

On skin contact: Immediately cool the skin by rinsing with cold water after contact with hot material. Wash off
immediately with soap and plenty of water. Consult a physician.

On contact with eyes: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and
continue flushing for at least 15 minutes. If eye irritation persists, consult a specialist.

On ingestion: No hazards which require special first aid measures.

Precautions: Processing vapors inhalation may be irritating to the respiratory tract. If symptoms are
experienced remove victim from the source of contamination or move victim to fresh air and
obtain medical advice.

5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media: Water spray mist or foam.

Unsuitable extinguishing Carbon dioxide and dry chemical are not recommended because their lack of cooling capacity
Media for safety reasons: may permit re-ignition.

Hazards from Combustion Fire will produce dense black smoke containing hazardous combustion products, carbon
Products: oxides, hydrocarbon fragments.

Specific Hazards: Take precautionary measures against static discharges. During processing, dust may form
explosive mixture in air. Thermal decomposition can lead to release of irritating gases and
vapors.

Special Protective Equipment Do not enter fire area without proper protection including self-contained breathing apparatus
for Firefighters: and full protective equipment. Fight fire from a safe distance and a protected location due to
the potential of hazardous vapors and decomposition products.

Exposure hazards: Do not release chemically contaminated water into drains, soil or surface water. Sufficient
measures must be taken to retain the water used for extinguishing. Dispose of contaminated
water and soil according to local regulations.

6. ACCIDENTAL RELEASE MEASURES

Personal Precautions: See section 8.

Environmental Precautions: Do not flush into surface water or sanitary sewer system. Should not be released into the
environment.

Clean up: Sweep up and shovel into suitable containers for disposal. Do not create a powder cloud by
using a brush or compressed air.

7. HANDLING AND STORAGE

Handling: Handle in accordance with good industrial hygiene and safety practice. Provide for appropriate
exhaust ventilation and dust collection at machinery. Avoid dust formation. All metal parts of
the mixing and processing equipment must be earthed.

Storage: Store in closed container in a dry and cool area. Keep away from heat sources and sources of
ignition. Keep away from food, drink and animal feeding stuffs. Keep container tightly closed in
a dry and well-ventilated place.

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 Incompatible Products: Strong acids, strong oxidizing agents.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Exposure limits: No components with information, unless noted below

Chemical Name US OSHA PEL Japan OEL(TWA) China OEL(TWA) Korea OEL(TWA) Singapore OEL(TWA) Thailand
(8 Hr) OEL(TWA)
Titanium dioxide FRL_TWA: 5 mg/m3 1 mg/m3 8 mg/m3 Total dust. TWA: 10 mg/m3 PEL_LT: 10 mg/m3 No Information
13463-67-7 Respirable fraction , 10 4 mg/m3
mg/m3 Total dust ;
TL_PEL: 5 mg/m3
Respirable fraction , 15
mg/m3 Total dust
Chromium antimony titanium FRL_TWA: 0.5 mg/m3 0.1 mg/m3 0.5 mg/m3 Sb TWA: 0.5 mg/m3 as Sb 0.5 mg/m3 1 mg/m3
oxide yellow as Cr ; TL_PEL: 0.5 0.5 mg/m3
68186-90-3 mg/m3 as Cr

Chemical Name India TWA Malaysia OEL(TWA) Taiwan OEL(TWA) Australian OEL(TWA) Phillipines OEL(TWA) SABIC
Recom.(8 Hr)*
3 3 3
Titanium dioxide No Information PEL_TWA8: 10 mg/m PC: 10 mg/m No Information 15 mg/m No Information
13463-67-7
Chromium antimony titanium No Information PEL_TWA8: 0.5 mg/m3 PC: 0.5 mg/m3 as Sb No Information 0.5 mg/m3 No Information
oxide yellow as Sb
68186-90-3 1 mg/m3

SABIC limit *SABIC Innovative Plastics Recommended Exposure Limits have been established for certain chemicals.

Engineering Measures to Handle in accordance with good industrial hygiene and safety practice. Provide for appropriate
Reduce Exposure: exhaust ventilation at machinery. Processing fume condensate may be a fire hazard and toxic;
remove periodically from exhaust hoods, ductwork, and other surfaces using appropriate
personal protection.

Hand Protection: Protective gloves should be worn

Eye Protection: Safety glasses with side-shields or chemical goggles. In addition, use full-face shield when
cleaning processing vapor condensates from hood, ducts, and other surfaces.

Respiratory Protection: When using this product at elevated temperatures, implement engineering systems,
administrative controls or a respiratory protection program (including a respirator approved for
protection from organic vapors, acid, gases, and particulate matter) if processing vapors are
not adequately controlled or operators experience symptoms of overexposure. If dust or
powder are produced from secondary operations such as sawing or grinding, use a respirator
approved for protection from dust.

Body Protection: Long sleeved clothing

Hygiene Measures: When using, do not eat, drink or smoke.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Appearance: Pellets
Color: Varies
Odor: None or slight
Odor Threshold: No information available.
pH Not applicable
Melting point/range: This product does not exhibit a sharp melting point but softens gradually over a wide range of
temperatures.

Boiling point/range: Not applicable

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 9. PHYSICAL AND CHEMICAL PROPERTIES
Flash Point: Not applicable
Evaporation Rate: Negligible
Flammability (solid, gas): Blend; neither component is flammable
Explosive Limits
upper: Not determined
lower: Not determined
Vapor Pressure: Negligible
Vapor Density: No information available
Specific gravity: >1; (water = 1)
Water Solubility: Insoluble
Autoignition Temperature: 630°C (1166°F) estimated
Explosive Properties: Dust may form explosive mixture in air
Oxidising Properties: Not oxidising
Molecular Weight: Polymer
VOC content (%): Negligible
Surface tension: No data available

10. STABILITY AND REACTIVITY

Reactivity: Not reactive under recommended conditions of handling, storage, processing and use.

Stability: Stable under ambient conditions. Hazardous polymerization does not occur.

Polymerization: Hazardous polymerization does not occur

Conditions to Avoid: Avoid temperatures above 320°C. To avoid thermal decomposition, avoid elevated
temperatures. Heating can result in the formation of gaseous decomposition products, some of
which may be hazardous. Do not exceed melt temperature recommendations in product
literature. Purgings of hot material should be collected in small, flat, thin shapes and quenched
with water to allow for rapid cooling. Do not allow product to remain in barrel at elevated
temperatures for extended periods of time.

Materials to Avoid: May react with strong oxidizing agents, strong acids or other highly reactive chemicals.

Hazardous Decomposition Process vapors under recommended processing conditions may include trace levels of
Products: hydrocarbons, phenols, alkylphenols, diarylcarbonates.

11. TOXICOLOGICAL INFORMATION

Acute Toxicity
Product Information:
LD50/oral/rat: >5000 mg/kg
LD50/dermal/rabbit: >2000 mg/kg

Component Information:
Component Information Text: No data available

Sensitization
Respiratory Sensitization: Not classified

Irritation:
Eye Irritation: no data available

Subchronic Toxicity (28 days)

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 Repeated Oral Toxicity(28d): No information available
Repeated Dermal Toxicity(28d):No Information available
Subchronic Toxicity: No information available

Chronic Toxicity
Carcinogenicity: There are no known carcinogenic chemicals in this product except specifically mentioned
below.
Chemical Name IARC:
Titanium dioxide 2B
13463-67-7
Chromium antimony titanium oxide yellow 3
68186-90-3

Mutagenic Effects: No data is available on the product itself

Reproductive Toxicity: No information available
Developmental Toxicity: No information available

Neurological effects: No information available

Specific Target Organ Toxicity(STOT)

Target Organ Effects: Not established

Aspiration Hazard
Aspiration Hazard Statement: No data available

Other relevant toxicity information

IARC: Not listed
OSHA: Not regulated
NTP: Not tested

Remarks: The toxicological data has been taken from products of similar composition.

Special Studies: Titanium Dioxide: The International Agency for Research on Cancer (IARC) has determined
titanium dioxide to be a possible human carcinogen (class 2B) based on evidence in
experimental animals. Rats exposed to high doses of titanium dioxide by inhalation or
intratracheal installation showed an increased incidence of lung tumors.

12. ECOLOGICAL INFORMATION

Ecotoxicity
Component Information:
99.817% of the mixture consists of components(s) of unknown hazards to the aquatic environment.
Chemical Name Toxicity to Fish Toxicity to Algae Daphnia Magna (Water Flea) Toxicity to Microorganisms
Titanium dioxide No data available No data available No data available No data available
13463-67-7
Chromium antimony titanium No data available No data available No data available No data available
oxide yellow
68186-90-3

Product Information:

Persistence and Degradability

Biodegradation: Not inherently biodegradable
Partition coefficient (n-octanol/water) Not established

Bioaccumulative Potential:
Bioaccumulation: Not established

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Mobility
Mobility: May be separated mechanically in waste water plants.

Other Adverse Effects

Ecotoxicity Effects: Do not flush into surface water or sanitary sewer system.

13. DISPOSAL CONSIDERATIONS

Waste from residues / unused Where possible recycling is preferred to disposal or incineration Dispose of in accordance with
products: local regulations

Contaminated Packaging: Empty containers should be transported/delivered using a registered waste carrier for local
recycling or waste disposal.

Waste Disposal: Recycling is encouraged. Landfill or incinerate in accordance with federal, state and local
requirements. Collected processing fume condensates and incinerator ash should be tested to
determine waste classification.

14. TRANSPORT INFORMATION

IMO / IMDG Not regulated

ICAO Not regulated

IATA-DGR Not regulated

DOT Not regulated

ADR/RID Not regulated

ADR Not regulated

ADN Not regulated

15. REGULATORY INFORMATION

International Inventories:
TSCA (USA): Listed
DSL(Canada): Listed
EINECS/ELINCS (Europe): Listed
ENCS (Japan): Listed
IECSC(China): Listed
KECL(Korea): Listed
PICCS (Philippines): Listed
AICS (Australia): Listed

Other Inventory Information:

A "Listed" entry above means all chemical components are on the respective inventory list and/or a qualifying exemption exists for one
or more components. A "Not listed" entry above indicates one or more components is restricted from import or manufacture into that
country/region. Articles are exempt from registration and are therefore not listed on the national chemical inventories.

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SARA (313) Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA)
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and and Title 40 of the Code of Federal Regulations, Part 372.

SARA (311, 312) hazard class:

Acute Health Hazard N
Chronic Health Hazard N
Fire Hazard N
Sudden Release of Pressure Hazard N
Reactive Hazard N

Canada:
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS
contains all the information required by the CPR.

WHMIS hazard class:

Non-controlled

California Proposition 65:

Components in this product known to the State of California to cause cancer and/or reproductive effects, are listed below:
Chemical Name Weight % California Proposition 65:
Carbon black 0.01-0.10 Listed: February 21, 2003 Carcinogenic. (airborne, unbound particles of
1333-86-4 respirable size)

RoHS EU Directive 2002/95/EC:

This product complies with RoHS - it does not intentionally contain banned chemicals.

Remarks:
This product consists primarily of high molecular weight polymers which are not expected to be hazardous. The ingredients in this
product are present within the polymer matrix and are not expected to be hazardous.
.

HMIS Rating Health: 0 Flammability: 1 Reactivity: 0

16. OTHER INFORMATION

LEXAN* is a registered trademark of SABIC Innovative Plastics IP BV

Prepared by: Product Stewardship & Toxicology.

DISCLAIMER: This Material Safety Data Sheet [MSDS] information is provided based on the Hazard Communication
Regulations for your region or country and for the use of the persons required to receive this information under those regulations.
The information is neither designed nor recommended for any other use or for use by any other person, including for compliance
with other laws. SABIC Innovative Plastics does not warrant the suitability for use of this MSDS for any other material or product
not specifically identified herein. SABIC Innovative Plastics does not warrant the accuracy or authenticity of this MSDS unless it
has been obtained directly from SABIC Innovative Plastics, or posted or viewed on a SABIC Innovative Plastics website.
Modification of this MSDS, unless specifically authorized by SABIC Innovative Plastics, is strictly prohibited. This MSDS is based
on information, that is believed to be reliable, but may be subject to change as new information becomes available. Because it is
not possible to anticipate all conditions of use, additional safety precautions may be required. Since the use of this material is not
under SABIC Innovative Plastics' control, each user is responsible for making its own determination as to the safe and proper
handling of this material in its own particular use of this material. SABIC INNOVATIVE PLASTICS MAKES NO
REPRESENTATION OR WARRANTY, EITHER EXPRESS OR IMPLIED, INCLUDING AS TO MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE. Each user should read and understand this information and incorporate it into
individual site safety programs as required by applicable hazard communication standards and regulations.

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 End of Material Safety Data Sheet

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