Energy From Liquid Alcohols & Hydrocarbons

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Comparing heat energy

from burning alcohols and


liquid hydrocarbons
In this investigation, a spirit burner is used to burn gasoline
and different alcohols which heat a flask containing water, to
measure and compare the amount of heat energy produced.

Equipment
Apparatus

● Eye protyection
● Stand and clamp
● Conical flask (150 ml or laarger)
● Measuring cylinder 100ml
● Thermometer -10°c < 110°c
● Digital balance
● Spirit burners with wicks and caps, containing the fuels

Chemicals
● Ethanol
● Methanol
● Propanol
● Hexanes
● Gasoline (petrol)
STRUCTURAL FORMULAE OF THE FUELS

METHANOL

ETHANOL

PROPANOL

HEXANES
Hexanes are a mixture of similar hydrocarbons.
Hexane has a formula C6H14

GASOLINE
The general formula for a mixture of
hydrocarbons: C8H18
Procedure
Before starting the experimental investigation, read
all the instructions carefully and design a suitable
results table.

Equipment required for measuring heat energy from burning alcohol.


-SETTING UP THE INVESTIGATION-
Use this format to prepare for an investigation, by completing each of the boxes.

YOUR NAME (underlined) and NAMES OF GROUP MEMBERS DATE

WHAT IS BEING INVESTIGATED? Be specific!

WHAT WILL BE MEASURED? Be specific!

THE INDEPENDENT VARIABLE IS:

THE DEPENDENT VARIABLE IS:

THESE VARIABLES WILL BE CONTROLLED IN ORDER TO MAKE THE INVESTIGATION A FAIR


TEST:

THIS IS THE HYPOTHESIS AND THE JUSTIFICATION FOR THE HYPOTHESIS:


DESIGN A TABLE IN WHICH TO COLLECT RESULTS
1. Measure 100 cm3 of cold tap water into a conical flask.
2. Clamp the flask at a suitable height so that a spirit burner
can easily be placed below.
3. Weigh the spirit burner (and cap) containing the alcohol and
record this mass and the name of the alcohol.
4. Record the initial temperature of the water in the flask.
5. Place the spirit burner under the flask and light the wick.
6. Allow the alcohol to heat the water so the temperature rises
by about 40 °C.
7. Replace the cap to extinguish the flame.
8. Reweigh the spirit burner and cap, and record this mass.
9. Work out the mass of alcohol used.
10. Using a fresh 100 cm3 of cold tap water, repeat the
experiment with another alcohol.
Questions
1. Calculate the energy released during the combustion
of petrol and each of the alcohols by using this
equation:
energy released per gram of alcohol (J) =
mass of water (g) × temperature change (°C)
× 4.2 ÷ mass of alcohol (g)
2. Which fuel produced the most energy per gram?
3. Write equations for the complete combustion of each
alcohol.
4. Does all the heat produced by combustion go into
raising the temperature of the water? Comment on
the efficiency of the combustion reactions in your
investigation.
5. Some of the fuels burn ‘clean’ while others burn
‘dirty’ - with yellow flames and the production of soot.
What is going on?
6. Alcohols can be made commercially and used as a
substitute for hydrocarbon fuels. What process
converts sugar into alcohol and carbon dioxide?
What might be some advantages of using
commercially produced alcohols instead of
hydrocarbons?
7. List three procedures which might have led to errors
in your investigation and suggest ways in which you
would change or improve the three procedures.

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