SOLUTIONS (MCQ BASED ON NCERT BOOK)

1. Match the items given in Column I with the type of solutions given in Column II.

Column I Column II
(i) Soda water (a) A solution of the gas in solid
(ii) Sugar solution (b) A solution of the gas in gas
(iii) German silver (c) A solution of solid in liquid
(iv) Air (d) A solution of solid in solid
(v) Hydrogen gas in palladium (e) A solution of the gas in liquid
(f) A solution of liquid in solid
2. Match the items given in Column I (Type of Solution) with the Example given in Column II.
Column I Type of Solution Column II Example
Camphor in nitrogen A solution of Solid in Gas

Solution of hydrogen in palladium A solution of gas in solid

Amalgam of mercury with sodium A solution of liquid in solid

Copper dissolved in gold A solution of solid in solid

3.

4.

5. “The importance of many pure substance in life depends on their composition.” Which of the following statement
justify the above fact? (a) 1 ppm of fluoride ions in water prevents tooth decay. (b) 1.5 ppm of fluoride ions causes
tooth decay. (c) Concentration above 1.5 ppm can be poisonous. (d) All of the above.
6. Most of the processes in our body occur in (a) solid solution (b) liquid solution (c) gaseous solution (d) colloidal
solution
7. The term homogenous mixtures signifies that (a) its composition is uniform throughout the mixture. (b) its
properties are uniform throughout the mixture. (c) both composition and properties are uniform throughout the
mixture. (d) neither composition nor properties are uniform throughout the mixture.
MAHENDRA KALRA 9462305605
8. Which of the following mixture is(are) called solution? (i) water + ammonia (ii) water + acetone (iii) acetone +
alcohol (iv) hexane + water (a) (i), (ii) and (iii) (b) (i), (iii) and (iv) (c) (i) and (iv) (d) (ii) and (iii)
9. Which of the following is a quantitative description of the solution? (a) Dilute (b) Concentrated (c) Saturated (d)
Molar
10. Molarity and molality of a solution of NaOH is calculated. If now temperature of the solution is increased then which
of the following statement(s) is/are correct ? (i) Molarity of solution decreases (ii) Molality of the solution increases
(a) Both statements are correct (b) Statement (i) is correct only (c) Statement (ii) is correct only (d) Both
statements are incorrect.
11. The molarity of pure water is (a) 50 M (b) 18 M (c) 55.6 M (d) 100 M
12. Calculate molarity of 98%by mass H2SO4 at308K temperature having density1.84 gm/ml? (a) 18.4 M (b) 4.18 M (c)
8.14 M (d) 1.8 M
13. If 2 gm of NaOH is present is 200 ml of its solution, its molarity will be(a) 0.25(b) 0.5(c) 5 (d) 10
14. The atmospheric pollution is generally measured in the units of(a) mass percentage(b) volume percentage(c) volume
fraction (d) ppm
15. 234.2 gm of sugar syrup contains 34.2 gm of sugar. What is the molal concentration of the solution.(a) 0.1(b) 0.5(c)
5.5 (d) 55
16. When a solute is present in trace quantities the following expression is used (a) Gram per million (b) Milligram
percent (c) Microgram percent (d) Parts per million
17. 10 g of NaCl is dissolved in 106 g of the solution. Its concentration is (a) 100 ppm (b) 0.1 ppm (c) 1 ppm (d) 10 ppm
18. Molarity of liquid HCl will be, if density of solution is 1.17 gm/cc (a) 36.5 (b) 32.05 (c) 18.25 (d) 42.10
19. 200 ml of water is added to 500 ml of 0.2 M solution. What is the molarity of this diluted solution ? (a) 0.5010 M (b)
0.2897 M (c) 0.7093 M (d) 0.1428 M
20. Mole fraction of glycerine C3H5(OH)3 in solution containing 36 g of water and 46 g of glycerine is (a) 0.46 (b) 0.40 (c)
0.20 (d) 0.36
21. A solution made by dissolving 40 g NaOH in 1000 g of water is (a) 1 molar (b) 1 normal (c) 1 molal (d) None of these
22. A solution is heated from 25oC to 50oC. its molarity will be (a) same (b)less (c) more. (d) can be any same,less or
more
23. What is the sum of the mole fractions of all the components in a three component system? (a)1 (b)0 (c)>1(d)<1
24. The molarity of a solution containing 5 g of NaOH in 450ml solution (a)0.27M (b)2.7M (c)1.27M (d)2.27M
25. Which of the following concentration terms is/are independent of temperature? (a)Molality only (b) Molality and
mole fraction (c) Molarity and mole fraction (d) Molality and normality
26. Which of the following units is useful in relating concentration of solution with its vapour pressure? (a) mole
fraction (b) parts per million (c) mass percentage (d) molality
27. Which of the following statements, regarding the mole fraction (x) of a component in solution, is incorrect? (a) 0≤ x
≤1 (b) x ≤ 1 (c) x is always non-negative (d) None of these
28. Which of the following concentration unit is independent of temperature ? (a) Normality (b) Molarity (c) Formality
(d) Molality
29. Which of the following statements is incorrect? (a) A solution in which no more solute can be dissolved at the same
temperature and pressure is called a saturated solution. (b) An unsaturated solution is one in which more solute can
be dissolved at the same temperature. (c) The solution which is in dynamic equilibrium with undissolved solute is
the saturated solution. (d) The minimum amount of solute dissolved in a given amount of solvent is its solubility.
30. On dissolving sugar in water at room temperature solution feels cool to touch. Under which of the following cases
dissolution of sugar will be most rapid ? (a) Sugar crystals in cold water. (b) Sugar crystals in hot water. (c)
Powdered sugar in cold water. (d) Powdered sugar in hot water.
31. PA and PB are the vapour pressure of pure liquid components, A and B, respectively of an ideal binary solution. If XA
represents the mole fraction of component A, the total pressure of the solution will be. (a) PA + X (PB – PA ) (b) PA + X
(PA – PB ) (c) PB + X (PB – PA ) (c) PB + X (PB – PA )
32. The vapour pressure of the solution at a given temperature is found to be ................... than the vapour pressure of
the pure solvent at the same temperature. (a) higher (b) lower (c) equal (d) can't calculate
33. The decrease in the vapour pressure of solvent depends on the (a) quantity of non-volatile solute present in the
solution (b) nature of non-volatile solute present in the solution (c) molar mass of non-volatile solute present in the
solution (d) physical state of non-volatile solute present in the solution
34. The liquids at a given temperature vapourise and under equilibrium conditions the pressure exerted by the vapours
of the liquid over the liquid phase is called (a) osmotic pressure (b) atmospheric pressure (c) hydrostatic pressure
(d) vapour pressure
MAHENDRA KALRA 9462305605
35. The vapour pressure of two liquids ‘P’ and ‘Q’ are 80 and 60 torr, respectively. The total vapour pressure of solution
obtained by mixing 3 mole of P and 2 mole of Q would be (a) 72 torr (b) 140 torr (c) 68 torr (d) 20 torr
36. 18 g of glucose (C6H12O6) is added to 178.2 g of water. The vapour pressure of water for this aqueous solution is (a)
76.00 torr (b) 752.40 torr (c) 759.00 torr (d) 7.60 torr
37. The vapour pressure of two liquids X and Y are 80 and 60 torr respectively. The total vapour pressure of the ideal
solution obtained by mixing 3 moles of X and 2 moles of Y would be (a) 68 Torr (b) 140 Torr (c) 48 Torr (d) 72 Torr
38. Henry’s law states that the ________________________? (a) Partial pressure of a component over a solution is
proportional to its mole fraction in the liquid (b)Partial pressure of a component over a solution is proportional to
the mole fraction in the vapour(c)Vapour pressure is equal to the product of the mole fraction and total pressure
(d)Partial pressure is equal to the product of the mole fraction and total pressure
39. The law which states that the amount of gas dissolved in a liquid is proportional to its partial pressure is (a). Raoults
law (b)Henrys law (c) Gay Lussacs law (d)Daltons law
40. The law which indicates the relationship between solubility of a gas in liquid and pressure is (a) Raoult’s law (b)
Henry’s law (c) Lowering of vapour pressure (d) Van’t Hoff
41. Value of Henry's constant KH . (a) increases with increase in temperature. (b) decreases with increase in
temperature. (c) remains constant. (d) first increases then decreases.
42. The value of Henry's constant KH is . (a) greater for gases with higher solubility. (b) greater for gases with lower
solubility. (c) constant for all gases. (d) not related to the solubility of gases.
43. Partial pressure of a solution component is directly proportional to its mole fraction. This is known as(a) Henry’s
law(b) Raoult’s law(c) Distribution law (d) Ostawald’s dilution law
44. People living at high attitudes often reported with a problem of feeling weak and inability to think clearly. The
reason for this is. (a) at high altitudes the partial pressure of oxygen is less than at the ground level. (b) at high
altitudes the partial pressure of oxygen is more than at the ground level. (c) at high altitudes the partial pressure of
oxygen is equal to at the ground level. (d) None of these.
45. “If temperature increases solubility of gas decreases”. For this situation which of the following statement(s) is/are
correct ? (i) Reaction is endothermic (ii) Le-chatelier’s principle can be applied (a) Statement (i) and (ii) both are
correct (b) Statement (i) is correct only (c) Statement (ii) is correct only (d) Both statement(s) (i) and (ii) are
incorrect
46. . _ a contemporary of Henry concluded independently that solubility of a gas in a liquid solution is a function of _ of
the gas. (a) Mosley, temperature (b) Dalton, temperature (c) Dalton, partial pressure (d) Mosley, partial pressure
47. Which is an application of Henry’s law? (a) Spray paint (b) Bottled water (c) Filling up a tire (d) Soft drinks (soda)
48. Painful condition known as bends is explained with the help of (a) Henry’s law.(b) Raoults law (c) Gay Lussacs law
(d)Daltons law
49. Feeling of weakness and discomfort in breathing at high altitude (a) Henry’s law (b) Raoults law (c) Gay Lussacs law
(d)Daltons law
50. Low concentration of oxygen in the blood and tissues of people living at high altitude is due to . (a) low temperature
(b) low atmospheric pressure (c) high atmospheric pressure (d) both low temperature and high atmospheric
pressure
51. Scuba divers may experience a condition called . To avoids this, the tanks used by scuba divers are filled with air
diluted with . (a) Migrains, Hydrogen (b) Cramps, Nitrogen (c) Nausea, Oxygen (d) Bends, Helium
52. The statement “If 0.003 moles of a gas are dissolved in 900 g of water under a pressure of 1 atmosphere, 0.006
moles will be dissolved under a pressure of 2 atmospheres”, illustrates (a) Dalton’s law of partial pressure (b)
Graham’s law (c) Raoult’s law (d) Henry’s law
53. Solubility of gases in liquids ____________with rise in temperature (a) decreases (b) Increases (c) remains same (d)
firstly Increases than decreases rapidly
54. Raoult’s law becomes a special case of Henry’s law when (a)kH = p0 (b)kH > p0(c)kH< p0 (d)kH≥ p0.
55. Higher the value of KH at a given pressure (a) lower is the solubility of the gas (b) higher is the solubility of the gas (c)
same is the solubility of the gas (d)Vary according to gas
56. According to Henry’s law, the amount of gas that will dissolve in blood plasma or any other liquid is determined by
which of these factor? (a) Solubility of the gas in the liquid. (b) The total pressure of the gas mixture . (c) pH of the
liquid. (d) The osmotic pressure of the gas mixture.

MAHENDRA KALRA 9462305605

57. Which of the following graph is a correct representation of Henry’s law?

58. Henry’s law constant of oxygen is 1.4 × 10–3 mol. lit–1. atm–1 at 298 K. How much of oxygen is dissolved in 100 ml at
298 K when the partial pressure of oxygen is 0.5 atm? (a) 1.4 g (b) 3.2 g (c) 22.4 mg (d) 2.24 mg
59. Read the following statements carefully and choose the correct option. (i) Different gases have different KH values at
the same temperature. (ii) Higher the value of KH at a given temperature, lower is the solubility of the nature of gas
in the liquid. (iii) KH is a function of the nature of the gas. (iv) Solubility of gases increases with increase of
temperature. (a) (i), (ii) and (iv) are correct. (b) (ii) and (iv) are correct. (c) (i), (ii) and (iii) are correct. (d) (i) and (iv)
are correct.
60. Which one of the following gases has the lowest value of Henry’s law constant? (a) N 2 (b) He (c) H2 (d) CO2
61. H2S is a toxic gas used in qualitative analysis. If solubility of H2S in water at STP is 0.195 m. what is the value of KH?(a)
0.0263 bar(b) 69.16 bar(c) 192 bar (d) 282 bar
62. Henry’s law constant for molality of methane is benzene at 298 K is 4.27 × 10 5 mm Hg. The mole fraction of methane
in benzene at 298 K under 760 mm Hg is(a) 1.78 × 10-3(b) 17.43(c) 0.114 (d) 2.814
63. When a gas is bubbled through water at 298 K, a very dilute solution of the gas is obtained. Henry’s law constant for
the gas at 298 K is 100 kbar. If the gas exerts a partial pressure of 1 bar, the number of millimoles of the gas
dissolved in one litre of water is (a) 0.555 (b) 5.55 (c) 0.0555 (d) 55.5
64. KH value for Ar(g), CO2(g), HCHO (g) and CH4(g) are 40.39, 1.67, 1.83 × 10–5 and 0.413 respectively. Arrange these
gases in the order of their increasing solubility. (a) HCHO < CH4 < CO2 < Ar (b) HCHO < CO2 < CH4 < Ar (c) Ar < CO2 <
CH4 < HCHO (d) Ar < CH4 < CO2 < HCHO
65. At same temperature, hydrogen is more soluble in water than helium. (a) helium will have larger value of K H (b)
hydrogen will have larger value of KH (c) hydrogen & helium will have same value of KH
66. An ideal solution is formed when its components (a) have no volume change on mixing (b) have no enthalpy change
on mixing (c) Both (a) and (b) are correct (d) Neither (a) nor (b) is correct
67. Which one of the following is not correct for an ideal solution? (a) It obeys Raoult’s law over the entire range of
Concentration (b) Enthalpy of mixing of the pure components to form the solution is zero (c Volume of mixing is
zero, (d) All are correct
68. Which of the following condition is not satisfied by an ideal solution? (a) ΔHmixing = 0 (b) ΔVmixing = 0 (c) Raoult’s Law is
obeyed (d) Formation of an azeotropic mixture
69. The boiling point of an azeotropic mixture of water and ethanol is less than that of water and ethanol. The mixture
shows (a) no deviation from Raoult’s Law. (b) positive deviation from Raoult’s Law. (c) negative deviation from
Raoult’s Law. (d) that the solution is unsaturated.
70. All form ideal solution except (a) C6H6 and C6H5CH3 (b) C2H6 and C2H5I (c) C6H5Cl and C6H5Br (d) C2H5 I and C2H5OH.
71. A solution containing components A and B follows Raoult's law when (a) A – B attraction force is greater than A – A
and B – B (b) A – B attraction force is less than A – A and B – B (c) A – B attraction force remains same as A–A and B
–B (d) volume of solution is different from sum of volume of solute and solvent
72. If the intermolecular attractive forces between the A-A and B-B are nearly equal to those between A-B, this leads to
the formation of (a) ideal solution (b) Non-ideal Solutions showing positive deviation (c) Non-ideal Solutions
showing negative deviation (d) None of the above
73. Which one of the following is ideal solution (a)n-hexane and n-heptane (b)bromoethane and chloroethane
(c)benzene and toluene (d) all the above
74. When the he vapour pressure of Non ideal solution is higher than that predicted by Raoult’s law the solution
exhibits (a)positive deviation from Raoult’s law. (b) negative deviation from Raoult’s law (c) can be both positive or
negative deviation from Raoult’s law (d)None of the above
75. When the he vapour pressure of Non ideal solution is lower than that predicted by Raoult’s law the solution
exhibits (a)positive deviation from Raoult’s law. (b) negative deviation from Raoult’s law (c) can be both positive or
negative deviation from Raoult’s law (d)None of the above
76. In case of positive deviation from Raoult’s law : (a) A – B attraction force is greater than A – A and B – B (b) A-B
interactions are weaker than those between A-A or B-B (c) A – B attraction force remains same as A–A and B –B
MAHENDRA KALRA 9462305605
77. Mixtures of ethanol and acetone show positive deviation. The reason is (a) In pure ethanol, molecules are hydrogen
bonded. (b) In pure acetone, molecules are hydrogen bonded (c) In both molecules are hydrogen bonded (d) None
of these
78. A solution of carbon disulphide in acetone (a) shows a positive deviation from Raoult’s law (b) obeys Raoult’s law
solution (c) shows a negative deviation from Raoult’s law (d) None of the above
79. In case of negative deviations from Raoult’s law : (a) the intermolecular attractive forces between A-A and B-B are
weaker than those between A-B and leads to decrease in vapour pressure (b) (a) the intermolecular attractive
forces between A-A and B-B are weaker than those between A-B and leads to increase in vapour pressure (c) the
intermolecular attractive forces between A-A and B-B are greater than those between A-B and leads to decrease in
vapour pressure (c) the intermolecular attractive forces between A-A and B-B are greater than those between A-B
and leads to increase in vapour pressure
80. The solution with negative deviation from Raoult’s law are (a) phenol and aniline. (b) chloroform and acetone (c)
Both (a) & (b) (d) None of the above
81. A mixture of components A and B will show – ve deviation when (a) ΔVmix > 0 (b) ΔHmix < 0 (c) A – B interaction is
weaker than A – A and B – B interactions (d) A–B interaction is stronger than A–A and B–B interactions.
82. Which of the following liquid pairs shows a positive deviation from Raoult’s law ? (a) Water - Nitric acid (b) Benzene
- Methanol (c) Water - Hydrochloric acid (d) Acetone - Chloroform
83. Which one of the following is non-ideal solution (a) Benzene + toluene (b) n-hexane + n-heptane (c) Ethyl bromide +
ethyl iodide (d) CCl4 + CHCl3
84. A solution of acetone in ethanol (a) shows a positive deviation from Raoult’s law (b) behaves like a non ideal
solution (c) obeys Raoult’s law (d) shows a negative deviation from Raoult’s law
85. Negative deviation from Raoult’s law is observed in which one of the following binary liquid mixtures? (a) Ethanol
and acetone b) Benzene and toluene (c) Acetone and chloroform (d) Chloroethane and bromoethane
86. Which one of the following binary liquid systems shows positive deviation from Raoult’s law? (a) Benzene-toluene
(b) Carbon disulphide-acetone (c) Phenol-aniline (d) Chloroform-acetone
87. A binary liquid solution is prepared by mixing n-heptane and ethanol. Which one of the following statements is
correct regarding the behaviour of the solution? (a) The solution is non-ideal, showing negative deviation from
Raoult’s Law. (b) The solution is non-ideal, showing positive deviation from Raoult’s Law. (c) n-heptane shows
positive deviation while ethanol shows negative deviation from Raoult’s Law. (d) The solution formed is an ideal
solution.
88. Which one is not equal to zero for an ideal solution: (a) ΔSmix (b) ΔVmix (c) ΔP = Pobserved - PRaoult (d) ΔHmix
89. Chloroform and acetone are added to each other, Raoult’s law shows negative deviation.what does this suggests ?
(a)Exothermic reaction (b) Endothermic reaction (c) Zero change in enthalpy (d) None of these
90. If two liquids A and B form minimum boiling azeotrope at some specific composition then . (a) A – B interactions
are stronger than those between A – A or B – B (b) vapour pressure of solution increases because more number of
molecules of liquids A and B can escape from the solution. (c) vapour pressure of solution decreases because less
number of molecules of only one of the liquids escape (d) A – B interactions are weaker than those between A – A
or B – B
91. Considering the formation, breaking and strength of hydrogen bond, predict which of the following mixtures will
show a positive deviation from Raoult’s law? (a) Methanol and acetone. (b) Chloroform and acetone. (c) Nitric acid
and water. (c) Phenol and aniline.
92. If two liquids A and B form minimum boiling azeotrope at some specific composition then _______________. (a) A–B
interactions are stronger than those between A–A or B–B. (b) vapour pressure of solution increases because more
number of molecules of liquids A and B can escape from the solution. (c) vapour pressure of solution decreases
because less number ofmolecules of only one of the liquids escape from the solution. (d) A–B interactions are
weaker than those between A–A or B–B.
93. On the basis of information given below mark the correct option. (i) In bromoethane and chloroethane mixture
intermolecular interactions of A-A and B-B type are nearly same as A-B type interactions. (ii) In ethanol and acetone
mixture A-A or B-B type intermolecular interactions are stronger than A-B type interactions. (iii) In chloroform and
acetone mixture A-A or B-B type intermolecular interactions are weaker than A-B type interactions. (a) Solution (ii)
and (iii) will follow Raoult's law. (b) Solution (i) will follow Raoult's law. (c) Solution (ii) will show negative deviation
from Raoult's law. (d) Solution (iii) will show positive deviation from Raoult's law.
94. On the basis of information given below mark the correct option. Information: On adding acetone to methanol
some of the hydrogen bonds between methanol molecules break. (a) At specific composition methanol-acetone
mixture will form boiling azeotrope and will show positive deviation from Raoult’s law. (b) At specific composition
MAHENDRA KALRA 9462305605
 methanol-acetone mixture forms boiling azeotrope and will show positive deviation from Raoult’s law (c) At specific
composition methanol-acetone mixture will form minimum boiling azeotrope and will shownegative deviation from
Raoult’s law. (d) At specific composition methanol-acetone mixture will form boiling azeotrope and will show
negative deviation from Raoult’s law.
95. Negative deviation from Raoult’s law is observed in which one of the following binary liquid mixtures? (a) Ethanol
and acetone (b) Benzene and toluene (c) Acetone and chloroform (d) Chloroethane and bromoethane
96. Which one of the following binary liquid systems shows positive deviation from Raoult’s law? (a) Benzene-toluene
(b) Carbon disulphide-acetone (c) Phenol-aniline (d) Chloroform-acetone
97. Which of the following solutions shows positive deviation from Raoult’s law?(a) Acetone + Aniline(b) Acetone +
Ethanol(c) Water + Nitric acid (d) Chloroform + Benzene
98. A binary liquid solution is prepared by mixing n-heptane and ethanol. Which one of the following statements is
correct regarding the behaviour of the solution? (a) The solution is non-ideal, showing negative deviation from
Raoult’s Law. (b) The solution is non-ideal, showing positive deviation from Raoult’s Law. (c) n-heptane shows
positive deviation while ethanol shows negative deviation from Raoult’s Law. (d) The solution formed is an ideal
solution.
99. A mixture of two completely miscible non-ideal liquids which distill as such without change in its composition at a
constant temperature as though it were a pure liquid. This mixture is known as (a) binary liquid mixture (b)
azeotropic mixture (c) eutectic mixture (d) ideal mixture
100. The azeotropic mixture of water (b.p.100°C) and HCl (b.p.85°C) boils at 108.5°C. When this mixture is distilled it is
possible to obtain (a) pure HCl (b) pure water (c) pure water as well as pure HCl (d) neither HCl nor H 2O in their
pure states
101. The system that forms maximum boiling azeotrope is (a) carbondisulphide – acetone (b) benzene – toluene (c)
acetone – chloroform (d) n-hexane – n-heptane
102. Which one of the following binary mixtures forms an azeotrope with minimum boiling point type? (a) acetone-
ethanol (b) H2O-HNO3 (c) benzene-toluene (d) n-hexane-n-heptane
103. The system that forms maximum boiling azetrope is(a) Acetone-chloroform(b) ethanol-acetone(c) n-hexane-n-
heptane(d) carbon disulphide-acetone
104. Which will form maximum boiling point azeotrope (a) HNO3 + H2O solution (b) C2H5OH + H2O solution (c) C6H6 +
C6H5CH3 solution (d) None of these
105. When X and Y are mixed the solution becomes warmer. The solutions will exhibit (a)positive deviation from Raoult’s
law (b) negative deviation from Raoult’s law (c) Can be both (d)None of the above
106. When Y and Z are mixed the solution becomes cooler. The solutions will exhibit (a)positive deviation from Raoult’s
law (b) negative deviation from Raoult’s law (c) Can be both (d)None of the above
107. What general name is given to binary mixtures which show deviation from Raoult’slaw and whose components
cannot be separated by fractional distillation (a) binary liquid mixture (b) azeotropic mixture (c) eutectic mixture (d)
ideal mixture
108. Acetone (bp329K) and carbon disulphide (bp320K) are mixed in a definite composition so that the mixture of two
behaves like pure liquid and boils at 312 what name can be given to such a mixture? (a) binary liquid mixture (b)
Minimum boiling azeotrope (c) Maximum boiling azeotrope (d) ideal mixture
109. In non-ideal solution what type of deviation shows the formation of maximum boiling azeotrope (a)positive
deviation from Raoult’s law (b) negative deviation from Raoult’s law (c) Can be both (d)None of the above
110. In non ideal solution what type of deviation shows the formation of mimimum boiling azeotrope. : (a)positive
deviation from Raoult’s law (b) negative deviation from Raoult’s law (c) Can be both (d)None of the above
111. 10cc of a liquid A is mixed with 10 cc of liquid B.The volume of resulting solution was found to be 19.9cc. The solutions
is : (a)positive deviation from Raoult’s law (b) negative deviation from Raoult’s law (c) Can be both (d)None of the
above
112. The example of minimum boiling azeotrope is : (a) Nitric acid and water (b) ethanol-water (c) n-hexane – n-heptane
(d) benzene-toluene
113. The example of maximum boiling azeotrope is : (a) Nitric acid and water (b) ethanol-water (c) n-hexane – n-heptane
(d) benzene-toluene
114. The approximate composition of nitric acid & water azeotrope is (a) 68% acid and 32% (b) 58% acid and 42%
(c)98% acid and 2% (d)88% acid and 12%
115. Intermolecular forces between two benzene molecules are near to same strength as those between two toluene
molecules. For a mixture of benzene and toluene, which of the following are not true? (a) ∆ mix H = zero (b) ∆mix V =
zero (c) These will not form azeotrope. (d) These will not form the ideal solution
MAHENDRA KALRA 9462305605
116. Which of the following binary mixtures will have the same composition in the liquid and vapour phase? (a) Benzene
– Toluene (b) Water-Nitric acid (c) bromoethane and chloroethane (d) n-Hexane – n-Heptane
117. Which one of the following is a colligative property ? (a) Boiling point (b) Vapour pressure (c) Osmotic pressure (d)
Freezing point
118. The rise in the boiling point of a solution containing 1.8 g of glucose in 100 g of solvent is 0.1°C. The molal elevation
constant of the liquid is (a) 0.01 K/m (b) 0.1 K/m (c) 1 K/m (d) 10 K/m
119. For an electrolyte, elevation of B.P. is directly proportional to (a) molarity (b) molality (c) mole fraction (d) All of
these
120. The relative lowering of vapour pressure in case of a solution of non- volatile solute is equal to the mole fraction of
solute. The statement is based on- (b)Henry‘s law (b) Arrhenius law (c) Raoult‘s law (d) Ostwald‘s law
121. A solution is prepared by dissolving 10 g of non volatile solute in 200 g of water .It has a vapour pressure of 31.84
mm of Hg at 308 K.Calculate the molar mass of the solute.(Vapour pressure of pure water at 308K is 32 mm of Hg.)
(a)180 (b)80 (c)90 (d)270
122. At 250C the saturated vapour pressure of water is 3.165 k Pa (23.75 mm Hg).Find the saturated vapour pressure
of a 5% aqueous solution of urea at same temperature.(molar mass of urea =60.05 g/mol) (a) 3.118 k Pa(b) 3.818 k
Pa (c) 3.178 k Pa (a) 3.888 k Pa
123. Calculate the mass of a nonvolatile solute (molecular mass = 40) which should be dissolved in 114g octane to reduce
its vapour pressure to 80%. (a) 8g (b)80g (c)16g (d)24g
124. Vapour pressure of benzene at 30°C is 121.8 mm. When 15g of a non-volatile solute is dissolved in 250 g of
benzene, its vapour pressure is decreased to 120.2 mm. The molecular weight of the solute is (a) 35.67 g (b) 356.7 g
(c) 432.8 g (d) 502.7 g
125. According to Raoult‘s law relative lowering in vapour pressure of non-volatile solute is equally proportional to-
(a) mole fraction of solvent (b) mole fraction of solute (c) mass fraction of solute (d) mass fraction of solution
126. If 200 ml water is added to 0.2 M 500 ml solution calculate molarity (M) of diluted solution? (a) 0.5010 M (b)
0.2847 M (c) 0.7093 M (d) 0.1428 M
127. On dissolving definite amount having molecular mass 60 gm/mole of substance in 180 gm of water, the vapour
pressure of water decreases by 10% then calculate the amount dissolved ? (a) 30 gm (b) 120 gm (c) 12 gm (d) 60
gm
128. At a definite temperature vapour pressure of pure benzene is 0.85 bar. When 0.5 gm of solid non-volatile
electrolyte is dissolved in 39.0 gm benzene vapour pressure of solution becomes0.845 bar calculate molecular mass
of the solid substance ? (a) 58 gm mol–1 (b) 170 gm mol–1 (c) 180 gm mol–1 (d) 135 gm mol–1
129. The vapour pressure of a dilute solution of a solute is not influenced by: (a) Temperature of solution (b) melting
point of solute (c) Mole fraction of solute (d) degree of dissociation of solute
130. An aqueous solution of methanol in water has vapour pressure: (a) equal to that of water (b) equal to that of
methanol (c) more than that of water (d) less than that of water
131. Which of the following solution containing components A and B follow Raoult's Law?: (a). A-B attraction force is
greater than A-A and B-B (b). A-B attraction force is less than A-A and B-B (c). A-B attraction force remains same as
A-A and B-B (d). Volume of solution is different from sum of volume of A and B
132. The vapour pressure of the solution containing non-volatile solute is: (a). greater than vapour pressure of pure
solvent (b). lesser than vapour pressure of pure solvent (c). equal to the vapour pressure of pure solvent (d). the sum
of the vapour pressure of the solute and the solvent
133. When a substance is dissolved in a solvent, the vapour pressure of solvent decreases. This brings: (a) an increase
in b.pt. of the solution (b) a decrease in b.pt of a solution (c) an increase in f. pt of the solvent (d) none
134. If the vapour pressure of solutions of two liquids are less than those expected from ideal solution they are said to
have : (a) negative deviation from ideal behaviour (b) positive deviations from ideal behaviour (c) ideal behaviour (d)
sometime positive and sometime negative deviations .
135. Which of the following conditions is not correct for ideal solution: (a) no change in volume on mixing (b) no
change in enthalpy on mixing (c) it obey’s Raoult’s law (d) lonisation of solute should occurs to a small extent
136. Solutions distilled without change in composition at a temperature are called : (a) Amorphous (b) Azeotropic
mixture (c) Ideal solution (d) Super saturated solution
137. An azeotropic solution of two liquids has boiling point higher than either of them when it: (a) shows a negative
deviation from Raoult’s law (b) is saturated (c) shows no deviation from Raoult’s law (d) shows positive deviation
from Raoult’s law

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138. An azeotropic solution of two liquids has a boiling point lower than either of them when it: (a) shows negative
deviation from Raoult's law (b) shows no deviation from Raoult's law (c) shows positive deviation from Raoult's law
(d) is saturated
139. For a dilute solution, Raoult's law state that: (a) the lowering of vapour pressure is equal to mole fraction of
solute (b) the relative lowering of vapour pressure is equal to the mole fraction of solute (c) the relative lowering of
vapour pressure is proportional to the amount of solute in solution (d) the vapour pressure of the solution is equal
to the mole fraction of solvent
140. The osmotic pressure associated with the fluid inside the blood cell is equivalent to that of 0.9% (mass/volume)
sodium chloride solution. If RBC is placed the solution having the concentration more than 2.9% (w/V)NaCl solution
then (a) RBC will burst (b) RBC will shrink (c) No change will be seen RBC (d) RBC will become flaccid
141. A 5 % solution of canesugar is isotonic with 0.877% of substance X.Find the molecular weight of X.
(a) 60 gmmol-1 (b)120 gmmol-1 (c)78 gmmol-1 (d)30gmmol-1
142. In osmosis (a) Solvent molecules move from higher concentration to lower concentration (b) Solvent molecules
move from lower concentration to higher concentration (c) Solute molecules move from higher concentration to
lower concentration (d) Solute molecules move from lower concentration to higher concentration
143. Two solutions A and B are separated by semi-permeable membrane. If the liquid flows from A to B then (a) A is
less concentrated than B (b) A is more concentrated than B (c) Both have the same concentration (d) B is less
concentrated than A
144. Which colligative property is more useful to determine the molecular mass of the proteins and polymers? (a)
Lowering in vapour pressure (b) Elevation in boiling point (c) Depression in freezing point (d) Osmotic pressure
145. Molal depression constant depends upon: (a) nature of the solute (b) nature of the solvent (c) vapour pressure of
the solution (d) heat of solution
146. When a particular solution has a higher osmotic pressure than the given standard solution, it is most
appropriately called as ……… with respect to the standard solution (a) Hypotonic (b) Hypertonic (c) Isotonic (d) None
of these
147. What will happen if RBC are placed in (i)0.5% NaCl Solution (ii)1% NaCl Solution? (a) (i) swell (ii) shrink (b) (i)
shrink (ii) swell (c) (i) shrink (ii) shrink (d) (i) swell (ii) swell
148. A raw mango placed in concentrated salt solution shrivels into pickle is due to (a)Osmosis (b)Reverse Osmosis (c)
Henry law application (d)Raoults law application
149. Wilted flowers revive when placed in fresh water. (a)Osmosis (b)Reverse Osmosis (c) Henry law application
(d)Raoults law application
150. A carrot that has become limp placed into the water making it firm once again. (a)Osmosis (b)Reverse Osmosis
(c) Henry law application (d)Raoults law application
151. Water movement from soil into plant roots and subsequently into upper portion of the plant (a)Osmosis
(b)Reverse Osmosis (c) Henry law application (d)Raoults law application
152. The preservation of meat by salting and of fruits by adding sugar protects against bacterial action. (a)Osmosis
(b)Reverse Osmosis (c) Henry law application (d)Raoults law application
153. Measurement of _____________ method is preferred for the determination of molecular masses of
macromolecules such as proteins and polymers (a)Osmotic Pressure (b)Elevation in boiling point (c)Depression in
freezing point (d)Relative lowering of vapour pressure
154. People add sodium chloride to water while boiling eggs. This is to(a) decrease the boiling point.(b) increase the
boiling point.(c) prevent the breaking of eggs.(d) make eggs tasty
155. The molal elevation constant depends upon(a) nature of solute.(b) nature of the solvent.(c) vapour pressure of
the solution. (d) enthalpy change
156. Sprinkling of salt helps in clearing the snow covered roads in hills. The phenomenon involved in the process is(a)
lowering in vapour pressure of snow(b) depression in freezing point of snow(c) melting of ice due to increase in
temperature by putting salt (d) increase in freezing point of snow
157. Which of the following statements is correct? (a) Solutes that dissociates in water experience a decrease in
colligative properties (b) Colligative properties are independent of the number of particles of the solute in the
solution (c) Solutes that dissociate in water have molar mass higher than the molar mass of the solute calculated
theoretically (d) Solutes that associate in water have molar mass higher than the molar mass of the solute calculated
theoretically.
158. A set of solutions is prepared using 180 g of water as a solvent and 10 g of different nonelectrolyte and non-
volatile solutes A, B and C. The relative lowering of vapour pressure in the presence of these solutes are in the order

MAHENDRA KALRA 9462305605

 (given: Molar mass of A = 100 g mol-1, B = 200 g mol-1, C = 10,000 g mol-1) (a) A > B> C (b) B > C > A (c) C > B > A (d) A
>C>B
159. The osmotic pressure of 5 % aqueous solution of glucose ( ) is related to that of 5 % aqueous solution of urea ( )
as (a) π1= π2 (b) π1< π2 (c) π1> π2 (d) π1= π2/2
160. Osmotic pressure of urea solution at 100C is 500 mm Hg. Osmotic pressure of the solution becomes 105.3 mm
Hg, when it is diluted and temperature raised to 250C. The extent of dilution is: (a) 6 times (b) 5 times (c) 7 times (d)
4 times
161. If molality of the dilute solution is doubled, the value of molal depression constant (Kf) will be (a) Halved (b)
Tripled (c) Unchanged (d) Doubled.
162. 18 g of glucose, C6H12O6, is dissolved in 1 kg of water in a saucepan. At what temperature will water boil at 1.013
bar? Kb for water is 0.52 K kg mol-1. (a) 100.2 °C (b) 100.3 °C (c) 100.1 °C (d) 100.02 °C
163. Pure water can be obtained from sea water by (a) Centrifugation (b) Plasmolysis (c) reverse osmosis (d)
Sedimentation.
164. A solution prepared by dissolving 1.25g of oil of wintergreen in 99.0g of benzene has a boiling point of 80.310C
Determine the molar mass of this compound(B.P. of pure benzene = 80.100C and Kb for benzene is 2.53 KKgmol-1.) (a)
152 gmmol-1 (b) 1052 gmmol-1 (c)52 gmmol-1 (d)15 gmmol-1
165. A 4% solution (by mass) of sucrose in water has freezing point of 271 K. calculate the freezing point of 5% glucose
in water if freezing point of water is 273.15 K (a) 269.06 K. (b) 279.06 K (c)289.06 K.(d)none of these
166. 1.00 g of a non-electrolyte solute dissolved in 50 g of benzene lowered the freezing point of benzene by 0.40 K.
The freezing point depression constant of benzene is 5.12 K kg mol –1. Find the molar mass of the solute. (A) 254 g
mol-1 (B) 256 g mol–1 (C) 265 g mol–1 (D) 245 g mol–1
167. The boiling point of 0.2 mol kg–1 solution of X in water is greater than equimolal solution of Y in water. Which
one of the following statements is true in this case? (a) Molecular mass of X is less than the molecular mass of Y. (b)
Y is undergoing dissociation in water while X undergoes no change. (c) X is undergoing dissociation in water. (d)
Molecular mass of X is greater than the molecular mass of Y.
168. The relative lowering of the vapour pressure is equal to the ratio between the number of (a) solute molecules to
the solvent molecules (b) solute molecules to the total molecules in the solution (c) solvent molecules to the total
molecules in the solution (d) Solvent molecules to the total number of ions of the solute.
169. 1 g of a non-volatile, non-electrolyte solute of molar mass 250 g/mol was dissolved in 51.2 g of benzene. If the
freezing point depression constant Kf of benzene is 5.12 kg K mol–1. The freezing point of benzene is lowered by (a)
0.3 K (b) 0.5 K (c) 0.2 K (d) 0.4 K
170. If 0.1 M solution of glucose and 0.1 M solution of urea are placed on two sides of the semipermeable membrane
to equal heights, then it will be correct to say that (a) there will be no net movement across the membrane (b)
glucose will flow towards urea solution (c) urea will flow towards glucose solution (d) water will flow from urea
solution to glucose
171. Which of the following statements is false? (a) Units of atmospheric pressure and osmotic pressure are the
same. (b) In reverse osmosis, solvent molecules move through a semipermeable membrane from a region of lower
concentration of solute to a region of higher concentration. (c) The value of molal depression constant depends on
nature of solvent. (d) Relative lowering of vapour pressure, is a dimensionless quantity.
172. During osmosis, flow of water through a semipermeable membrane is (a) from both sides of semipermeable
membrane with equal flow rates (b) from both sides of semipermeable membrane with unequal flow rates (c) from
solution having lower concentration only (d) from solution having higher concentration only
173. Osmotic pressure of a solution at a given temperature (a) increases with concentration (b) decreases with
concentration (c) remains same (d) initially increases and then decreases
174. At 25°C, at 5 % aqueous solution of glucose (molecular weight = 180 g mol–1) is isotonic with a 2% aqueous
solution containing an unknown solute. What is the molecular weight of the unknown solute? (a) 60 (b) 80 (c) 72 (d)
63
175. A solution of sucrose (molar mass = 342 g mol–1) has been prepared by dissolving 68.5 g of sucrose in 1000 g of
water. The freezing point of the solution obtained will be (Kf for water = 1.86 K kg mol–1). (a) – 0.372°C (b) – 0.520°C
(d) + 0.372°C (d) – 0.570°C
176. A solution containing 1.8 g of a compound (empirical formula CH2O) in 40 g of water is observed to freeze at –
0.465° C. The molecular formula of the compound is (Kf of water = 1.86 kg K mol –1) (a) C2H4O2 (b) C3H6O3 (c) C4H8O4
(d) C6H12O6
177. Blood cells retain their normal shape in solution which are (a) hypotonic to blood (b) isotonic to blood (c)
hypertonic to blood (d) equinormal to blood.
MAHENDRA KALRA 9462305605
178. Isotonic solutions have same (a) molar concentration (b) molality (c) normality (d) None of these
179. As a result of osmosis, the volume of more concentrated solution (a) gradually decreases (b) gradually increases
(c) is not affected (d) suddenly increases
180. At 300 k, 36g of glucose present per litre in its solution has an osmotic pressure of 4.98 bar. If the osmotic
pressure of solution is 1.52 bars at the same temperature, what would be the concentration? (a)0.061M (B)0.661M
(c) (a)0.081M (d)1.061M
181. Complete the following analogy: Molarity : Mol/Litre :: _ _ _ _ _ _ : Mol/Kg (a) Mole Fraction (b) Molality (c) Strength (d)
Formality
182. Which of the following analogies is correct? a. Solid in solid : Alloy :: Liquid in liquid : Coolant in cars b. Molality:
Temperature:: Molarity : Volume c. Henry’s Law: Scuba Diver :: Raoult’s Law : RO d. Helium : Cold Drinks:: Nitrogen : Bend
183. Ebullioscopy: Boiling point elevation : : _____________________ : Freezing point depression. a. Osmotic pressure b.
Raoult’s law c. Cryoscopy d. Relative lowering in vapour pressure
184. Boiling point elevation: molality : : Molarity : ________________. a. Freezing point depression b. Osmotic pressure c.
Vapour pressure d. Relative lowering in vapour pressure
185. Assertion: When molecular mass of Acetic acid in Benzene and in water is calculated using depression in freezing point it
gives different values. Reason: Water is polar and benzene is non polar solvent.
186. Assertion: In liquid state molarity changes with change in temperature. Reason: Volume changes with change in
temperature.
187. Assertion: Molarity of the solution does not change on dilution. Reason: Ratio of moles of solute to the volume of solution
is called molarity.
188. Assertion: Ideal solution is prepared by mixing benzene and toluene. Reason: On mixing 25 ml benzene with 25ml toluene,
the volume of solution become 50 ml and there is no change in the enthalpy of mixing.
189. Assertion: 1 molal aqueous solution of urea contains 60 gm urea in 1Kg water. Reason: 1 mole solute dissolved in 1000gm
solvent the resultant solution is called a 1 Molal solution.
190. Assertion: 0.9% (w/w) solution of NaCl is isotonic with blood cells. Reason: isotonic solutions have equal osmotic pressure.
191. Assertion: Osmotic pressure of 0.1 M urea solution is greater than that of 0.1M NaCl solution. Reason: Osmosis is a
colligative property.
192. Assertion: To remove snow from road, salt is used. Reason: NaCl decrease freezing point of water.
193. Assertion: Pressure cooker decreases time of cooking food. Reason: Boiling point of water decrease in pressure cooker.
194. Assertion: The boiling point of water is higher than H2S. Reason: H2S has a greater molecular mass than H2O.
195. Assertion: Ethanol in water is an emulsion Reason: As 95% aqueous solution of ethanol is called as absolute alcohol.
196. Assertion: When sugar is added to water, vapour pressure of water decreases. Reason: When a non-volatile solute is
added to a volatile solvent, it allows less vapour to escape from the surface.
197. Assertion:When Scuba diver breaths in their special cylinders, no bends occur. Reason: The Cylinders are filled with 11%
Argon gas to reduce harmful impact of N2 gas.
198. Assertion: Molality of a solution does also vary with temperature. Reason: The Mass of the solvent does not change with
rise in temperature.
199. Assertion: Depression of freezing point is a colligative property. Reason: The depression of freezing point for a solution is
directly proportional to the molality of the solution.––
200. Assertion: When methyl alcohol is added in water, boiling point is increased. Reason When a volatile solute is added in a
volatile solvent elevation in boiling point is observed.
201. Assertion: When a solution is separated from pure solvent by a semi-permeable membrane, solvent molecules pass
through it from solvent side to solution side. Reason: Diffusion is the movement of particles from an area of higher
concentration to lower concentration
202. Assertion:The osmotic pressure method has got advantages over other colligative properties.Reason:Because the
measurement of osmotic pressure is around the room temperature and molarity of the solution is used instead of molality.
203. Assertion: It is difficult to separate Azeotropic Mixture. Reason Azeotropic mixture boils as a single component at a
constant temperature so that fractional distillation doesn’t work.
204. Assertion : Azeotropic mixtures are formed only by non-ideal solutions and they may have boiling points either greater than
both the components or less than both the components. Reason : The composition of the vapour phase is same as that of the
liquid phase of an azeotropic mixture.
205. Assertion : If one component of a solution obeys Raoult’s law over a certain range of composition, the other component
will not obey Henry’s law in that range. Reason : Raoult’s law is a special case of Henry’s law.
206. Assertion : Molarity of a solution in liquid state changes with temperature. Reason : The volume of a solution changes
with change in temperature.

MAHENDRA KALRA
MAHENDRA KALRA 9462305605