3E5NA Sci Chem Qualitative Analysis Notes Student's
3E5NA Sci Chem Qualitative Analysis Notes Student's
3E5NA Sci Chem Qualitative Analysis Notes Student's
CHAPTER 11
Qualitative Analysis
Name : ________________________
Class : __________
Date : __________
1
NOTES 11.1
LESSON OBJECTIVES
At the end of the lesson, you will be able to
o define salt.
o determine the solubility of salts in water.
Formation of salts
Example 1: Acid + Reactive metal → Salt + Hydrogen gas
o Word equation:
hydrochloric acid + magnesium → magnesium chloride + hydrogen gas
o Chemical equation:
2 HCl + Mg → MgCl2 + H2
Example 2: *Acid + Base (Metal oxide/ Metal hydroxide/ Ammonium hydroxide) → Salt + Water
*Neutralisation reaction
o Word equation:
sulfuric acid + ammonium hydroxide → ammonium sulfate + water
o Chemical equation:
H2SO4 + 2 NH4OH → (NH4)2SO4 + 2 H 2O
Water of crystallisation
Hydrated salts Anhydrous salts
o Many salts combine with water molecules (these o Anhydrous salts do not contain water
water molecules are known as water of of crystallisation.
crystallisation) to form hydrated salts.
o Hydrated salts contain water of crystallisation.
o Appearance: crystals o Appearance: powders
o Examples: o Examples:
hydrated copper (II) sulfate: CuSO4.5H2O copper (II) sulfate: CuSO4
hydrated sodium carbonate: Na2CO3.10H2O sodium carbonate: Na2CO3
Note:
White anhydrous CuSO4 can be used to test for the presence of water. White anhydrous CuSO4
turns blue when water is added to it.
All chlorides are soluble in water, except Student Leader o silver chloride
Committee o lead(II) chloride
are insoluble in water.
All sulfates are soluble in water, except CLB Student o calcium sulfate
o lead(II) sulfate
o barium sulfate
are insoluble in water.
Soluble bases o All metal hydroxides are o Soluble bases are also
o Only Group I oxides insoluble (except Group I and known as alkalis! They
o Only SPA hydroxides some Group II). are also not salts!
(alkalis) o All metal oxides are insoluble
o Calcium hydroxide (alkali) (except Group I)
(sparingly soluble)
LESSON OBJECTIVES
At the end of the lesson, you will be able to
o describe the procedures and state the reagents used to identify cations and anions in
salts during Qualitative Analysis.
o state, with reasoning, the results of the tests used identify cations and anions in salts.
o describe tests to identify the following gases:
ammonia [using moist red litmus paper]
chlorine [using moist litmus paper]
carbon dioxide [using limewater]
sulfur dioxide [using acidified potassium manganate (VII)]
hydrogen [using a lighted splint]
Oxygen [using a glowing splint]
Qualitative Analysis
o Qualitative analysis is a process used by a chemist to identify the cations and anions in an
unknown solution.
o All salts are composed of cations (positive ions) and anions (negative ions). For example,
iron(II) sulfate consists of iron (II) ions (Fe2+ ions) and sulfate ions (SO42– ions).
Tip: In order to identify an unknown salt, it must be dissolved in water.
Aqueous ammonia is added to a solution of a salt. A white precipitate is formed which dissolves
in an excess of aqueous ammonia.
A Al3+ C Cu2+
B Ca2+ D Zn2+
( )
Question
1. A student forgot to label two reagent bottles. The two bottles contain either aqueous
calcium chloride or aqueous sodium chloride. How could be done to identify the two
solutions?
A Addition of aqueous lead (II) nitrate
B Addition of dilute sulfuric acid
C Addition of blue litmus paper
D Addition of aqueous sodium hydroxide
( )
chloride (Cl–) o Add dilute nitric acid, o White precipitate o The unknown salt
followed by aqueous is formed. solution contains
silver nitrate to the chloride ions.
unknown salt solution.
o Do not confuse the test for nitrate ions with the test for ammonium
ions! Nitrate ions require the aluminium foil.
Add aqueous
ammonia
(ii) R: ______________________________
(iii) S: ______________________________
(b) Write a balanced chemical equation, with state symbols, for the formation of gas S.
_______________________________________________________
1. A student forgot to label two reagent bottles. The two bottles contain either
aqueous potassium nitrate or aqueous sodium chloride. How could be done to
identify the two solutions?
A Addition of aqueous lead (II) nitrate
B Addition of dilute sulfuric acid
C Addition of blue litmus paper
D Addition of aqueous sodium hydroxide
( )
2. A student performed two tests on solution X, and she recorded the observations
as shown below.
Test I: A colourless gas was produced with calcium carbonate.
Test II: A white precipitate was produced with acidified silver nitrate solution.
filter
green
n
solution white residue L
add sodium
hydroxide solution
green precipitate M
(a) Identify
(i) K: ________________________________________________________
(ii) L: ________________________________________________________
(iii) M: ________________________________________________________
(b) Write the ionic equation, with state symbols, for the formation of white residue L.
__________________________________________________________________
(c) Write the chemical equation for the reaction between the aqueous solution of solid K
and acidified barium nitrate.
___________________________________________________________________
Hydrogen Colourless Place a lighted splint at the mouth of the test The lighted
and tube. splint is
odourless extinguished
with a ‘pop’
sound.
pop
lighted
splint
Oxygen Colourless Insert a glowing splint into the test tube. The glowing
and splint is
odourless relighted
/rekindled.
glowing splint
Sulfur dioxide Colourless Bubble the gas through acidified potassium Purple
gas with a manganate (VII). acidified
pungent potassium
smell manganate
Dilute
hydrochloric (VII) turns
acid colourless.
Sodium sulfite
Acidified potassium
manganate (VII)
Carbon dioxide Colourless Bubble the gas through limewater (calcium A white
and hydroxide). precipitate
odourless with
limewater.
Dilute
hydrochloric
acid
Calcium
Calcium carbonate hydroxide
(limewater)
Chlorine Greenish- Place a piece of moist blue litmus paper at the The moist
yellow gas mouth of test tube. blue litmus
with a paper turns
pungent red, and is
smell moist blue then
litmus paper bleached.
Ammonia Colourless Place a piece of moist red litmus paper at the The moist
gas with a mouth of the test tube. red litmus
pungent paper turns
smell blue.
Ammonia
gas is
alkaline.
o Example: alkali/base + ammonium salt → salt + water + ammonia
o Did you know?: The moist litmus paper allows the ammonia gas to dissolve
in water to form ammonium hydroxide, which provides the hydroxide ions
that turn red litmus paper blue!
o Precaution: Ensure that the moist litmus paper do not touch the (inner)
surface of the test tube. The solution on the surface of the test tube could
give a false positive result.
Question
Which change occurs to the damp red litmus paper in the experiment above?
(Q2/P1/2013)
A remains red
B turns blue and is then bleached
C turns blue and remains blue
D turns blue and then turns red ( )
LESSON OBJECTIVES
At the end of the lesson, you will be able to:
o define thermal decomposition.
o describe tests to identify the gas liberated from the thermal decomposition of common
salts.
Example 2:
Zinc nitrate decomposes on heating to give zinc oxide, nitrogen dioxide and oxygen.
Chemical equation: 2 Zn(NO3)2 (s) → 2 ZnO (s) + 4 NO2 (g) + O2 (g)
Before heating:
Observation Possible Deductions
Coloured compound Transition metal compound
White compound Group I, II, III metal compounds; ammonium compounds,zinc
compounds
Powdery solid or fine Likely to be a carbonate
powder
Large crystals Likely to be salts such as chlorides, nitrates and sulfates
Grey powder / silver Metals such as Mg, Al, Zn & Fe
powder
After heating:
Observation Possible Deductions
White residue or white deposits Compounds of Group I, II and III metals. / Ammonium
salts.
Residue is likely to be oxides of Group I, II and III
metals.
Black powdery residue Copper (II) compounds, iron (II) compounds.
Residue is likely to be CuO, FeO.
Yellow residue when hot, white residue Zinc compound; residue is zinc oxide.
when cold.
Solid changes colour from green to Solid is copper (II) carbonate. CuO residue is formed.
black powder residue.
Oxygen and Nitrogen All other metal nitrates e.g. Ca(NO3)2 , Zn(NO3)2 , Pb(NO3)2 ,
dioxide are produced. Cu(NO3)2.
Colourless droplets of liquid Water droplets are produced. Water of crystallisation from
condensed on cool walls of hydrated crystals e.g. CuSO4.5H2O, FeSO4.7H2O, Na2CO3.10H2O or
test tube. water from thermal decomposition of metal hydroxides