Foxboro 871 PH
Foxboro 871 PH
Foxboro 871 PH
871PH Series
pH, ORP, and Fluoride Sensors and Accessories
871PH multi-purpose precision electrochemical sensors, used in conjunction with 871PH accessories, are
suitable for pH, ORP, and Fluoride measurement applications. As symbolized by the “CE” marking, these
Sensors conform to the European Union directive.
These sensors are used with 873 Electrochemical ORP is related to the logarithm of the ratio of
Analyzers, 870ITPH Intelligent Transmitters, and oxidation activity to reduction activity, just as pH is
870PH Analog Transmitters. Measurement of pH by related to the logarithm of the hydrogen ion activity. A
the Foxboro 871PH Sensors is accomplished by solution that contains an excess of oxidizing agent
immersing a glass or metal electrode, with a has a positive ORP while one containing an excess
reference electrode, into a process solution. The of reducing agent has a negative ORP.
glass or metal electrode produces an electrical Typical ORP applications include treatment of
potential proportional to the hydrogen ion activity. chromate and cyanide wastes produced by plating,
The reference electrode completes the circuit and chemical, and metal treatment plants. ORP
provides a stable reference for the glass or metal monitoring enables industry to determine reaction
electrode. These two electrodes constitute an end points and to meet today's stringent
electrolytic cell having a millivolt output that is environmental requirements.
proportional to the pH of the solution.
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Fluoride measurement is accomplished by means of Metallic (antimony) pH electrodes are available for
an ion-selective electrode, or ISE. A pH electrode is abrasive solutions or for solutions containing
an example of an ISE which is sensitive to hydrogen hydrofluoric acid or other chemicals which attack
ion activity. Similarly, the fluoride electrode utilizes a glass. Antimony electrodes should not be used in
lanthanum fluoride crystal which is sensitive to acid copper solutions nor in oxidizing or reducing
fluoride ion activity. When immersed in a solution solutions such as chromates, chlorine, hypochlorites,
containing free fluoride ions, the electrode develops or sulfides.
a millivolt potential proportional to the ion activity. Platinum or gold ORP electrodes are also available.
Typical fluoride applications include control and (Gold is primarily used in cyanide reduction systems.)
monitoring of fluoridation of drinking water supplies.
The newest addition to the 871PH's electrode
SINGLE MULTI-PURPOSE ASSEMBLY offering is an ion-selective electrode for the
This multi-purpose sensor assembly is suitable for measurement of ppm fluoride. The fluoride electrode
virtually all process pH, ORP, and fluoride consists of a lanthanum fluoride crystal in an epoxy
measurement applications. Its flexibility is further body, and is compatible with the 873DPX Analyzer
enhanced when used with a variety of mounting and 870ITPH Transmitter.
accessories. The sensor accepts a variety of glass
SENSOR DIAGNOSTICS
pH, metallic pH, and ORP electrodes, as well as a
new ion-selective electrode for fluoride When used with the Foxboro 870ITPH Intelligent
measurement. The unit is not affected by normally Transmitter, the intelligent configurations of the
encountered chemical solutions and is capable of sensor (Model Code Sensor Selections “–3”, “–4”,
withstanding continuous operation in a wide range of “–5”, and “–6”) provide diagnostic information.
process pressures and temperatures. Sensor health checks will reveal the following faults:
• Broken Glass Electrode
CHOICE OF SENSOR BODY • Aging Glass Electrode
The sensor assembly is available in either a Ryton or • Liquid Leakage into Sensor Body
CPVC body. The Ryton body can be used in almost • Failure of High Impedance Amplifier in Sensor
any normally encountered chemical solution, and is (Sensor Selection Codes “–3” and “–4” only)
the preferred material where organic chemicals are • Failure of Temperature Compensation Element
present. The CPVC body is used in applications • Excessive Coating of the Reference Electrode
involving hypochlorites or peroxides (e.g., bleach).
FIELD INTERCHANGEABLE ELECTRODES
CHOICE OF SENSING ELECTRODES Interchangeable plug-in sensing electrodes are
Glass pH electrodes offer the best performance in available to suit most applications. All electrodes are
most solutions and inherently provide the most compatible with the same basic sensor body. If the
accurate measurement. The flat ruggedized measurement conditions or application needs
electrode or the small bulb results in a durable change, it is simple to change from one
electrode suitable for industrial service. measurement electrode to another in the field.
The flat, ruggedized glass electrode with a Ryton
FIELD REPLACEABLE REFERENCE JUNCTION
body is recommended for most pH measurements
because of its very durable, abrasion-resistant The reference electrode is a nonflowing type. A
construction. This electrode is particularly resistant to silver/silver chloride half cell immersed in saturated
wear, stress, and abuse caused by physical potassium chloride is used because of its highly
operating conditions. Its optimum accuracy is in the stable output voltage. The filling solution and the
range of 2 to 12 pH, although it can be used with ceramic junction may be readily replaced in the field.
Analyzers and Transmitters that are ranged from 0 to See Model Code section for choice of body material.
14 pH. INTEGRAL PREAMPLIFIER
The spherical glass, low sodium error electrode with An integral preamplifier (Model Code Sensor
a Ryton body is recommended for applications where Selections “–1” through “–4”) converts the high
the pH is routinely in the range of 10 to 14 pH. It impedance pH signal to a low impedance signal,
features a glass formulation with minimal sodium ion which is less prone to interference.
error. It should also be selected for applications in
low conductivity water (down to 10µS/cm).
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PERFORMANCE SPECIFICATION
Ryton Body
Ball Valve or Submersible Installation In-Line Installation
Measuring Maximum Temperature Maximum Temperature
Electrode Type Pressure Range Pressure Range
Flat Glass pH 1 MPa –5 to + 80°C 1 MPa –5 to +105°C
(150 psi) (20 to 175°F) (150 psi) (20 to 220°F)
Spherical Glass pH 0.7 MPa –5 to + 80°C 0.7 MPa –5 to +105°C
(100 psi) (20 to 175°F) (100 psi) (20 to 220°F)
Antimony pH 1 MPa –5 to + 80°C 1 MPa –5 to +125°C
(150 psi) (20 to 175°F) (150 psi) (20 to 255°F)
ORP 1 MPa –5 to + 80°C 1 MPa –5 to +125°C
(150 psi) (20 to 175°F) (150 psi) (20 to 255°F)
Fluoride ISE 0.7 MPa –5 to + 60°C 0.7 MPa –5 to +60°C
(100 psi) (20 to 140°F) (100 psi) (20 to 140°F)
CPVC Body
Ball Valve or Submersible Installation In-Line Installation
Measuring Electrode Maximum Pressure at Operating Maximum Pressure at Operating
Type Temperature Temperature
Flat Glass pH 0.9 MPa 0.6 MPa 0.3 MPa 0.9 MPa 0.3 MPa 0.1 MPa
Spherical Glass pH(a) (125 psi) (90 psi) (50 psi) (125 psi) (50 psi) (15 psi)
Antimony pH at at at at at at
ORP –5°C 50°C 80°C –5°C 80°C 100°C
Fluoride ISE(b) (20°F) (120°F) (175°F) (20°F) (175°F) (212°F)
(a)Maximum Pressure at –5°C (20°F) for Spherical Glass pH electrode is 0.7 MPa (100 psi).
(b)Maximum operating temperature of Fluoride ISE is 60°C (140°F). Maximum pressure at –5°C (20°F) is 0.7 MPa (100 psi).
PSS 6-1C2 A
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MODEL CODE
Description Model
pH/ORP/ISE Sensor 871PH
Example: 871PH–1F1A–4
(a) Compatible with 870ITPH Intelligent Transmitter only.
(b) Optimum accuracy is in the range of 2 to 12 pH. It can, however, be used with pH instruments ranged from 0 to 14 pH.
(c) Except for the possible combination “–34”, only one optional selection may be chosen. Optional selections “–3” and “–4” may
each be selected individually or as a combination.
(d) Standard cable length if not specified = 6 m (20 ft).
(e) Optional Selection Code “–4” required when sensor is used with 873PH Series Analyzers.
(f) Requires Patch Cable.
(g) Not compatible with ball valve assembly mountings.
NOTE
See Sensor/Analyzer/Transmitter Compatibility Table on next page.
PSS 6-1C2 A
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NOTE
These sensors have been designed to meet the electrical safety descriptions
listed in the table above. For detailed information, or status of testing laboratory
approvals, or certifications, contact Foxboro.
PSS 6-1C2 A
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FUNCTIONAL SPECIFICATIONS
PHYSICAL SPECIFICATIONS
Sensor Mountings
Type Description
In-Line via Ball Valve Unit Permits sensor to be removed from process stream or tank, under rated
Assembly (Figure 1A) temperature and pressure, without draining the system or resorting to a bypass
arrangement.
Sample Line Twist-Lock Available for clean sample stream applications. A 316 ss flow chamber is
Flow Chamber (Figure 1B) recommended for pure water pH measurement.
In-Line via Twist-Lock For permanent installation in pipeline or tank.
Bushing (Figure 1C)
In-Line via Twist-Lock Tee For permanent installation in pipeline.
(Figure 1D)
In-situ (Figure 1E) In tank or trough, etc. An electrode protection sleeve is required for this use.
OUTLET
D E
C
B
ACCESSORIES
Accessory Selection for Parts Common to all Sensors (See Next Page for Parts which vary with Sensor)
Part Description Select Foxboro Part
Complete Ball Valve Assembly
For AISI Type 316 stainless steel (316 ss) Process Connection and Housing
With nonpurgeable housing BS805JN(a)
With purgeable housing BS805JP(b)
For Titanium Process Connection and Housing
With purgeable housing BS805JQ(c)
Flow Chamber (See Table 2 for rated pressure and temperature)
PVC 0051181
316 ss 0051179
Bushing (See Table 3 for rated pressure and temperature)
PVC
1 1/4 NPT 0051183
316 ss
1 1/4 NPT 0051185
1 1/2 NPT 0051186
Plug (See Table 4 for rated pressure and temperature)
PVC 0051187
316 ss 0051188
PVC Tee (See Table 5 for rated pressure and temperature) 0051184
CPVC Submersion Adaptor with Viton O-Ring BS805PU(d)
PVC Electrode Protection Sleeve 0051189
Buffers (see Table 6)
Electrode and Reference Kits (See Table 7 and Table 8)
(a)Previously specified as Part Number 0051361 plus 0051362 (shaft assembly).
(b)Previously specified as Part Number 0051380 plus 0051362 (shaft assembly).
(c)Previously specified as Part Number 0051360 plus 0051365 (shaft assembly).
(d)Supplied as standard on models dated Aug. 1987 to Dec. 1988. Not required on sensors dated on or later than Jan. 1989.
PSS 6-1C2 A
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ACCESSORIES (Cont.)
Accessory Selection for Parts which Vary with Sensor Selection
Select Foxboro Part for Sensors
Part Description 871PH–1,2 871PH–3,4 871PH–5,6
Junction Box 0051052 BS807BZ Q0101CF
IEC IP65 and NEMA 4 specifications, watertight fittings
Extension Cable Assembly with Spade Terminals 0060301 BS807CK BS805SK
Specify length up to 150 m (500 ft)
Extension Cable without Spade Terminals 6000–130 P0170RG P0170LF
Specify length up to 330 m (1000 ft)
Patch Cable, Standard Length, 3 m (10 ft) BS806NP N/A N/A
Patch Cable, Length to Sales Order up to 33 m (100 ft) BS806NQ N/A N/A
Maximum
Temperature
Rated at Rated
Pressure Pressure Material of Process Wetted Parts(a) Foxboro Part Number
Process Process
Line Connection Non-
Connection and Ball Ball Purgeable purgeable
(in) MPa psi °C °F Housing Seat Valve O-Ring Housing Housing
1 1/2 NPT 1.0 145 20 70 316 ss ptfe Glass- Viton BS805JP BS805JN
0.4 55 65 150 filled poly- (b) (c)
0.07 10 88 190 propylene
1 1/2 NPT 1 145 60 140 Titanium ptfe Kynar Viton BS805JQ N/A
0.6 85 100 212 (d)
0.4 60 120 250
(a)Refer to Foxboro for other materials.
(b)Previously specified as Part Number 0051380 plus 0051362 (shaft assembly).
(c)Previously specified as Part Number 0051361 plus 0051362 (shaft assembly).
(d)Previously specified as Part Number 0051360 plus 0051365 (shaft assembly).
PSS 6-1C2 A
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ACCESSORIES (Cont.)
Flow Chambers
Flow chambers (Figure 3) are a convenient way of Table 2. Flow Chamber Specifications
mounting sensors in a system where a sample is
Rated Pressure at
provided by small diameter sample line. The flow
Rated Temperature
chamber connects to the system via user supplied Foxboro
1/4 NPT fittings, and provides a chamber for the Material MPa psi °C °F Part
sample. A flow chamber with sensor in place, will PVC 0.4 60 50 120 0051181
pass up to 125 mL/s (2 gpm) of sample (see Table 2 0.2 30 60 140
for specifications). 316 ss 1.4 200 125 260 0051179
Figure 4. Bushing
(Foxboro Part 0051185 Illustrated)
Plugs
A plug (Figure 5) replaces a sensor to provide Table 4. Plug Specifications
system sealing (if a sensor is removed from the
process for maintenance, cleaning, etc). The plug is Rated Pressure at
compatible with any Foxboro Twist-Lock receptacle Rated Temperature
Foxboro
(e.g., flow chamber, bushing, tee, etc.) (see Table 4 Material MPa psi °C °F Part
for specifications). PVC 0.4 60 50 120 0051187
0.2 30 60 140
316 ss 1.4 200 125 260 0051188
ACCESSORIES (Cont.)
Figure 6. Tee
(Foxboro Part 0051184 Illustrated)
INPUT
4
5
6
7
INPUT
Patch Cord
Patch cords provide connections between sensors
with optional selections –5 and –7 and either an
Figure 7. Submersion Adaptor
analyzer, transmitter, or junction box. Specify
(Foxboro Part BS805PU)
Foxboro Part BS806NP for the standard 3 m (10 ft)
length or BS806NQ for the nonstandard lengths up
to 30 m (100 ft).
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ACCESSORIES (Cont.)
BLUE
Extension Cable
The extension cable (see Figure 11) is a PVC
jacketed multi-conductor cable, unterminated, that
GRAY PVC
provides intra-system connections.
MYLAR WHITE
DRAIN/CLEAR
BLACK
BLACK PVC
RED
MYLAR
BLUE DRAIN/CLEAR
BROWN
Buffers
Table 6. Buffers
Buffers (see Table 6) are available in dry powder
and solution. Dry powder makes 0.47 L (16 fl oz) of Type Foxboro
buffer when mixed with distilled water. Buffer Description Part
Solution Buffer 4.00 pH, 0.47 L (16 fl oz) Q0104KC
Buffer 7.00 pH, 0.47 L (16 fl oz) Q0104KB
Buffer 10.0 pH, 0.47 L (16 fl oz) Q0104KA
Dry 4.00 pH 1600-100
Powder 7.00 pH 1600-101
10.0 pH 1600-102
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ACCESSORIES (Cont.)
Electrode and Reference Kits The reference kit contains replaceable reference
The electrode and reference kits (see Table 7) junction, a 50 ml bottle of saturated potassium
provide all the parts necessary for fast and easy field chloride (KCl) filling solution, replacement locking
installation. keeper and stud, electrode removal tool, and
complete instructions.
The electrode kit contains a measuring electrode,
replacement locking keeper and stud, electrode
removal tool, and complete instructions.
Table 7. Electrode and Reference Kits
Multiple Electrode and Reference Kits The multiple reference electrode kits (see Table 8)
The multiple measuring electrode kits (see Table 8) contain ten replacement reference junctions,
contain ten measuring electrodes, one replacement 500 mL of saturated potassium chloride (KCl) filling
locking keeper and stud, an electrode removal tool, solution, one replacement locking keeper and stud,
and complete instructions. an electrode removal tool, and complete
instructions.
DIMENSIONS–NOMINAL
mm
in
871PH SENSOR
38
1.5
SENSOR CABLE
(SEE NOTE)
191
7.5
246
9.7
44
51 56
1.7
2.0 2.2
NOTE:
THE STANDARD CABLE LENGTH IS 6 m (20 ft).
THE CABLE IS TERMINATED WITH NO. 6 SPADE
TERMINALS, OR STRIPPED AND TINNED. OPTIONAL
CABLE LENGTHS ARE AVAILABLE.
PSS 6-1C2 A
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DIMENSIONS–NOMINAL (Cont.)
mm
in
SENSOR ACCESSORIES
BUSHINGS
SENSOR
SENSOR
SENSOR
BUSHING
64 21
51
2.5 51 0.8
2.0
2.0
28 BUSHING
BUSHING 1.1
*
51
14 2.0
32
0.6
1.3
1 1/4 NPT (PVC) 1 1/4 NPT (316 ss) 1 1/2 NPT (316 ss)
FOXBORO PART 0051183 FOXBORO PART 0051185 FOXBORO PART 0051186
SENSOR
SENSOR SENSOR
1/4 NPT
51
2.0
TEE
SLEEVE
51
OUTLET 2.0
51
2.0
78
3 20
0.8
INLET FLOW
8 94
CHAMBER
0.3 3.7
1/4 NPT
PVC PVC DN 25 OR 1 in (PVC)
FOXBORO PART 0051189 FOXBORO PART 0051181 FOXBORO PART 0051184
316 ss
FOXBORO PART 0051179
DIMENSIONS–NOMINAL (Cont.)
mm
in
660 77 25
26 3 1
812 86
32 3.4 25
1
REFERENCE DOCUMENTS
PSS 6-1B1 B 870ITPH Intelligent pH/ORP Electrochemical Transmitters
PSS 6-1C1 A 870PH Analog pH/ORP Electrochemical Transmitters
PSS 6-1C1 E 873 Series Electrochemical Analyzers
PSS 6-1A2 C Electrode Cleaning System (ECS)
ORDERING INSTRUCTIONS
1. Model Number.
2. Cable length, if nonstandard.
3. Mounting hardware, if required.
4. Cable and junction box, or patch cord, if required.
5. Accessories, if required.
6. Customer Tag Data.