Current Recycling Regulations and Technologies For The Typical Plastic Components of End-Of-Life Passenger Vehicles: A Meaningful Lesson For China
Current Recycling Regulations and Technologies For The Typical Plastic Components of End-Of-Life Passenger Vehicles: A Meaningful Lesson For China
Current Recycling Regulations and Technologies For The Typical Plastic Components of End-Of-Life Passenger Vehicles: A Meaningful Lesson For China
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REVIEW
Received: 6 January 2013 / Accepted: 17 July 2013 / Published online: 16 August 2013
Ó Springer Japan 2013
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188 J Mater Cycles Waste Manag (2014) 16:187–200
vehicle include the bumper, grilles, lights, instrument panel China are deliberated, at the same time, some constructive
(including the sub-dashboard), seats, inner door panels, ideas and suggestions for the industry are provided.
roof, glove compartment, fuel tank and so on.
As the increase in the number of end-of-life vehicles
(ELVs) occurs, automotive plastic recycling has become Importance of automotive plastic recycling
one of the most important issues in the world today. from the viewpoint of law
Studying automotive plastic recycling technology is sig-
nificant to energy conservation and to the promotion of the After several years of automotive industry development,
sustainable development in the Chinese automotive the United States (US), European Union (EU), Japan,
industry [6, 7]. In the following sections, automotive Korea, and China—top countries in automotive production
plastics recycling-related rules and regulations about and consumption—have been fully aware that the disposal
developed countries and China are the first ones to be of scrapped vehicles cannot be ignored, and that recycling
discussed. Then, the recycling technologies for typical must be enforced. Therefore, these countries have gradu-
plastic components of end-of-life passenger vehicles are ally enacted relevant laws and regulations on dealing with
analyzed comprehensively according to the part types. abandoned vehicles and have established a number of
Based on the results of analysis, the problems and future requirements for vehicle recycling.
development for the ELVs plastic recycling industry in The EU proclaimed an act for ELV recycling numbered
2000/53/EC on September 18, 2000. This act was amended
in 2002, 2005, 2008 and 2010. The act had a number of
18 objectives for scrapped vehicle recycling, estimating that
Output and sales/(million vehicles)
ABS, 8.0%
POM, 1.8%
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J Mater Cycles Waste Manag (2014) 16:187–200 189
(obtained through the removal of metal, plastics, and other Automotive Recycling’’ was enacted into law in 2001. This
useful substances after grinding) recycling rate should have law outlined a 95 % ELV recovery target for 2015 [24]. In
increased to 30 % in 2005, 50 % in 2010 (actual recycling the United States today, more than 95% of vehicles are
rate in 2010 is 70.5 % [14]), and must exceed 70 % after recycled in a process that is market-driven rather than
2015 [15]. government-mandated. Of end-of-life vehicles (ELVs),
The Korean government promulgated the ‘‘Act for more than 75% of material, by weight, is recycled [25].
Resource Recycling of Electrical/Electronic Products and It can be seen that most countries have very high ELV
Automobiles’’ on April 27, 2007, which was officially recovery requirements from the above mentioned regula-
implemented on January 1, 2008 [16]. This legislation tions. The US, EU, Japan and Korea have set the ELV
aimed to improve the ELV recycling rate to 85 % in 2008, recycling rate to be 95 % by 2015, and that in China should
and to more than 95 % by January 1, 2015 [17, 18]. More increase to 95 % by 2017. However, automotive plastic
than 85 % of the vehicle is recycled in Hyundai [19]. components account for 10–15 % of the whole vehicle
Moreover, the new law indicated that all related industries weight. In order to reach the recycling rates in the future,
must comply with its requirements. every country must devote much more energy to automotive
China promulgated the ‘‘Act for Recycling Technology plastic recycling, and develop more advanced technologies
of Automotive Products’’ on February 6, 2006. This law for ELV plastic recycling. Therefore, enhancing the effec-
targets three phases in China’s ELV recycling [20, 21]. The tiveness of ELV plastic recycling to meet the requirements
first stage requires that all domestic and imported vehicles of these regulations and to promote the development of the
in the M21 and M3 and in the N2 and N3 categories must automotive industry is urgently necessary [26, 27].
achieve a recycling rate of approximately 85 % by 2010
with a material re-utilization rate of\80 % [22]. Similarly,
the recycling rate for all domestic and imported M1 and Current local and international status of the passenger
N12 vehicles should increase to 80 %, with a material vehicles plastic recycling
recovery rate of \75 % (Up till the present moment, the
recycling rates have not been reached).The second stage The environmentally friendly and financially feasible
requires that the recovery rate for all domestic and methods used in the automotive plastic recycling industry
imported cars should increase to 90 % by 2012, with a are usually reuse, remanufacturing, physical recycling, and
material re-utilization rate of \80 %. The third stage chemical recycling. Reuse refers to the direct installation of
requires that the recovery rate for all domestic and a number of recycling components into a new vehicle. This
imported vehicles should increase to 95 % by 2017, with a recycling method is considered the most environmentally
material re-utilization rate that must not be \85 %. friendly among the four approaches. Plastic part remanu-
The US has no national rule for ELVs recycling, but the facturing is also an environmentally friendly recycling
related laws on the joint and multiple liability of production, method wherein recyclable plastic parts are remanufac-
along with a sound environmental regulation system, tured by adopting some plastic manufacturing methods,
strictly limited waste landfill activities and minimized the such as repairing and mending rather than destroying the
environmental contamination attributable to ELVs. As early parts. This method can not only reduce resource waste, but
as 1991, three large American automobile firms—General also maintain or restore the appearance and performance of
Motors, Ford, Daimler Chrysler—have set up a vehicle products. If an automotive plastic part is made of a single
recycling alliance (VRP) aiming to regulate the ELV plastic component with no paint on its surface, it can be
recycling process, to establish a joint venture for research recycled using the physical method. Chemical recycling
on ELV recycling technology, and to share technologies in a refers to the breaking down of waste plastics into mono-
non-competitive field [23]. With the leadership of these mers through chemical decomposition. These monomers
large companies, the US ‘‘Guidelines for Future are then used as raw materials for polymer synthesis. This
method is particularly suitable for mixed plastics. How-
1
ever, this approach requires an excessive amount of energy
Category M: Motor vehicles with at least four wheels designed and
during the decomposition process. The energy recovery
constructed for the carriage of passengers. M1 is comprised by no
more than eight seats in addition to the driver’s seat, M2 and M3 are method utilizes combustion or other processes to recover
comprised by more than eight seats in addition to the driver’s seat. energy and is considered the last acceptable method for
M2 has a maximum mass not exceeding 5 tons and M3 is exceeding 5 automotive plastic recycling [28, 29]. The often-used and
tons.
2
basic automotive plastic recycling methods include melt
Category N: Motor vehicles with at least four wheels designed and
processing, direct forming, dissolve recovery, modification,
constructed for the carriage of goods. N1 has a maximum mass not
exceeding 3, 5 tons, N2 exceeding 3, 5 tons but not exceeding 12 tons, gasification, chemical depolymerization, oil generation by
and N3 exceeding 12 tons. pyrolysis, catalytic cracking, hydrogenation, etc. [30].
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190 J Mater Cycles Waste Manag (2014) 16:187–200
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J Mater Cycles Waste Manag (2014) 16:187–200 191
principal development aspects in recycling of these typical Aside from chemical methods, foreign automotive
exterior parts. bumper recycling enterprises adopt the physical recovery
method to separate different plastic materials, based on
Bumper Figure 3 shows an ELV bumper dismantled from translucency, density, or solubility. The efficient removal
a scrapped passenger vehicle. As a result of the dismantling of the coatings on bumper surfaces presents a technical
process, the bumper was dismantled. Hence, the dismantled difficulty in the bumper recycling procedure. Numerous
bumper cannot be used on a new car and must be processed foreign institutions are engaged in related research on this
using others recycling methods. Figure 4 shows the bum- issue. The use of a modifier allows the ether linkage in the
per recycling process under general conditions. A large paint film to be stripped from the bumper surface [43].
proportion of the domestic ELV recycling enterprises Plastic recycling firms are attempting to employ a number
recycle bumpers using the melt method. Soaking the of chemicals in the pyrolysis process to alter the material
bumper in a chemical solvent removes the coating on the properties of the bumper so that they can be used in bumper
bumper surface. The obtained polypropylene (PP) or remanufacturing or other industries [44]. In order to
polycarbonates (PC) then undergo a simple or complex remove the coatings, Hyundai Motor Company uses water-
regeneration process, and are utilized to produce compo- jets to generate a strong impact on bumper surfaces [45].
nents that do not require good appearance or performance. After paint removal, the adoption of twin-screw extruder
This method has a low capacity for coating removal, and processing on recycled bumper materials yields new plastic
the resulting waste liquid is extremely harmful to the granules that meet the manufacturing requirements of a
environment. A number of local companies recycle bum- new bumper [46]. Scrapped bumpers are crushed into
pers using the pyrolysis method, in which bumpers are used 0.8 mm thick piles [47], and then a high-speed shot peeling
to refine oil or gas. The scrap materials produced after method is applied to the plastic surface to peel the paint off.
pyrolysis are difficult to handle, and the recycling process In other studies, an apparatus employing the differential
easily produces secondary pollution [42]. roller velocity method is used to remove the coatings
during the ELV bumpers recycling process [48]. The
comparison of different bumper coating removal technol-
ogies is shown in Table 3 [49].
Besides, pyrolysis can be used in the bumper recycling
progress. Pyrolysis refers to a form of treatment that
chemically decomposes organic materials by heat to pro-
duce fuel oil, gas or raw materials for chemicals.
In our current study, a high pressure abrasive water jet is
used to remove paint from scrapped passenger vehicle
bumpers. To use the recycled bumper materials in the new
Fig. 3 Bumper of scrapped passenger vehicle bumper manufacturing process and to achieve the high
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Scrapped pas-
application of recycled radiator grille and lamp materials
senger vehicle depend on whether the films on the grille surface can be
bumper effectively removed and whether the lamp materials can
Remove paint by be separated well.
New bumper high pressure
At present, no special reports on the recycling technol-
abrasive water jet
ogy for radiator grilles and lamps in China have been
published. In addition to direct landfill disposal and
Separate PP incineration, most of the materials are used to produce low-
Bumper recycling Preliminary
and PC by level plastic products or are modified for other areas. For
process crushing
density method
example, PMMA can be added to an acetone
(CH2COCH2) solution after cleaning, drying, and grind-
Separate em- ing. This mixture can also be used as an adhesive for glass,
Fine crushing bedded metal ceramics, stone, and other materials.
parts
A large number of international studies on radiator grille
Cleaning and and lamp recycling problems are being conducted. The
drying difficulty within the radiator grilles recycling process is
how to remove coatings from the grille surface. Foma
Fig. 5 End-of-life passenger vehicle bumper recycling process Engineering Company [50] developed a centrifugal sepa-
ration system for the separation of PMMA and ABS, which
value-added recycling of bumper materials, a preliminary is also capable of yielding fine separated plastics. This
bumper recycling technology has been developed, as system lays a good foundation for high value-added radi-
shown in Fig. 5, and further related experiments are under ator grille and lamp recycling. The mechanical, thermal
study. and chemical properties of ABS products are evaluated
after two types of recycling process; a recycling process
Radiator grilles and lamps Figure 6 shows a photo- involving grinding and extrusion is compared to a chemical
graph of a radiator grille and lamp. An automotive recycling process that uses a solvent [51]. The fluidized bed
radiator grille is made of acrylonitrile butadiene styrene thermal decomposition method can decompose PMMA to
(ABS) and is difficult to recycle because of its complex methyl methacrylate (MMA), increasing the recovery rate
shape and surface coating. The primary ingredients of PMMA up to 90–98 % [52]. After the lamps are crushed
comprising lamps are ABS and polymethylmethacrylate and after the metal ingredients in the crushed materials are
(PMMA). The lamp housing is made of ABS, and the separated, GARAMTECH utilizes the recycled and the
lamp mask is made of PMMA. Moreover, glass and new ABS materials to manufacture new lamp housings
metals are also utilized in lamps. The quality and [53].
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J Mater Cycles Waste Manag (2014) 16:187–200 193
Pure ABS
ABS Air
Drying
(not pure) separation
PMMA
ELVs Cleaning Remove Magnetic Electrostatic
radiator grille and Grinding Flotation
and lamp drying coating separation separation
Pure PMMA
PMMA Air
Drying
Remove Remove (not pure) separation
ferrous nonferrous ABS
metal metal
Fig. 7 End-of-life passenger vehicle radiator grille and lamp recycling process
The authors are working with recycling companies to Significant effort has been made in the study of instru-
conduct related research work on the high value-added ment recycling by scholars from abroad. PP-type dash-
recycling of automotive radiator grilles and lamps. Figure 7 boards are crushed and mixed with an additive comprising
shows the developed preliminary road map for the recycling 70–92 % wax polymer and 8–30 % of an inorganic filler
of radiator grilles and lamps. Experiments on the recycling mixture. The mixture is then melted and milled to produce
procedure have been performed, and the details of the synthetic resin, which is composed of 45–65 % PP,
recovery process will be described in subsequent articles. 10–20 % ethylene rubber, and 20–40 % inorganic filler.
The obtained resin materials are used to produce a new
Interior trim parts dashboard matrix [54]. A recycling technology for a multi-
layer hydrocarbon poly-vinyl dashboard was also devel-
The typical interior parts in a passenger vehicle includes: oped. In this method, the ethylene-propylene copolymer
instrument panel, seat, inner door panel, roof headliner, and and PP are added into the recycling materials during the
the trunk. Their main components, characteristics and remanufacturing process to improve its performance. The
principal aspects under development in recycling typical remanufactured plastics can be used to produce a new
interior trim parts are shown in Table 4. dashboard or similar plastic parts [55].The instrument
panel components and all-polyurethane instrument panels
Instrument panel Most soft dashboards consist of three can be recycled by the glycolysis method (a metabolic
parts: the surface, the buffer layer and the skeleton. Most process that breaks down carbohydrates and sugars through
surfaces are made of polyvinylchloride (PVC), the buffer a series of chemical reactions) [56]. Several design-for-
layers are made of polyurethane (PU) foam by reaction recycling rules(for example, removal of usable parts as
injection molding, and the skeletons are composed of ABS used parts, rebuilding used parts, shredding the remaining
or PC. The automotive dashboard is an important func- hulk and separating steel and other high-value materials,
tional and trim part, as shown in Fig. 8, and the composi- and discarding the residue to an incinerator or landfill) are
tion and shape of a dashboard is extremely complex, presented in the paper and integrated with the cost-benefit
making it difficult to recycle. In China, most dashboards analysis model (obtain the maximum economic benefits in
are recycled through energy recovery and thermal decom- recycling), which can reduce the cost of recycling of
position methods, which are also employed for fuel tanks. dashboards and other plastics [57]. Using a life cycle
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Table 4 Information for typical passenger vehicle interior trim parts recycling
Vehicle Part Materials Weight percentage Recycling developmental highlights
of total vehicle
Dashboard PU, PP, ABS/PVC alloy About 0.5% Separating different plastics
(including sub-dashboard)
Seat PU, PVC About 0.5% Removing external dirt, cutting and sorting
Inner door panel ABS, PP About 0.35 % Crushing and sorting
Roof headliner PP, PU, ABS/PVC About 0.6% Separating different plastics
(Including the rear window trim plate)
Trunk PP, soft PVC, rubber About 0.45 % Separating different plastic, cleaning
(Including luggage compartment
mat and floor mats)
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J Mater Cycles Waste Manag (2014) 16:187–200 195
TPO
PP foam
Float Floating Electrostatic
Floatation
materials material drying separation
Inner PU foam
door Crushing Filtering Flotation
panels
PP
Submerged Magnetic Electrostatic Electrostatic
Remove material drying separation separation separation
fabrics ABS
Interior Remove
PVC
trim parts metallic
materials
ABS/PC
Fig. 10 The recycling route for a scrapped passenger vehicle dashboard and inner door panel
Fig. 11 Seat of scrapped passenger vehicle Fig. 12 Roof headliner of a passenger vehicle
leather. The skeleton is mostly made of thermoplastic that the recovery of waste PU seat has a high economic
reinforced PP materials. Cushioning pads are usually made value.
of soft flexible PU materials. Recycled seat cushioning pad
materials can be used in energy absorbance applications, Roof headliner The roof headliner of the vehicle is an
such as vibration and sound damping, sports ground sur- important part of the vehicle interior, functioning not only
facing, and carpet underlay. The granulated polyester PU as decoration, but is also for heat insulation, noise reduc-
foam and foam/fabric laminates are made into new foam by tion, and comfort and safety enhancement. Figure 12
adding diphenylmethane diisocyanate (MDI) in the gran- shows the roof headliner of a vehicle.
ulation process [60]. Some researchers have presented a The roof headliner is produced by bonding different
novel design for recycling (DFR) strategy-extended pro- composites, such as PU, PP, and ABS/PVC. The roof mate-
ducer responsibility—these were incorporated in a new rials are complicated, so separating the different layers is very
software tool, combining the use of emerging technologies difficult. No specific recycling technology for roof headliner
dedicated to automobile shredder residue recycling, toge- has been proposed locally and abroad. Most roofs are made
ther with a design for dismantling strategies [61]. The into fuel and gas through pyrolysis, similar to other plastic
recovery costs in various recycle stages and the values of materials that are difficult to reuse. In addition, some roof
the finished products are analyzed in the study, showing materials that cannot be recycled are processed by landfill.
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Trunk and mats Most trunks of passenger vehicles are New recycling technologies for fuel tanks have been
mostly made of PP, and their recovery process is relatively recently discovered in foreign countries. In the US, a scrap
simple compared to that of other parts. Cleaned trunks are fuel tank recovery system has been established [62]. The
recycled with other PP materials or are used to refine oil recycled HDPE material was found to have good perfor-
and gas through pyrolysis. mance and can be used for the reproduction of fuel tanks.
Trunk cushions and floor mats are mostly made of rubber The steam explosion method is also used for HDPE fuel
and soft PVC. The recycling methods for rubber are already tank recovery [63]. In this method, the HDPE post-con-
well developed. Cushions and mats are not processed sep- sumer automotive fuel tanks are combined with wood fibers
arately because of the low density and light weight of soft to create a new material suitable as an automotive substrate.
PVC materials, but are rather reused with other refractory The scrap fuel tanks and other plastics are made into
materials through pyrolysis and combustion. hydrocarbons, which can be used as raw material by
numerous industries [64], through thermal decomposition, a
Functional parts series of catalytic reactions, and a distillation process.
BASF uses distillation to remove oil and highly explosive
The typical functional parts in a passenger vehicle include materials from the tank surface. The company adopts the
the fuel tank, water radiator room, some pipes, and so on. method of extending the heating time to prevent plastic
Their main components, characteristics and principal performance degradation [65]. The possibility of mechani-
development aspect for recycling typical functional parts cal recycling of the polyethylene (PE) from post-use auto-
are shown in Table 5. motive fuel tanks is performed by some extrusion tests [66].
Special methods for processing the fuel tank are consid-
Fuel tank The main material of a fuel tank is high-density ered in the crushing process because of the remaining gas-
polyethylene (HDPE). The recycling methods currently oline in the tank. Relevant businesses cooperated with our
used for a scrapped fuel tank are main energy recovery and laboratory to develop a recycling route for HDPE fuel tanks.
thermal decomposition. Figure 13 shows a scrapped pas- Figure 14 shows the initially developed route. The detailed
senger car fuel tank. The energy recovery method refers to research results will be reported in subsequent papers.
the utilization of heat during the incineration process of a
waste fuel tank mixed with coal in cement kilns. Thermal Radiator recycling technology The radiator tank is usu-
decomposition refers to the generation of fuel and gas ally made of glass fiber-reinforced nylon 66 (PA66-GF).
using some processing methods, such as pre-processing, The water radiator room will be disposed by landfill when
thermal cracking, pyrolysis, cooling, and other processes. scrapped because polyamide tanks continuously age with
The recovery efficiency of the two methods is low, and the usage (long-term molecular decline in a working environ-
recycling process produces secondary pollution. ment at 90 °C with cooling fluid).
Fuel tank HDPE About 0.1% Removing oil pollution and metal impurities
Radiator room PA66-GF About 0.1 Removing impurities
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J Mater Cycles Waste Manag (2014) 16:187–200 197
Remove Remove
ferrous nonferrous
metal metal
Fig. 14 The recycling route for a retired passenger vehicle fuel tank
The technology called ‘‘Nylon Composite Recycle’’ was resources and serious environmental problems. There-
developed in 2003, providing a new recycling technology for fore, no matter from the point of view of resource
polyamide using one of the largest automotive applications, consumption or the environmental pollution, the
the radiator, and the tank, which has been previously viewed government agencies should strengthen the supervision
as degraded material because of hydrolysis and was deemed for automotive plastics recycling. In addition, almost
as shredder residue. The process of the technology includes everyone is polluting the environment, but do not want
the collection of post-consumer radiator end tanks that are to clean the earth voluntarily. Too many people only
then reground, dissolved, filtered for glass fiber removal, consider their own economic interests, irrespective of
precipitated, recovered, and compounded into a usable resin environmental protection. Even a considerable number
[67]. According to the research, the physical and mechanical of local leaders only care about their political career
properties of the recycled radiator tanks made of PA66-GF and GDP (gross domestic product) growth and rarely
equivalent to the new PA66-GF can be obtained using this consider how to reduce waste generation, waste
method. Satisfactory physical–mechanical properties of recycling and processing, resulting in China‘s very
recycled glass fiber reinforced polyamide composites are serious environmental problems. If not as soon as
attained after they are dried for 3, 6 and 9 h before repro- possible, something must be done to enhance environ-
cessing [68], because polyamides in equilibrium with the mental education, wake up the Chinese people to
environment contain a small amount of moisture and the environmental awareness, or Chinese people will
probability of hydrolysis occurring in these materials will breathe polluted air and drink contaminated water in
change their properties. The recycling technology for the the near future, resulting in many diseases.
radiator tanks has not been reported in China. 2. The information flow in China’s ELVs recycling
process is blocked, which further complicates the
current situation in the automotive recycling industry.
Especially, the information exchanges in the recycling
Problems and future development for the ELVs plastic
process of automotive plastics are not effective
recycling system in China
enough. For example, according to our research,
Shanghai East China Vehicle Dismantling Co., Ltd.
Europe, the US, Japan, and other developed countries have
has no idea how to identify the different plastic parts
established several comprehensive laws and regulations
because the parts manufacturers are unwilling to share
relating to ELV plastics recycling, and a more effective
their information with them. At the same time,
recovery and reuse system have been established in these
dismantlers don’t know how to deal with the disman-
countries. The relevant laws and regulations on the auto-
tled plastic parts and who will take over the plastics.
motive plastic recycling industry are imperfect in China,
As a result, most plastic parts are landfilled with other
and the comprehensive recovery system has not yet been
wastes. Therefore, the national information exchange
built. The reason for the slow development of China’s ELV
platform for automotive plastic recycling should be
plastics recycling industry is very complicated, and the
established and the sub-centers in each provincial area
fundamental reasons are the following:
should be developed as well. It should have a lot of
1. China’s relevant government agencies have slowly interfaces that connect plastic parts manufacturers,
supervised the ELV plastics recycling, and there is a distributors, scrap car collection points, vehicle dis-
lack of awareness of automotive recycling in the public mantlers and plastic material processing units. Plastic
view. At present, the dismantling enterprises just parts manufacturers upload manufacturing information
recycle some single material parts for selling, such as and dismantling technologies. Distributors upload
bumpers; other ingredient complicated components are sales information. Scrap car collection points upload
usually treated as waste for landfill, such as the collecting information. Dismantlers upload disman-
multilayer dashboard, which brings the waste of tling information, including the collection information
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