Reference 12 - Elecrrochromic Material PDF
Reference 12 - Elecrrochromic Material PDF
Reference 12 - Elecrrochromic Material PDF
114
Keywords:
smart windows, electrochromic, photovoltaic, Si-TFSC, optical performance,
energy saving potential
Indonesian Journal of Energy Vol. 5 No. 1 (2022) 1 – 14 2
1. Introduction
Energy and climate change are problems that concern the world today. Energy demand is expected to
increase as a consequence of population and economic growth so that providing sufficient and
affordable energy is required to increase human welfare and living standards (Türkoğlu & Kardogan,
2017). One of the problems in the energy sector that is currently of concern is energy efficiency,
including in the building. The global building sector is responsible for 30% of final energy consumption
and more than 55% of electricity demand (Corrado, 2018; IEA, 2019). Thus, energy consumption in
the building sector, especially in office and commercial buildings, is the highest when compared to
various other sectors (Gul & Patidar, 2015). The high level of energy consumption in buildings is caused
by the need to improve the quality of living comfort, which includes regulating air temperature,
ventilation and lighting, which results in the highest energy consumption in buildings compared to other
sectors (Ke et al., 2019; Park, 2019).
In recent years, adaptive window innovation has made rapid progress in creating a comfortable life with
the development of smart window technology, both passive and active control (Casini, 2014). This
window is able to control the transmission of solar radiation into the building by turning it transparent
or opaque by adjusting the intensity of sunlight that can enter the building (Balakrishnan & Pattathil,
2019). Among the various types of smart window technologies, such as chromogenic windows
(thermochromic, photochromic, gasochromic and electrochromic), polymer-dispersed liquid crystals
(PDLC) or suspended particle devices (SPD), electrochromic windows are the most interesting
technology that has undergone continuous evolution for many years and are in great demand in the
market (Ke et al., 2019). The electrochromic window is attracting attention because it has dynamic
modulation over a wide spectrum range and can be controlled by the user to meet personal preferences
(Y. Wang et al., 2016). Although these windows can save energy consumption in buildings very
effectively, electrochromic windows actually require energy to operate, because electrochromic
windows operate when given a voltage difference between the conductive layers which causes ions to
move from the accumulated layer to the electrochromic layer to change their optical properties
(Balakrishnan & Pattathil, 2019; Ke et al., 2019). On the other hand, windows have the potential to
obtain solar radiation supply in high intensity. Thus, seeing the potential for greater energy savings
from electrochromic windows, it is interesting to develop the integration of electrochromic and
photovoltaic technology because this development will be able to increase energy efficiency in
buildings, while increasing building performance, and maximizing the potential of solar energy. There
are several literatures that have reported the combination of these two technologies. The results obtained
also tend to be low and actually require high material and fabrication costs (Arifin et al., 2017;
Fernandes & de Zea Bermudez, 2021; Zhang et al., 2019). Therefore, this research was conducted to
obtain a comprehensive design opportunity of the electrochromic-photovoltaic configuration, especially
in terms of material selection which will be used as smart windows to improve building performance
and energy efficiency.
Indonesian Journal of Energy Vol. 5 No. 1 (2022) 1 – 14 3
2. Method
The most widely used transparent conductor or transparent conducting electrode (TCE) coatings in
electrochromic configurations are indium tin oxide (ITO) coated glass or fluorine-doped tin oxide
(FTO) coated glass. This is due to the high transmittance and high electronic conductivity of these two
materials (Balakrishnan & Pattathil, 2019; Ke et al., 2019). Meanwhile, for the electrochromic layer
material, several types of materials can be used, including inorganic metal oxides (WO3, NiO, Nb2O5,
TiO2, V2O5, Ta2O5, MoO3, etc.) (Granqvist, 2014; Ke et al., 2019; Mortimer, 2011), Prussian blue,
conductive polymers (poly-3,4-ethylenedioxythiophene (PEDOT), polyaniline (PANI), polypyrrole,
etc.) (Cai et al., 2017; Ke et al., 2019), viologens and transition metal coordination complexes (Ke et
al., 2019; Mortimer, 2011). While in the ion storage layer, NiO, CeO2 and IrO2 materials are often used
(Choi et al., 2018; Mortimer, 2011).
As a window technology, it is important to review the optical and thermal parameters. In some
electrochromic windows, the optical and thermal parameters are represented by VT/VLT (Visible
Transmittance/Visible Light Transmittance), UV Transmittance, SHGC (Solar Heat Gain Coefficient)
Indonesian Journal of Energy Vol. 5 No. 1 (2022) 1 – 14 4
and UV Transmittance. In general, the characteristics of the electrochromic window are shown in Table
1.
The characteristics of the electrochromic window not only refer to two conditions: a clear state and a
dark state, but the state can change continuously depending on the electrical input in a certain gradient.
This is one of the characteristics of the electrochromic window that makes it superior to other smart
windows, such as PDLC and SPD which only have two states without gradients, or compared to other
chromogenic (photochromic and thermochromic) windows which are passive and cannot be controlled.
3.2 Photovoltaic Technology: Semi-Transparent Thin Film Silicon Solar Cell (Si-TFSC)
As an energy conversion element, solar cells are elements that convert solar energy into electricity. In
terms of structure, a solar cell is a connecting device obtained by electronically placing two different
materials together with a thin electronic barrier between them to separate the charges (Chopra et al.,
2004). In this structural arrangement, when a photon with sufficient energy strikes a p-type and n-type
junction, an electron is expelled by obtaining energy from the striking photon and moves from one layer
to another creating electrons and holes in a power-generating process (Sharma et al., 2015).
Basically, solar cells can be classified into first generation cells (also called conventional, traditional or
wafer-based cells) which are made of polycrystalline and monocrystalline silicon, second generation
cells (also called thin film solar cells) which include amorphous silicon cells, cadmium telluride (CdTe)
and copper indium gallium selenide (CIGS) and third generation solar cells (often described as
emerging photovoltaics) which include nanocrystalline based solar cells, polymer based solar cells, dye-
sensitized solar cells, perovskite based solar cells and concentrated solar cells (Askari et al., 2015; Salve,
2020; Sharma et al., 2015). Of the other types of thin film solar cells, amorphous silicon (a-Si) is
interesting to discuss because it is the most well-developed thin film technology that has been on the
market for over 15 years (Askari et al., 2015). Besides, amorphous silicon (a-Si) solar cells can be
produced at low processing temperatures, enabling the use of a wide variety of low-cost substrates,
polymers and other flexible substrates (Sharma et al., 2015).
Figure 2. Amorphous silicon solar cell structure configuration (Adapted from Fraas, 2014).
However, the efficiency of these amorphous silicon type solar panels tends to be low at 4–8% partly
due to the Staebler-Wronski effect, which manifests itself in the first hours when the panels are exposed
Indonesian Journal of Energy Vol. 5 No. 1 (2022) 1 – 14 5
to sunlight, and results in a decrease in the energy yield of the amorphous silicon panels (Askari et al.,
2015; Sharma et al., 2015).
The integrated electrochromic-photovoltaic technology system will combine the use of electrochromic
and photovoltaic technology in one smart window system. Basically, this combination requires
photovoltaic which has transparent/semitransparent properties, one of which is dye-sensitized solar cell
(DSSC) and thin film solar cell (TFSC). There is some literature that says that the combination of the
two photovoltaic technologies with electrochromic layers is possible and interesting to make, with
variations of photovoltaic materials and technologies as well as variations of electrochromic coating
materials. The combinations made are quite diverse, as shown in Table 2.
Looking at the various configurations offered by several literatures, the configuration using WO3-based
electrochromics and thin film solar cells is an interesting development, because as a smart window,
optical parameters including transmittance change are preferred considering their main function is to
regulate the optical transmissivity that enters the building. In this case, based on Table 2, the
combination of a-Si:H thin film solar cells and WO3-based electrochromic showed a very good
performance compared to the combination of electrochromic and dye-sensitized solar cells when
viewed from the value of the transmittance change, although in terms of the energy gains obtained,
almost all combinations are still inferior to various photovoltaic technologies which have greater energy
efficiency.
Of the TFSC type itself, so far, only TFSC with a-Si: H material which is silicon-based photovoltaic is
the only material that has been reported to be combined with electrochromic. This is because the success
of the a-Si: H thin film material with its high throughput and large area deposition process for solar
cells enables a wide application of this type of material. Meanwhile, in terms of the electrochromic
coating material itself, several types of materials have been developed in combination which have been
reported in several literatures. If it is seen from a comparison with the same PV material, both using
DSSC and using TFSC, the electrochromic coating material made of tungsten oxide (WO3) is the most
superior compared to other materials, which in the literature found viologen material, PProDot-Et2, or
polyaniline (PANI) added polystyrene sulfonate (PSS). This illustrates that the development of TFSC
with a-Si:H material with electrochromic tungsten oxide (WO3) coating has superior potential compared
to other combinations. However, the combination shown in Table 2 is only limited to certain
electrochromic materials, and in fact there are still many electrochromic materials that have not been
reported to have been combined with photovoltaic, although there are other electrochromic materials
with more potential.
Some electrochromic materials do have their own uniqueness, with different performances for each
material, especially looking at the type of layer electrochromic material which is metal oxide, metal
complex, metal alloy and organic molecules. To provide an overview of the performance of each
electrochromic material, Table 3 is compiled to describe the various types of electrochromic materials
Indonesian Journal of Energy Vol. 5 No. 1 (2022) 1 – 14 6
used, without being combined with photovoltaic, thus bridging the search for other electrochromic
materials with more potential for this combination.
PProDOTEt2
75.0% 580 nm 20 (Cl et al., 2002)
with 0.1M TBAP/ACN
PANI-PSS//PEDOT-PSS (Lm et al.,
40.0% 630 nm 15000
with PEO-PC-LiClO4 2006)
PDPN (Soyleyici,
60.0% 900 nm 50
with 0.05M LiClO4 ACN 2019)
Various electrochromic materials and electrolytes work very varied. Various electrochromic materials
reported in the literature have varying values of transmittance change, which represents the ability to
change the optical transmissivity of each material. Referring to Table 3, the electrochromic material
made from tungsten oxide (WO3) still has the best performance so far, the only electrochromic material
that achieves a transmittance change above 85%, even though this material is actually the most
frequently used material in electrochromic studies (Rai et al., 2020). In addition, the coloration
efficiency of WO3 material is also not the best compared to other technologies (Buch et al., 2016).
Considering the comparison to the literature studies conducted previously, a combination design of
electrochromic and photovoltaic technologies was developed. In principle, this configuration simply
superimposes a photovoltaic layer and an electrochromic layer on a transparent substrate such as glass
or polyethylene terephthalate (PET). This system configuration will use semi-transparent silicon thin
film solar cells (Si-TFSC) by adding an electrochromic layer in the form of an electrochromic solution
placed between a transparent non-conductive substrate and a Si-TFSC semitransparent substrate. The
use of the electrochromic component in the solution form has the advantage of a simpler structure and
the structure is formed by a top transparent conductive layer and a bottom transparent conductive layer,
which are bonded by a polymer adhesive in the direction facing the electrode layer, and the
electrochromic solution is placed between the top and bottom of the bottom transparent conductive
layer (Huang et al., 2012; Liu et al., 2020). The system configuration is structured as shown in Figure
3.
(a) (b)
Figure 3. Configuration design of the thin layer electrochromic-photovoltaic system (a) and Schematic
perspective view of the solution type electrochromic-photovoltaic device (b).
As shown in Figure 3 (a), the design of this integrated technology is arranged in the form of a thin
stacked film attached to a transparent glass substrate or PET (polyethylene terephthalate) which later
becomes the media for the smart window. The use of this transparent substrate is similar to the use of
glass in ordinary electrochromic windows pasted on glass or on PET if you want to make a flexible
substrate (Ji et al., 2015; Ke et al., 2019; Qu et al., 2015). In this configuration, since both the
electrochromic and photovoltaic substrates require an anode and a cathode, the functional parts of the
anode and cathode using the transparent conductive oxide (TCO) material of this system can be
Indonesian Journal of Energy Vol. 5 No. 1 (2022) 1 – 14 8
combined, overlapping the anode and cathode of the Si-TFSC photovoltaic. Therefore, the requirement
for anode-cathode in an electrochromic configuration can be cut off leaving a portion of the
electrochromic solution in the form of a gel (Huang et al., 2012), as shown in Figure 3 (b).
In the proposed configuration, the performance of electrochromic technology still uses the principle of
reduction and oxidation reactions (redox). This redox reaction occurs because it is induced by
photopotential differences due to sunlight entering the Si-TFSC photovoltaic device. This redox
reaction occurs because it is triggered by a current generated by photovoltaics and converted into ionic
currents in an electrochromic solution (Huang et al., 2012). Together with the occurrence of this redox
reaction, the window will change its coloring state from clear state to dark state, which means the
window is on. In other words, when a smart window is exposed to high intensity sunlight, the
photovoltaic layer will generate an electronic current and simultaneously trigger the electrochromic
layer to change its optical state from clear to opaque. Conversely, if no sunlight enters the photovoltaic
device in this configuration, then there is no production of electron holes in the semiconductor layer of
the photovoltaic. The absence of photo-potentials in this condition results in the absence of ionic
currents in the electrochromic solution so that the redox reaction does not occur. Thus, in the absence
of a redox reaction, the electrochromic component does not change its color state. In this condition, the
optical state of the window will be in clear state or in off condition. The working scheme on this device
is shown in Figure 4.
In this arrangement, the amorphous photovoltaic layers of the silicon are arranged planar so that the
electrochromic gel solution in the center is also planar. The hope is that, with this planar arrangement,
the window opacity will be uniform for the entire window area (Huang et al., 2012; Lee & Di
Bartolomeo, 2002). Further, in a larger design, to deal with the problem of voltage decrease in the TCO
layer (as anode and cathode) which reduces charging currents and window staining, adding metal bus-
bars on the window edges and installing each panel column with a cell strip connector in series will
reduce the loss of resistive energy at the electrodes (Gao et al., 1999). So, the electrochromic-
photovoltaic integrated technology design on a larger scale, such as in office buildings, apartments, can
still be an option.
One of the parameters to assess the performance of this electrochromic-photovoltaic integrated device
is through its optical parameters. This is because the main function of the smart window is to provide
the ability to adjust the optical layer of the window according to its needs to create a comfortable
occupancy in it. Therefore, at least two optical states of the smart window, namely when it is opaqued
and when it is cleared (Y. Wang et al., 2016; Zakirullin & Zakirullin, 2020), it is important to check
whether the smart window is sufficiently opaque in its opaque state and whether the smart window is
sufficiently clear in its clear state, especially with the addition of a photovoltaic layer that is not
completely transparent.
In this case, the optical contrast and the spectral response by the electrochromic solution can be
illustrated in terms of a graph of the light transmissivity versus time. Referring to Huang et al. (2012),
when a device with heptyl viologen and TMPD (N, N ′, N, N′-tetramethyl-p-phenylenediamine) solution
is illuminated by a solar simulator under 100 mW/cm2 irradiation, the screen darkens to the lowest
Indonesian Journal of Energy Vol. 5 No. 1 (2022) 1 – 14 9
transmission state in 200 seconds, corresponding to a transmission change (ΔT%) of about 70% at 590
nm as shown in Figure 5.
The window model with the electrochromic-photovoltaic technology developed by Huang et al. (2012)
show an optical performance that is not inferior to conventional electrochromic windows, although the
presence of photovoltaic components embedded together in this system to some extent affects
electrochromic performance. The change in transmissivity (ΔT%) which reaches 70% in this model
with heptyl viologen and TMPD can still be increased by replacing more sophisticated electrochromic
materials, one of which is by using a tungsten oxide (WO3) nanostructured material in its configuration
which has a higher transmittance change, compared to various other electrochromic materials (Buch et
al., 2016; Khanapuram et al., 2016; Rai et al., 2020).
Electrochromic technology as one of the smart window technologies has an energy-saving feature with
the presence of an outside heat prevention scheme. Windows with electrochromic technology have the
potential to reduce primary energy consumption by 39.5% compared to conventional glass (Cannavale
et al., 2020) with a 60% reduction in lighting requirements and a 25% reduction in HVAC load
(Rajendran & Charde, 2018). However, conventional electrochromic windows require an external
power supply. The minimum amount of power needed by the system to change different staining states
(1–2.5 Wp/m2) (Casini, 2014). So, the total net energy consumption is the difference between the energy
saved and the power required to activate the electrochromic window. Whereas on the other hand, the
use of photovoltaic windows can also help energize the building. The study reported the efficiency of
TFSC photovoltaic technology of about 7.8% for 6 µm nanocrystalline films and 8.4% for 12 µm thick
nanocrystalline films, with an average transmission range of 20–23% at 400–700 nm wavelengths
(Husain et al., 2018). How much of the energy saving potential of buildings with electrochromic
windows and the potential for energy production by photovoltaic layers is highly dependent on various
environmental and building conditions (Nageib et al., 2020).
Given the large potential savings from the two technologies used in the proposed system, it is hoped
that the combination of electrochromic and photovoltaic technologies can generate significant energy
saving opportunities. Referring to Deb et al. (2001), using a tandem combination of monolithic
photovoltaic with electrochromic in nine layers, it was found that 1 kWp of photovoltaic power can
remove about 3 Wp of heat from the building envelope through electrochromic performance, while the
same 1 kWp of photovoltaic is used for activates an electrochromic-photovoltaic smart window that can
reverse 110 kWp. Given the more advanced development of electrochromic and photovoltaic
technologies over the last decade, energy production through photovoltaic layers should be higher than
this, and electrochromic energy consumption can be further saved (Tällberg et al., 2019; Tavares et al.,
2014).
Indonesian Journal of Energy Vol. 5 No. 1 (2022) 1 – 14 10
6. Optimization Strategy
As one of the components in a building, this adaptive smart window can be optimized to obtain optimal
energy saving potential and maximum living comfort. To improve performance, automation or remote-
control systems can be implanted to provide comfortable living, ease of use, and maximum energy
benefits. In its implementation, adaptive smart windows can be integrated with other smart technologies
in buildings to automatically control the performance of each of its components in one smart home
framework. One application of the control system to this electrochromic-photovoltaic integrated device
is shown in the block diagram in Figure 6.
In this scheme, the control device can be arranged based on a control algorithm according to
occupational sensor readings that detect the presence of humans in the room, as well as sensors for
interior and exterior parameters of the room, such as sensors for light intensity, temperature, humidity
or other parameters that are considered applicable. This control mechanism can be arranged through
automatic control or through user control which is displayed through the control device, including one
through the control of the interface on the user’s gadget. Thus, even though the solar intensity is high
and there is a current emerging from the photovoltaic that should be electrochromic turning into an
opaque state, the occupancy can set the electrochromic condition to remain in clear state if needed, or
if the sensor reads the need for clear state conditions as well.
With the addition of automatic control based on readings of environmental conditions by sensors, the
performance of the integrated electrochromic-photovoltaic technology is also expected to increase. This
performance increase can be obtained through an increase in optical, thermal performance and energy
benefits. In practice, the optical and thermal performance, and in particular the energy benefits obtained,
are highly dependent on the environmental conditions in which this adaptive window is used (Ghosh &
Norton, 2018; Nageib et al., 2020).
7. Conclusions
A design that integrates electrochromic and photovoltaic devices has been developed by combining an
electrochromic solution with a tungsten oxide (WO3) material that is disposed of between a transparent
non-conductive substrate and a semi-transparent Si-TFSC substrate. The performance of this device is
affected by the redox reaction of the electrochromic solution which is triggered by electricity generated
by photovoltaics. The combination of the two technologies does not reduce the optical performance of
the electrochromic coating but still results in a large change in transmissivity. In its application in
buildings, to improve device performance, control systems can be applied by adjusting environmental
conditions according to sensor system readings to get better device performance.
Indonesian Journal of Energy Vol. 5 No. 1 (2022) 1 – 14 11
8. Acknowledgments
This research did not receive any specific grant from funding agencies in the public, commercial or not-
for-profit sectors.
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