F.R. Home Work Problem

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University of technology

Petroleum tecgnology department

Supervised by:
Dr. Ghazwan Nouri

Submitted by:
GE 12
Ali Hammed Zighayier
Rasool Sabah Jumah
Ali Hussein Hadi
Mortada Hassoun Abdel Nabi
Sora Ghazi Naji
Saif faisl Ali
Group GE 6

Q1/ Calculate the vapour pressure of normal decane at 355 K, using:


a. The cox chart
b. The Lee-Kesler equation
c. A linear relation between the logarithm of vapour pressure and inverse
of temperature connecting the normal boiling point and the critical point

Q2/A 1000 cu ft tank contains 85 STB of crude and 20,000 SCF of gas, all
at 120°F. When equilibrium is established, (i.e., when as much gas has
dissolved in the oil as will), the pressure in the tank is 500 psia. If the
solubility of the gas in the crude is 0.25 SCF/STB/psi and the deviation
factor for the gas at 500 psia and 120°F is 0.90, find the liquid formation
volume factor at 500 psia and 120°F.

Q3/A well produces 45.3 STB of condensate and 742 M SCF of sales gas
daily. The condensate has a molecular weight of 121.2 and a gravity of
52.0°API at 60°F. (a) What is the gas-oil ratio on a dry gas basis? (b) What
is the liquid content expressed in barrels per million standard cubic feet on
a dry gas basis? (c) What is the liquid content expressed in GPM on a dry
gas basis? (d) Repeat parts (a), (b), and (c) expressing the figures on a wet,
or gross, gas basis.

Q4/Calculate the volume 1 lb-mole of ideal gas will occupy at:


(a) 14.7 psia and 60°F
(b) 14.7 psia and 32°F
(c) 14.7 plus 10 oz and 80°F
(d) 15.025 psia and 60°F

Reference

B. C. CRAFT and M. F. HAWKINS


Q1/Calculate the vapour pressure of normal decane at 355 K
using:
a. The cox chart
b. The Lee-Kesler equation
c. A linear relation between the logarithm of vapour pressure and
inverse of temperature connecting the normal boiling point and
the critical point.
Ans/
a-
The cox chart
(𝑻°𝑭 + 𝟒𝟓𝟗. 𝟔𝟕)
𝑻 = 𝟑𝟓𝟓𝑲 , 𝑻𝑲 = → 𝑻°𝑭 = 𝟏𝟕𝟗. 𝟑𝟑 °𝑭
𝟏. 𝟖
Then, according to the cox diagram having the temperature in
Fahrenheit and considering the normal decane line, we read the
steam pressure:

𝟏𝟎−𝟑 𝑴𝒑𝒂 𝑷𝒔 = 𝟒. 𝟐𝟒 × 𝟎. 𝟔𝟏𝟓 𝒑𝒔𝒊𝒂 , 𝑴𝑷𝒂 = 𝟎. 𝟎𝟎𝟔𝟖𝟗𝟓 𝒑𝒔𝒊𝒂 = 𝑷𝒔


b- The Lee-Kesler equation
𝑷𝒔
= 𝒆𝒙𝒑( 𝒇(𝒐) + 𝒇(𝟏) )
𝑷𝒄
𝑷𝒔 = 𝑷𝒄 × 𝒆𝒙𝒑( 𝒇(𝒐) + 𝒇(𝟏) )
𝟔. 𝟎𝟗𝟔𝟒𝟖
𝒇(𝒐) = 𝟓. 𝟗𝟐𝟕𝟏𝟒 − − 𝟏. 𝟐𝟖𝟖𝟔𝟐 𝒍𝒏(𝑻𝒓 ) + 𝟎. 𝟏𝟔𝟗𝟑𝟒(𝑻𝟔𝒓 )
𝑻𝒓
𝟏𝟓. 𝟔𝟖𝟕𝟓
𝒇(𝟏) = 𝟏𝟓. 𝟐𝟓𝟏𝟖 − − 𝟏𝟐𝟑. 𝟒𝟕𝟐 𝒍𝒏(𝑻𝒓 ) + 𝟎. 𝟒𝟑𝟓𝟕𝟕(𝑻𝟔𝒓 )
𝑻𝒓
Then from the attached table (A-1):
𝝎 = 𝟎. 𝟒𝟗𝟐𝟑 , 𝑷𝒄 = 𝟐. 𝟏𝟏𝑴𝒑𝒂 , 𝑻𝒄 = 𝟔𝟏𝟕. 𝟕 𝒌
After this 𝑇𝑟 value of the formula:
𝑻 𝟑𝟓𝟓
𝑻𝒓 = = = 𝟎. 𝟓𝟕𝟒𝟕 𝑲
𝑻𝒄 𝟔𝟏𝟕. 𝟕
𝟔. 𝟎𝟗𝟔𝟒𝟖
𝒇(𝒐) = 𝟓. 𝟗𝟐𝟕𝟏𝟒 − − 𝟏. 𝟐𝟖𝟖𝟔𝟐 𝒍𝒏(𝟎. 𝟓𝟕𝟒𝟕 )
𝟎. 𝟓𝟕𝟒𝟕
+ 𝟎. 𝟏𝟔𝟗𝟑𝟒(𝟎. 𝟓𝟕𝟒𝟕𝟔 ) = −𝟑. 𝟗𝟔𝟎𝟗𝟖
𝟏𝟓. 𝟔𝟖𝟕𝟓
𝒇(𝟏) = 𝟏𝟓. 𝟐𝟓𝟏𝟖 − − 𝟏𝟐𝟑. 𝟒𝟕𝟐 𝒍𝒏(𝟎. 𝟓𝟕𝟒𝟕 )
𝟎. 𝟓𝟕𝟒𝟕
+ 𝟎. 𝟒𝟑𝟓𝟕𝟕(𝟎. 𝟓𝟕𝟒𝟕𝟔 ) = −𝟒. 𝟓𝟔𝟕𝟗𝟓

𝟐. 𝟏𝟏
𝑷𝒄 = = 𝟑𝟎𝟔. 𝟎𝟏𝟗 𝑷𝒔𝒊𝒂
𝟎. 𝟎𝟎𝟔𝟖𝟗𝟓
𝑷𝒔 = 𝟑𝟎𝟔. 𝟎𝟏𝟗 × 𝒆𝒙𝒑{( − 𝟑. 𝟗𝟔𝟎𝟗𝟖 + 𝟎. 𝟒𝟗𝟐𝟑(−𝟒. 𝟓𝟔𝟕𝟗𝟓)}
𝑷𝒔 = 𝟎. 𝟔𝟐𝟐𝟗 𝑷𝒔𝒊𝒂 = 𝟒. 𝟐𝟗𝟒𝟗 × 𝟏𝟎−𝟑 𝑴𝒑𝒂

c-
A linear relation between the logarithm of vapour pressure and inverse of
temperature connecting the normal boiling point and the critical point.
According to the attached table (A-1) we have:
𝑷𝒄 = 𝟐. 𝟏𝟏𝑴𝒑𝒂 , 𝑻𝒄 = 𝟔𝟏𝟕. 𝟕 𝒌 , 𝑻𝒃 = 𝟒𝟒𝟕. 𝟑 𝒌 ,
𝑷𝒃 = 𝟏 𝒂𝒕𝒎 = 𝟎. 𝟏𝟎𝟏𝟑 𝑴𝒑𝒂
Boiling point pressure is usually considered equal to one atmosphere
Then, using the straight-line equation or interpolation at 355 K, we can
obtain the logarithm value of the vapor pressure, and the logarithm value
can be the vapor pressure value.
𝟏 𝟏
𝒍𝒐𝒈(𝑷𝒄 ) → 𝒍𝒐𝒈(𝟐. 𝟏𝟏) = 𝟎. 𝟑𝟐𝟒 , → = 𝟏. 𝟔𝟏𝟖𝟗 × 𝟏𝟎−𝟑
𝑻𝒄 𝟔𝟏𝟕. 𝟕
𝟏 𝟏
𝒍𝒐𝒈(𝑷𝒃 ) → 𝒍𝒐𝒈(𝟎. 𝟏𝟎𝟏𝟑) = −𝟎. 𝟗𝟗𝟒 , → = 𝟐. 𝟐𝟑𝟓𝟔 × 𝟏𝟎−𝟑
𝑻𝒃 𝟒𝟒𝟕. 𝟑
𝑷𝒔 = 𝟎. 𝟖𝟕 𝑷𝒔𝒊𝒂
Q2/A 1000 cu ft tank contain 85 STB of crude and 20,000 SCF of
gas, all at 120 °F. When equilibrium is established, (i.e., when as
much gas has dissolved in the oil as will), the pressure in the tank
is 500 psia. If the solubility of the gas in the crude is 0.25
SCF/STB/psi and the deviation factor for the gas at 500 psia and
120°F is 0.90, find the liquid formation volume factor at 500 psia
and 120°F.
Ans/
𝑺𝑪𝑭
𝑹𝑺 = 𝟎. 𝟐𝟓(𝟓𝟎𝟎) = 𝟏𝟐𝟓
𝑺𝑻𝑩

Solution gas at surface = 85(125) = 10625 SCF

Free gas at surface 2000 - 10625 = 9375 SCF

𝒁 ×𝑻 𝟎. 𝟗 × 𝟓𝟖𝟎 𝒇𝒕𝟑
𝑩𝒈 = 𝟎. 𝟎𝟐𝟖𝟐𝟗 = 𝟎. 𝟎𝟐𝟖𝟐𝟗 × = 𝟎. 𝟎𝟐𝟗𝟓
𝑷 𝟓𝟎𝟎 𝑺𝑪𝑭

Free gas at reservoir condition = 9375(0.0295) = 276.56 ft3

𝐬𝐨𝐥𝐮𝐭𝐢𝐨𝐧 𝐠𝐚𝐬 𝐚𝐭 𝐫𝐞𝐬𝐞𝐫𝐯𝐨𝐢𝐫 𝐜𝐨𝐧𝐝𝐢𝐭𝐢𝐨𝐧 + 𝐨𝐢𝐥 𝐯𝐨𝐥𝐮𝐦𝐞

𝟏𝟎𝟎𝟎 − 𝟐𝟕𝟔. 𝟓𝟔
= = 𝟏𝟐𝟖. 𝟖 𝒃𝒃𝒍
𝟓. 𝟔𝟏𝟓

𝟏𝟐𝟖. 𝟖 𝒃𝒃𝒍
𝑩𝒐 = = 𝟏. 𝟓𝟐𝟓
𝟖𝟓 𝒔𝒕𝒃
Q3/A well produce 45.3 STB of condensate and 742 M SCF of sales
gas daily. The condensate has a molecular weight of 121.2 and a
gravity of 52.0°API at 60°F. (a) What is the gas-oil ratio on a dry
gas basis? (b) What is the liquid content expressed in barrels per
million standard cubic feet on a dry gas basis? (c) What is the
liquid content expressed in GPM on a dry gas basis? (d) Repeat
parts (a), (b), and (c) expressing the figures on a wet, or gross, gas
basis.
Ans/
a-
𝟕𝟒𝟐 𝑴𝒔𝒄𝒇 𝟕𝟒𝟐 × 𝟏𝟎𝟎𝟎 𝒔𝒄𝒇
𝐆𝐎𝐑 = = = 𝟏𝟔𝟑𝟖𝟎
𝟒𝟓. 𝟑 𝒃𝒃𝒍 𝟒𝟓. 𝟑 𝒃𝒃𝒍
b-
𝟒𝟓. 𝟑 𝒃𝒃𝒍 𝒃𝒃𝒍
= 𝟎. 𝟎𝟔𝟏𝟏
𝟕𝟒𝟐 𝑴𝒔𝒄𝒇 𝑴𝒔𝒄𝒇
c-
𝟒𝟓. 𝟑 × 𝟒𝟐
= 𝟐. 𝟓𝟕 𝒈𝒑𝒎
𝟕𝟒𝟐
d-
𝟏𝟒𝟏.𝟓 𝟏𝟒𝟏.𝟓
i- 𝜸𝒐 = = = 𝟎. 𝟕𝟕𝟏𝟏
𝑨𝑷𝑰+𝟏𝟑𝟏.𝟓 𝟓𝟐+𝟏𝟑𝟏.𝟓
𝟏𝟑𝟑𝟎𝟎𝟎 × 𝜸𝒐 𝟏𝟑𝟑𝟎𝟎𝟎 × 𝟎. 𝟕𝟕𝟏𝟏
𝑮𝑬𝒐 = ×𝒏 = × 𝟒𝟓. 𝟑 = 𝟑𝟖. 𝟑𝟑 𝑴𝒔𝒄𝒇
𝑴𝒘𝒐 𝟏𝟐𝟏. 𝟐
𝐆 = 𝟑𝟖. 𝟑𝟑 + 𝟕𝟒𝟐 = 𝟕𝟖𝟎. 𝟑𝟑 𝑴𝒔𝒄𝒇
𝟕𝟖𝟎. 𝟑𝟑 𝑴𝒔𝒄𝒇 𝑴𝒔𝒄𝒇
𝐆𝐎𝐑 = = 𝟏𝟕𝟐𝟐𝟓
𝟒𝟓. 𝟑 𝒃𝒃𝒍 𝒃𝒃𝒍
ii-
𝟒𝟓. 𝟑 𝒃𝒃𝒍 𝒃𝒃𝒍
= 𝟎. 𝟎𝟓𝟖𝟏
𝟕𝟖𝟎. 𝟑𝟑 𝑴𝒔𝒄𝒇 𝑴𝒔𝒄𝒇
iii-
𝟒𝟓. 𝟑 × 𝟒𝟐
= 𝟐. 𝟒𝟑 𝒈𝒑𝒎
𝟕𝟖𝟎. 𝟑𝟑
Q4/Calculate the volume 1 lb-mole of ideal gas will occupy at:
a- 14.7 psia and 60°F
b- 14.7 psia and 32°F
c- 14.7 plus 10 oz and 80°F
d- 15.025 psia and 60°F
Ans/

a- 𝑷𝑽 = 𝒏𝑹𝑻
𝒏𝑹𝑻 𝟏 × 𝟏𝟎. 𝟕𝟑 × (𝟒𝟔𝟎 + 𝟔𝟎)
𝑽= → = 𝟑𝟕𝟗. 𝟔𝒇𝒕𝟑
𝑷 𝟏𝟒. 𝟕

b- 𝑷𝑽 = 𝒏𝑹𝑻
𝒏𝑹𝑻 𝟏 × 𝟏𝟎. 𝟕𝟑 × (𝟒𝟔𝟎 + 𝟑𝟐)
𝑽= → = 𝟑𝟓𝟗. 𝟏𝒇𝒕𝟑
𝑷 𝟏𝟒. 𝟕

c- 𝑷𝑽 = 𝒏𝑹𝑻
𝟏 𝒑𝒔𝒊𝒂
𝑷 = 𝟏𝟒. 𝟕 𝒑𝒔𝒊𝒂 + 𝟏𝟎𝟎𝒁 ( ) = 𝟏𝟓. 𝟑𝟐𝟓 𝒑𝒔𝒊𝒂
𝟏𝟔𝟎 𝒁
𝒏𝑹𝑻 𝟏 × 𝟏𝟎. 𝟕𝟑 × (𝟒𝟔𝟎 + 𝟖𝟎)
𝑽= → = 𝟑𝟕𝟖. 𝟕 𝒇𝒕𝟑
𝑷 𝟏𝟓. 𝟑𝟐𝟓

d- 𝑷𝑽 = 𝒏𝑹𝑻
𝒏𝑹𝑻 𝟏 × 𝟏𝟎. 𝟕𝟑 × (𝟒𝟔𝟎 + 𝟔𝟎)
𝑽= → = 𝟑𝟕𝟏. 𝟒 𝒇𝒕𝟑
𝑷 𝟏𝟓. 𝟎𝟐𝟓

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