Internal assessment resource Chemistry 3.

1B v2 for Achievement Standard 91387

NZQA
PAGE FOR TEACHER USE Approved

Internal Assessment Resource

Chemistry Level 3

This resource supports assessment against:

Achievement Standard 91387

Carry out an investigation in chemistry involving quantitative
analysis

Resource title: How stable is your aspirin?

4 credits
This resource:
 Clarifies the requirements of the standard
 Supports good assessment practice
 Should be subjected to the school’s usual assessment quality assurance
process
 Should be modified to make the context relevant to students in their school
environment and ensure that submitted evidence is authentic

Date version published February 2017 Version 2

by Ministry of Education
To support internal assessment from 2017

Quality assurance status These materials have been quality assured by NZQA.
NZQA Approved number: A-A-02-2017-91387-02-6370

Authenticity of evidence Teachers must manage authenticity for any

assessment from a public source, because students
may have access to the assessment schedule or
student exemplar material.
Using this assessment resource without modification
may mean that students’ work is not authentic. The
teacher may need to change figures, measurements or
data sources or set a different context or topic to be
investigated or a different text to read or perform.

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Internal assessment resource Chemistry 3.1B v2 for Achievement Standard 91387
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Internal Assessment Resource

Achievement Standard Chemistry 91387: Carry out an
investigation in chemistry involving quantitative analysis
Resource reference: Chemistry 3.1B v2
Resource title: How stable is your aspirin?
Credits: 4

Teacher guidelines

The following guidelines are supplied to enable teachers to carry out valid and
consistent assessment using this internal assessment resource.
Teachers need to be very familiar with the outcome being assessed by Achievement
Standard Chemistry 91387. The achievement criteria and the explanatory notes
contain information, definitions, and requirements that are crucial when interpreting
the Standard and assessing students against it.

Context/setting
This activity requires students to investigate the hydrolysis of aspirin to salicylic acid
under different conditions.
Students may plan and carry out the investigation in groups, but each student must
collect data for at least one independent variable. Students may also carry out the
whole investigation individually.
Students keep a logbook, process the group data, and write their report individually.
If temperature is the independent variable, students need to dissolve the aspirin in
water before heating it so that hydrolysis can occur.

Conditions
Please refer to the conditions of assessment for this standard.
Students must be given sufficient time to show their understanding.
Ensure that students follow standard laboratory safety procedures as outlined in
Safety and Science: A Guidance Manual for New Zealand Schools.
Provide students with instructions on how to use the colorimeter.

Resource requirements
 colorimeter (with instructions)
 solid salicylic acid
 95% ethanol
 .0250 mol L-1 Iron (III) nitrate solution.

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Additional information
Further information on assessment and management issues, other practical
investigation examples, and a question and answer archive can be found at
www.chemteach.ac.nz

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Internal Assessment Resource

Achievement Standard Chemistry 91387: Carry out an
investigation in chemistry involving quantitative analysis
Resource reference: Chemistry 3.1B v2
Resource title: How stable is your aspirin?
Credits: 4
Achievement Achievement with Merit Achievement with
Excellence
Carry out an investigation in Carry out an in-depth Carry out a comprehensive
chemistry involving investigation in chemistry investigation in chemistry
quantitative analysis. involving quantitative involving quantitative
analysis. analysis.

Student instructions

Introduction
This activity requires you to investigate the stability of aspirin (acetyl salicylic acid) in
different conditions (such as different pH, temperature, and moisture levels). You can
plan and carry out the investigation as a group, but you need to keep your own
logbook throughout the investigation. You must process the data on your own and
write an individual report for submission.
You will be assessed on the comprehensiveness of your investigation, which
involves:
 keeping a logbook that contains details of the development of the purpose,
procedure, raw data, and calculations
 developing and carrying out a procedure to collect data
 processing the data to reach a conclusion
 discussing the investigation in terms of the procedure used and the reliability of
the data
 reporting your investigation in a written report.
You have two to three weeks to complete this task.

Task
Aspirin (acetyl salicylic acid) breaks down (by hydrolysis) to form salicylic acid. The
amount of salicylic acid can be determined by colorimetric analysis. You are to
conduct an investigation into the stability of acid under different circumstances.
A method used to measure the amount of salicylic acid in solution is given in
Resource A.
In a group define the purpose of your investigation, conduct background research,
and identify how you will ensure safety (for example, safety considerations and how
you will reduce any possible risks). The purpose should include exploring possible
trend or pattern in the quantity of acetyl salicylic.

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Plan your practical work and conduct some trials to refine your method. Each
member of the group should collect and record data for at least one of the
independent variables. Record this information in a logbook. All data should then be
collected together and shared with everyone in the group.
Working individually, process the data and write a report. Your report should be a
maximum of 1,000 words and include the following sections:
 purpose
 description of procedure – this must include a description of how significant
variables are controlled, preparation of samples, and any modifications made to
the method during the course of the investigation
 results
 conclusion
 discussion – an evaluation of the whole investigation that considers:
– an evaluation of the reliability of data by considering the procedure used and
sources of error
– reasons for any modifications made to the original method
– the accuracy and reliability of the data collected
– comments on the significance and validity of the conclusion
– links between the conclusion(s) and chemical principles and/or real life
applications
 a bibliography that acknowledges and identifies sources of information.
Hand in your report along with your logbook containing the raw data you collected
and a summary of all the data collected by the group.

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Resource A
Determination of the amount of aspirin
Taken from “The Synthesis and Analysis of Aspirin”
http://www.p-forster.com/Attachments/Aspirin/Aspirin Synt & Beer-Lambert.pdf
To access this PDF, paste the text into your search engine and select Quick View.
Test the colorimetric absorbance of an aspirin sample
Salicylic acid reacts with acidified iron (III) nitrate to produce a violet complex,
tetraaquosalicylatroiron (III).
You will prepare a set of standard solutions of the violet complex,
tetraaquosalicylatroiron (III). The absorbance of the standard solutions can be
determined using a colorimeter. A standard curve can then be created and used to
determine the amount of salicylic acid in the aspirin tablets.
Prepare a set of salicylic acid standard solutions and a standard curve
1. Measure out about 0.200 g of salicylic acid. Record the precise mass that you
use.
2. Transfer the salicylic acid to a 250 mL beaker and add 10 mL of 95% ethanol.
Swirl the beaker to dissolve the solid.
3. Add 150 mL of distilled water to the beaker. Mix the solution.
4. Transfer the solution from the beaker to a 250 mL volumetric flask and make up
to the mark with distilled water, making sure that you have transferred all the
salicylic acid to the flask. Mix the solution.
5. Calculate the precise concentration of your stock solution and record it in your
logbook.
6. To prepare 100 mL of the violet complex solution, quantitatively transfer 10 mL of
the stock salicylic acid solution you prepared above to a 100 mL volumetric flask.
7. Add 0.0250 mol L-1 Fe (NO3)3 solution to the flask to make precisely 100 mL.
8. Use this solution to prepare a set of standard solutions according to the table
below. Mix these thoroughly.

Standard solution Volume of complex Water (mL)

number solution (mL)
1 10.0 0.0
2 7.5 2.5
3 5.0 5.0
4 2.5 7.5

9. Calculate the precise concentrations of the four standard solutions in the table
above and record them in your logbook.
10. Set up the colorimeter according to the manufacturer’s instructions.
11. Record the absorbances of your set of standard solutions.
12. Prepare a standard curve showing absorbance vs. concentration of salicylic acid
in the standard solutions.

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Determine the concentration of salicylic acid in samples

1. Measure out about 0.200 g of each of your treated aspirin samples (for example,
exposed to different temperatures, pH levels, moisture levels) and transfer them
to 250 mL beakers. Record the precise mass of aspirin that you use for each
sample.
2. Add 10 mL of 95% ethanol to each beaker of aspirin sample. Swirl the mixture to
dissolve the solid.
3. Add 150 mL of distilled water to each beaker. Mix the solutions.
4. Quantitatively transfer the solutions from the beakers to 250 mL volumetric flasks.
Make up to the mark using distilled water. Mix thoroughly.
5. Transfer 5 mL of each of the aspirin solutions from the 250 mL volumetric flasks
to clean, dry 100 mL volumetric flasks. Add 0.025 M Fe (NO3)3 solution to each
flask to make precisely 100 mL. Mix the solutions thoroughly.
6. Measure and record the absorbance of the treated aspirin samples. This must be
done within five minutes.
7. Repeat Steps 5 and 6 twice with new aliquots of the treated aspirin samples.
8. Use your standard curve to determine the concentration of salicylic acid in the
samples.

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Assessment schedule: Chemistry 91387 How stable is your aspirin?

Evidence/Judgements for Achievement Evidence/Judgements for Achievement with Evidence/Judgements for Achievement with
Merit Excellence
The student carries out an investigation in The student carries out an in-depth investigation The student carries out a comprehensive
chemistry involving quantitative analysis. in chemistry involving quantitative analysis. investigation in chemistry involving quantitative
They do this by investigating the stability of acid They do this by investigating the stability of acid analysis.
under certain conditions leading to a conclusion under certain conditions leading to a conclusion They do this by investigating the stability of acid
based on the processed data. that links the processed data to the purpose of the under certain conditions leading to a
They have kept a logbook and produced a report. investigation. comprehensive conclusion
In their investigation the student has: They have kept a logbook and produced a report. They have kept a logbook and produced a report.
 developed a purpose In their investigation the student has: In their investigation the student has:
 explored a possible trend or pattern in the  carried out trials  accurately processed the data and used
quantity of substance in a sample  controlled significant variables appropriate significant figures
 developed and carried out a procedure to  chosen a valid range of values for the  justified the steps used in the procedure in
collect data independent variable relation to the reaction(s) and to the nature of
the samples being analysed
 described the procedure, including preparation  described their method in sufficient detail to
of samples and the analytical technique used enable it to be duplicated  justified how the processed data supports the
conclusion(s)
 chosen a range of values for the independent  standardised standard solution(s)
variable  evaluated the reliability of the data by
 shown the mathematical steps used to process considering the procedure used and sources of
 collected and recorded sufficient data to enable the data error
a conclusion to be reached  accurately processed the data to reach a valid  linked the conclusion(s) to chemical principles
 provided a summary of the collected and conclusion and/or real life applications.
processed data  made a valid conclusion relevant to the .
 made a conclusion based on processed data. purpose of the investigation
 explained how the procedure used contributed
to the collection of quality data.
.

Final grades will be decided using professional judgement based on a holistic examination of the evidence provided against the criteria in the
Achievement Standard.

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