(2022PJM14072022) Major Test - 88 Test Pattern

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�� CENTRE OF EXCELLENCE
CLASSROOM CONTACT PROGRAMME MT-88 JEE(Main)
FULL SYLLABUS
(Academic Session : 2021- 2022) 14-07-2022

JEE(Main+Advance) : TARGET COURSE (SCORE-V)

PHYSICS SECTION-A
5. A Carnot engine take 5000 kcal of heat from a
1. Identify the pair of physical quantities that have
reservoir at 727°C and gives heat to a sink at
same dimensions :
127°C. The work done by the engine is :
(A) velocity gradient and decay constant
(B) wien's constant and Stefan constant (A) 3 × 106 J (B) Zero
(C) angular frequency and angular momentum (C) 12.6 × 106 J (D) 8.4 × 106 J
(D) wave number and Avogadro number

2. The distance between Sun and Earth is R. The

duration of year if the distance between Sun and 6. Two massless springs with spring constants 2 k
Earth becomes 3R will be :
and 2 k, carry 50 g and 100 g masses at their free
ends. These two masses oscillate vertically such
(A) 3 years (B) 3 years
(C) 9 years that their maximum velocities are equal. Then, the
(D) 3 3 years
ratio of their respective amplitudes will be :
(A) 1 : 2 (B) 3 : 2
3. A stone of mass m, tied to a string is being whirled
(C) 3 : 1 (D) 2 : 3
in a vertical circle with a uniform speed. The
tension in the string is :
(A) the same throughout the motion
(B) minimum at the highest position of the circular
7. What will be the most suitable combination of
path
(C) minimum at the lowest position of the circular three resistors A = 2W, B = 4W, C = 6 W so that
path æ 22 ö
(D) minimum when the rope is in the horizontal ç ÷ W is equivalent resistance of combination?
è 3 ø
position
(A) Parallel combination of A and C connected in
series with B.
4. Two identical charged particles each having a mass (B) Parallel combination of A and B connected in
–7
10 g and charge 2.0 × 10 C area placed on a
series with C.
horizontal table with a separation of L between
then such that they stay in limited equilibrium. (C) Series combination of A and C connected in
If the coefficient of friction between each parallel with B.
particle and the table is 0.25, find the value of L.
(D) Series combination of B and C connected in
[Use g = 10 ms–2]
(A) 12 cm (B) 10 cm parallel with A.
(C) 8 cm (D) 5 cm

1
8. The soft-iron is a suitable material for making an 11. Potential energy as a function of r is given by

electromagnet. This is because soft-iron has : A B

U= - , where r is the interatomic distance,
r 10 r 5
(A) low coercively and high retentively
A and B are positive constants. The equilibrium
(B) low coercively and low permeability distance between the two atoms will be :
1 1
(C) high permeability and low retentively æ A ö5 æ B ö5
(A) ç ÷ (B) ç ÷
(D) high permeability and high retentively è Bø èAø
1 1
æ 2A ö 5 æ B ö5
(C) ç ÷ (D) ç ÷
è B ø è 2A ø

9. A proton, a deuteron and an a-particle with same

kinetic energy enter into a uniform magnetic field 12. An object of mass 5 kg is thrown vertically

at right angle to magnetic field. The ratio of the upwards from the ground. The air resistance
produces a constant retarding force of 10 N
radii of their respective circular paths is :
throughout the motion. The ratio of time of
(A) 1: 2 : 2 (B) 1:1: 2 ascent to the time of descent will be equal to :
[Use g = 10 ms–2]
(C) 2 :1:1 (D) 1: 2 :1
(A) 1 : 1 (B) 2: 3

(C) 3: 2 (D) 2 : 3

10. Given below are two statements :

Statement-I : The reactance of an ac circuit is 13. A fly wheel is accelerated uniformly from rest and
rotates through 5 rad in the first second. The angle
zero. It is possible that the circuit contains a
rotated by the fly wheel in the next second, will be :
capacitor and an inductor.
(A) 7.5 rad (B) 15 rad
Statement-II : In ac circuit, the average poser (C) 20 rad (D) 30 rad
delivered by the source never becomes zero.

In the light of the above statements, choose the

14. A 100 g of iron nail is hit by a 1.5 kg hammer
correct answer from the options given below :
striking at a velocity of 60 ms–1. What will be the
(A) Both Statement I and Statement II are true. rise in the temperature of the nail if one fourth of
(B) Both Statement I and Statement II are false. energy of the hammer goes into heating the nail?
[Specific heat capacity of iron = 0.42 Jg–1 °C–1]
(C) Statement I is true but Statement II in false.
(A) 675°C (B) 1600°C
(D) Statement I is false but Statement II is true. (C) 160.7°C (D) 6.75°C

2
15. If the charge on a capacitor is increased by 2 C, the 20. In Bohr's atomic model of hydrogen, let K. P and E
energy stored in it increases by 44%. The original are the kinetic energy, potential energy and total
charge on the capacitor is (in C) :
energy of the electron respectively. Choose the
(A) 10 (B) 20
(C) 30 (D) 40 correct option when the electron undergoes
transitions to a higher level :
(A) All K. P and E increase.
16. A long cylindrical volume contains a uniformly
(B) K decreases. P and E increase.
distributed charge of density r. The radius of
(C) P decreases. K and E increase.
cylindrical volume is R. A charge particle (q)
revolves around the cylinder in a circular path. The (D) K increases. P and E decrease.
kinetic of the particle is :
rqR 2 rqR 2
(A) (B)
4e0 2e 0
SECTION-B
qr 4e R 2
(C) (D) 0 1. A body is projected from the ground at an angle of
4e0 R 2 qr
45° with the horizontal. Its velocity after 2s is
20 ms–1. The maximum height reached by the body
17. An electric bulb is rated as 200 W. What will be during its motion is _______m. (use g = 10ms–2)
the peak magnetic field at 4 m distance produced
by the radiations coming from this bulb? Consider 2. An antenna is placed in a dielectric medium of
this bulb as a point source with 3.5% efficiency. dielectric constant 6.25. If the maximum size of
(A) 1.19 × 10–8 T (B) 1.71 × 10–8 T
that antenna is 5.0 mm. it can radiate a signal of
(C) 0.84 × 10–8 T (D) 3.36 × 10–8 T
minimum frequency of ______GHz.
(Given mr = 1 for dielectric medium)
18. The light of two different frequencies whose
photons have energies 3.8 eV and 1.4 eV
respectively, illuminate a metallic surface whose 3. A potentiometer wire of length 10 m and resistance
work function is 0.6 eV successively. The ratio of 20 W is connected in series with a 25 V battery and
maximum speeds of emitted electrons for the two an external resistance 30 W . A cell of emf E in
frequencies respectivly will be :
secondary circuit is balanced by 250 cm long
(A) 1 : 1 (B) 2 : 1
(C) 4 : 1 (D) 1 : 4 potentiometer wire. The value of E (in volt) is
x
. The value of x is _______.
10
19. Two light beams of intensities in the ratio of 9 : 4
are allowed to interfere. The .ratio of the intensity
of maxima and minima will be :
(A) 2 : 3 (B) 16 : 81
(C) 25 : 169 (D) 25 : 1

3
4. Two travelling waves of equal amplitudes and 8. A circular coil of 1000 turns each with area 1m2 is
equal frequencies move in opposite directions rotated about its vertical diameter at the rate of one
along a string. They interfere to produce a
revolution per second in a uniform horizontal
stationary wave whose equation is given by
2 pt magnetic field of 0.07T. The maximum voltage
y = (10 cos p x sin ) cm
T generation will be _______V.
4
The amplitude of the particle at x = cm will be
3
_______ cm.

Q
9. A monoatomic gas performs a work of where
4

5. In the given circuit- the value of current IL will be Q is the heat supplied to it. The molar heat
______ mA.
capaticy of the gas will be ________R during this
(When RL = lkW)
transformation.
800W
Where R is the gas constant.
IL
5V RL = 1kW
10V

10. In an experment ot verify Newton's law of cooling,

a graph is plotted between, the temperature

6. A sample contains 10–2 kg each of two substances difference (DT) of the water and surroundings and
A and B with half lives 4 s and 8 s respectively.
The ratio of then atomic weights is 1 : 2. The ratio time as shown in figure. The initial temperature of
of the amounts of A and B after 16 s is x/100. water is taken as 80°C. The value of t2 as
the value of x is _______.
mentioned in the graph will be _______.

7. A ray of ligh is incident at an angle of incidence DT(°C)

60° on the glass slab of refractive index 3 . After 60
refraction, the light ray emerges out from other 40
parallel faces and lateral shift between incident ray
20
and emergent ray is 4 3 cm. The thickness of
the glass slab is _______ cm.
0 6 t2 Time (minute)

4
 CHEMISTRY SECTION-A

5. For a first order reaction, the time required for

completion of 90% reaction is 'x' times the half life
1. 120 of an organic compound that contains only
of the reaction. The value of 'x' is
carbon and hydrogen gives 330g of CO2 and 270g
(Given: ln 10 = 2.303 and log 2 = 0.3010)
of water on complete combustion. The percentage
of carbon and hydrogen, respectively are. (A) 1.12 (B) 2.43
(C) 3.32 (D) 33.31
(A) 25 and 75 (B) 40 and 60
(C) 60 and 40 (D) 75 and 25

6. Metals generally melt at very high temperature.

2. The energy of one mole of photons of radiation of Amongst the following, the metal with the highest
wavelength 300 nm is melting point will be
(Given : h = 6.63 × 10–34 Js, NA = 6.02 × 1023mol–1, (A) Hg (B) Ag
c = 3 × 108 ms–1)
(C) Ga (D) Cs
(A) 235 kJ mol–1 (B) 325 kJ mol–1
(C) 399 kJ mol–1 (D) 435 kJ mol–1

7. Which of the following chemical reactions

3. The correct order of bound orders of C2– 2–
2 , N 2 and represents Hall-Heroult Process?
2–
O 2 is, respectively.
(A) Cr2O3 + 2Al  Al2O3 + 2Cr
2  N2  O2
(A) C2– 2  N 2  C2
2– 2–
(B) O2– 2– 2–

(B) 2Al2O3 + 3C  4Al + 3CO2

2  O2  N 2
(C) C2– 2  C2  O2
2– 2–
(D) N2– 2– 2–

(C) FeO + CO  Fe + CO2

(D) 2 Au  CN 2   Zn(s)  2Au(s)  Zn  CN4  2–

–

 aq 

4. At 25°C and 1 atm pressure, the enthalpies of

combustion are as given below:

Substance H2 C(graphite) C2H6(g)

8. In the industrial production of which of the
C H  –286.0 –394.0 –1560.0 following, molecular hydrogen is obtained as a
kJmol –1 byproduct?
The enthalpy of formation of ethane is (A) NaOH (B) NaCl
–1 –1
(A) +54.0 kJ mol (B) –68.0 kJ mol (C)Na metal (D) Na2CO3
(C) –86.0 kJ mol–1 (D) +97.0 kJ mol–1

1
9. Which one of the following compounds is used as 13. Arrange the following carbocations in decreasing
order of stability.
a chemical in certain type of fire extinguishers?
 O O
(A) Baking Soda (B) Soda ash

(C) Washing Soda (D) Caustic Soda

A B C

(A) A > C > B (B) A > B > C

(C) C > B > A (D) C > A > B
10. PCl5 is well known. but NCl5 is not. Because.

(A) nitrogen is less reactive than phosphorous.

(B) nitrogen doesn't have d-orbitals in its valence 14. Given below are two statements.

shell. Statement I : The presence of weaker - bonds

make alkenes less stable than alkanes.
(C) catenation tendency is weaker in nitrogen than
Statement II : The strength of the double bond is
phosphorous. greater than that of carbon-carbon single bond.
In the light of the above statements, choose the
(D) size of phosphorous is larger than nitrogen.
correct answer from the options given below.
(A) Both Statement I and Statement II are correct.
(B) Both Statement I and Statement II are
incorrect.
(C) Statement I is correct but Statement II is
11. Transition metal complex with highest value of
incorrect.
crystal field splitting (0) will be (D) Statement I is incorrect but Statement II is
3 3
correct.
(A) Cr  H 2 O 6  (B)  Mo  H 2 O 6 

3 3
(C)  Fe  H 2 O 6  (D) Os  H 2 O 6 
15. Which of the following reagents/ reactions will
convert 'A' to 'B'?

CH2 CHO

12. Some gases are responsible for heating of H3C

H3C
atmosphere (green house effect). Identify from the (A) (B)
following the gaseous species which does not
(A) PCC oxidation
cause it. (B) Ozonolysis
(A) CH4 (B) O3 (C) BH3,H2O2 / –OH followed by PCC oxidation
(D)HBr, hydrolysis followed by oxidation by
(C) H2O (D)N2
K2Cr2O7 .

2
16. Hex-4-ene-2-ol on treatment with PCC gives 'A'. 20. In the flame test of a mixture of salts, a green
'A' on reaction with sodium hypoiodite gives 'B', flame with blue centre was observed. Which one of
which on further heating with soda lime gives 'C'. the following cations may be present?

The compound 'C' is (A) Cu2+ (B) Sr2+

(C) Ba2+ (D) Ca2+
(A) 2- pentene (B) proponaldehyde

(C) 2-butene (D) 4-methylpent-2-ene

SECTION-B
1. At 300 K, a sample of 3.0 g of gas A occupies the
17. The conversion of propan-1-ol to n-butylamine same volume as 0.2 g of hydrogen at 200 K at the
involves the sequential addition of reagents. The same pressure. The molar mass of gas A is____ g

correct sequential order of reagents is. mol–1 (nearest integer) Assume that the behaviour
of gases as ideal. (Given: The molar mass of
(A)(i) SOCl2 (ii) KCN (iii) H2/Ni,Na(Hg)/C2H5OH
hydrogen (H2) gas is 2.0 g mol–1)
(B) (i) HCl (ii) H2/Ni, Na(Hg)/C2H5OH

(C) (i) SOCl2 (ii) KCN (iii) CH3NH2 2. A company dissolves 'X' amount of CO2 at 298 K
(D) (i) HCl (ii) CH3NH2 in 1 litre of water to prepare soda water
X =____ × 10–3g. (nearest integer)
(Given: partial pressure of CO2 at 298 K= 0.835
bar.
18. Which of the following is not an example of a
Henry's law constant for CO2 at 298 K = 1.67 kbar.
condensation polymer?
Atomic mass of H,C and O is 1, 12 and 6 g mol–1,
(A) Nylon 6,6 (B) Decron respectively)
(C) Buna-N (D) Silicone

3. PCl5 dissociates as
19. The structure shown below is of which
PCl 5  g  PCl3  g   Cl 2  g 
well-known drug molecule?
H 5 moles of PCl5 are placed in a 200 litre vessel
CN which contains 2 moles of N2 and is maintained at
N 600 K. The equilibrium pressure is 2.46 atm. The
N
equilibrium constant Kp for the dissociation of PCl5
N S is_____ × 10–3. (nearest integer)
N NHCH3
H (Given: R = 0.082 L atm K–1 mol–1 : Assume ideal
(A) Ranitidine (B) Seldane gas behaviour)
(C) Cimetidine (D) Codeine

3
4. The resistance of conductivity cell containing 8. 0.2 g of an organic compound was subjected to
0.01 M KCl solution at 298 K is 1750 . If the estimation of nitrogen by Dumas method in which
conductively of 0.01 M KCl solution at 298 K is volume of N2 evolved (at STP) was found to be
0.152 × 10–3 S cm–1, then the cell constant of the 22.400 mL. The percentage of nitrogen in the
conductivity cell is_______× 10–3 cm–1. compound is____.[nearest integer]
(Given: Molar mass of N2 is 28 mol–1. Molar
5. When 200 mL of 0.2 M acetic acid is shaken with volume of N2 at STP : 22.4 L)
0.6 g of wood charcoal, the final concentration of
acetic after adsorption is 0.1 M. The mass of acetic
acid adsorbed per garm of carbon is_____ g. Cl
6. (a) Baryte, (b) Galena, (c) Zinc blende and 9.
(d) Copper pyrites. How many of these minerals
NaOH P
H2O (Major Product)
are sulphide based?
Consider the above reaction. The number of
 electrons present in the product 'P' is____.

7. Manganese (VI) has ability to disproportionate in

acidic solution. The difference in oxidation states
of two ions it forms in acidic solution is______

10. In alanylglycylleucylalanylvaline, the number of

peptide linkages is______.

4
 MATHEMATICS
SECTION-A ì sin ( x - [ x ])
2 3
Let x*y = x + y and (x*1)*1 = x*(1*1). ï , x Î ( -2, -1)
1.
ï x - [x ]
ï
Then a value of 2sin -1 ç
æ x 4 + x2 - 2 ö
ç x 4 + x 2 + 2 ÷÷ is
5. Let ƒ ( x ) = ímax 2x,3 ëé x ûù { } , x <1
è ø ï
ï 1 , otherwise
p p ï
(A) (B) î
4 3
where [t] denotes greatest integer £ t. If m is the
p p number of points where ƒ is not continuous and n
(C) (D)
2 6
is the number of points where ƒ is not
differentiable, then the ordered pair (m, n) is :
(A) (3, 3) (B) (2, 4)
2. The sum of all the real roots of the equation
(C) (2, 3) (D) (3, 4)
(e2x – 4) (6e2x – 5ex + 1) = 0 is
(A) loge3 (B) –loge3
(C) loge6 (D) –loge6
6. The value of the integral
p2
dx
ò is equal to
3. Let the system of linear equations
-p 2 (1 + e )(sin x 6
x + cos6 x )
x + y + az = 2
(A) 2p (B) 0
3x + y + z = 4
x + 2z = 1 p
(C) p (D)
have a unique solution (x*, y*, z*). If (a, x*), (y*, 2

a) and (x*, –y*) are collinear points, then the sum

of absolute values of all possible values of a is :
(A) 4 (B) 3 7. æ ö
n2 n2 n2 n2
lim ç + + + ... + ÷
(C) 2 (D) 1 n ®¥ ç
è (n 2
)
+ 1 ( n + 1) (n 2
)
+ 4 ( n + 2) (n 2
)
+ 9 ( n + 3) (n 2
+n 2
) ( n + n ) ÷ø

is equal to

p 1 p 1
4. Let x, y > 0. If x3y2 = 215, then the least value of
(A) + loge 2 (B) + loge 2
8 4 4 8
3x + 2y is
p 1 p
(A) 30 (B) 32 (C) - loge 2 (D) + loge 2
4 8 8
(C) 36 (D) 40

1
8. A particle is moving in the xy-plane along a curve 12. A random variable X has the following probability
C passing through the point (3, 3). The tangent to distribution :
the curve C at the point P meets the x-axis at Q. If X 0 1 2 3 4
the y-axis bisects the segment PQ, then C is a P(X) k 2k 4k 6k 86
parabola with
The value of P(1 < X < 4 | X £ 2) is equal to :
(A) length of latus rectum 3
4 2
(B) length of latus rectum 6 (A) (B)
7 3
æ4 ö 3 4
(C) focus ç , 0 ÷ (C) (D)
è3 ø 7 5
æ 3ö
(D) focus ç 0, ÷
è 4ø
13. The number of solutions of the equation
æ pö æp ö 1
cos ç x + ÷ cos ç - x ÷ = cos2 2x , x Î [–3p,
è 3ø è3 ø 4
9. Let the maximum area of the triangle that can be
3p] is :
x 2 y2
inscribed in the ellipse 2 + = 1 , a > 2, having (A) 8 (B) 5
a 4
(C) 6 (D) 7
one of its vertices at one end of the major axis of the
ellipse and one of its sides parallel to the y-axis, be
6 3 . Then the eccentricity of the ellispe is :
14. If the shortest distance between the lines
3 1 1 3 x -1 y - 2 z - 3 x -2 y-4 z-5
(A) (B) (C) (D) = = and = =
2 2 2 4 2 3 l 1 4 5
1
is , then the sum of all possible values of l is :
3
(A) 16 (B) 6
10. Let the area of the triangle with vertices A(1, a),
(C) 12 (D) 15
B(a, 0) and C(0, a) be 4 sq. units. If the point
(a, –a), (–a, a) and (a2, b) are collinear, then b is
equal to
15. Let the points on the plane P be equidistant from
(A) 64 (B) –8
the points (–4, 2, 1) and (2, –2, 3). Then the acute
(C) –64 (D) 512
angle between the plane P and the plane 2x + y +
3z = 1 is
p p
(A) (B)
11. The number of distinct real roots of the equation 6 4
x7 – 7x – 2 = 0 is p 5p
(C) (D)
(A) 5 (B) 7 (C) 1 (D) 3 3 12

2
16. Let â and b̂ be two unit vectors such that 19. The slope of normal at any point (x, y), x > 0, y > 0

( aˆ + bˆ ) + 2 ( aˆ ´ bˆ ) = 2 . If q Î (0, p) is the angle on the curve y = y(x) is given by

x2
xy - x 2 y 2 - 1
.

between â and b̂ , then among the statements : If the curve passes through the point (1, 1), then
e.y(e) is equal to
(S1) : 2 aˆ ´ bˆ = aˆ - bˆ
1 - tan (1)
(A) (B) tan(1)
(S2) : The projection of â on â + bˆ is
1
2
( ) 1 + tan (1)

(A) Only (S1) is true

1 + tan (1)
(C) 1 (D)
1 - tan (1)
(B) Only (S2) is true
(C) Both (S1) and (S2) are true
(D) Both (S1) and (S2) are false
20. Let l* be the largest value of l for which the
function fl(x) = 4lx3 – 36lx2 + 36x + 48 is
increasing for all x Î R. Then fl*(1) + fl*(–1) is
p 3p
17. If y = tan (secx – tanx ). < x3 <
–1 3 3
, then equal to :
2 2
(A) 36 (B) 48
(A) xy² + 2y¢ = 0
(C) 64 (D) 72
3p
(B) x 2 y¢¢ - 6y + = 0
2
(C) x2y² – 6y + 3p = 0
SECTION-B
(D) xy² – 4y¢ = 0 1. Let S = {z Î £ : z - 3 £ 1 and z ( 4 + 3i ) + z ( 4 - 3i ) £ 24} .
If a + ib is the point in S which is closest to 4i,
then 25(a + b) is equal to _____.
18. Consider the following statements :
A : Rishi is a judge.
B : Rishi is honest.
C : Rishi is not arrogant.
The negation of the statement "if Rishi is a judge ìæ -1 a ö ü
2. Let S = íç ÷ ; a, b Î {1, 2, 3,...100}ý and let
and he is not arrogant, then he is honest" is îè 0 b ø þ
(A) B ® (A Ú C) Tn = {A Î S : An(n + 1) = I}. Then the number of
(B) (~B) Ù (A Ù C) 100
elements in I Tn is _____.
(C) B ® ((~A) Ú (~C)) n =1

(D) B ® (A Ù C)

3
3. The number of 7-digit numbers which are x2
9. Let the hyperbola H : 2
- y 2 = 1 and the ellipse
multiples of 11 and are formed using all the digits a
1, 2, 3, 4, 5, 7 and 9 is _____. E : 3x2 + 4y2 = 12 be such that the length of latus
rectum of H is equal to the length of latus rectum

4. The sum of all the elements of the set of E. If eH and eE are the eccentricities of H and E

{a Î {1, 2, ..., 100} : HCF (a, 24) = 1} is _____. (

respectively, then the value of 12 e 2H + e 2E ) is

5. The remainder on dividing 1 + 3 + 32 + 33 + ... + 32021 equal to _____.

by 50 is _____.

6. The area (in sq. units) of the region enclosed between 10. Let P1 be a parabola with vertex (3, 2) and focus (4, 4)
2
the parabola y = 2x and the line x + y = 4 is _____. and P2 be its mirror image with respect to the line
7. Let a circle C : (x – h)2 + (y – k)2 = r2, k > 0, touch the x + 2y = 6. Then the directrix of P2 is x + 2y = _____.
x-axis at (1, 0). If the line x + y = 0 intersects the
circle C at P and Q such that the length of the chord
PQ is 2, then the value of h + k + r is equal to _____.
8. In an examination, there are 10 true-false type
questions. Out of 10, a student can guess the answer

3
of 4 questions correctly with probability and the
4
1
remaining 6 questions correctly with probability .
4
If the probability that the student guesses the
answers of exactly 8 questions correctly out of 10 is
27k
, then k is equal to _____.
410