Hudson 20aaa Floor Varnish Topcoat (PH)
Hudson 20aaa Floor Varnish Topcoat (PH)
Hudson 20aaa Floor Varnish Topcoat (PH)
2 Hazards identification
· Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008
GHS02 flame
Repr. 1B H360FD May damage fertility. May damage the unborn child.
GHS07
R60-61: May impair fertility. May cause harm to the unborn child.
Xn; Harmful
34.0
Page 2/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 11.10.2012 Version number 1 Revision: 11.10.2012
(Contd. of page 1)
Xi; Irritant
F; Highly flammable
T Toxic
F Highly flammable
34.0
Page 3/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 11.10.2012 Version number 1 Revision: 11.10.2012
3 Composition/information on ingredients
· Chemical characterization: Mixtures
· Description: Mixture of substances listed below with nonhazardous additions.
· Dangerous components:
CAS: 108-10-1 4-methylpentan-2-one 50-100%
EINECS: 203-550-1 Xn R20; Xi R36/37; F R11
R66
Flam. Liq. 2, H225; Acute Tox. 4, H332; Eye Irrit. 2, H319; STOT SE
3, H335
CAS: 111-15-9 2-ethoxyethyl acetate 2.5-10%
EINECS: 203-839-2 T Repr. Cat. 2 R60-61; Xn R20/21/22
Repr. 1B, H360FD; Acute Tox. 4, H302; Acute Tox. 4, H312; Acute
Tox. 4, H332
CAS: 1330-20-7 Xylol, Isomerengemisch (wenn Flammpunkt<21°C) ≤ 2.5%
Xn R20/21; Xi R38; F R11
Flam. Liq. 2, H225; Acute Tox. 4, H312; Acute Tox. 4, H332; Skin
Irrit. 2, H315
CAS: 108-94-1 cyclohexanone ≤ 2.5%
T+ R28
Acute Tox. 1, H300
· SVHC
111-15-9 2-ethoxyethyl acetate
· Additional information: For the wording of the listed risk phrases refer to section 16.
5 Firefighting measures
· Extinguishing media
· Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· Special hazards arising from the substance or mixture No further relevant information available.
(Contd. on page 4)
PH
34.0
Page 4/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 11.10.2012 Version number 1 Revision: 11.10.2012
(Contd. of page 3)
· Advice for firefighters
· Protective equipment: Mouth respiratory protective device.
34.0
Page 5/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 11.10.2012 Version number 1 Revision: 11.10.2012
(Contd. of page 4)
· Control parameters
· Ingredients with limit values that require monitoring at the workplace:
108-10-1 4-methylpentan-2-one
PEL (USA) 410 mg/m³, 100 ppm
REL (USA) Short-term value: 300 mg/m³, 75 ppm
Long-term value: 205 mg/m³, 50 ppm
TLV (USA) Short-term value: 307 mg/m³, 75 ppm
Long-term value: 82 mg/m³, 20 ppm
BEI
IOELV (EU) Short-term value: 208 mg/m³, 50 ppm
Long-term value: 83 mg/m³, 20 ppm
111-15-9 2-ethoxyethyl acetate
PEL (USA) 540 mg/m³, 100 ppm
Skin
REL (USA) 2.7 mg/m³, 0.5 ppm
Skin
TLV (USA) 27 mg/m³, 5 ppm
Skin; BEI
1330-20-7 Xylol, Isomerengemisch (wenn Flammpunkt<21°C)
PEL (USA) 435 mg/m³, 100 ppm
REL (USA) Short-term value: 655 mg/m³, 150 ppm
Long-term value: 435 mg/m³, 100 ppm
TLV (USA) Short-term value: 651 mg/m³, 150 ppm
Long-term value: 434 mg/m³, 100 ppm
BEI
· Additional information: The lists valid during the making were used as basis.
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
· Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure
use self-contained respiratory protective device.
· Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
(Contd. on page 6)
PH
34.0
Page 6/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 11.10.2012 Version number 1 Revision: 11.10.2012
(Contd. of page 5)
application.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection:
34.0
Page 7/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 11.10.2012 Version number 1 Revision: 11.10.2012
(Contd. of page 6)
11 Toxicological information
· Information on toxicological effects
· Acute toxicity:
· LD/LC50 values relevant for classification:
108-10-1 4-methylpentan-2-one
Oral LD50 2080 mg/kg (rat)
Dermal LD50 16000 mg/kg (rab)
Inhalative LC50/4 h 8.3-16.6 mg/l (rat)
111-15-9 2-ethoxyethyl acetate
Oral LD50 -3900 mg/kg (rat)
Dermal LD50 10300 mg/kg (rabbit)
108-94-1 cyclohexanone
Oral LD50 1.62 mg/kg (rat)
· Primary irritant effect:
· on the skin: Cause mild irritation
· on the eye: Irritating effect.
· Sensitization: No sensitizing effects known.
· Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EU Classification
Guidelines for Preparations as issued in the latest version:
Harmful
Irritant
12 Ecological information
· Toxicity
· Aquatic toxicity: No further relevant information available.
· Persistence and degradability No further relevant information available.
(Contd. on page 8)
PH
34.0
Page 8/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 11.10.2012 Version number 1 Revision: 11.10.2012
(Contd. of page 7)
· Behaviour in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.
13 Disposal considerations
· Waste treatment methods
· Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.
14 Transport information
· UN-Number
· ADR, IMDG, IATA UN1993
· UN proper shipping name
· ADR 1993 FLAMMABLE LIQUID, N.O.S. (METHYL ISOBUTYL
KETONE), special provision 640D
· IMDG, IATA FLAMMABLE LIQUID, N.O.S. (METHYL ISOBUTYL KETONE)
· Transport hazard class(es)
· ADR
34.0
Page 9/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 11.10.2012 Version number 1 Revision: 11.10.2012
(Contd. of page 8)
· Environmental hazards:
· Marine pollutant: No
· Special precautions for user Warning: Flammable liquids.
· Danger code (Kemler): 33
· EMS Number: F-E,S-E
· Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
· Transport/Additional information:
· ADR
· Tunnel restriction code D/E
· UN "Model Regulation": UN1993, FLAMMABLE LIQUID, N.O.S. (METHYL ISOBUTYL
KETONE), special provision 640D, 3, II
15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the substance or mixture
· Philippines Inventory of Chemicals and Chemical Substances
108-10-1 4-methylpentan-2-one
111-15-9 2-ethoxyethyl acetate
1330-20-7 Xylol, Isomerengemisch (wenn Flammpunkt<21°C)
100-41-4 ethylbenzene
1119-40-0 dimethyl glutarate
627-93-0 dimethyl adipate
106-65-0 dimethyl succinate
77-58-7 dibutyltin dilaurate
71-36-3 butan-1-ol
108-88-3 toluene
· National regulations:
· Other regulations, limitations and prohibitive regulations
· Substances of very high concern (SVHC) according to REACH, Article 57
111-15-9 2-ethoxyethyl acetate
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
· Relevant phrases
H225 Highly flammable liquid and vapour.
H300 Fatal if swallowed.
H302 Harmful if swallowed.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
(Contd. on page 10)
PH
34.0
Page 10/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 11.10.2012 Version number 1 Revision: 11.10.2012
(Contd. of page 9)
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H360FD May damage fertility. May damage the unborn child.
R11 Highly flammable.
R20 Harmful by inhalation.
R20/21 Harmful by inhalation and in contact with skin.
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
R28 Very toxic if swallowed.
R36/37 Irritating to eyes and respiratory system.
R38 Irritating to skin.
R60 May impair fertility.
R61 May cause harm to the unborn child.
R66 Repeated exposure may cause skin dryness or cracking.
· Department issuing MSDS:
Research and Development Section
Elizabeth Lorenzo- [email protected]
Ruth Cua - [email protected]
· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the
International Transport of Dangerous Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
ICAO: International Civil Aviation Organization
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
· * Data compared to the previous version altered. 11.10.2012
PH
34.0