Hudson 20aaa Floor Varnish Topcoat (PH)

Download as pdf or txt
Download as pdf or txt
You are on page 1of 10

Page 1/10

Safety data sheet


according to 1907/2006/EC, Article 31
Printing date 11.10.2012 Version number 1 Revision: 11.10.2012

1 Identification of the substance/mixture and of the company/undertaking


· Product identifier
· Trade name: HUDSON 20AAA FLOOR VARNISH TOPCOAT
· Relevant identified uses of the substance or mixture and uses advised against
THIS IS A TWO COMPONENT POLYURETHANE COATING SYSTEM WHICH COMBINE EXCELLENT
HARDNESS AND FLEXIBILITY, HIGH ABRASION RESISTANCE AND HIGH GLOSS APPEARANCE.
· Application of the substance / the preparation
EXCELLENT FOR WOODEN FLOOR PARQUET, FURNITURES AND OTHER WOOD FINISHES.
· Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
Century Chemical Corporation
No. 49 Toctocan Street
Bo. Masambong, Quezon City
Philippines
· Further information obtainable from: Product safety department
· Emergency telephone number:
TELEPHONE NO: +63 2 365 2618; +63 2 365 2619 TO 21
FACSIMILE NO : +63 2 364 9962
EMAIL ADDRESS : [email protected]
WEBSITE ADDRESS: www.centurychemicals.com

2 Hazards identification
· Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008

GHS02 flame

Flam. Liq. 2 H225 Highly flammable liquid and vapour.

GHS08 health hazard

Repr. 1B H360FD May damage fertility. May damage the unborn child.

GHS07

Acute Tox. 4 H302 Harmful if swallowed.


Acute Tox. 4 H332 Harmful if inhaled.
Eye Irrit. 2 H319 Causes serious eye irritation.
STOT SE 3 H335 May cause respiratory irritation.
· Classification according to Directive 67/548/EEC or Directive 1999/45/EC
T; Toxic

R60-61: May impair fertility. May cause harm to the unborn child.

Xn; Harmful

R20/22: Harmful by inhalation and if swallowed.


(Contd. on page 2)
PH

34.0
Page 2/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 11.10.2012 Version number 1 Revision: 11.10.2012

Trade name: HUDSON 20AAA FLOOR VARNISH TOPCOAT

(Contd. of page 1)

Xi; Irritant

R36/37: Irritating to eyes and respiratory system.

F; Highly flammable

R11: Highly flammable.


· Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification guideline for
preparations of the EU" in the latest valid version.
· Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and literature
data.
· Label elements
· Labelling according to EU guidelines:
The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous
Materials.
· Code letter and hazard designation of product:

T Toxic
F Highly flammable

· Hazard-determining components of labelling:


2-ethoxyethyl acetate
4-methylpentan-2-one
cyclohexanone
· Risk phrases:
60 May impair fertility.
61 May cause harm to the unborn child.
11 Highly flammable.
20/22 Also harmful by inhalation and if swallowed.
36/37 Irritating to eyes and respiratory system.
· Safety phrases:
53 Avoid exposure - obtain special instructions before use.
1/2 Keep locked up and out of the reach of children.
9 Keep container in a well-ventilated place.
13 Keep away from food, drink and animal feedingstuffs.
29/56 Do not empty into drains, dispose of this material and its container at hazardous or special waste
collection point.
45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
· Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
PH
(Contd. on page 3)

34.0
Page 3/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 11.10.2012 Version number 1 Revision: 11.10.2012

Trade name: HUDSON 20AAA FLOOR VARNISH TOPCOAT


(Contd. of page 2)

3 Composition/information on ingredients
· Chemical characterization: Mixtures
· Description: Mixture of substances listed below with nonhazardous additions.
· Dangerous components:
CAS: 108-10-1 4-methylpentan-2-one 50-100%
EINECS: 203-550-1 Xn R20; Xi R36/37; F R11
R66
Flam. Liq. 2, H225; Acute Tox. 4, H332; Eye Irrit. 2, H319; STOT SE
3, H335
CAS: 111-15-9 2-ethoxyethyl acetate 2.5-10%
EINECS: 203-839-2 T Repr. Cat. 2 R60-61; Xn R20/21/22
Repr. 1B, H360FD; Acute Tox. 4, H302; Acute Tox. 4, H312; Acute
Tox. 4, H332
CAS: 1330-20-7 Xylol, Isomerengemisch (wenn Flammpunkt<21°C) ≤ 2.5%
Xn R20/21; Xi R38; F R11
Flam. Liq. 2, H225; Acute Tox. 4, H312; Acute Tox. 4, H332; Skin
Irrit. 2, H315
CAS: 108-94-1 cyclohexanone ≤ 2.5%
T+ R28
Acute Tox. 1, H300
· SVHC
111-15-9 2-ethoxyethyl acetate
· Additional information: For the wording of the listed risk phrases refer to section 16.

4 First aid measures


· Description of first aid measures
· General information:
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
· After inhalation:
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms
persist.
In case of unconsciousness place patient stably in side position for transportation.
· After skin contact: Immediately wash with water and soap and rinse thoroughly.
· After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
· After swallowing: Call for a doctor immediately.
· Information for doctor:
· Most important symptoms and effects, both acute and delayed No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.

5 Firefighting measures
· Extinguishing media
· Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· Special hazards arising from the substance or mixture No further relevant information available.
(Contd. on page 4)
PH

34.0
Page 4/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 11.10.2012 Version number 1 Revision: 11.10.2012

Trade name: HUDSON 20AAA FLOOR VARNISH TOPCOAT

(Contd. of page 3)
· Advice for firefighters
· Protective equipment: Mouth respiratory protective device.

6 Accidental release measures


· Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
· Environmental precautions:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
· Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents
· Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

7 Handling and storage


· Handling:
· Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation of aerosols.
· Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Keep respiratory protective device available.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: Store in a cool location.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
· Specific end use(s) No further relevant information available.

8 Exposure controls/personal protection


· Additional information about design of technical facilities: No further data; see item 7.
(Contd. on page 5)
PH

34.0
Page 5/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 11.10.2012 Version number 1 Revision: 11.10.2012

Trade name: HUDSON 20AAA FLOOR VARNISH TOPCOAT

(Contd. of page 4)

· Control parameters
· Ingredients with limit values that require monitoring at the workplace:
108-10-1 4-methylpentan-2-one
PEL (USA) 410 mg/m³, 100 ppm
REL (USA) Short-term value: 300 mg/m³, 75 ppm
Long-term value: 205 mg/m³, 50 ppm
TLV (USA) Short-term value: 307 mg/m³, 75 ppm
Long-term value: 82 mg/m³, 20 ppm
BEI
IOELV (EU) Short-term value: 208 mg/m³, 50 ppm
Long-term value: 83 mg/m³, 20 ppm
111-15-9 2-ethoxyethyl acetate
PEL (USA) 540 mg/m³, 100 ppm
Skin
REL (USA) 2.7 mg/m³, 0.5 ppm
Skin
TLV (USA) 27 mg/m³, 5 ppm
Skin; BEI
1330-20-7 Xylol, Isomerengemisch (wenn Flammpunkt<21°C)
PEL (USA) 435 mg/m³, 100 ppm
REL (USA) Short-term value: 655 mg/m³, 150 ppm
Long-term value: 435 mg/m³, 100 ppm
TLV (USA) Short-term value: 651 mg/m³, 150 ppm
Long-term value: 434 mg/m³, 100 ppm
BEI
· Additional information: The lists valid during the making were used as basis.
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
· Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure
use self-contained respiratory protective device.
· Protection of hands:

Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
(Contd. on page 6)
PH

34.0
Page 6/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 11.10.2012 Version number 1 Revision: 11.10.2012

Trade name: HUDSON 20AAA FLOOR VARNISH TOPCOAT

(Contd. of page 5)
application.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection:

Tightly sealed goggles

9 Physical and chemical properties


· Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Liquid
Colour: According to product specification
· Odour: Like ketone
· Odour threshold: Not determined.
· pH-value: Not determined.
· Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 114°C
· Flash point: 14°C
· Flammability (solid, gaseous): Not applicable.
· Ignition temperature: 380°C
· Decomposition temperature: Not determined.
· Self-igniting: Product is not selfigniting.
· Danger of explosion: Product is not explosive. However, formation of explosive air/
vapour mixtures are possible.
· Explosion limits:
Lower: 1.7 Vol %
Upper: 9.0 Vol %
· Vapour pressure at 20°C: 8 hPa
· Density: Not determined.
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility with
water: Not miscible or difficult to mix.
· Segregation coefficient (n-octanol/water): Not determined.
· Viscosity:
Dynamic: Not determined.
(Contd. on page 7)
PH

34.0
Page 7/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 11.10.2012 Version number 1 Revision: 11.10.2012

Trade name: HUDSON 20AAA FLOOR VARNISH TOPCOAT

(Contd. of page 6)

Kinematic: Not determined.


· Solvent content:
Organic solvents: 70.7 %
VOC (EC) 70.73 %
Solids content: 28.9 %
· Other information No further relevant information available.

10 Stability and reactivity


· Reactivity
· Chemical stability
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· Possibility of hazardous reactions No dangerous reactions known.
· Conditions to avoid No further relevant information available.
· Incompatible materials: No further relevant information available.
· Hazardous decomposition products: No dangerous decomposition products known.

11 Toxicological information
· Information on toxicological effects
· Acute toxicity:
· LD/LC50 values relevant for classification:
108-10-1 4-methylpentan-2-one
Oral LD50 2080 mg/kg (rat)
Dermal LD50 16000 mg/kg (rab)
Inhalative LC50/4 h 8.3-16.6 mg/l (rat)
111-15-9 2-ethoxyethyl acetate
Oral LD50 -3900 mg/kg (rat)
Dermal LD50 10300 mg/kg (rabbit)
108-94-1 cyclohexanone
Oral LD50 1.62 mg/kg (rat)
· Primary irritant effect:
· on the skin: Cause mild irritation
· on the eye: Irritating effect.
· Sensitization: No sensitizing effects known.
· Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EU Classification
Guidelines for Preparations as issued in the latest version:
Harmful
Irritant

12 Ecological information
· Toxicity
· Aquatic toxicity: No further relevant information available.
· Persistence and degradability No further relevant information available.
(Contd. on page 8)
PH

34.0
Page 8/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 11.10.2012 Version number 1 Revision: 11.10.2012

Trade name: HUDSON 20AAA FLOOR VARNISH TOPCOAT

(Contd. of page 7)
· Behaviour in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.

13 Disposal considerations
· Waste treatment methods
· Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.

14 Transport information
· UN-Number
· ADR, IMDG, IATA UN1993
· UN proper shipping name
· ADR 1993 FLAMMABLE LIQUID, N.O.S. (METHYL ISOBUTYL
KETONE), special provision 640D
· IMDG, IATA FLAMMABLE LIQUID, N.O.S. (METHYL ISOBUTYL KETONE)
· Transport hazard class(es)
· ADR

· Class 3 (F1) Flammable liquids.


· Label 3
· IMDG, IATA

· Class 3 Flammable liquids.


· Label 3
· Packing group
· ADR, IMDG, IATA II
(Contd. on page 9)
PH

34.0
Page 9/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 11.10.2012 Version number 1 Revision: 11.10.2012

Trade name: HUDSON 20AAA FLOOR VARNISH TOPCOAT

(Contd. of page 8)

· Environmental hazards:
· Marine pollutant: No
· Special precautions for user Warning: Flammable liquids.
· Danger code (Kemler): 33
· EMS Number: F-E,S-E
· Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
· Transport/Additional information:
· ADR
· Tunnel restriction code D/E
· UN "Model Regulation": UN1993, FLAMMABLE LIQUID, N.O.S. (METHYL ISOBUTYL
KETONE), special provision 640D, 3, II

15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the substance or mixture
· Philippines Inventory of Chemicals and Chemical Substances
108-10-1 4-methylpentan-2-one
111-15-9 2-ethoxyethyl acetate
1330-20-7 Xylol, Isomerengemisch (wenn Flammpunkt<21°C)
100-41-4 ethylbenzene
1119-40-0 dimethyl glutarate
627-93-0 dimethyl adipate
106-65-0 dimethyl succinate
77-58-7 dibutyltin dilaurate
71-36-3 butan-1-ol
108-88-3 toluene

· National regulations:
· Other regulations, limitations and prohibitive regulations
· Substances of very high concern (SVHC) according to REACH, Article 57
111-15-9 2-ethoxyethyl acetate
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
· Relevant phrases
H225 Highly flammable liquid and vapour.
H300 Fatal if swallowed.
H302 Harmful if swallowed.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
(Contd. on page 10)
PH

34.0
Page 10/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 11.10.2012 Version number 1 Revision: 11.10.2012

Trade name: HUDSON 20AAA FLOOR VARNISH TOPCOAT

(Contd. of page 9)
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H360FD May damage fertility. May damage the unborn child.
R11 Highly flammable.
R20 Harmful by inhalation.
R20/21 Harmful by inhalation and in contact with skin.
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
R28 Very toxic if swallowed.
R36/37 Irritating to eyes and respiratory system.
R38 Irritating to skin.
R60 May impair fertility.
R61 May cause harm to the unborn child.
R66 Repeated exposure may cause skin dryness or cracking.
· Department issuing MSDS:
Research and Development Section
Elizabeth Lorenzo- [email protected]
Ruth Cua - [email protected]
· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the
International Transport of Dangerous Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
ICAO: International Civil Aviation Organization
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
· * Data compared to the previous version altered. 11.10.2012
PH

34.0

You might also like