Revision date: 01/01/2022 Revision: 03 Supersedes date: 13/09/2020

SAFETY DATA SHEET

Hydrochloric Acid 31 -33 %

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name Hydrochloric Acid 31 -33 %

CAS number 7647-01-0

EU index number 017-002-00-2

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses No information available.

Application of the substance / Chemicals for synthesis

the mixture

Uses advised against No information available.

1.3. Details of the supplier of the safety data sheet

Manufacturer Jubail Chemical Industries Company (JANA)
Tareeq 263, Jubail 1, Jubail Industrial City, 31961
Kingdom of Saudi Arabia, (PO Box 10661)
Tel. +966 13 3585002
Fax. +966 13 3583192
[email protected]

Only Representative REACH NAMA Germany GmbH

1907/2006/EC Article 8 Röntgenstrasse 12
79539 Lörrach
Tel. + 49 762 1940 5410
Fax. + 49 762 1940 5420

1.4. Emergency telephone number

Emergency telephone Emergency CONTACT (24-Hour-Number):GBK GmbH +49 (0)6132-84463

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical hazards Not Classified

Health hazards Skin Corr. 1A - H314 Eye Dam. 1 - H318 STOT SE 3 - H335

Environmental hazards Not Classified

2.2. Label elements

Hazard pictograms

Signal word Danger

1/9
Revision date: 01/01/2022 Revision: 03 Supersedes date: 13/09/2020

Hydrochloric Acid 31 -33 %

Hazard statements H314 Causes severe skin burns and eye damage.
H335 May cause respiratory irritation.

Precautionary statements P260 Do not breathe vapour/ spray.

P264 Wash skin thoroughly after handling.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water or shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P501 Dispose of contents/ container in accordance with national regulations.

Contains hydrogen chloride

2.3. Other hazards

Results of PBT and vPvB Not applicable.
assessment:

SECTION 3: Composition/information on ingredients

3.2. Mixtures

hydrogen chloride 30-60%

CAS number: 7647-01-0 EC number: 231-595-7

Classification
Met. Corr. 1 - H290
Skin Corr. 1A - H314
STOT SE 3 - H335

The full text for all hazard statements is displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

General information Remove contaminated clothing and wash the skin thoroughly with soap and water after work.

Inhalation IF INHALED: Place unconscious person on their side in the recovery position and ensure
breathing can take place. Move affected person to fresh air at once. Get medical attention
immediately.

Ingestion IF SWALLOWED: Promptly get affected person to drink large volumes of water to dilute the
swallowed chemical. Remove person to fresh air and keep comfortable for breathing. Do not
induce vomiting. Get medical attention immediately.

Skin contact IF ON SKIN: Wash skin thoroughly with soap and water or use an approved skin cleanser.

Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove any contact lenses and
open eyelids wide apart. Get medical attention.

4.2. Most important symptoms and effects, both acute and delayed
General information No information available.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor No information available.

SECTION 5: Firefighting measures

5.1. Extinguishing media

2/9
Revision date: 01/01/2022 Revision: 03 Supersedes date: 13/09/2020

Hydrochloric Acid 31 -33 %

Suitable extinguishing media Water spray, dry powder or carbon dioxide. Alcohol-resistant foam.

5.2. Special hazards arising from the substance or mixture

Specific hazards Toxic gases or vapours. Hydrogen chloride (HCl).

5.3. Advice for firefighters

Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Wear suitable protective equipment, including gloves, goggles/face shield, respirator, boots,
clothing or apron, as appropriate.

For non-emergency personnel Keep unnecessary and unprotected personnel away from the spillage.

6.2. Environmental precautions

Environmental precautions Flush contaminated area with plenty of water. Avoid the spillage or runoff entering drains,
sewers or watercourses.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up Absorb spillage to prevent material damage. Contain spillage with sand, earth or other
suitable non-combustible material. Collect and dispose of spillage as indicated in Section 13.
Provide adequate ventilation.

6.4. Reference to other sections

Reference to other sections Follow precautions for safe handling described in this safety data sheet. For personal
protection, see Section 8. For waste disposal, see Section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Provide adequate general and local exhaust ventilation. Prevent formation of aerosols.

Information about fire - and No special treatment required.

explosion protection

7.2. Conditions for safe storage, including any incompatibilities

Requirements to be met by No special requirements.
storerooms and receptacles

Storage precautions Store in tightly-closed, original container in a dry and cool place.

7.3. Specific end use(s)

Specific end use(s) No information available.

SECTION 8: Exposure controls/Personal protection

8.1. Control parameters

MAK (Germany)/MAK (EU) Long-term value: 200 mg/m³, 300 ppm

8.2. Exposure controls

3/9
Revision date: 01/01/2022 Revision: 03 Supersedes date: 13/09/2020

Hydrochloric Acid 31 -33 %

Protective equipment

Personal protection Keep away from food and drink. Remove contaminated clothing and wash the skin thoroughly
with soap and water after work. Wash hands and any other contaminated areas of the body
with soap and water before leaving the work site. Avoid contact with eyes. Avoid contact with
skin.

Eye/face protection Wear tight-fitting, chemical splash goggles or face shield.

Hand protection Wear protective gloves. It is recommended that chemical-resistant, impervious gloves are
worn. Wear protective gloves made of the following material: Nitrile rubber. Rubber (natural,
latex). Considering the data specified by the glove manufacturer, check during use that the
gloves are retaining their protective properties and change them as soon as any deterioration
is detected.

Other skin and body Wear protective clothing.

protection

Hygiene measures Keep away from food, drink and animal feeding stuffs. Wash hands thoroughly after handling.
Avoid contact with skin, eyes and clothing. Use appropriate skin cream to prevent drying of
skin. If ventilation is inadequate, suitable respiratory protection must be worn.

Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment. Wear self-contained
breathing apparatus.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance Fluid

Colour According to product specification

Odour Characteristic.

pH <1

Melting point Not determined.

Initial boiling point and range 107 °C

Flash point Not applicable.

Vapour pressure 12 hPa @20°C

Vapour density 1.12 g/cm³ @20°C

Solubility(ies) Miscible with water.

Auto-ignition temperature Product is not self-igniting

Viscosity Not determined.

Explosive properties There are no chemical groups present in the product that are associated with explosive
properties.

Organic solvents 0.0%

VOC (EC) 0,00%

9.2. Other information

4/9
Revision date: 01/01/2022 Revision: 03 Supersedes date: 13/09/2020

Hydrochloric Acid 31 -33 %

Other information No information available.

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity No information available.

10.2. Chemical stability

Stability Stable at normal ambient temperatures and when used as recommended.

Thermal decomposition / Does not decompose when used and stored as recommended. To avoid thermal
conditions to be avoided decomposition do not overheat.

10.3. Possibility of hazardous reactions

Possibility of hazardous Under normal conditions of storage and use, no hazardous reactions will occur.
reactions

10.4. Conditions to avoid

Conditions to avoid No information available.

10.5. Incompatible materials

Materials to avoid The following materials may react strongly with the product: Aluminium. Amines. Inorganic
hydrides. Alkali metals. Aldehydes. Carbides, metals potassium permanganate, strong
alcalsics, saltes of halogeneoxygene acids, and sulfides

10.6. Hazardous decomposition products

Hazardous decomposition No known hazardous decomposition products.
products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity - oral
Notes (oral LD₅₀) 900 mg/kg, Oral, Rabbit

Skin corrosion/irritation
Skin corrosion/irritation Causes severe skin burns and eye damage.

Serious eye damage/irritation

Serious eye damage/irritation May cause serious eye damage.

Respiratory sensitisation
Respiratory sensitisation Based on available data the classification criteria are not met.

Skin sensitisation
Skin sensitisation Based on available data the classification criteria are not met.

Germ cell mutagenicity

Genotoxicity - in vitro Based on available data the classification criteria are not met.

Genotoxicity - in vivo Based on available data the classification criteria are not met.

Carcinogenicity
Carcinogenicity Based on available data the classification criteria are not met.

Reproductive toxicity
Reproductive toxicity - fertility Based on available data the classification criteria are not met.

5/9
Revision date: 01/01/2022 Revision: 03 Supersedes date: 13/09/2020

Hydrochloric Acid 31 -33 %

Specific target organ toxicity - single exposure

STOT - single exposure May cause respiratory system irritation.

Specific target organ toxicity - repeated exposure

STOT - repeated exposure Based on available data the classification criteria are not met.

Aspiration hazard
Aspiration hazard Based on available data the classification criteria are not met.

SECTION 12: Ecological information

General Notes Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water.

12.1. Toxicity
Toxicity No information available.

Chronic aquatic toxicity

Chronic toxicity - aquatic No information available.
invertebrates

12.2. Persistence and degradability

Persistence and degradability No information available.

12.3. Bioaccumulative potential

Bioaccumulative potential No information available.

12.4. Mobility in soil

Mobility No information available.

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB Not applicable.
assessment

12.6. Other adverse effects

Other adverse effects No information available.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

General information External recovery, treatment, recycling and disposal of waste should comply with all
applicable local and/or national regulations.

European waste catalogue: 06 01 02* hydrochloric acid

SECTION 14: Transport information

14.1. UN number
UN No. (ADR/RID) 1789

UN No. (IMDG) 1789

UN No. (ICAO) 1789

14.2. UN proper shipping name

Proper shipping name HYDROCHLORIC ACID
(ADR/RID)

Proper shipping name (IMDG) HYDROCHLORIC ACID

6/9
Revision date: 01/01/2022 Revision: 03 Supersedes date: 13/09/2020

Hydrochloric Acid 31 -33 %

Proper shipping name (ICAO) HYDROCHLORIC ACID

14.3. Transport hazard class(es)

ADR/RID class 8

ADR/RID classification code C1

ADR/RID label 8

IMDG class 8

ICAO class/division 8

Transport labels

14.4. Packing group

ADR/RID packing group II

IMDG packing group II

ICAO packing group II

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

No.

14.6. Special precautions for user

IMDG Code segregation 1. Acids
group

EmS F-A, S-B

ADR transport category 2

Emergency Action Code 2R

Hazard Identification Number 80

(ADR/RID)

Tunnel restriction code (E)

Segregation Code: SG35 Stow "separated from" acids.

IMDG ; DOT- Stowage E

Location & Category

Transportation Additional
Information: ADR/IMDG/DOT

Excepted Quantities (EQ): Code: E2

Limited Quantities (LQ): 1L

Maximum Net Quantity per 30 ml

Inner Packaging:

Maximum Net Quantity per 500 ml

Outer Packaging:

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code

7/9
Revision date: 01/01/2022 Revision: 03 Supersedes date: 13/09/2020

Hydrochloric Acid 31 -33 %

Transport in bulk according to Not applicable.

Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

15.2. Chemical safety assessment

No chemical safety assessment has been carried out.

SECTION 16: Other information

Abbreviations and acronyms RID: European Agreement concerning the International Carriage of Dangerous Goods by
used in the safety data sheet Rail.
IATA-DGR : Dangerous Goods Regulation by the "International Air Trasport
Association"(IATA).
ICAO: International Civil Aviation Organisation
ICAO: Technical Instructions for the Safe Transport of Dangerous Goods by Air.
ADR: European Agreement concerning the International Carriage of Dangerous Goods by
Road.
IMDG: International Maritime Dangerous Goods.
IATA: International Air Transport Association.
GHS: Globally Harmonized System.
EINECS: European Inventory of Existing Commercial and Chemical Substances
CAS: Chemical Abstracts Service.
VOC: Volatile Organic Compounds (USA,EU)
LC₅₀: Lethal Concentration to 50 % of a test population.
LD₅₀: Lethal Dose to 50% of a test population (Median Lethal Dose).
PBT: Persistent, Bioaccumulative and Toxic substance.
vPvB: Very Persistent and Very Bioaccumulative.
Met. Corr.1: Corrosive to metals, Hazard Category 1
Skin Corr. 1B: Skin corrosion/irritation, Hazard Category 1B
Eye Dam. 1: Serious eye damage/eye irritation, Hazard Category 1
STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water.

Revision comments SECTION 01: Identification of the substance/mixture and of the company/undertaking
SECTION 16: Other Information

Revision date 01/01/2022

Revision 03

Supersedes date 13/09/2020

SDS number 4590

Hazard statements in full H290 May be corrosive to metals.

H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H335 May cause respiratory irritation.

Disclaimer This information relates only to the specific material designated and may not be valid for such
material used in combination with any other materials or in any process. Such information is,
to the best of the company's knowledge and belief, accurate and reliable as of the date
indicated. However, no warranty, guarantee or representation is made to its accuracy,
reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of
such information for his own particular use.

8/9
Revision date: 01/01/2022 Revision: 03 Supersedes date: 13/09/2020

Hydrochloric Acid 31 -33 %

9/9