CURATIVES

OVERALL PORTFOLIO
Ethacure 100, 100-LC, 270, 300, & 420

www.albemarle.com
ETHACURE 100

Value in Polyurea Applications:

Ethacure 100 is the workhorse curative for polyurea and polyurethane Product Market
applications particularly, spray applications.
Segmentation
It is a high quality, liquid product that delivers exceptional product
benefits such as: ETHACURE curatives are low-viscosity, pour-
• Adjustable reaction times • Outstanding mechanical performance able liquids that are easy to mix, meter and
• Ease of processing • Zero dust exposure dispense.
• High purity
Integrating E100 in polyurea coating engineering equips formulators
and end-users with increased versatility, adjustability, and dynamic • 100% active
performance advantages. • Simple to blend & handle without heating

Spray Polyurea Formulations

MDI prepolymer 15.5% NCO
100 • Spray Polyurea
(has a high 2,4’-isomer content)
• PU Cast Elastomers
B-Side Components, %wt. E100 • Epoxy Composites
ETHACURE 100 18.69 • PU Foam
ETHACURE 420 9.35
Polyether amine D-2000 60.75
Polyether amine T-5000 4.67 E100- LC • Cast Elastomers
Pigment 4.67
UV absorber 1.87
Gel time, sec. 12 E270 • Epoxy Composites
Physical Properties
Tensile Strength, psi (Mpa) 2420 (16.7)
Elongation, % 455 • PU Cast Elastomer
Tear Strength, pli (N/mm) 382 (67)
• Epoxy Composite
E300 • PU Foam
• Adhesives
Value in Epoxy Applications:
Ethacure 100 is a viable curative for use in epoxy applications, and as an MDA
replacement in the production of filament wound pipe. Cured parts display • Spray Polyurea
E420 • PU Foam
high-grade benefits such as:
• Good “wetting” characteristics
• High glass transition temperatures (Tgs) • Polyurethane Roof
• Exceptional chemical resistance E500 Coating
• Low moisture accumulation

Epoxy Formulation
Epoxy Resin (WPE = 183 g/eq) 100

ETHACURE 100, phr. 25.5

Gel Times for Ethacure 100 and Epoxy Resin (183
Cure Cycle 1.5 hrs. at 175 °C WPE) System
350
Gel Time (min)

301
Physical Properties 300
250
Tensile Strength, Mpsi 11.3 188
200
150
Tensile Modulus, Mpsi. 390
100 61
40
Elongation, % 6.3 50 12
0
Flexural Modulus, Mpsi. 390 90 100 115 135 175
Temperature ( ºC)
Tg,°C 154
Post Cure 30 min. 250°C Gel times have been determined at different temperatures as guidance for our
potential customers.
Tg, after post, °C 188
ETHACURE 100

Ethacure 100 Applications

Spray Polyurea Coatings

• Truck Bed Liners

– OEM
– After Market
• Water Proofing Membrane
– Amusement park tanks
– Bridges
– Pipe coating
– High speed rail
– Concrete
• Secondary Containment
– Oil and Gas

Epoxy Composites

• Filament wound epoxy pipe

• Syntactic foam
• Grinding wheel
• Electrical laminates

Polyurethane Cast Elastomer PU Foam RIM

Wheels, Belts, Tools, Rollers Building Insulation, Vehicle parts

Roofing
ETHACURE 100-LC

Value in Low Color Applications:

Ethacure 100-LC is the lowest-colored aromatic
diamine commonly available. Specialized production
techniques and a proprietary, patented stabilizer
system produce a curative with extremely low initial
color and increased color stability.

Specifying Ethacure 100-LC in formulations

results in:
• Lower color in final parts
• Reduced pigment loading
• Easier color matching
• Increased shelf life in epoxy
coatings, polyurethane and
polyurea spray coatings

Ethacure 100-LC Applications

Polyurea Cast Elastomer

• Optically clear wheels

• Ballistic-proof applications
• Optically clear eye glasses
• Golf balls
 ETHACURE 270

Value in Epoxy Applications:

Albemarle’s Ethacure 270 curing agent is strategically formulated These characteristics make it an excellent curative for fiber reinforced
to provide longer and adjustable reaction times when cured with pipe and composites.
epoxy resins.

Polymers cured with Ethacure 270 deliver exceptional properties Concentration & Performance Optimization:
such as high temperature performance, substantial mechanical Optimum level for maximum temperature performance is 24.7 phr
strength, and good chemical resistance. for resins with WPE’s of 187g/eq.

Ethacure 270 Tg Development at 140 ° C Thermal Performance of Gel Times for Ethacure 270 and Epoxy Resin (187 g/eq)
Ethacure 270 and Epoxy Resin System
170
169
(185 g/eq) 60 55
168 2 50
167
Heat Flow (w/g) 41

Gel Time (min)

1 40
166
Tg(°C)

165 0 30
164 20
20
163 -1
162 10
161 -2
160
-50 50 150 250 350 0
22.3 23.5 24.7 25.9 Temp (°C) 100 115 130
Temperature ( ºC)
Concentration (phr)
E270
Gel times have been determined at different temperatures as guidance
for our potential customers.

Ethacure 270 Applications

Epoxy Composites

• Filament wound epoxy pipe

• Advanced composites for
aerospace applications
ETHACURE 300

Value in Cast Elastomer Applications:

Albemarle’s Ethacure 300 puts users in control. Incorporating
this versatile, easy-to-handle liquid into operations results in
immediate benefits:
• A safer solution
• High quality product with reduced odor
• Ability to mix and match prepolymers to fit needs
• Adjustable reaction times
• Eliminated dust exposure and melting
• Reduced costly, inconvenient heating
• Simplified handling and blending
• Reduced exposure to hazardous materials

Exhibiting outstanding physical performance, Ethacure 300 cured E300 is a liquid curative which allows formulators to fine-tune
polymers compete favorably with competitive alternatives, making processing conditions and reaction times.
it the leading alternative for MOCA replacement.
Utilizing Ethacure 300 in cast elastomer applications gives
Cured polymers display excellent strength, hardness, modulus, and users reassurance that they will be able to meet application
elongation at break point. specification requirements when formulating.

Formulation Examples & Performance in Cast Elastomer Applications

Prepolymers Type PTMEG PTMEG PPG
Adiprene Adiprene Vibrathane
Prepolymer
L-100 L-100 B-627
Curative E300 E300 E300
Processing Data
Prepolymer, % NCO 4.12 9.46 6.20
Prepolymer, temp., °C 80 80 50
Curative, phr. 10.0 22.9 15
Pour time, min 5.0 0.9 7.0
Gel time, min. 6.0 1.3 11
Post-cure, (hrs./100°C) 18 3 18

Curative E300 E300 E300

Polymer Properties
Hardness, Shore A 88 -- 94
Hardness, Shore D -- 73 --
Tensile, psi 5760 7560 4910
M-100 %, psi 1070 4600 1770
M-300 %, psi 2140 -- 3240
Elongation 410 260 350
Die-C tear, pli 260 -- 260
Split tear, pli 80 100 60
Compression set, % 31 -- 34
Resilience, % 45 51 50
ETHACURE 300

Ethacure 300 Applications

Polyurethane Cast Elastomers
(hot)
• Rollers
– Computer printers
– Copy machines
– Boat trailers
• Belts
– Drive belts
– Conveyor belts
• Tires
• Wheels
• CMP polishing pads
• Golf balls

Polyurethane Cast Elastomers

(cold)

• Athletic surfaces
• Tire fill
• Thermal break

Epoxy Composites
(cold)

• Carbon reinforced composite

for aerospace applications
ETHACURE 420

Value in Polyurea Applications:

Ethacure 420 increases versatility for polyurea
applicators. It is a liquid curative that boosts
polymer performance, particularly elasticity,
surface finish, and adherence capabilities.
Formulators can easily produce the soft elastomers
needed in caulks and sealants and appreciate the
way Ethacure 420 improves pot-life.

Property performance is enhanced while tailored

reaction times maintained.

Ethacure 420 Applications

Spray Polyurea Coatings

• Truck bed liners

• Water proofing membrane
• Secondary containment
• Flooring coatings

Polyurea/Polyurethane PU Foam

Sealants and Caulks Building insulation and Roofing

TECHNICAL SERVICE

Technical Service
and Support
Our Technical Service team is committed to offer-
ing best-in-class support to our customer networks
throughout the development process. We make it a
priority to add value for our customers by diligently
identifying performance optimization strategies that
best suit their individual needs. Our qualified team
of professionals share decades of knowledge and
experience to support a results-focused approach,
ensuring our customers have what they need to
create value-added solutions and overcome their
most challenging issues.
TECHNICAL SERVICE

Core Capabilities and Instrumentation

• Polyurethane Formulation & Testing

- Starter formulations
- Optimization strategies utilizing Design of
Experiment (DOE)
• Mechanical Testing
- Tensile, tear, elongation, hardness, compression
set, resilience
• Thermal Testing
- DSC, TGA, R-Value
• Cone Calorimetry
• Polyurea Spraying
• UV Weatherometer
CAPABILITIES

Largest Ethacure 100

(DETDA) Global Capacity
Albemarle’s Ethacure curatives are produced in world-
class manufacturing facilities, supported by dedicated
and experienced teams who are committed to producing
material of the highest quality. Our global capacity of
the Ethacure 100 (DETDA) curative and robust produc-
tion capabilities across our entire product portfolio are
unmatched, allowing us to be the reliable and sustain-
able supplier that our customers deserve. Together, with
our customer networks, we are dedicated to supporting
continuous innovation and unparalleled growth in the
polyurethanes industry.
Locations Around the World
From Charlotte to Shanghai, Albemarle operates sites in many countries around the globe. Our team is comprised of over 5,400 dedicated
employees spread across approximately 100 different countries. As a global supplier of specialty chemicals, we strive to benefit the world
in which we all live. As a neighbor to the world, we feel it is our responsibility to address diverse social and environmental issues, and we
are committed to making a positive contribution to society at large.

Curatives Manufacturing, Technical Service, and Business Sites:

Louisiana | Arkansas | Texas | North Carolina | Belgium | Brazil | China | Japan | Korea

AMERICAS
4250 Congress Street, Suite 900 • Charlotte, NC 28209
Tel: +1 980 299 5700 • Fax: +1 980 299 5511

EUROPE, MIDDLE EAST, AFRICA

Parc Scientifique Einstein, Rue du Bosquet 9, 1348 • Louvain-la-Neuve, Belgium
Tel: +32 10 48 17 11 • Fax: +32 10 48 1717 • [email protected] www.albemarle.com
ASIA PACIFIC
CHINA Room 3202, No. 757 Mengzi Road, Gopher Center, Huangpu District • Shanghai, PRC. 200023
Tel: 86.21.6103.8666 • Fax: +86 21 6103 8777 • [email protected]

ALBEMARLE is a registered trademark of Albemarle Corporation. The information presented herein is believed to be accurate and reliable, but is presented without guarantee or responsibility on the part of Albemarle
Corporation and its subsidiaries to ensure the accuracy or reliability of the information. It is the responsibility of the user to comply with all applicable laws and regulations and to provide for a safe workplace. The user
should consider all information contained herein only as a guide, and should take precautions that the user considers necessary or prudent to promote a safe work environment, such as considering all applicable health
and safety hazards, developing safe work practice procedures and properly instructing employees. Further, nothing contained herein shall be taken as an inducement or recommendation to manufacture or use any of the
materials or processes mentioned herein in violation of existing or pending patents.
Albemarle is an Equal Opportunity Employer. © September 2019 Albemarle Corporation. All rights reserved.