AC 2019 Winter

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Seat No.: ________ Enrolment No.

___________
GUJARAT TECHNOLOGICAL UNIVERSITY
BE - SEMESTER– III (New) EXAMINATION – WINTER 2019
Subject Code: 3130506 Date: 28/11/2019
Subject Name: Applied Chemistry
Time: 02:30 PM TO 05:00 PM Total Marks: 70
Instructions:
1. Attempt all questions.
2. Make suitable assumptions wherever necessary.
3. Figures to the right indicate full marks.
Marks
Q.1 (a) Explain condensed system. ? (CH-5 ) 03
(b) Derive Gibbs phase rule thermodynamically. ? (CH-5) 04
CH-7 (c) State the Hess law and illustrate with suitable examples. 07

Q.2 (a) Describe: Liquid crystal Ch-8 03


Ch-9 (b) Explain principle of Mass spectrometry 04
CH-5 (c) Discuss the Phase diagram of Zn-Cd system. 07
OR
CH-4 (c) Explain concept hybridisation with simple organic molecules 07
Q.3 (a) Difference between the terms configuration and conformation. CH-3 03
CH-4 (b) Derive Schrödinger wave equation. 04
CH-3 (c) Discuss stereochemistry of tartaric acid. 07
OR
Q.3 (a) Discuss the terms carbanion and free radical CH-2 03
CH-2 (b) Explain mechanism of nucleophilic substitution 04
CH-3 (c) Explain recemisation of optical isomers with suitable examples. 07
Q.4 (a) Define: Degree of freedom and component CH-5 03
CH-6 (b) A first order reaction is 10% completed in 20 minutes. How long 04
will it take to be 70% complete?
CH-6 (c) Explain pseudo order first reaction. Derive the equation for first 07
order reaction.
OR
Q.4 (a) Explain Heisenberg Uncertainty Principle CH-4 03
CH-8 (b) Discuss the properties of insulators 04
CH-1 (c) Discuss Parachor and Explain role of parachor in determining the 07
chemical constitution of a compound
Q.5 (a) Predict the NMR spectrum of CH3 .CH2.OH CH-9 03
CH-7 (b) The heat of combustion of methane is -890.65kJ mol-1 and heat of 04
formation of CO2 and H2O are -395.5kJ mol-1 and 286.0kJ.mol-1
respectively. Calculate the heat of formation of methane.
(R=8.314J/degree.mol)
CH-9 (c) Name any four important surface characterization techniques and 07
explain any one technique in detail.
OR
Q.5 (a) Define terms : (i) Order of reaction 03
CH- 6 and 7 (ii) thermo chemistry
CH-9 (b) Explain Florescence spectroscopy 04
CH-8 (c) Discuss the properties and application of zeolites 07

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