Cbo 5
Cbo 5
Cbo 5
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Chemical Bonding-V
B-2. Of the following molecules, the one, which has permanent dipole moment, is :
(A) SiF4 (B) BF3 (C) PF3 (D) PF5
B-3. Which of the following has the least dipole moment ?
(A) NF3 (B) CO2 (C) SO2 (D) NH3
B-4. Which of the following compounds possesses zero dipole moment?
(A) Benzene (C6H6) (B) Carbon tetrachloride
(C) Boron trifluoride (D) All of these
B-5. The geometry of H2S and its dipole moment are :
(A) angular and non zero (B) angular and zero
(C) linear and non zero (D) linear and zero
B-6. Which of the following has been arranged in order of decreasing dipole moment ?
(A) CH3Cl CH3F CH3Br CH3I (B) CH3F CH3Cl CH3Br CH3I
(C) CH3Cl CH3Br CH3I CH3F (D) CH3F CH3Cl CH3I CH3Br
B-7. The dipole moment of chlorobenzene is 1.73 D. The dipole moment of p-dichlorobenzene is expected
to be:
(A) 3.46 D (B) 0.00 D (C) 1.73 D (D) 1.00 D
Section (C) : Acidic & basic character
C-1._ Which of the following is the strongest oxy-acid among the following :
(A) H2SO4 (B) H3PO4 (C) HClO4 (D) H2SiO3
C-2._ Which of the following is the anhydride of Nitric acid (HNO 3) :
(A) NO2 (B) N2O3 (C) N2O5 (D) N2O
Marked questions are recommended for Revision.
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Chemical Bonding-V
3. How many of the following are correct orders of property indicated against it ?
(i) I– > Br– > Cl– > F– (order of polarizability)
(ii) Li+ > Na+ > K+ > Cs+ (order of polarising power)
(iii) Li+ > Mg2+ > Al3+ (order of polarising power)
(iv) LiI > NaI > KI (order of ionic character)
(v) AgI > AgBr > AgCl (order of solubility in water)
(vi) (Si–Si bond) Si > SiO2 (Si–O bond) (order of % covalent character of bond.
4. How many of the following oxides are acidic ?
(a) Mn2O7 (b) SO2 (c) CO (d) N2O
(e) NO2 (f) PbO2 (g) Na2O (h) CrO3
(i) ZnO (j) Fe2O3 (k) SiO2 (l) SnO
PART - IV : COMPREHENSION
Read the following passage carefully and answer the questions.
Comprehension # 1
The degree of polarity of a covalent compound is measured by the dipole moment (bond) of the bond
defined as:
bond = Charge on one of the poles bond length
bond is a vector quantity. The dipole moment of a molecule is the vector addition of all the bond dipole
moments present in it. For a triatomic molecule, containing two bond's like H2O, molecule is given by
2molecule = 2bond + 2bond + 2bond.bond cos
= bond angle
The % ionic character of a bond is calculated using the equations
% ionic character = obs 100
ionic
ionic = dipole moment when the molecule is assumed to be completely ionic.
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Chemical Bonding-V
1. Which of the follwing molecule has non-zero dipole moment -
(A) XeF2 (B) ClF3 (C) XeO2F4 (D) XeF4
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Comprehension # 4
Answer 11, 12 and 13 by appropriately matching the information given in the three columns of
the following table.
According to Fajan covalency is favoured by :
(i) Small size of cation
(ii) Large size of anion
(iii) High charge on cation, anion or both
(iv) Cation with non-noble gas configuration
Column-1 Column-2 Column-3
Covalent character
(I) NaF, NaCl, NaBr, NaI (i) Size of cation increases (P)
increases
(II) NaCl, MgCl2, AlCl3 (ii) Size of anion increases (Q) Ionic character increases
MgCO3, CaCO3, SrCO3,
(III) (iii) Charge on anion increases (R) Melting point increases
BaCO3
Charge density decreases
(IV) LiOH, NaOH, KOH, RbOH (iv) (S) Solubility increases
(Magnitude)
2. Which contains both polar and non-polar bonds ? [IIT JEE 1997]
(A) NH4Cl (B) HCN (C) H2O2 (D) CH4
3. The geometry of H2S and its dipole moment are : [IIT JEE 1999]
(A) angular and non-zero (B) angular and zero
(C) linear and non-zero (D) linear and zero
4.* The molecules that will have dipole moment are [IIT JEE 1992]
(A) 2, 2-dimethyl propane (B) trans-2-pentene
(C) cis-3-hexene (D) 2, 2, 3, 3-tetramethyl butane
7. Identify the correct order of acidic strengths of CO2, CuO, CaO, H2O. [JEE-2002, 3/150]
(A) CaO < CuO < H2O < CO2 (B) H2O < CuO < CaO < CO2
(C) CaO < H2O < CuO < CO2 (D) H2O < CO2 < CaO < CuO
8.* The correct statement(s) regarding, (i) HClO, (ii) HClO2, (iii) HClO3 and (iv) HClO4 is(are)
(A) The number of Cl=O bonds in (ii) and (iii) together is two [JEE(Advanced) 2015, 4/168]
(B) The number of lone pairs of electrons on Cl in (ii) and (iii) together is three
(C) The hybridization of Cl in (iv) is sp3
(D) Amongst (i) to (iv), the strongest acid is (i)
2. Which of the following pair of molecules will have permanent dipole moments for both members?
[AIEEE-2003, 3/225]
(1) SiF4 and NO2 (2) NO2 and CO2 (3) NO2 and O3 (4) SiF4 and CO2
3. Among Al2O3, SiO2, P2O3 and SO2 the correct order of acid strength is : [AIEEE-2004, 3/225]
(1) Al2O3 < SiO2 < SO2 < P2O3 (2) SiO2 < SO2 < Al2O3 < P2O3
(3) SO2 < P2O3 < SiO2 < Al2O3 (4) Al2O3 < SiO2 < P2O3 < SO2
4. The charge/size ratio of a cation determines its polarizing power. Which one of the following sequences
represents the increasing order of the polarizing power of these cationic species, K+, Ca2+, Mg2+, Be2+?
[AIEEE-2007, 3/120]
(1) K+ < Ca2+ < Mg2+ < Be2+ (2) Ca2 < Mg2+ < Be2+ < K+
(3) Mg2+ < Be2+ < K+ < Ca2+ (4) Be2+ < K+ < Ca2+ < Mg2+
5. Among the following the maximum covalent character is shown by the compound :
[AIEEE-2011, 4/120]
(1) FeCl2 (2) SnCl2 (3) AlCl3 (4) MgCl2
Cl CN OH SH
(1) Only (i) (2) (i) and (ii) (3) Only (iii) (4) (iii) and (iv)
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8. Which of the following compounds contain(s) no covalent bond(s) ? [JEE(Main)-2018, 4/120]
KCl, PH3, O2, B2H6, H2SO4
(1) KCl (2) KCl, B2H6 (3) KCl, B2H6, PH3 (4) KCl, H2SO4
1. Amongst LiCl, RbCl, BeCl2 and MgCl2 the compounds with the greatest and the least ionic character
respectively are : [JEE(Main) 2014 Online (19-04-14), 4/120]
(1) LiCl and RbCl (2) RbCl and BeCl2 (3) MgCl2 and BeCl2 (4) RbCl and MgCl2
2. Which of the alkaline earth metal halides given below is essentially covalent in nature ?
[JEE(Main) 2015 Online (11-04-15), 4/120]
(1) SrCl2 (2) CaCl2 (3) BeCl2 (4) MgCl2
3. Molecule AB has a bond length of 1.61 Å and a dipole moment of 0.38 D. The fractional charge on each atom
(absolute magnitude) is : (e0 = 4.802 × 10–10 esu) [JEE(Main) 2015 Online (11-04-15), 4/120]
(1) 0.5 (2) 0.05 (3) 0 (4) 1.0
5. Which of the following is a Lewis acid ? [JEE(Main) 2018 Online (15-04-18), 4/120]
(1) PH3 (2) NF3 (3) NaH (4) B(CH3)3
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EXERCISE - 1
PART - I
A-1 (a) NaF < Na2O < Na3N (b) NaCl < MgCl2 < AlCl3 < SiCl4 < PCl5
A-2. According to Fajan's rule, as charge on cation increases its polarising power increases resulting in to
the greater polarisation of anion. Thus covalent character increases and melting point decreases.
A-3. Bigger anion has higher polarisability; more polarisation greater is the intensity of colour (valence shell
electrons are loosely bound with the nucleus).
B-1. Inorganic benzene (N3B3H6) contains polar covalent B –N bonds while benzene (C6H6) contains non-
polar covalent C–C bonds.
B-2.
B-3. CCl4 is a symmetrical and non polar molecule while CHCl3 is an unsymmetrical and polar molecule.
B-5. 84.5%
C-2. As En (difference in electronegativities between element and oxygen) decreases, the acidic character
increases. So, SiO2 < CO2 < N2O5 < SO3 .
C-3. Higher the metallic character, greater will be the basic character of its oxide as En (difference in
electronegativities between element and oxygen) increases.
So, NiO < MgO < SrO < K2O < Cs2O
PART - II
A-1. (C) A-2. (B) A-3. (C) A-4. (B) B-1. (A)
B-2. (C) B-3. (B) B-4. (D) B-5. (A) B-6. (A)
B-7. (B) C-1. (C) C-2. (C) C-3. (A) C-4. (D)
C-5. (A)
PART - III
1. (A – p,q,r) ; (B – s,t) ; (C –q,r,t) ; (D – s,t)
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EXERCISE - 2
PART - I
1. (D) 2. (C) 3. (B) 4. (C) 5. (C)
PART - II
1. 3 (a, b, h) 2. 3 (a, c, f) 3. 3 (i, ii, vi) 4. 5 (a, b, e, h, k)
PART - III
1. (ABCD) 2. (ABD) 3. (BC) 4. (ABCD) 5. (BD)
6. (ABCD)
PART - IV
1. (B) 2. (B) 3. (C) 4. (C) 5. (C)
EXERCISE - 3
PART - I
1. (B) 2. (C) 3. (A) 4.* (BC) 5. (A)
PART - II
JEE(MAIN) OFFLINE PROBLEMS
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