Page 1/8

Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 05.09.2020 Version number 3 Revision: 05.09.2020

1 Identification of the substance/mixture and of the company/undertaking

· Product identifier
· Trade name: RUCOGEN WBL
· Article number: 74034002
· Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
· Application of the substance / the mixture Textile auxiliary
· Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
RUDOLF PAKISTAN Pvt. Ltd.
W-16 Doctor's Society, Canal
Bank, Lahore, Pakistan.
Tel.: +92 42 3751 0231-7
Fax.: +92 42 3751 0238
e-mail: [email protected]
· Further information obtainable from: Product safety department
· Emergency telephone number: +92 303 333 6937

2 Hazards identification
· Classification of the substance or mixture

corrosion

Eye Dam. 1 H318 Causes serious eye damage.

Skin Irrit. 2 H315 Causes skin irritation.

Acute Tox. 5 H303 May be harmful if swallowed.
· Classification according to Directive 67/548/EEC or Directive 1999/45/EC
Xi; Irritant
R38-41: Irritating to skin. Risk of serious damage to eyes.
· Information concerning particular hazards for human and environment:
When sprayed the respiratory tracts may be irritated by aerosol drops.
The product has to be labelled due to the calculation procedure of the "General Classification guideline for
preparations of the EU" in the latest valid version.
· Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and literature
data.
· Label elements
· GHS label elements
The product is classified and labelled according to the Globally Harmonised System (GHS).
(Contd. on page 2)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 05.09.2020 Version number 3 Revision: 05.09.2020

Trade name: RUCOGEN WBL

(Contd. of page 1)
· Hazard pictograms

GHS05

· Signal word Danger

· Hazard statements
May be harmful if swallowed.
Causes skin irritation.
Causes serious eye damage.
· Precautionary statements
Wear protective gloves / eye protection / face protection.
Wash thoroughly after handling.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
Immediately call a POISON CENTER/doctor.
Specific treatment (see on this label).
If skin irritation occurs: Get medical advice/attention.
· Information concerning particular hazards for human and environment:
When sprayed the respiratory tracts may be irritated by aerosol drops.
The product has to be labelled due to the calculation procedure of the "General Classification guideline for
preparations of the EU" in the latest valid version.
· Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.

3 Composition/information on ingredients
· Chemical characterisation: Mixtures
· Description:
Preparation of:
Nonionic surfactants
Solvents
· Dangerous components:
nonionic surfactants (polymers) 15-20%
Xi R36/38
R52/53
Skin Irrit. 2, H315; Eye Irrit. 2A, H319; Aquatic Acute 3, H402; Aquatic Chronic 3,
H412
69011-36-5 fatty alcohol ethoxylate 25-50%
Xn R22; Xi R41
Eye Dam. 1, H318; Acute Tox. 4, H302
111-46-6 2,2'-oxybisethanol 1-5%
Xn R22
STOT RE 2, H373; Acute Tox. 4, H302
34590-94-8 (2-methoxymethylethoxy)propanol 1-5%
Flam. Liq. 4, H227
(Contd. on page 3)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 05.09.2020 Version number 3 Revision: 05.09.2020

Trade name: RUCOGEN WBL

(Contd. of page 2)
· Additional information: For the wording of the listed hazard phrases refer to section 16.

4 First aid measures

· Description of first aid measures
· General information:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48
hours after the accident.
By continuous complaints consult a doctor.
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact: Immediately wash with water and soap and rinse thoroughly.
· After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.
· After swallowing:
Call for a doctor immediately.
Rinse out mouth and then drink plenty of water.
Do not induce vomiting.
Never give anything by mouth to an unconscious person.
· Information for doctor:
· Most important symptoms and effects, both acute and delayed No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.

5 Firefighting measures
· Extinguishing media
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· Special hazards arising from the substance or mixture
In case of fire, the following can be released:
Nitrogen oxides (NOx)
Carbon monoxide (CO)+ Carbon dioxide (CO2)
Under certain fire conditions, traces of other toxic gases cannot be excluded.
· Advice for firefighters
· Protective equipment: Wear self-contained respiratory protective device.
· Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.

6 Accidental release measures

· Personal precautions, protective equipment and emergency procedures
Keep people at a distance and stay on the windward side.
Particular danger of slipping on leaked/spilled product.
Refer to protective measures listed in sections 7 and 8.
· Environmental precautions: Do not allow to enter sewers/ surface or ground water.
· Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
· Reference to other sections
See Section 7 for information on safe handling.
(Contd. on page 4)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 05.09.2020 Version number 3 Revision: 05.09.2020

Trade name: RUCOGEN WBL

(Contd. of page 3)
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

7 Handling and storage

· Handling:
· Precautions for safe handling Keep receptacles tightly sealed.
· Information about fire - and explosion protection: No special measures required.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: Use polyolefine receptacles.
· Information about storage in one common storage facility: Pay attention to official rules regarding storage.
· Further information about storage conditions: Protect from frost.
· Recommended storage temperature: 5-30 °C
· Storage stability Storage period: Stable for at least 6 month if stored properly in originally closed containers.
· Specific end use(s) No further relevant information available.

8 Exposure controls/personal protection

· Additional information about design of technical facilities: No further data; see item 7.
· Control parameters
· Ingredients with limit values that require monitoring at the workplace:
34590-94-8 (2-methoxymethylethoxy)propanol
IOELV (EU) Long-term value: 308 mg/m³, 50 ppm
Skin
· Additional information: The lists valid during the making were used as basis.
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Do not inhale gases / fumes / aerosols.
Avoid contact with the eyes and skin.
· Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure
use self-contained respiratory protective device.
· Recommended filter device for short term use: A/P2
· Protection of hands: Not required.
· Material of gloves
Nitrile rubber, NBR
Butyl rubber, BR
Recommended thickness of the material: ≥ 0.4 mm
· Penetration time of glove material Value for the permeation: Level ≤ 6 (480 min)
· As protection from splashes gloves made of the following materials are suitable:
Butyl rubber, BR
Nitrile rubber, NBR
(Contd. on page 5)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 05.09.2020 Version number 3 Revision: 05.09.2020

Trade name: RUCOGEN WBL

(Contd. of page 4)
· Eye protection:

Tightly sealed goggles

· Body protection: Protective work clothing

9 Physical and chemical properties

· Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Fluid
Colour: Clear
-
Cloudy
Colourless
· Odour: Weak, characteristic
· pH-value at 20 °C: ca. 8
· Change in condition
Melting point/freezing point: ca. 0 °C
Initial boiling point and boiling range: ca. 100 °C
· Flash point: > 100 °C
· Auto-ignition temperature: Product is not selfigniting
· Explosive properties: Product does not present an explosion hazard
· Vapour pressure at 20 °C: ca. 23 hPa
· Density at 20 °C: ca. 1,02 g/cm³
· Solubility in / Miscibility with
water: Fully miscible
· Viscosity:
Kinematic at 20 °C: ca. 130 s (DIN 53211/4)
· Other information No further relevant information available.

10 Stability and reactivity

· Reactivity See chapter 10.3 "possibility of hazardous reactions"
· Chemical stability The product is stable under normal conditions.
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· Possibility of hazardous reactions
No hazardous reactions when stored and handled according to prescribed instructions.
· Conditions to avoid No further relevant information available.
· Incompatible materials: Reactions with strong oxidising agents.
· Hazardous decomposition products: None, if handled according to order.
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 05.09.2020 Version number 3 Revision: 05.09.2020

Trade name: RUCOGEN WBL

(Contd. of page 5)

11 Toxicological information
· Information on toxicological effects
· Acute toxicity
· LD/LC50 values relevant for classification:
Oral LD-50 > 2000 mg/kg (Rat)
· Primary irritant effect:
· Serious eye damage/irritation Strong irritant with the danger of severe eye injury.
· Respiratory or skin sensitisation No sensitising effects known.
· Additional toxicological information:
The product has not been tested. The information is derived from the properties of the individual components.
When sprayed in inadequately ventilated places, the aerosol drops may seriously irritate the respiratory tract!
Therefore it is absolutely necessary to strictly observe the instructions of chapter (para) 8.

12 Ecological information
· Toxicity
· Aquatic toxicity:
LC-50 > 10 mg/l (Vertebrata)
· Persistence and degradability No further relevant information available.
· Method OECD 302 B
· Analysing method DOC decrease
· Degree of elimination: > 80 %
· Classification: Readily eliminable from water
· Behaviour in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Ecotoxical effects:
· Behaviour in sewage processing plants:
EC-50 > 1900 mg/l (activated sludge)
Elimination > 80 % (OECD 302 B)
· Additional ecological information:
· COD-value: 1360 mg/g
· BOD5-value: 290 mg/g
· AOX-indication: Product does not contain any organic bound Halogens which could lead to AOX-values.
· According to the formulation contains the following heavy metals and compounds from the EU guideline
NO. 2006/11/EC:
The product does not contain heavy metals in waste water relevant concentrations.
· General notes:
The ecotoxic effect of the product has not been tested. The information on this was derived from products of
similar structure or composition.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.
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(Contd. on page 7)

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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 05.09.2020 Version number 3 Revision: 05.09.2020

Trade name: RUCOGEN WBL

(Contd. of page 6)

13 Disposal considerations
· Waste treatment methods
· Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
After prior treatment product has to be disposed of in an incinerator for hazardous waste adhering to the
regulations pertaining to the disposal of particularly hazardous waste.
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.
· Recommended cleansing agents: Water, if necessary together with cleansing agents.

14 Transport information
· UN-Number
· ADR, ADN, IMDG, IATA Void
· UN proper shipping name
· ADR, ADN, IMDG, IATA Void
· Transport hazard class(es)
· ADR, ADN, IMDG, IATA
· Class Void
· Packing group
· ADR, IMDG, IATA Void
· Environmental hazards: Not applicable.
· Special precautions for user Not applicable.
· Transport in bulk according to Annex II of Marpol
and the IBC Code Not applicable.
· Transport/Additional information: Not dangerous according to the above specifications.
· UN "Model Regulation": Void

15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the substance or mixture
· GHS label elements
The product is classified and labelled according to the Globally Harmonised System (GHS).
· Hazard pictograms

GHS05

· Signal word Danger

· Hazard statements
May be harmful if swallowed.
Causes skin irritation.
Causes serious eye damage.
(Contd. on page 8)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 05.09.2020 Version number 3 Revision: 05.09.2020

Trade name: RUCOGEN WBL

(Contd. of page 7)
· Precautionary statements
Wear protective gloves / eye protection / face protection.
Wash thoroughly after handling.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
Immediately call a POISON CENTER/doctor.
Specific treatment (see on this label).
If skin irritation occurs: Get medical advice/attention.
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
· Relevant phrases
H227 Combustible liquid.
H302 Harmful if swallowed.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H373 May cause damage to organs through prolonged or repeated exposure.
H402 Harmful to aquatic life.
H412 Harmful to aquatic life with long lasting effects.
R22 Harmful if swallowed.
R36/38 Irritating to eyes and skin.
R41 Risk of serious damage to eyes.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
· Department issuing SDS: Product safety department
· Contact: Product safety
· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Flam. Liq. 4: Flammable liquids – Category 4
Acute Tox. 4: Acute toxicity – Category 4
Acute Tox. 5: Acute toxicity – Category 5
Skin Irrit. 2: Skin corrosion/irritation – Category 2
Eye Dam. 1: Serious eye damage/eye irritation – Category 1
Eye Irrit. 2A: Serious eye damage/eye irritation – Category 2A
STOT RE 2: Specific target organ toxicity (repeated exposure) – Category 2
Aquatic Acute 3: Hazardous to the aquatic environment - acute aquatic hazard – Category 3
Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3
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