Chemlok 6100

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MATERIAL SAFETY DATA SHEET

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION


Product name: CHEMLOK 6100(HR)
Product Use/Class: ADHESIVE

TRANSPORTATION EMERGENCY:
LORD CORPORATION CHEMTREC 24 HR EMERGENCY NO.
111 LORD DRIVE 800 424-9300
CARY, NC 27511-7923 (Outside Continental U.S. 703 527-3887)

NON-TRANSPORTATION EMERGENCY:
INFORMATION TELEPHONE: 814 763-2345
814 868-0924

EFFECTIVE DATE: 01/30/2012

2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS Number Weight % ACGIH TLV- ACGIH TLV- OSHA PEL- OSHA PEL- Skin
Less Than TWA STEL TWA CEILING
Xylene 1330-20-7 65.0 % 100 ppm 150 ppm 435 mg/m3 N.E. N.A.
100 ppm
Ethyl benzene 100-41-4 15.0 % 20 ppm N.E. 435 mg/m3 N.E. N.A.
100 ppm
Nitrogen substituted PROPRIETARY 10.0 % N.E. N.E. N.E. N.E. N.A.
aromatic

Zinc compound PROPRIETARY 5.0 % N.E. N.E. N.E. N.E. N.A.


Carbon black 1333-86-4 5.0 % 3 mg/m3 N.E. 3.5 mg/m3 N.E. N.A.

N.A. - Not Applicable, N.E. - Not Established, S - Skin Designation

3. HAZARDS IDENTIFICATION
*** EMERGENCY OVERVIEW ***: Black Liquid, with Solvent odor. Flammable liquid and vapor. Vapor
harmful; may affect the brain or nervous system causing dizziness, headache or nausea. Harmful if swallowed. May
cause respiratory tract irritation. May cause skin and eye irritation.

EFFECTS OF OVEREXPOSURE - EYE CONTACT: May cause eye irritation.

EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May cause skin irritation. May cause dermatitis.

EFFECTS OF OVEREXPOSURE - INHALATION: May cause central nervous system depression characterized
by the following progressive steps: headache, dizziness, staggering gait, confusion, unconsciousness or coma. In
elevated-temperature applications, product may release vapors that may produce cyanosis in the absence of sufficient
ventilation or adequate respiratory protection. Possible irritation of the respiratory system can occur causing a variety of
symptoms such as dryness of the throat, tightness of the chest, and shortness of breath.

EFFECTS OF OVEREXPOSURE - INGESTION: Harmful if swallowed. Ingestion is not an expected route of


entry in industrial or commercial uses.

EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: May cause liver or kidney damage. May affect the
gastrointestinal system. May affect the blood and blood-forming organs. Repeated or prolonged solvent overexposure
may result in permanent central nervous system damage. Prolonged or repeated contact may result in dermatitis.
Ethylbenzene has been classified by IARC as a possible human carcinogen (Group 2B) and reported by NTP to show
clear evidence for carcinogenicity in animals. IARC has designated carbon black as Group 2B - inadequate evidence for
carcinogenicity in humans, but sufficient evidence in experimental animals. The nitrogen substituted aromatic in this
300000001230
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Product: CHEMLOK 6100(HR), Effective Date: 01/30/2012
product gave positive results for mutagenicity in an Ames Assay study while two other mutagenicity studies proved
negative.

PRIMARY ROUTE(S) OF ENTRY: Skin Contact, Inhalation, Ingestion, Eye Contact

4. FIRST AID MEASURES


FIRST AID - EYE CONTACT: Flush eyes immediately with large amount of water for at least 15 minutes holding
eyelids open while flushing. Get prompt medical attention.

FIRST AID - SKIN CONTACT: Flush contaminated skin with large amounts of water while removing contaminated
clothing. Wash affected skin areas with soap and water. Get medical attention if symptoms occur.

FIRST AID - INHALATION: Move person to fresh air. Restore and support continued breathing. If breathing is
difficult, give oxygen. Get immediate medical attention.

FIRST AID - INGESTION: If swallowed, do not induce vomiting. Give victim one or two glasses of water or milk.
Call a physician or poison control center immediately for further instructions. Never give anything by mouth if victim is
rapidly losing consciousness, unconscious or convulsing.

5. FIRE-FIGHTING MEASURES
FLASH POINT: 81 °F, 27 °C LOWER EXPLOSIVE LIMIT (%): 1 %(V)
Tagliabue Closed Cup UPPER EXPLOSIVE LIMIT (%): 7 %(V)

AUTOIGNITION TEMPERATURE: N.D.

EXTINGUISHING MEDIA: Carbon Dioxide, Dry Chemical, Foam, Water Fog

UNUSUAL FIRE AND EXPLOSION HAZARDS: Flammable liquid and vapor. Keep containers tightly closed.
Isolate from heat, electrical equipment, sparks, open flame, and other sources of ignition. Closed containers may rupture
when exposed to extreme heat. Use water spray to keep fire exposed containers cool. WARNING: Due to the
combustible nature of the dried film of this product and the potential for smoldering or fire, the accumulation and
buildup of the dried film on spray booth walls and floors, spindles, fixtures and other surfaces should be avoided, and
any buildup should be removed. Keep the dried film accumulations away from sparks, friction, impact, high heat (>235
F/>112 C) or other sources of ignition. These conditions could cause the dried film to ignite very readily and quickly,
and the resulting smoldering or fire may be difficult to extinguish. During removal of accumulation/buildup of this
product, take precautions to avoid heat, friction and impact during the cleaning process. Use paint stripper, brass brush,
or plastic scraper for cleaning. In the event of smoldering or a fire involving the dried product, Cold Fire®** fire
suppressing agent is preferred as the extinguishing medium. If Cold Fire® is not available, use water spray as the
extinguishing medium. Take efforts to ensure that these agents reach the base of the smoldering or fire. Lord
Corporation will not be responsible for personal injuries, property damage or any other damages arising from the
accumulation (buildup, cleaning/removal or any related smoldering or fire) resulting from the use of this product. Refer
to the Chemlok® Safe Handling Guide for additional information. **NOTE: LORD Corporation has determined Cold
Fire® fire suppressing agent to be effective in extinguishing fires involving dried Chemlok® adhesives. LORD does not
recommend any particular equipment or system for use in delivering or applying Cold Fire® products. Customer is
responsible for determining that Cold Fire® products and any delivery equipment or system is appropriate and effective
for customer's specific needs. During a fire, irritating and/or toxic gases and particulate may be generated by thermal
decomposition or combustion.

SPECIAL FIREFIGHTING PROCEDURES: Wear full firefighting protective clothing, including self-contained
breathing apparatus (SCBA). Water spray may be ineffective. If water is used, fog nozzles are preferable.

6. ACCIDENTAL RELEASE MEASURES


STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Keep non-essential personnel a
safe distance away from the spill area. Remove all sources of ignition (flame, hot surfaces, and electrical, static or
frictional sparks). Use self-contained breathing equipment. Notify appropriate authorities if necessary. Contain and
remove with inert absorbent material and non-sparking tools. Avoid contact. Avoid breathing vapors. Before attempting

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Product: CHEMLOK 6100(HR), Effective Date: 01/30/2012
cleanup, refer to hazard caution information in other sections of the MSDS form. See Section 5 for cautionary
information on the dried residue of this product.

7. HANDLING AND STORAGE


HANDLING: Keep closure tight and container upright to prevent leakage. Ground and bond containers when
transferring material. Avoid skin and eye contact. Wash thoroughly after handling. Avoid breathing of vapor or spray
mists. Do not handle until all safety precautions have been read and understood. Empty containers should not be re-used.
Use with adequate ventilation. Because empty containers may retain product residue and flammable vapors, keep away
from heat, sparks and flame; do not cut, puncture or weld on or near the empty container. Do not smoke where this
product is used or stored. See Section 5 for cautionary information on handling of the dried residue of this product.

STORAGE: Do not store or use near heat, sparks, or open flame. Refer to OSHA 29CFR Part 1910.106 "Flammable
and Combustible Liquids" for specific storage requirements. Store only in well-ventilated areas. Do not puncture, drag,
or slide container. Keep container closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION


ENGINEERING CONTROLS: Sufficient ventilation in pattern and volume should be provided in order to maintain
air contaminant levels below recommended exposure limits. Caution: Solvent vapors are heavier than air and collect in
lower levels of the work area. Sufficient ventilation (using explosion-proof equipment) should be provided to prevent
flammable vapor/air mixtures from accumulating.

RESPIRATORY PROTECTION: Use a NIOSH approved chemical/mechanical filter respirator designed to remove
a combination of particulates and organic vapor if occupational limits are exceeded. For emergency situations, confined
space use, or other conditions where exposure limits may be greatly exceeded, use an approved air-supplied respirator.
Observe OSHA regulations (29CFR 1910.134) for respirator use.

SKIN PROTECTION: Use neoprene, nitrile, or rubber gloves to prevent skin contact.

EYE PROTECTION: Use safety eyewear including safety glasses with side shields and chemical goggles where
splashing may occur.

OTHER PROTECTIVE EQUIPMENT: Use disposable or impervious clothing if work clothing contamination is
likely. Remove and wash contaminated clothing before reuse.

HYGIENIC PRACTICES: Wash hands before eating, smoking, or using toilet facility. Do not smoke in any
chemical handling or storage area. Food or beverages should not be consumed anywhere this product is handled or
stored. Wash thoroughly after handling.

9. PHYSICAL AND CHEMICAL PROPERTIES


ODOR: Solvent BOILING RANGE: 100 - 139 °C
APPEARANCE: Black VAPOR PRESSURE: N.D.
PHYSICAL STATE: Liquid VAPOR DENSITY: Heavier than Air
ODOR THRESHOLD: N.D. EVAPORATION RATE: Slower than n-butyl-
acetate
SOLUBILITY IN H2O: Insoluble DENSITY, LB/GL: 7.81 lb/gal
pH: N.A. VOLATILE BY WEIGHT: 77.49 %
FREEZE POINT: N.D. VOLATILE BY VOLUME: 86.03 %
COEFFICIENT OF WATER/OIL N.D.
DISTRIBUTION:

(See section 16 for abbreviation legend)

10. STABILITY AND REACTIVITY


CONDITIONS TO AVOID: High temperatures. Sources of ignition. For dried product issues, refer to Section 5 of
the MSDS, "Unusual Fire and Explosion Hazards".

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Product: CHEMLOK 6100(HR), Effective Date: 01/30/2012

INCOMPATIBILITY: Strong oxidizers, acids, bases, water.

HAZARDOUS DECOMPOSITION PRODUCTS: Decomposition due to high temperatures or a fire causes the
formation of irritating and/or toxic gases, organic vapors or fumes., Carbon dioxide, carbon monoxide, chlorine,
hydrogen chloride., Phosgene., Oxides of nitrogen.

HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur under normal conditions.

STABILITY: Product is stable under normal storage conditions.

11. TOXICOLOGICAL INFORMATION


PRODUCT LD50 (ORAL) No Data
(DERMAL) No Data
PRODUCT LC50 No Data

12. ECOLOGICAL INFORMATION


ECOLOGICAL INFORMATION: No Information

13. DISPOSAL CONSIDERATIONS


DISPOSAL METHOD: Disposal should be done in accordance with Federal (40CFR Part 261), state and local
environmental control regulations. If waste is determined to be hazardous, use licensed hazardous waste transporter and
disposal facility. Waste streams, including the dried adhesive residue, resulting from the use of this product should be
tested for RCRA characteristics, including ignitability, to determine any applicable waste classifications.

14. TRANSPORT INFORMATION


DOT PROPER SHIPPING NAME: Adhesives
DOT HAZARD CLASS: 3
SECONDARY HAZARD: None
DOT UN/NA NUMBER: 1133
PACKING GROUP: III
EMERGENCY RESPONSE GUIDE 128
NUMBER:

The listed transportation classification applies to US DOT non-bulk road shipments. It does not address regulatory
variations due to changes in package size, mode of shipment or other regulatory descriptors. For the most accurate
shipping information, refer to your transportation/compliance department.

15. REGULATORY INFORMATION


U.S. FEDERAL REGULATIONS: AS FOLLOWS -

This product is considered hazardous as defined by 29 CFR 1910.1200 (OSHA HazCom Standard.)

SARA SECTION 313


This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372.
:

Chemical Name CAS Number Weight % Less Than


Xylene 1330-20-7 65.0 %
Ethyl benzene 100-41-4 15.0 %

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Product: CHEMLOK 6100(HR), Effective Date: 01/30/2012
Zinc compound PROPRIETARY 5.0 %

TOXIC SUBSTANCES CONTROL ACT:

INVENTORY STATUS
The chemical substances in this product are on the TSCA Section 8 Inventory.

EXPORT NOTIFICATION
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if
exported from the United States:

Chemical Name CAS Number


Xylene 1330-20-7

16. OTHER INFORMATION


HMIS RATINGS - HEALTH: 2* FLAMMABILITY: 3 PHYSICAL HAZARD: 0

* - Indicates a chronic hazard; see Section 3

VOLATILE ORGANIC COMPOUNDS


Calculated: 6.05 lb/gal, 725 g/l
EPA Method 24: 6.55 lb/gal,

LEGEND: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined

DISCLAIMER
The information contained herein is, to the best of our knowledge and belief, accurate. However, since the conditions of
handling and use are beyond our control, we make no guarantee of results, and assume no liability for damages incurred
by use of this material. It is the responsibility of the user to comply with all applicable federal, state and local laws and
regulations.

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