Material Safety Data Sheet

Date of Issue 2018/8/1

MSDS No. SM-MSDS045-A
Section 1. Product & Company Identification

A. Product Name SpeedMate ATF-SP4

B. Recommended use of the chemical and restriction on use
Auto transmission fluid
C. Information of manufacturer, Supplier
○ Company
○ Company (Manufacturer) MICHANG OIL IND. CO., LTD.
241, Haeyang-ro, Yeongdo-gu, Busan, Korea
589, Sinhang-ro, Nam-gu, Ulsan, Korea
○ Company (Supplier) SK NETWORKS CO.,LTD.
○ Address 90, Namdaemun-ro, Jung-gu, Seoul 04534, Korea

○ Emergency Telephone No Plant (BUSAN) +82-51-409-5049

(ULSAN) +82-52-256-7851
Quality Assurance Team

Section 2. Hazards Identification

A. Classification
Physical·Chemical Hazards
Not classified
Health and Environmental Hazards
Not classified as hazardous
B. Label element, including precautionary statements
○ Hazard Pictogram (Symbols)
Not applicable

○ Signal word(s)
Not applicable
○ Hazard statements(s)
Not applicable
○ Precautionary statements(s)
P301+P310 : IF SWALLOWED : Immediately call a POISON CENTER or doctor/physician.
P331 : Do NOT induce vomiting.
P405 : Store locked up.
P501 : Dispose of contents/container to (in accordance with local/regional/national/international regulation).
C. Other hazard which do not result in classification
NFPA Hazard ID Health Flammability Reactivity
Distillates (petroleum) 0 1 0
hydrotreated heavy paraffinic
Lubricants Additive 1 1 0

Section 3. Composition / Information on Ingredients

Chemical identity Common name, synonym CAS No. Percentages(%) EINECS No ECL serial No
Distillates (petroleum) 64742-54-7 > 94.39 265-157-1 KE-12546
hydrotreated heavy paraffinic

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Lubricants Additive Confidential < 5.61 - -

Other Substances Words Signal CAS No. Percentages(%) EINECS No ECL serial No
Alkoxy heterocykic ether (*)1 Warning Confidential < 1.0 - -
Long chain alkaryl amine (*)1 Warning Confidential < 0.5 - -
Alkyl phosphites (*)1 Warning Confidential < 0.5 - -
Alkyl phenol (*)1 Warning Confidential < 0.5 - -
Dialkyl aryl dicarboxylate (*)1 Warning Confidential < 0.1 - -
PMA-Acrylic copolymer (*)2 No signal word None < 1.0 - -
PMA-Lubricating oil (*)2 Warning 72623-86-0 < 1.0 - KE-22620
PMA-Mineral oil (*)2 Warning 64742-79-6 < 1.0 - KE-17547
C.I. Solvent red 164 - - 92257-31-3 < 0.01 - -
(*)1 H315: Causes skin irritation.
H319: Causes serious eye irritation. Category 2A
H410: Very toxic to aquatic life with long lasting effects. Category 1
(2)1 H315: Causes skin irritation. Category 2
H412: Harmful to aquatic life with long lasting effects. Category 3
(**) Other ingredients (Trade secret) determined not to be hazardous up to 100%.

Section 4. First Aid Measures

A. Eye contact
Symptoms: slight irritation (unspecific). May cause burn in case of contact with product at high temperature.
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do so. Continue rinsing.
If irritation, blurred vision or swelling occurs and persists, obtain medical attention.
If hot product is splashed into the eye, it should be cooled immedical assessment and treatment for the casualty.
B. Skin contact
Symptoms: dry skin, irritation may arise in case of repeated or prolonged exposure.
May cause burn in case of contact with product at high temperature.
Remove contaminated clothing and footwear, and dispose of safely.
Wash affected area with soap and water.
Seek medical attention if skin irritation, swelling or redness develops and persists.
(if applicable) When using high-pressure equipment, injection of product can occur.
If high-pressure injuries occur, immediately seek professional medical attention.
Do not wait for symptoms to develop.
For minor thermal burns: Cool the burn. Hold the burned area under cold running water for at least five minutes,
or until the pain subsides.
However, body hypothermia must be avoided.
Do not put ice on the burn: Remove non-sticking garments carefully.
DO NOT attempt to remove portions of clothing glued to burnt skin but cut round them.
Seek medical attention in all cases of serious burns.
C. Inhalation
Inhalation at ambient temperature is unlikely because of the low vapour pressure of the substance.
Symptoms: irritation of the respiratory tract due to excess fume, mists or vapour exposure.
In case of symptoms arising from inhalation of fumes, mists or vapour: Remove casualty to a quiet and well
ventilated place if safe to do so if the casualty is unconscious and:
- Not breathing - ensure that there is no obstruction to breathing and give artificial respiration by trained personnel.
If necessary, give external cardiac massage and obtain medical assistance.
- Breathing: place in recovery position. Administer oxygen if necessary.
Obtain medical assistance if breathing remains difficult.
D. Ingestion
Symptoms: few or no symptoms expected. If any, nausea and diarrhea might occur.
(if applicable) Always assume that aspiration has occurred. Seek professional medical attention or send the casualty
to a hospital. Do not wait for symptoms to develop. Do not induce vomiting as there is a risk of aspiration.
Do not give anything by mouth to an unconscious person.
E. Most important symptoms/effect, acute and delayed

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 May cause slight eye and skin irritation. Not expected to be a sensitizer.
F. Indication of immediate medical attention and special treatment needed, if necessary
Treat symptomatically. Treatment of overexposure should be directed at the control of symptoms and the clinical
condition of the patient.

Section 5. Fire-Fighting Measures

A. Extinguishing media
Foam (Speccifically trained personnel only.)
Water fog (Specifically trained personnel only.)
Dry chemical powder.
Carbon dioxide.
Other inert gases (subject to regulations.)
Sand or earth.
B. Unsuitable extinguishing media
Do not use direct water jets on the burning product: they could cause splattering and spread the fire.
Simultaneous use of foam and water on the same surface is to be avoided as water destroys the foam.
C. Combustion products
Incomplete combustion is likely to give rise to a complex mixture of airborne solid and liquid particulates and gases,
including carbon monoxide and unidentified organic and inorganic compounds.
D. Protective equipment for firefighters
In case of a large fire or in confined or poorly ventilated spaces wear full fire resistant protecive clothing and
self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental Release Measured

A. General information
Stop or contain leak at the source if safe to do so. Avoid direct contact with released material. Stay upwind.
Keep non-involved personnel away from the area of spillage. Alert emergency personnel.
Except in case of small spillages, the feasibility of any actions should aways be assessed and advised,
if possible, by a trained, competent person in charge of managing the emergency.
It is recommended to eliminate all ignition sources if safe to do so (e.g. electricity, sparks, fires, flares).
If required, notify relevant authorities according to all applicable regulation.
B. Presonal protection equipment for emergency responders
Small spillages: normal antistatic working clothes are ususlly adequate.
Large spillages: full body suit of chemically resistant and antistatic materrial.
Work gloves providing adequate chemical resistance, specifically to aromatic hydrocarbons.
Note: gloves made of PVA are not water-resistant, and are not suitable for emergency use. Work helmet.
Antistatic non-skid safety shoes or boots. Goggles or face shield, if splashes or contact with eyes is possible or
anticipated. Respiratory protection will be necessary only in special case (e.g. formation of mists).
A half or full-face respirator with combined dust/organic vapour filter(s), or a Self-Contained Breathing
Apparatus (SCBA) can be used according to the extent of spill and predictable amount of exposure. If the situation
cannot be completely assessed, or if an oxygen deficiency is possible, only SCBA's should be used.
C. Land spillage
Prevent product from entering sewers, rivers, waterways or other bodies of water.
If necessary dike the product with dry earth, sand or similar non-combustible materials.
Large spillages may be cautiously coveded with foam, if avaiable, to limit fire risk. Do not use direct jets.
When inside buildings or confined space, ensure adequate ventilation.
Absorb spilled product with suitable non-combustible materials. Collect free product with suitable means.
Transfer collected product and other contaminated materials to suitable tanks or containers for recycle, recovery or
safe disposal. In case of soil contamination, remove contaminated soil for remediation or disposal according to
local regulations.
D. Spillages in water or at sea
In case of small spillages in closed water (i.e. ports), contain product with floating barriers or other equipment.
Collect spilled product by absorbing with specific floating absorbents. If possible, large spillages in open water
should be contained with floating barriers or other mechanical means. If this not possible, control the spreading

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 of the spillage, and collect the product by skimming or other suitable mechanical means.
The use of dispersants should be advised by an expert, and, if required, approved by local authorities. Collect
recovered product and other contaminated materials in suitable tanks or containers for recovery or safe disposal.
E. Additional information
Recommended measures are based on the most likely spillage scenarios for this material: however, local
conditions (wind, air temperature, wave/current direction and speed) may significantly influence the choice of
appropriate actions. For this reason, local experts should be consulted when necessary. Local regulations may
also proscribe or limit actions to be taken.

Section 7. Handling and Storage

A. General information
Ensure that all relevant regulations regarding handling and storage facilities of combustible products are followed.
It is recommended to keep away from sparks/open flames/hot surface. No smoking. Use and store only outdoors
or in a well-ventilated area. Avoid contact with the product. Avoid release to the environment.
B. Handling
Take precautionary measuree against static electricity. Avoid splash filling of bulk volumes when handling hot
liquid product. Avoid contact with skin. Avoid breathing fume/mist. Prevent the risk of slipping.
Use personal protective equipment as required. For more information regarding protective equipment and
operational conditions for a substance which is classified according to classification notes, see exposure scenarios.
These risk management measures represent a worst case. For a non-classified substance proportionate information
may be found in the Safety Data Sheet.
B. Storage
Storage area layout, tank design, equipment and operating procedures must comply with the relevant European,
national or local legislation. Storage in stallations should be designed with adequate bunds so as to prevent ground
and water pollution an case of leaks or spills. Cleaning, inspection and maintenance of internal structure of storage
tanks must be done only by properly equipped and qualified personnel as defined by national, local or company
regulations. Store separately from oxidizing agents.
C. Recommended and unsuitable materials for storage
Recommended materials: For containers, or container linings use mild steel, stainless steel.
Unsuitable materials: Some synthetic materials may be unsuitable for containers or container linings depending on
the material specification and intended use. Compatibility should be checked with the manufacturer.
D. Container advice
If the product is supplied in containers:
Keep only in the original container or in a suitable container for this kind of product.
Keep containers tightly closed and properly labeled.
Empty containers may contain combustible product residues.
Do not weld, solder, drill, cut or perform similar operations unless they have been properly cleaned.
E. Hygiene measures
Ensure that proper housekeeping measures are in place. Contaminated materials should not be allowed to
accumulate in the workplaces and should never be kept inside the pockets. Keep away from food and beverages.
Do not eat, drink or smoke when using this product. Wash the hands thoroughly after handling.
Change contaminated clothes at the end of working shift.
F. Load/ Unload temperature
℃ Ambient
G. Storage temperature
℃ Ambient

Section 8. Exposure Controls / Personal Protection

A. Exposure limit
TLV/TWA TLV/STEL
5 ㎎/㎥ mist 10 ㎎/㎥ mist
B. Engineering controls
Ventilation equipment should be explosion-resistant if explosive concentrations of material are present.
Ensure compliance with applicable exposure limits.

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 Provide an emergency eye wash fountain and quick drench shower in the immediate work area.
C. Respiratory protection
No special respiratory protection is normally required.
Under conditions of frequent use or heavy exposure, respiratory protection may be needed.
○ Eye protection
Normal industrial eye protection practices should be employed.
○ Skin protection
Wear suitable gloves to avoid direct skin contact.

Section 9. Physical and Chemical Properties

A. Appearance (physical state, color etc) Clear red liquid

B. Odor Mild petroleum odor
C. Odor threshold Not established
D. pH Not applicable
E. Melting point / freezing point Not established
F. Initial boiling point and boiling range 300~580℃
G. Flash point 210℃ (COC)
H. Evaporation rate Not established
I. Flammability (solid, gas) Not applicable
J. Upper/Lower flammability or explosive limits Not established
K. Vapor pressure < 0.01 ㎪ at 20℃
L. Solubility Negligible (in Water)
M. Vapor density > 5 (Air=1)
N. Specific gravity 0.85 at 15/4℃
O. Partition coefficient : n-octanol / water Expected to be > 7
P. Auto-ignition temperature > 290℃
Q. Decomposition temperature Not established
R. Viscosity 25.0 ㎟/s (cSt) at 40℃
S. Molecular weight Not established

Section 10. Stability and Reactivity

A. Stability (Thermal, Light, etc)

Stable under normal temperature & pressure
B. Condition to avoid
Extreme heat
C. Incompatibility (Materials to avoid)
Strong oxidizers
D. Hazardous decomposition products
Carbon monoxide
E. Hazardous polymerization
Will not occur.

Section 11. Toxicological Information

A. Information on the likely routes of exposures

○ Inhalation exposure
May cause slight irritation.
○ Ingestion exposure
May cause diarrhea.
○ Skin / Eye exposure
May cause slight skin irritation.
B. Delayed and immediate effects and also chronic effects from shout and long term exposure
○ Acute oral toxicity
Mineral oil LD50 > 5,000 ㎎/㎏ Practically non-toxic.

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 Lubricants additive LD50 > 5,000 ㎎/㎏
PMA LD50 > 2,000 ㎎/㎏ rat
○ Acute dermal toxicity
Mineral oil LD50 > 5,000 ㎎/㎏ Practically non-toxic.
Lubricants additive LD50 > 5,000 ㎎/㎏
PMA LD50 > 2,000 ㎎/㎏ rabbit
○ Acute inhalation toxicity
Mineral oil LC50 > 5.0 ㎎/ℓ Practically non-toxic.
Lubricants additive LC50 > 50 ㎎/ℓ
PMA LC50 > 1~5 ㎎/ℓ rabbit
○ Skin irritation
Mineral oil Either only weakly irritating or not irritating to the skin of rabbits and humans.
○ Eye irritation
Mineral oil Practically non-irritating.
○ Corrosivity
Mineral oil No corrosive action of this substance is expected.
○ Skin sensitization
Mineral oil This substance is not considered to be dermal sensitizer.
○ Respiratory sensitization
Mineral oil This substance is not expected to cause respiratory sensitization.
○ Repeat dose toxicity
Mineral oil Sub-chronic repeat dose dermal : NOAEL 1,000 ㎎/㎏
Sub-chronic repeat dose inhalation : NOAEL (local effects) > 220 ㎎/㎏
and NOAEL (systemic effects) > 980 ㎎/㎥
This substance is not classified for repeat-dose toxicity.
○ Mutagenicity
Mineral Oil This substance was found to be non-mutagenic.
○ Carcinogenicity
Mineral oil The DMSO extract by IP346 of this substance is less than 3%. (Typical 0.2%
with Maximum 0.5%). Consequently it is not classified as a carcinogen.
○ Toxicity for reproduction
Mineral oil Reproductive toxicity dermal NOAEL (development) > 2,000 ㎎/㎏.
This substance showed no effects on reproductive parameters.
○ Aspiration hazard :
Mineral oil No data available.
C. Numerical measures of toxicity (such as acute toxicity estimate)
Mineral oil No data available.

Section 12. Ecological Information

A. Ecotoxicity
Mineral oil Acute aquatic invertebrate EL50 > 10,000 ㎎/ℓ
Acute aquatic algae NOEL > 100 ㎎/ℓ
Acute fish LL50 > 100 ㎎/ℓ
Long-term invertebrate NOEL > 10 ㎎/ℓ
Long-term fish NOEL > 10 ㎎/ℓ
Alkyl phosphites Toxicity to fish
LC50 > 0.01~0.1 ㎎/ℓ
PMA LC50 > 1~10 ㎎/ℓ
B. Persistence and degradability Biodegradability
Mineral oil No data is available on the product itself.
C. Bioaccumulative potential
Mineral oil No data is available on the product itself.
D. Mobility in soil
Mineral oil No data is available on the product itself.
E. Environmental fates

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 Thos material is not expexted to present any environmental problems other than those associated with oil spills.

Section 13. Disposal Considerations

This product is a controlled waste. Collect and dispose of waste product at an authorized facility, in conformance
with national and local regulations, and in accordance with EEC Directives on the disposal of waste oil.

Section 14. Transport Information

Not classified as a dangerous good under transport regulations.
A. UN number
UN number Not applicable.
IATA UN number Not applicable.
IMDG UN number Not applicable.
ADN UN number Not applicable.
RID UN number Not applicable.
B. UN proper shipping name
Proper shipping name Not applicable.
IATA Proper shipping name Not applicable.
IMDG Proper shipping name Not applicable.
ADN Proper shipping name Not applicable.
RID Proper shipping name Not applicable.
C. Transport hazard class(es)
ADR Not applicable.
IATA UN classification Not applicable.
IMDG UN classification Not applicable.
ADN UN classification Not applicable.
RID UN classification Not applicable.
D. Packaging group
Packing group Not applicable.
IATA Packing group Not applicable.
IMDG Packing group Not applicable.
ADN Packing group Not applicable.
RID Packing group Not applicable.
E. Enviromental hazardsChemical name
Dangerous for the environment No
Marine pollutant Applicable
Other information No supplementary information available.
F. Special precautions for user Transport containers without causing any significant friction or shaking.
Overland transport Not applicable.
Transport by sea Not applicable.
Air transport Not applicable.
Rail transport Not applicable.
G. Transport in bulk according to Annex II of Marpol and the IBC Code
Not applicable.
H. Chemical name Not applicable. Not classified as dangerous for transport.
I. Class Not applicable. Not classified as dangerous for transport.
J. Classification code Not applicable. Not classified as dangerous for transport.
K. EmS number Not applicable. Not classified as dangerous for transport.
L. Labels Not applicable. Not classified as dangerous for transport.
M. Remark None

Section 15. Regulatory Information

A. Governmental inventory status

Distillate, hydrotreated light/heavy paraffines is listed on the following inventories:
EINECSS (European Inventory of Existing Commercial Chemical Substances), June 15, 1991

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 TSCA (US, Toxic Substances Control Act), December, 2006
AICS (Australian Inventory of Chemical Substances), June, 1996
DSL (Canadian Domestic Substanes List), January 26, 1991
IECSC (Chinese Chemical Inventory)
ENCS (Japanese Existing and New Chemical Substances)
ECL (Korea Existing Chemical Number), January, 1997
PICCS (Philippine Inventory of chemicals and Chemical Substances), 2000
NZIoC (New Zealand Inventory of Chemicals), 2006
SWISS (Swiss Giftliste 1 and Inventory of Notified New Substances)
B. US EPA SARA TITLE Ⅲ
Hazardous components CAS# Sec.302 Sec.313 Sec.110
(Chemical name)
Distillate (petroleum) 64742-54-7 No No No
hydrotreated heavy paraffinic
**SARA (Superfund Amendments and Reauthorization Act of 1986)
Sec.302: EPA SARA Title Ⅲ Section 302 Extremely Hazardous Chemical.
Sec.313: EPA SARA Title Ⅲ Section 313 Toxic Release Inventory.
Sec.110: EPA SARA Title Ⅲ Superfund Site Priority Contaminant List.
C. US EPA CAA, CWA
Hazardous components CAS# EPA CAA EPA CWA CA PROP 65
(Chemical name) NPDES
Distillate (petroleum) 64742-54-7 No No No
hydrotreated heavy paraffinic
** Other Important Lists:
CWA NPDES: EPA Clean Water Act NPDES Permit Chemical
CAA HAP: EPA Clean Air Act Hazardous Air Pollutant
CAA ODC: EPA Clean Air Act Ozone Depleting Chemical
CA PROP 65: California Proposition 65

Section 16. Other Information

A. Sources of key data

The recommendations presented in this Material Safety Data Sheet were complied from actual test data when
available, comparison with similar products, component information from suppliers and from recognized codes
of good practice.
The data and recommendation presented herein are based on our research and the research of others, and are
believed to be accurate. No guarantee of their accuracy is made: however, and the products discussed are
distributed without warranty, express or implied, and the person receiving them small make his own determination
of the suitability there of for his particular purpose.
B. Originated data 2018/8/1
C. Revision number and date
Revision number 00
st
1 revision data -

D. Remark

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