Adsorption at Solid Interface

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Hdsorption a Sad TntenJa

Dr. Parjanya Shuhla


numby of dhugs such as Dr. M. P.
&
Singh Clases

dys, alkaloids aty ouids and orgonic


auds and bass

Cabablu o geting adsorbd from soluhons


onto soidssuch as alumin o 0
charroal

Tk adsorphion soli'ds
on
t a unchion
ulahive odhophion soluBs and salunt
aund
Tinu plu oAdsorphon b-me
By- Sing
m.P.S i n g

trundich Adhorphion_Taoham adsoYbent.

trunduch propozad a sulaion inth om o


mahamakcal Rauahion -
and
k pn Cun vad graph abtainad
m
agalnst um and P
umut D= mas ogas adhorbad
m mas o adhorbe nt
P TAAUTL
k and n Contant. depends on nakure gas
on tempeYature.

Tak'ng Jog on bok sida

oq =m log k +Ln dog P Shaight bint abtauinrd


agonst Jog m and
angmuir Adsorphion LAothu m
Dr. Parjanya Shukla

Langmur ( 1916) dalvid a inothem Dr. M. P. Singh Classes

Asumphons-
() Th douea o o gas absorhad on ts Auya o
Solud adAor.hund ont molu ul Ec
(U) TK adsovhed layer is uni/om al oURL Hs
adsorbet
1) Tkau no interachon b/w a ad ja cent
adAovhad molsles

Devivaion
angmwr Consi derad that gas molu culus 6taikc a

Aoid &unatt and


O
f r a gas af consta
CouDud o tamTour a ds 0Tbad
bulau Naked Suau
OOOoaooOO (1-0) om malu tules 2vaporat
Ads ovben
dsOTbLd
A dynamic e9u'lbrum s estahlished b/w tuo
oppo's inq pTOCUAS AdsonpHon and Desoaphon.

4 0 is rochon o total Aufacs coud by adsorkud


mos ulls

sachon o nakd ouo ( - e )

ats d dasoxphon (,) is propovtional to

CoVeud arO &

Rd kd
Uuhu kd ib als constant fo duosphon
XTR aBs of adsosptrion (Ro) is propoional
Dr. Parjanya Shukla
to &
Dr. M. P. Singh Classea
avaulahl nakrd Auau (1-0)
and ruAUTAP gas

Ro ka (l-0) P
wh Ka
o is ats Constont for odsophon þrou
A2qulibium
Ras o desophon = Rats of adsorpion
=ka (1- 6) P
kd & KaP ko P@

Kd+Ka P ka P
kd + Ko P) Ka P

koP
kd + kaP
Sdi'vid ight Aidls oquahen toilk kd

ka/ku)P
ká/t P

KP
+ KP

uhev K is oquilibium tonstanB callud-AdsorpHon


COu'ant

xTK amount o gas adaoxbad pon qyom od adaorbank, x,


roporhenmad G
KP
14KP Dr. Parjanya Shukla
&
Dr.M.P.Singh Classe
= K KP
1+KP

is ts ong m.ui Adsonphom Botkum

gve ulahon b/w amount gas adsovbad

to prUT ogas
at tonstant temptrrakur

Appicahons Adsoprion By- Dr. M.P. Singh

() Adsovphon opoisonows gasos af Auyaa omask

) hoduchon o high vacuum


J
3) Kemoval colowwing matr Yom Aalukons.

4) avenhon o adaorphion
to Control moisturu
oku Kumidity. in midiune by
silico ga
6 AdAorphon o Coalyst on tactants in ordar o
ImCYL0 K Ha o ach'on

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