Module 2
Module 2
Module 2
(ME 3803)
Types of Plastics
Plastics can be divided into two major categories:
1. Thermoset or thermosetting plastics.
• Once cooled and hardened, these plastics retain their shapes and cannot return to their original form. They
are hard and durable.
• Thermosets can be used for auto parts, aircraft parts and tires.
• Examples include polyurethanes, polyesters, epoxy resins and phenolic resins.
2. Thermoplastics.
• Less rigid than thermosets, thermoplastics can soften upon heating and return to their original form.
• They are easily molded and extruded into films, fibers and packaging.
• Examples include polyethylene (PE), polypropylene (PP) and polyvinyl chloride (PVC).
Thermoset or Thermosetting Plastics
Classes of Thermosetting Plastics
• Polyurethane Plastics :-
• Polyurethane is the only plastic which can be made in both rigid and flexible foams.
• The flexible polyurethane foam is used in mattresses, carpets, furniture etc.
• The rigid polyurethane foam is used in chair shells, mirror frames and many more.
• Due to the property of high elasticity, some polyurethane plastics are used in decorative and protective coatings.
• The high elasticity makes these polyurethane plastics resistant to a chemical attack.
• Epoxy
• Epoxies are used in numerous ways.
• In combination with glass fibers, it is capable of producing composites that are of high strength and that are heat
resistant.
• This composite is typically used for filament wound rocket motor casings in missiles, in aircraft components, and in
tanks, pipes, tooling jigs, pressure vessels, and fixtures.
• Epoxies are also found in gymnasium floors, industrial equipment, sealants, and protective coatings in appliances.
• Phenolic
• Phenolic plastics are thermosetting resins used in potting compounds, casting resins, and laminating resins.
• They can also be used for electrical purposes and are a popular binder for holding together plies of wood for plywood.
Thermoplastics
Classes of Thermo-Plastics
• Vinyl Plastics
• Vinyl plastics belong to the thermoplastic group.
• Vinyl plastics are the sub-polymers of vinyl derivatives.
• These are used in laminated safety glasses, flexible tubing, molded products etc.
• Polyacrylics Plastics
• Polyacrylics belong to the group of thermoplastics.
• Polyacrylics are transparent and decorative.
• Polyacrylics plastics can be shaped in any form like the windshields for airplane.
• Polyvinyl Chloride
• Polyvinyl Chloride, commonly referred to as PVC or vinyl, was first invented in Germany around 1910.
• It didn't become a useful product in the United States, however, until the late 1920s.
• It became particularly useful during World War II when it was used as a substitute for rubber, which
was in short supply.
• Polyvinyl Chloride is resistant to abrasion and is both weather and chemical resistant.
• Today, it is commonly found in upholstery, wall coverings, flooring, siding, pipe, and even apparel. In
fact, vinyl is perhaps the best known of all plastics.
Thermoplastics
• Polyethylene Terephthalate (PETE)
• PETE is one the most recycled plastic. It finds usage in various bottles like that of soda and cooking oil, etc.
• High Density Polyethylene (HDPE)
• HDPE is generally used in detergent bottles and in milk jugs.
• Low Density Polyethylene (LDPE)
• LDPE finds its usage in dry cleaning bags, food storage containers etc.
• Polypropylene (PP)
• PP is commonly used in bottle caps and drinking straws.
• Polystyrene (PS)
• PS is used in cups, plastic tableware etc.
Some recyclable plastics
Characteristics of Plastics
❑ Mechanical properties
• Mechanical properties refer to displacement or breakage of plastic due to some mechanical change such as applying some
load.
• Mechanical properties are dependent on the temperature, force (load), and the duration of time the load is applied.
• It may also be affected by ultra-violet radiation when used outside.
❑ Thermal properties
• Thermal properties include heat resistance or combustibility.
• Thermoplastic has a larger coefficient of thermal expansion or combustibility and a smaller thermal conductivity or specific
heat than other material such as metals.
❑ Chemical properties
• Chemical resistance, environmental stress crack resistance , or resistance to environmental change are referred as
chemical properties.
• When a plastic contacts chemicals, there is some kind of change. After having a plastic in contacted with chemicals under
no stress for about a week, changes in appearance, weight and size of the plastic are examined. Such changes are
referred to as chemical properties.
❑ Electric properties
• Electric properties are also referred to as electromagnetic properties.
• Electric properties include insulation, conductivity and electro-static charges. Due to their good insulation property, plastics
are often used in electric fields.
• However, plastics do have a defect; they are easily electrified.
❑ Physical properties
• Specific gravity, index of refraction and moisture absorption are called physical properties.
• The specific gravity of the plastic is small, and it varies depending on the character of high polymer , or thermal and
mechanical treatment of the plastic.
Materials for Processing Plastics
Most Plastic resins have to be combined, compounded, or otherwise chemically treated with
processing materials before they are ready for processing.
One of the following additions are usually employed;
1. Plasticizers
2. Fillers
3. Catalyst
4. Initiators
5. Dyes and Pigments
Plasticizers
• Organic Solvents, resins, and even water are used as plasticizers.
• These substances act as internal lubricants improving flow of materials and giving toughness and
flexibility to the material
• Plasticizers are also used to prevent crystallization by keeping the chains separated from one
another.
• The most common plasticizer are, : phthalates, phosphates, carboxylic acid esters, epoxidized fatty
acid esters.
Materials for Processing Plastics
Fillers
• Typical fillers used include wood flour, asbestos fiber, glass fiber, cloth fiber, mica, slate powders
• They may be added in high proportion to many plastics essentially to improve strength, dimensional
stability and heat resistance.
Catalyst
• These are usually added to promote faster and more complete polymerization.
• As such they are also called accelerators and hardeners.
Initiators
• It is used to initiate the reaction, i.e., to allow polymerization to begin
• They stabilize the ends or reaction sites of the molecular chains.
• H2O2 is a common initiator.
Dyes and Pigments
• These are added in many cases, to color the material to different shades
Future of plastic and its application
Advantages of Plastics
Plastics of the following advantages over metals:
1. Plastics are highly flexible as compared to metals. For industries that need designing options, geometry and different kinds of textures, plastics
are going to be the most suited materials.
2. Plastics are cheaper as compared to metals. The manufacturing of plastic parts is budget-friendly.
3. Plastics are highly durable and can last for an indefinitely long period of time. Metals, on the other hand, are much more prone to chemical and
weather susceptibilities.
4. The specific gravity of plastic is much lower making it an extremely lightweight material.
5. Manufacturing of plastic is a faster process as compared to metals.
Applications of Plastics
Plastics are highly durable, lightweight and most importantly can be molded into any form or shape. These properties account for the largest usage of
plastics. Plastics are extremely versatile materials and can be used for a wide variety of purposes. Some usage of plastics are given below:
1. The ability to be moulded makes plastic an ideal packaging material. Plastics in packaging help to keep foods safe and fresh.
2. Being durable and lightweight, plastics have helped in the electronic field. From computers and cell phones to television and microwave, almost all
appliances around us make some use of plastic.
3. Plastics are used to make safety gear like helmets, goggles etc. Plastics are used in the construction industry due to their low maintenance and
high durability.
4. Plastic is strong and lightweight, that is why it is useful in making toys, electrical switches and other household products.
5. Being non-reactive with air and water, plastic is used to store water in plastic bottles and other chemicals in chemical laboratories.
6. Plastic is a poor conductor of electricity and heat. Its insulation property is used for coating the electric wire and to make handles of cooking
utensils and various household products.
Future of plastic and its application
Challenges in Using Plastics
• Plastics are typically made from resources that are non-renewable:
• Although the first materials of plastic came from fibers that were plant-based, most of the items that are
produced now have fossil fuels as their foundation.
• The majority of the pollution discovered in the world’s oceans is plastic:
• Up to 80% of all marine waste comprises plastic. This problem comes from marine and land sources, often
accumulating in large areas of open water where tides come together.
• Plastic pollution can lead to several economic losses:
• Plastic packaging pollution by itself generates an economic loss of approximately $80 billion annually to the global
economy. It makes up approximately 50% of all waste from this industry, and practically every other industry
practices the item in some way.
• Plastic products cannot be infinitely recycled:
• Metals, because of the properties of the material, can be numerous times recycled into a variety of different
products. Plastics don’t bestow that opportunity. People can only recover or reuse it a specific number of times
before it loses its integrity and quality.
• We must spend energy to clean plastics to recycle items:
• Plastics that produce cross-contamination with diverse types formulate unusable products. Before recyclers can
transform the things into new pieces, they also require to have the items cleaned.
Future of plastic and its application
Future of Plastics
As suggested by the futurist Hammond (2007) in his recent publication
• Plastics are already becoming ‘smart’ and will likely serve numerous important roles in future
living, including human tissue or even organ transplants,
• Plastics may act as key materials used in ultra-low-emission lightweight cars and aircraft.
• Plastics may be used as superior insulation for homes that run on photovoltaic technology based
on plastic collectors.
• It may be used as reusable electronic graphic media for books or magazines,
• There are plans to use plastics as smart packaging that monitors food content continuously for
signs of spoilage.
• Polymer based high-efficiency solid-state lighting organic diode technology is also under
development
• As petroleum reserves become more limited, new varieties of plastics are likely to increasingly
be made from renewable biomass.
Plastic Moulding
What is Moulding?
Moulding is a manufacturing process that involves shaping a liquid or malleable raw material by using a
fixed frame; known as either a mould or a matrix.
2. Molten Plastic:
Molten plastic acts as a medium for the creation of plastic hollow components.
3. Extruder Head:
Molten plastic has to be sent to the extruder head so that it can be passed through various other channels.
4. Air tube:
The air tube is used to pressurize the air when the molten plastic enters into the mould cavity and it is about to bulge.
5. Parison:
It is a Tubular shape of hot plastic with a hole at one end through which compressed air can pass.
6. Mould:
Mould cavity consists of patterns where molten plastic is to be deposited and solidification takes place and after solidification, final
product is obtained.
7. Air Pressure:
When the molten plastic enters from the parison into the mould cavity, air pressure is forced into the cavity such that the molten
plastic touches the mould corners and thereafter solidification takes place.
8. End Product:
Finally the end product is obtained after the solidification.
Blow Moulding
Working Principle of Blow Moulding Process:
• The Overview of all the parts of Moulding Machine is shown in the
diagram under Segment A.
• The Feed from the Extruder is given as an input into the Blow
Molding Machine. The feed or the semi-molten plastic it is to be
passed through the extruder head section and thus forming a
parison.
• The parison is a tube-like piece of plastic with a hole at one end
through which compressed air can pass. The parison is to be
passed through the mould.
• The Cope and Drag of mold are to be pressed against each other
and at the same time compressed air is to be passed from the air
tube as shown in segment B.
• By blowing high-pressure air on the soft sheet (parison), it will bend
according to the internal shape of the mold and deposit on the
internal surface of the mould and hence achieve the shape of the
component.
• By the cooling process, the product will regain its hardness.
• This is how you can get the final product in the segment C of the
figure.
• Air pressure required for common products
Water Bottles; P<1 bar
Plastic Buckets; P= 1-2 bar
Large Liquid Containers; P= 2-5 bar
Blow Moulding
Blow Moulding
Advantages
• To produce high thickness plastic parts, high blowing pressure is required.
• Fast production rate.
• Recycling can be done
• Low tool cost in the case of the Blow Moulding process.
Disadvantages
• Difficult to produce Complex geometry of the components with good dimensional accuracy.
• It can be applied only for hollow parts.
• Thick parts cannot be manufactured.
• If the shape of the mold is complex
❖ resulting distribution is non-uniform
❖ compaction of the film is non-uniform
❖ thickness is non-uniform and
❖ dimensional accuracy is low.
Applications
• By this process we can able to make:
• Water Bottles
• Plastic Buckets
• Liquid Containers
• Plastic Cups
• Mugs etc.
Compression Moulding
Compression Moulding is a moulding method in which the moulding material(especially Thermoplastics or
Thermoset plastics) is generally preheated, is placed in a mold cavity and compressed to form different
components.
• Compression Moulding Setup
Compression Moulding
Working Principle
Case 1: For Thermosetting Plastics
• In this Process, the Thermoset liquid is kept in the mould of a required shape and is subjected to the
heating process.
• During heating, the liquid will undergo the following changes i.e.
• liquid gets converted in the form of a gel,
• and by the application of pressure, it turns to solid.
• After that, the Compression load is applied at the gel condition of the liquid so that the shaping of the
component takes place.
• Heating converts the liquid into solid whereas, compression load will give the shape to the component.
Case 2: For Thermoplastics
• The molten charge is kept in the mould of the required shape and subjected to compression followed
by a cooling of the mould.
• Compression gives the shape of the component whereas cooling converts the molten liquid into solid.
• Density and the Strength of the plastic can be controlled by varying the compression load.
• Small and simple shapes of the component can be produced with uniform density.
• Larger and complex shapes of the components are difficult to produce with uniform density.
• Difficult to insert metal pieces in the plastic part during the production of the component.
Compression Moulding
Compression Moulding
Advantages
• It achieves good surface finish.
• The wastage is relatively very small.
• The initial setup cost is low.
• It can be applied to composite thermoplastics with randomly orientated fiber mat, woven fabrics etc.
• It is suitable for manufacturing large and intricate parts.
Disadvantages
• The repetitive nature of the compression molding process leads to wearing of the molds.
• This molding process is not suitable for making complex parts.
• The labor cost is higher in this molding process.
Applications
• Outer envelopes of a washing machine
• Refrigerators
• Automotive Exterior Panels
• Gaskets
• Helmets
• Automobile auto parts etc.
Extrusion Moulding
Introduction
• Extrusion is used for processing most types of thermoplastics and rubbers.
• The extrusion process is a simple process in which molten polymer is forced through a shaped die
using pressure.
• The pressure is generated from the action of screw rotation against barrel wall.