Various PV Module Technologies

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Overview of Different PV Module Technologies

By

S. P. Singh, EX- AGM


BHEL R&D – ASSCP

Workshop on solar energy technologies


at
HRDI, BHEL, Noida
June 09, 2016
Environmental loss per kWh use of electrical energy if it is
coming from coal based power plant

• ~ 1.0 Kg of CO2 is added to the atmosphere - increasing the


greenhouse effect

• Over 2.0 liters of water is evaporated

• About 5-10 gms of NOx and SO2 is added to the atmosphere

• ~ 1.0 gram of particulate matter is added causing a health


hazard
Contents of Presentation

Introduction

Silicon Based Solar Cells and Modules

Thin Film Solar Cells and Modules

Concentrator Based Solar Cells and Modules

Emerging Technologies, Flexible solar cells and Advanced


Concepts

Conclusions
Sun is a Huge Nuclear Generator functioning on fission of
hydrogen. All fossil fuels are fixed in the energy form by the
energy deposited due to sun energy
ASSCP 8
Generation of Electron Hole
Pairs with Light
• Photon enters, is absorbed,
and sends an electron from VB
to CB

• A hole is left behind in VB,


creating absorption process:
electron-hole pairs

• Because of this, only part of


solar spectrum can be
converted.

ASSCP 9
PERC/PERL(passivated
emitter rear locally
diffused),Cells
PERT(passivated emitter
rear totally diffused) have
used rear passivation
techniques utilizing a oxide
layer between the metal
and semiconductor layer.
H type Fingers
High Efficiency (~25%) Solar Cell
- Back Contact Back Junction (BCBJ) Solar Cells on
silicon wafers
1. Diffused Junction Based:

Process steps involved:


Patterning, diffusion of boron & phosphorous, growth
of SiO2, deposition of SiOx, Deposition of Metal
contact and patterning etc.
Sunpower cell
Heterojunction Silicon Solar Cells

Conventional c-Si Solar Cell Passivated Interface Heterojunction (PIHJ)/ HIT Solar Cell

Process Temperature Requirement

1000
Temperature (°C)

PI Solar Cell/ HIT


500 ARC Contact Firing
Diffusion
Conventional
Plasma a-Si Low Temp Technology
0
0 Contact
5 35 36 46 48 49
Time (minutes) 55
Bifacial Solar Module
High Efficiency (~25%) Solar Cell
- Back Contact Back Junction (BCBJ) Solar Cells on silicon
wafers

Processes Involved:
Wafer texturing, thin film deposition of amorphous silicon and indium tin
oxide, patterning, rear contact metallization etc.
Predicted Trend Curve for the Module Power
Expected share of different technologies
Thin Film Solar Cells and Modules
Interconnection is possible automatically
CIGS and CdTe Device Structure

CdTe
Glass
CTO/ZTO,SnO2
ZnO, ITO 0.2-0.5 µm
2500 Å
CdS
CdS
700 Å
600-2000 Å

CIGS
1-2.5 µm
CdTe
2-8 µm

Mo
0.5-1 µm
Glass, C-Paste
Metal Foil, with Cu,
Plastics
CIGS or Metals

CTO/ZTO = Cd2SnO4/ZnSnOx
Silicon energy band diagram
* Amorphous silicon
absorption is better due to
relaxation on wave
number requirement

ASSCP 33
ve
CONTACT
METAL (Al/ Ag)

n-a-Si H

I-a-SiH

p-a- Si H

TCO
+ ve
CONTACT

GLASS

LIGHT RAYS

Single junction amorphous silicon solar cell


ASSCP 35
Tandem Cells
Silver Grid
• Tandem cell-
– Top cell has
Indium Tin Oxide
p-a-Si:H large bandgap
– Middle cell mid
Blue Cell
i-a-Si:H

bandgap
n-a-Si:H
p
Green Cell
i-a-SiGe:H (~15%) – Bottom cell
small bandgap.
n
p
Red Cell
i-a-SiGe:H (~50%)
n
Textured Zinc Oxide

Silver
Stainless Steel Substrate

Schematic diagram of state-of-the-art a-Si:H


based substrate n-i-p triple junction cell structure.
ASSCP 37
Concentrator Based Solar Cells and Modules
A multi junction cell is fabricated with matching current.
The solar cell provides very high efficiency about 42%.
The solar cells for concentrators depends on the
concentration of radiation we want to work.
Low Medium High
concentration concentration concentration

Degree of
2 - 10 10 - 100 > 100
concentration

Dual axis
No tracking 1-axis tracking
Tracking? tracking
necessary sufficient
required

Active cooling
No cooling Passive cooling
Cooling required in
required sufficient
most instances.

Photovoltaic High- quality Multi-junction


Material silicon cells
Emerging Technologies, Flexible solar cells and Advanced
Concepts
Types of Technology:
• Amorphous Silicon
Based Power Film,
USA (4-6%)

• CdTe EMPA,
Switzerland (8-12%),
NREL, USA

• CIGS EMPA, Switzerland


(10-13%),

• NREL, USA, Organic


Solar ~6%
Flexible Solar Cells with CdTe
TCO
Fabrication CdS
• Closed Space Sublimation (CSS)
• Electrodeposition (ED) CdTe
• Magnetic sputtering (MS),
Interlayer
• High vacuum thermal evaporation
(HVE) Metallic
• Treatment by CdCl2 Substrate
• Annealing is EssentialMetal Substrate ~7-8%

Issues:
Metal
• CSS – high efficiency – high
Interlayer temperature process (~400-650 C)
• ED : Low Temperature- low
CdTe efficiency
CdS • MS – Low temperature, best
TCO efficiency on substrate structure
• HVE – Medium temperature – Low
Polymer
Substrate
efficiency
• Back contact Degradation and high
Superstrate ~13% (Polymide Films) resistance
MIT – Graphene based organic solar cell
Wonder Material Perovskite
The band gap in a
quantum dot can be tuned
by changing the size of a
quantum dot
Conclusions
Silicon Solar modules are expected to remain main
components for solar photovoltaic systems for another
decade

A lot of research is required to improve performance and


reduce cost in silicon based modules. New concepts are to be
tried to improve efficiency.

Thin film solar Cells have yet to prove their reliability in the
field. At present, They are thought to be coexist with
crystalline silicon and may cater to other niche applications.

New materials are required to be developed which can


produce high efficiency using cheaper technology and
materials .

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