Success Key Test Series Subject: Chemistry: Annual Examination

SUCCESS KEY TEST SERIES
Annual Examination
Std: 11th Science Subject: Chemistry Time: 3 Hours
Date : Sample Question Paper Max Marks: 70
Section A ( MCQ & VSA 1 MARKS Questions)
Q.1 Select and write the correct answer: 10

(i) Through separating funnel, immiscible solutions
(a) cannot be dissolved. (b) cannot be separated completely.
(c) can be easily decanted. (d) can be centrifuged.
(ii) The correct set of quantum numbers for the unpaired electron of F atom is
(a) 2, 0, 0, +1/2 (b) 2, 0, 0, +1/2 (c) 2, 1, 1, +1/2 (d) 3, 1, 1, +1/2
(iii) The angle between two covalent bonds is minimum in:
(a) CH₄ (b) C₂H₂ (c) NH₃ (d) H₂O
(iv) Consider this reaction:
3Au(s) + 8H⁺ + 2NO₃- → 3Au₂⁺(aq) + 2NO(g) + 4H₂O(l)
(a) Au(s) is reduced during the reaction.
(b) The oxidation state of nitrogen changes from +6 to +2.
(c) Hydrogen ions are oxidized when they form H₂O(l).
(d) All are false
(v) Amphoteric hydroxides react with both alkalies and acids. Which of the following Group 2 metal
hydroxide is soluble in sodium hydroxide?
(a) Be(OH)₂ (b) Mg(OH)₂
(c) Ca(OH)₂ (d) Ba(OH)₂
(vi) One mole of oxygen at 273 k and one mole of sulphur dioxide at 546 k are taken in two separate
containers, then,
(a) kinetic energy of O₂> kinetic energy of SO₂ .
(b) kinetic energy of O₂< kinetic energy of SO₂.
(c) kinetic energy of both are equal.
(d) None of these
(vii) Isotope Iron-59 is used in
(a)treatment of thyroid cancer.
(b)bone marrow function.
(c)treatment of leukemia.
(d)spleen imaging.
(viii) Which of the following compound is heterocyclic in nature?
(a) Benzene
(b) Cyclohexene
(c) Cyclobutane
(d) Piperidine
(ix) toluene is aromatic because it has
(a) 4n π electrons (b) (4n+2) π electrons
(c) non-planar geometry (d) none of these
(x) Quinones undergo polymerization giving brown colour products called_____.
(a) tannins (b) proteins (c) amino acids (d) fatty acids
Page 1 of 4
Q.2 Answer the following: 8
(i) Which is more paramagnetic Fe³⁺ or Fe²⁺?
(ii) Covalent bond is directional in nature. Justify.
(iii) The amount of energy released when 1 × 10¹° atoms of chlorine in vapour state are converted to Cl¯
(g) ion is 5.786 × 10¯⁹ J. Calculate the electron gain enthalpy of chlorine atom in kJ/mol and
ev/atom.
(iv) Name the member of group 14 that forms the most acidic oxide?
(v) What is the cause of Brownian movement?
(vi) If a stress is applied to a reaction mixture at equilibrium, then in which direction will the reaction
take place?
(vii) What is electromeric effect?
(viii) Arrange following hydrocarbons in the increasing order of acidic character.
Propane, propyne, propene.
Section B (SA I - 2 MARKS EACH)
Attempt any Eight: 16
Q.3 In two moles of acetaldehyde (CH₃CHO) calculate the following
(a) Number of moles of carbon
(b) Number of moles of hydrogen
(c) Number of moles of oxygen
(d) Number of molecules of acetaldehyde
Q.4 How many litres of oxygen at STP are required to burn completely 2.2 g of propane, C₃H₈ ?
Q.5 Never heat organic solvents with a Bunsen burner. Explain?
Q.6
Q.7 Which type of hybridization is present in ammonia molecule? Write the geometry and bond angle
present in ammonia.
Q.8 Compare chemical properties of metals and non metals.
Q.9 Write the biological importance of magnesium and calcium.
Q.10 The volume occupied by a given mass of a gas at 298 K is 25 ml at 1 atmosphere pressure. Calculate
the volume of the gas if pressure is increased to 1.25 atmosphere at constant temperature.
Q.11 Two processes which are taking place in opposite directions in equilibrium. How to write
equilibrium constant expression for heterogeneous equilibrium?
Q.12 Write the equilibrium constant expression for the decomposition of baking soda. Deduce the unit of
Kc.
Q.13 Find out the type of isomerism exhibited by the following pairs.
Page 2 of 4
Q.14 Acetone and acetaldehyde are the ozonolysis products of an alkene. Write the structural formula of
an alkene and give IUPAC name of it.
Section C (SA II - 3 MARKS EACH)

Attempt any Eight: 24
Q.15 Find the formula mass of
(i) NaCl (ii) Cu (NO₃)₂
Q.16 Write electronic configurations of Fe, Fe²⁺, Fe³⁺
Q.17
Q.18 The first ionization enthalpy values of Si, P and CI are 780, 1060 and 1255 kJ mol⁻¹ respectively.
Predict whether the first ionization enthalpy of S will be closer to 1000 or 1200 kJ mol⁻¹.
Q.19 What happens when dihydrogen react with halogens?
Q.20 Discuss the nature of bonding of compounds of group 13, 14 and 15 elements.
Q.21 With the help of graph answer the following -
At constant temperature,
(a) Graph shows relation between pressure and volume. Represent the relation mathematically.
(b) Identify the law.
(c) Write the statement of law.
Q.22 Explain Bredig's arc method.
Q.23 Explain in short homogeneous equilibrium and heterogeneous equilibrium.
Q.24 Calculate the binding energy per nucleon of ⁸⁴₃₆Kr whose atomic mass is 83.913 u. (Mass of neutron
is 1.0087 u and that of H atom is 1.0078 u).
Q.25 Write the balanced chemical reactions to get benzene from

(a) Sodium benzoate.
(b) Phenol.
Q.26 What do you meant by rancidity of oils and fats ? Explain how does it lead to rancidity.
Page 3 of 4
Section D (SA II - 4 MARKS EACH)
Attempt any Three: 12
Q.27 1. Distinguish between accuracy and precision.
2. Calculate the molarity of NaOH in the solution prepared by dissolving its 4 g in enough water to
form 250 mL of the solution.
Q.28 Explain geometry of methane molecule on the basis of Hybridisation.
Q.29 Explain structure and bonding of diborane.
Q.30 1. Which of the CH₃- CHCl₂ and CH₃CH₂Cl is expected to have stronger -I effect ?
2. Write three resonance structures for CH₃-CH = CH-CHO. Indicate their relative stabilities and
explain.
Q.31 How many monochlorination products are possible for
(a) 2-methylpropane ?
(b) 2-methylbutane ?
Draw their structures and write their IUPAC names.
-------- All the Best --------
Page 4 of 4

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SUCCESS KEY TEST SERIES

Section A ( MCQ & VSA 1 MARKS Questions)

Q.1 Select and write the correct answer: 10

Section C (SA II - 3 MARKS EACH)

Q.21 With the help of graph answer the following -

Q.22 Explain Bredig's arc method.

Q.23 Explain in short homogeneous equilibrium and heterogeneous equilibrium.

Q.25 Write the balanced chemical reactions to get benzene from

-------- All the Best --------

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