Material Safety Data Sheet For BOSS WELD ELECTRODES - 84651098. 1106, 1117, 1128

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MATERIAL SAFETY DATA SHEET FOR

BOSS WELD ELECTRODES – 84651098. 1106, 1117, 1128

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY

Product type: Electric arc welding coated electrode


Intended use: For professional use only
Trade Name: BOSS Weld Electrode
Supplier of product: The BSS Group Ltd
Registered Office: Travis Perkins PLC, Lodge Way House, Lodge Way, Harlestone Road, Northampton
NN5 7UG.
Telephone/Fax Numbers: 0116 262 3232 / 0116 253 1343
E-mail Address [email protected]
Web site Address www.bss-group.co.uk

2. HAZARD IDENTIFICATION

By delivery: Not hazardous


Risk by general use:
General: Electric shock
Inhalation: Inhalation of welding fumes may cause respiratory irritation. Cough
Skin contact: UV, IR radiations. Heat. May product skin irritation. Slag can cause burns
Eye contact: UV, IR radiations. Heat. May product eye irritation. Slag can cause burns

3. COMPOSITION/INFORMATION ON INGREDIENTS.

This product is not considered to be hazardous but contains hazardous components

Main Constituents: Value (s) % CAS No/EC No/EC Index Symbol (s) R-Phrase (s)
Iron 58 to 78 7439 / 231-096-4 /-----
Titanium Oxide 11 to 23 13463-67-7 /236-675-5 /-----
Silica (Quartz) 3.5 to 8.7 14808-60-7 / 238-878-4 / -----
Potassium Silicate 4 to 6 1312-76-1 / 215-199-1 /----- Xi 36/37/38
Manganese 1.5 to 4 7439-96-5 / 231-105-1 /-----
Calcium Carbonate 0.4 to 4.5 471-34-1 / 207-439-9 /----- Xi 36
Aluminium Oxide 0.4 to 3 1344-28-1 /215-691-6 /-----
Cellulose 0.5 to 1.5 9004-34-6 / 232-674-9
Zirconium Oxide 0.7 to 1 1314-23-4 / 215-227-2 /-----
Iron (III) Oxide up to 0.5 1309-37-1 /215-168-2 /-----
Magnesium Oxide 0.1 to 1.5 1309-48-4 / 215-171-9 / ----- Xn 22-36/37/38
Potassium Oxide 0.2 to 1.5 12136-45-7 / ----- / -----

BOSS MSDS – 008 REVIEWED: 04/03/2013 Page: 1 of 4


MATERIAL SAFETY DATA SHEET FOR
BOSS WELD ELECTRODES – 84651098. 1106, 1117, 1128
4. FIRST AID MEASURES

Inhalation: Assure fresh air breathing


Skin Contact: Stop exposure
Eye Contact: Minimise exposure to light
Ingestion: Ingestion unlikely. Rinse mouth
Electric shock: Electrical circuits must be shut off as soon as possible. Prepare to administer
resuscitation in case of cardiac or respiratory failure. In case of respiratory arrest
administer artificial respiration.
General Information: In all cases obtain medical attention. If possible show this sheet.

5. FIRE FIGHTING MEASURES

Flammable Class: The product is not flammable


Prevention: Welding hot slag or sparks may cause fire. Keep away from combustible material
Surrounding Fires: Use water spray or mist for cooling exposed containers
Protection against Fire: Wear suitable protective equipment

6. ACCIDENTAL RELEASE MEASURES

Personal Precautions: Equipment clean up crew with suitable protection


After spillage or leakage: On land sweep or shovel into suitable containers

7. HANDLING AND STORAGE:

Storage precautions: Store in a dry protected location to prevent moisture contact. Keep container closed
when not in use
Handling: Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Respiratory Protection: Do not breathe gas/fumes/vapour


In case of insufficient ventilation, wear suitable respiratory equipment
Hand Protection: Welding gloves
Skin Protection: Skin protection appropriate to the conditions of use should be provided
Eye Protection: Use mask protection with suitable filter lens
Interdiction to wear contact lens
Ingestion: When using do not eat, drink or smoke
Industrial Hygiene: Provide local exhaust or general room ventilation to minimize fume concentration

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Solid


Colour: Grey
Odour: Odourless
Melting Point ºC: ca. 1500

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MATERIAL SAFETY DATA SHEET FOR
BOSS WELD ELECTRODES – 84651098. 1106, 1117, 1128
10. STABILITY AND REACTIVITY

Stability: Stable under normal conditions (<300ºC)


Hazardous decomposition Formation of dangerous fumes during use
products:
According to process conditions, hazardous decomposition may generate. Such as:

AL₂O₃ CAS 001344-28-1 EC 215-691-6 TLV (mg/m3) 10


CO CAS 000630-08-0 EC 211-128-3 TLV (mg/m3) 29
CO₂ CAS 000124-38-9 EC 204-696-9 TLV (mg/m3) -
CaO CAS 001305-78-8 EC 215-138-9 TLV (mg/m3) 2 (Ca)
Cr CAS 007440-47-3 EC 231-157-5 TLV (mg/m3) 0.5
Fe CAS 007439-89-6 EC 231-096-4 TLV (mg/m3) 1 (insoluble)
F CAS 007789-96-5 EC 232-188-7 TLV (mg/m3) 2.5
MgO CAS 001309-48-4 EC 215-171-9 TLV (mg/m3) 10
Mn CAS 007439-98-7 EC 231-105-1 TLV (mg/m3) 0.2
Mo CAS 007439-98-7 EC 231-107-2 TLV (mg/m3) 10
Ni CAS 007440-02-0 EC 321-111-4 TLV (mg/m3) 1 (insoluble)
Ni CAS 007440-02-0 EC 231-111-4 TLV (mg/m3) 0.05 (soluble)
PbO CAS 001317-36-8 EC 215-267-0 TLV (mg/m3) 0.05
Si CAS 007440-21-3 EC 231-130-8 TLV (mg/m3) 10 (Si0₂)
SiO₂ CAS 014808-60-7 EC 238-878-4 TLV (mg/m3) 10

TiO₂ CAS 013463-67-7 EC 236-675-5 TLV (mg/m3) 10


Cr (III) CAS 012018-00-7 - TLV (mg/m3) 0.5
Cr (VI) CAS 001308-39-9 - TLV (mg/m3) 0.05
K₂O CAS 012136-45-7 - TLV (mg/m3) -

Na₂O CAS 001313-59-3 - TLV (mg/m3) 2(NaOH)


BaO CAS 001304-28-5 - TLV (mg/m3) 0.5(Ba)
Threshold Limit values – TLV-TWA given according to ACGIH
The TLV limit of the above elements is a function of the national reglementation
Hazardous Properties: Welding fumes are classified carcinogenic by the ICRC (International Centre of Research
on Cancer): Group 2B. Cancer suspect agent
Materials to Avoid: Avoid contact with acids and oxidizing agents
Other information: In case of work on parts covered by coatings such as lubricants, solvent, paint, metallic
compounds, grease etc the thermal or photochemical decompositional products of these
elements cumulate with dust and fumes emitted by melting of the welding product.
The solution to adopt must be, in any case, preceded by a spot study. Refer to the
document “Health & Safety in Welding” published by the International Institute of
Welding (IIS/IIW)

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MATERIAL SAFETY DATA SHEET FOR
BOSS WELD ELECTRODES – 84651098. 1106, 1117, 1128
11. TOXICOLOGICAL INFORMATION

Toxicological Information: This material or its emissions may induce an allergic or sensitization reaction and thereby
aggravate existing systemic disease
Acute Toxicity Overexposure to weld fumes may cause Fever, nausea, giddiness, eye irritation, irritation
to the respiratory tract and to other mucous membranes.
Chronic Toxicity
Overexposure to welding May cause pulmonary/bronchial disease and/or cause breathing difficulty
fumes:
Overexposure to Manganese This material to its emissions may attack the nervous system and/or aggravate pre-existing
(MN): disorders.

Quartz inhalation: May cause lung damage. May cause cancer.

12. ECOLOGICAL INFORMATION

This product contains no hazardous components for the environment. Avoid release into the environment.

13. DISPOSAL CONSIDERATIONS

Disposal: Comply with local regulations for disposal


Apply the same procedure for slag remaining from welding
Industrial Waste Number: 120113 Welding waste
120101 Ferrous metallic scrap

14. TRANSPORT INFORMATION

General Information: Not regulated

15. REGULATORY INFORMATION

Symbols: None
R Phrases: None
S Phrases: None

16. OTHER INFORMATION

Warning: Fumes and gases emitted during welding may be dangerous. Good ventilation of the workplace required.
Electric rays may burn eyes and skin. Electric shock can kill. Wear protective clothing.

Training advice: Ensure that the user is aware of the potential hazards and knows what to do in the event of an accident or
an emergency

DISCLAIMER

This information relates only to the specific material designated and may not be valid for such material used in
combination with any other material or in any process. Such information is, to the best of the company’s knowledge
and belief, accurate and reliable as of the date indicated. However, the user’s responsibility to satisfy himself as to
the suitability of such information for his own particular use.

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