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    Solvent Extraction LANTHANIDE SEPARATION

    Uploaded by

    Gandiya
    1) Ion exchange is an important and effective method for separating and purifying lanthanide elements. Lanthanide ions are passed through a column containing an ion exchange resin, where they exchange with hydrogen ions on the resin. 2) As a complexing agent like citric acid passes through the column, it forms complexes with the lanthanide ions on the resin. Heavier lanthanide ions form stronger complexes and elute from the column first in separate bands. 3) The process is monitored spectroscopically and fractions are collected automatically. This allows for the individual separation of lanthanide elements at high purity levels of 99.9% or more.

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    © All Rights Reserved
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    Solvent Extraction LANTHANIDE SEPARATION

    Uploaded by

    Gandiya
    183 views4 pages
    1) Ion exchange is an important and effective method for separating and purifying lanthanide elements. Lanthanide ions are passed through a column containing an ion exchange resin, where they exchange with hydrogen ions on the resin. 2) As a complexing agent like citric acid passes through the column, it forms complexes with the lanthanide ions on the resin. Heavier lanthanide ions form stronger complexes and elute from the column first in separate bands. 3) The process is monitored spectroscopically and fractions are collected automatically. This allows for the individual separation of lanthanide elements at high purity levels of 99.9% or more.

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    Solvent extraction LANTHANIDE SEPARATION

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    1) Ion exchange is an important and effective method for separating and purifying lanthanide elements. Lanthanide ions are passed through a column containing an ion exchange resin, where they exchange with hydrogen ions on the resin. 2) As a complexing agent like citric acid passes through the column, it forms complexes with the lanthanide ions on the resin. Heavier lanthanide ions form stronger complexes and elute from the column first in separate bands. 3) The process is monitored spectroscopically and fractions are collected automatically. This allows for the individual separation of lanthanide elements at high purity levels of 99.9% or more.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    183 views4 pages

    Solvent Extraction LANTHANIDE SEPARATION

    Uploaded by

    Gandiya
    1) Ion exchange is an important and effective method for separating and purifying lanthanide elements. Lanthanide ions are passed through a column containing an ion exchange resin, where they exchange with hydrogen ions on the resin. 2) As a complexing agent like citric acid passes through the column, it forms complexes with the lanthanide ions on the resin. Heavier lanthanide ions form stronger complexes and elute from the column first in separate bands. 3) The process is monitored spectroscopically and fractions are collected automatically. This allows for the individual separation of lanthanide elements at high purity levels of 99.9% or more.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 4

    SEPARAfio of LANTHANIDE ELEMENrs!

    dekeamio ed bt
    Thpropevties of metal ions a T debeamín
    their siae and charge. the Lanthanides are tyeitaly
    tivalent ave almost dentca io ze 4o h e r

    chemica' propeties are alm as t dentica


    The Sepavaion of one Lanthaoide #rom anoher is

    ifeicult task În recent years the ooky m ethod4 use

    4Te on xcbang *
    valen cy cha
    other methods aso us o sepavoui on D Lanha-

    nides are
    preipi taio
    i) Therma reoction
    Fractionad cm4FallicaHon
    i Cmplex formao
    v solvent exttaction.

    TON ExCH ANG


    This is most
    impertaot, Yapid effectiNe gentra
    the for separaion <puificaHon ofhe Lanth

    anides. So of Laothanides ions is Tuo


    down a coloumn of synthetie ion exchange resin such

    as Dow ex 50 This is sulphoneted poy styrene


    contains the
    the fun ckona groups - s°2. the Ln 3t iOnS
    reio
    ave abserbed dnto e pla ce he
    ydogen
    atom on -S03H.

    Ln
    Ln co) cag 3HCresin)=: Ln (resin), 3
    HCag.)
    The H ions procuead ar washed throuh cdeumn
    then the meld ions 4Yeluted aYe Washed off he|
    coloumn in a sedective manner. The eluting 4gent s

    a
    Compling ag«ntfoY 9 buffered soluiono of
    citvie acid ammonium citrate. oY dilute sol

    H)CH eDrA) at p 8. consider the eitvate CAse


    CAse
    An is set up.

    LnCvesin),+ aH+(citvate) 3u (vesin) + Ln Ccitrat)


    As the citrate solui on flows dowdn
    the coloumn Ln ons are Temoved frem the ecin

    3 fro the itrate complex.


    A ittle loDeY dod he coloumo he Lo
    ions go back ino he the citvate
    recin As so
    YunS down the coloumo he mea ions form complexee
    alternatel wi the vesio 8 the citrate so many
    Hmes.
    The metal ion raduall travek deudn Hhe coloumm

    eventually paases ou o the boitom o the coloum


    as he eitvate complx
    the smalleY Lanthanide ions suc as Au form
    shonger Comple wi the citrate ions than larger
    jons tiee La

    2
    Thus the maller heavier ions spend
    Spend more
    timein soluHon (ess t'me on the coloumbo
    are eluted from the coldmn
    irstth ditter ent metal
    mekaions present separate int bands which
    Pass
    donthe coteumn
    The Proresss of bands Fotloe2 spech scopicall
    by aomaie Scence.3 collected in aubomaiee
    fraction collector in sepavate centainers. By this
    means the individual elements can separated.
    u i n a a ong ion exchange
    coloumn the elemeots may be
    obhauned 99 9 .

    puT with Pass


    Raw w a t e r

    To vacuum
    pump
    Cation
    Anion
    'exchanger Exchanger
    BedBed 20 Bed Alkali Steam
    jacket
    Regenerting era

    Regenerating solution
    solution

    Washing Washing Demineralized


    water
    Degasifier

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