8.2129 - 38.393*T-0.04107825*(T^2)+ 3.

851602603*(10^

T ΔHRx
298 -92400
300 -
90459.8851
400 45334.6336
9
500 272746.05
600 614883.979
3
700 1094858.03
7
800 1735777.84
900 2560753.00
9000000 2
1000 3592893.14
8000000 1100 4855307.86
9
7000000
1200 6371106.80
6000000 5
1300 8163399.56
5000000 3
4000000

3000000 0 200 400 600 800 10 00 12 00 14 00

-1000000
Tº
2000000
ΔH

1000000

0
 ((5.78*(t^2)-513056.57)/1000) -0.0821565*t-ln(T)+ln(298)-173.52

T ΔS
29 -198 -198.0
8
30 - -191.5
0 191.51134
8
40 193.64629 193.4
0 73
50 696.82984 696.1
0 84
60 1317.1287 1315.8
0 56
70 2054.0573 2052.0
0 07
8000 80 2907.3255 2904.4
0 72
7000 90 3876.7465 3872.8
0 42
10 4962.1925 4957.0
6000
00 27
11 6163.5724 6157.1
5000 00 54
12 7480.8190 7472.8
4000 00 74
77 2665.4898 2662.8
3000 3 11
0 200 400 600 800 1000 1200 1400
ΔS

2000
-1000
Tº
1000

0
 0.00385*(T^3) -0.041*(T^2)-46.703*T-179202.7512

T ΔURx
298 -94876.38
300 -
92953.651
2
400 41956.048
8
500 268445.74
9
600 609615.44
9
700 1088565.1
5
800 1728394.8
5
900 2552204.5
5
1000 3583094.2
5
1100 4844163.9
5
1200 6358513.6
5

ΔURx
7000000

6000000

5000000

4000000
3000000

2000000

1000000

0
0 200 400 600 800 1000 1200 14
-1000000 00
G=H-T*S

T G
298 -33396
300 -33005
350 -27696
400 -31986
450 -47348
500 -75247
550 -117143
600 -174492
650 -248747
700 -341358
750 -453775
800 -587446
850 -743815
900 -924330
950 -1130434
1000 -1363573
1050 -1625188

*-0.00191*(T^3)+0.03892175*(T^2)+648.182*T+38.39*T*LN(0.00335*T)-179238.2129

G
0
-200000 0 200 400 600 800 1000 1200

-400000
-600000
-800000
-1000000
-1200000

-
1400000
-
1600000
-
1800000
 Kp=Exp(-G/RT)

T Kp
2 719235.34
9 05
8
3 561951.07
0 5
0
3 13663.974
5 11
0
4 15105.277
0 44
0
4 315400.87
5 03
0
5 73295291.
0 56
0
5 1.35232E+
5 11
0
6 1.58031E+
0 15
0
6 9.99741E+
5 19
0
7 3.05951E+
0 25
0

Kp
3.5E+25

3E+25

2.5E+25

2E+25

1.5E+25

1E+25

5E+24

0 0 100 200 300 400 500 600 700 800

-5E+24
 α kp
0 0
0.1 0.008973
38
0.2 0.241126
54
0.3 44.48838
36
0.328 13981.24
74
0.3281 14811.13
25
0.329 26295.79
58
0.3291 28228.37
59
0.3291 28228.37
0.30 = 59
0.3315 354915.6
61
0.33187 700199.2
99
0.331871 701642.8
800000
71
700000 0.331871 702366.1
5 42
600000 0.33188 714814.9
78
500000
0.331882 719129.2
400000 9 04
0.331883 719278.7
Kp

300000 43
200000

100000

0
35
-100000
α

0 0.05 1 0. 15 2 0. 25 3 0.
 Kp2 = 7.19141*105 *

T KP
2
298 719141
300 560767.98
9
325 32402.881
7
350 2813.6476
6
375 338.42646
400 53.043794
6
425 10.339289
8
450 2.4168611
9
475 0.6583531
5
500 0.2042421
7
525 0.0708341
5
550 0.0270488
8
575 0.0112308
3
600 0.0050174
8
625 0.0023908
6
650 0.0012061
1
675 0.0006400
7
700 0.0003554
1
725 0.0002055
2
750 0.0001232
6
775 7.6406E-05
800 4.8799E-05

KP2
800000

700000

600000
500000

400000

300000

200000

100000
0 100200300400500600700800900
P KP
0
0.1 7191410
0
0.1 31961822
5 .2
0.2 1797852
5
0.2 1150625
5 6
0.3 7990455.
56
0.3 5870538.
5 78
0.4 4494631.
25
0.4 3551313.
5 58
0.5 2876564
0.5 2377325.
5 62
0.6 1997613.
89
0.6 1702108.
P VS KP
5 88
0.7 1467634.
80000000 69
70000000 0.8 1123657.
60000000 81
0
50000000 0 0.90.2 887828.3
0.4 0.6 0.8 1 1.2
40000000 95 P(atm)
30000000 1 719141
20000000 10 7191.41
10000000 20 1797.852
5
30 799.0455
KP

56
40 449.4631
25
10 71.9141
0
20 17.97852
0 5
Kmol/h Flujos

Compon Entrada Produc Reaccio Salida Composicion de salida

ent e na (Fi/FT)
H2 4545.45 0 1500 3045.45 0.6
02
N2 1515.15 0 500 1015.15 0.2
01
NH3 0 1000 0 1000 0.1
98
Total 6060.6 5060.6 1.0
00

Entrada Sali
da h)
Compon PM(kg/Km Flujo Masa Flujo Masa
ent ol (Kg/ (Kg/
H 2 4545.45 9090.9 3045.45 6090.9
2
N 28 1515.15 42424.2 1015.15 28424.
 T Ln(Kp)
298 13.485943
9
300 13.239170
1
350 9.5225180
2
400 9.6227994
6
450 12.661599
7
500 18.110006
9
550 25.630259
4
600 34.996396
9
650 46.051442
4
700 58.682882
4
750 72.807922
9
180 800 88.364256
160
1
850 105.30407
140 2
120 900 123.59005
LN(KP)

100
9
950 143.19266
80 2
60 1000 164.08815
40
4
20
0
0 200 400 600 800 1000 1200
Temperatura