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JEE (ADVANCED) _2021 PART-TEST_08_PAPER-II

Time:3 Hours Maximum Marks: 186

Please read the instruction carefully. You are allotted 5 minutes specifically for this purpose.

INSTRUCTIONS

GENERAL :

1. This sealed booklet is your Question Paper. Do not break the seal till you are instructed to do so.

2. The question paper CODE is printed on the left hand top corner of this sheet and the right hand top corner of
the back cover of this booklet.

3. Use the Optical Response Sheet (ORS) provided separately for answering the questions.

4. The ORS CODE is printed on its left part as well as the right part. Ensure that both these codes are identical
and same as that on the question paper booklet. If not, contact the invigilator.

5. Blank spaces are provided within this booklet for rough work.

6. Write your name and roll number in the space provided on the back cover of this booklet.

7. After breaking the seal of the booklet, verify that the booklet contains 32 pages and that all the 60 questions
along with the options are legible

DARKENING THE BUBBLES ON THE ORS

8. The ORS consists of an original (top sheet) and its carbon-less copy (bottom sheet).

9. Darken the appropriate bubbles on the original by applying sufficient pressure. This will leave an impression at
the corresponding place on the carbon-less copy.

10. The original is machine-gradable and will be collected by the invigilator at the end of the examination.

11. You will be allowed to take away the carbon-less copy at the end of the examination.

12. Do not temper with or mutilate the ORS.

13. Write your name, roll number and the name of the examination center and sign with pen in the space provided
for this purpose on the original. Do not write any of these details anywhere else. Darken the appropriate bubble
under each digit of your roll number

SYLLABUS
PHYSICS Ray Optics, Wave Optics
CHEMISTRY Solid State, Chemical Kinetics and Nuclear Chemistry, Aldehydes, Ketones & P-Block G - 13,14
MATHEMATICS Indefinite Integration, Definite Integration, Area Under the Curve & Differential Equations
JEE (ADVANCED) _2021 PART-TEST_08_PAPER-II
PART-I PHYSICS
SECTION-I (Maximum Marks: 32)

This section contains SIX (06) questions.


• Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is (are) correct
answer(s).
• For each question, choose the option(s) corresponding to (all) the correct answer(s).
• Answer to each question will be evaluated according to the following marking scheme:

Full Marks: +4 If only (all) the correct option(s) is(are) chosen;


Partial Marks: +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct;
Partial Marks: +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks: 0 If unanswered;
Negative Marks: −2 In all other cases.
• For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers, then
choosing ONLY (A), (B) and (D) will get +4 marks;
choosing ONLY (A) and (B) will get +2 marks;
choosing ONLY (A) and (D) will get +2marks;
choosing ONLY (B) and (D) will get +2 marks;
choosing ONLY (A) will get +1 mark;
choosing ONLY (B) will get +1 mark;
choosing ONLY (D) will get +1 mark;
choosing no option(s) (i.e. the question is unanswered) will get 0 marks and
choosing any other option(s) will get −2 marks.
1. A prism of refractive index  and angle A is placed in the minimum deviation position.
The angle of minimum deviation is  .
1    1
 2 
A) If   A, then A  2cos   B) If   A, then A  cos   1
2  2 
 
 3      
C) If   2 A, then A  2sin 1   D) If   2 A, then A  2cos1  
 2   2 
2. In physics experiment with convex lens, the distance between a screen and a light
source fixed on the optical bench is 120 cm. When a convex lens is placed in between,
sharp image of the source is obtained on the screen at two positions of the lens. The ratio
of the magnifications in the two cases is 1: 9.
A) The focal length of the convex lens measured is 22.5 cm
B) The focal length of the convex lens measured is 45 cm
C) Smaller one of the two images obtained on the screen is brighter
D) Bigger one of the two images obtained on the screen is brighter
JEE (ADVANCED) _2021 PART-TEST_08_PAPER-II
3. An observer inspects image of the rod AB formed by a plane mirror PQ as shown in
figure. Match the region specified in column-I with the description of image he sees as
given column-II.

Column I Column II
P) Region RPS 1. Full image
Q) Region SVQT 2. Image of some portion near the end A
R) Region TQU 3. Image of some portion near the end B
S) Region PQV 4. Image of middle portion leaving some portion
Near both ends
A) P-2 B) Q-1 C) R-3 D) S-1

4. A monochromatic parallel beam of light of wavelength is incident normally on the


plane containing slits S1 and S2 . The slits are of unequal width such that intensity only
due to one slit on screen is four times that only due to the other slit. The screen is placed
along y-axis as shown. The distance between slits is d and that between screen and slit is
D

The distance between two points on screen having equal intensities, such that intensity at
those points is 3/9th of maximum intensity
D D 2D 3D
A) B) C) D)
3d d d d
JEE (ADVANCED) _2021 PART-TEST_08_PAPER-II
5. Column I lists the changes introduced in Young’s interference experiment and Column II
lists the corresponding changes observed in the interference pattern.

Column I Column II
P) Distance between coherent sources is doubled 1. The fringe width doubled
Q) Green monochromatic light is replaced by 2. The fringe width increases
yellow monochromatic light
R) Distance between source and screen is doubled 3. Fringes disappear
S) One of the slits closed 4. Fringe width is halved
A) P - 4 B) Q - 2 C) R - 1, 2 D) S - 3

6. In a Young’s double -slit experiment, the separation between the two slits is d and
wavelength of light is  . The intensity of light falling on slit 1 is four times the intensity
of light falling on slit 2. Then,

I I 5
A) max  4 B) max 
I min I min 3

C) If the intensity of light falling on slit 1 is reduced then the darks get darker

D) If the intensity of light falling on slit 2 is reduced then the darks get darker
JEE (ADVANCED) _2021 PART-TEST_08_PAPER-II
SECTION-II (Maximum Marks: 18)
This section contains THREE (03) question stems.
There are TWO (02) questions corresponding to each question stem.
•The answer to each question is a NUMERICAL VALUE.
• For each question, enter the correct numerical value corresponding to the answer in the designated place using the mouse and the
on-screen virtual numeric keypad.
• If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
• Answer to each question will be evaluated according to the following marking scheme:

Full Marks : +2 If ONLY the correct numerical value is entered at the designated place;
Zero Marks : 0 In all other cases.

Question Stem for Question Nos. 7 and 8


Question Stem
The figure, shows a transparent sphere of radius R and refractive index μ. An object O is placed
at a distance x from the pole of the first surface so that a real image is formed at the pole of the
exactly opposite surface.

7. If an object is placed at a distance R from the pole of first surface, then the real image is
formed at a distance R from the pole of the second surface. The refractive index μ of the
sphere is given by

8. If x   , then the value of μ is

Question Stem for Question Nos. 9 and 10


Question Stem
Four particles are moving with different velocities in front of stationary plane mirror (lying in
y-z plane). At t = 0, velocity of A is v A  iˆ, velocity of B is vB   iˆ  3 ˆj , velocity of C is
vC  5 iˆ  6 ˆj, velocity of D is vD  3iˆ  ˆj. Acceleration of particle A is a A  2iˆ  ˆj and
acceleration of particle C is aC  2t ˆj. The particle B and D move with uniform velocity
(Assume no collision to take place till t = 2 seconds). All quantities are in S.I. Units. Relative
velocity of image of object A with respect to object A is denoted byV ' . Consider situation at
A ,A
t = 2s.
JEE (ADVANCED) _2021 PART-TEST_08_PAPER-II

V
A' , A
9. Find
V
B' , B

V
D' , D
10. Find
V
C' , C
JEE (ADVANCED) _2021 PART-TEST_08_PAPER-II
Question Stem for Question Nos. 11 and 12
Question Stem
A parallel beam of light of diameter 4 cm falls on a thin convex lens of focal length 40 cm and then on a thin
convex lens of focal length 10 cm as shown in figure (A). In figure (B) the second lens is an equiconcave lens
of focal length 10 cm and made of material of refractive index 1.5. In both the case, the second lens has an
aperture equal to 1 cm.

11. Compare the area figure(A)/figure(B) illuminated by the beam of light on the screen,
which passes through the second lens in the two cases.
12. Now liquid of refractive index  is filled to the right of the second lens in case B such
that the area illuminated in both the cases is the same. Determine the refractive index of
the liquid.
JEE (ADVANCED) _2021 PART-TEST_08_PAPER-II
SECTION-III (Maximum Marks: 12)
• This section contains TWO (02) paragraphs. Based on each paragraph, there are TWO (02) questions.
• Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
• For each question, choose the option corresponding to the correct answer.
• Answer to each question will be evaluated according to the following marking scheme:

Full Marks : +3 If ONLY the correct option is chosen;


Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases.

PARAGRAPH-I FOR QUESTION NOS. 13-14


The ciliary muscles of eye control the curvature of the lens in the eye and hence can alter the
effective focal length of the system. When the muscles are fully relaxed, the focal length is
maximum. When the muscles are strained the curvature of lens increases (that means radius
of curvature decreases) and focal length decreases. For a clear vision the image must be on
retina. The image distance is therefore fixed for clear vision and it equals the distance of retina
from eye-lens. It is about 2.5 cm for a grown-up person.
A person can theoretically have clear vision of objects situated at any large distance from
the eye. The smallest distance at which a person can clearly see is related to minimum possible
focal length. The ciliary muscles are most strained in this position. For an average grown-up
person minimum distance of object should he around 25 cm.
A person suffering for eye defects uses spectacles (Eye glass). The function of lens of
spectacles is to form the image of the objects within the range in which person can see clearly.
The image of the spectacle-lens becomes object for eye-lens and whose image is formed on
retina.
The number of spectacle-lens used for the remedy of eye defect is decided by the power
of the lens required and the number of spectacle-lens is equal to the numerical value of the
power of lens with sign. For example power of lens required is +3D (converging lens of focal
100
length cm) then number of lens will be +3.
3
For all the calculations required you can use the lens formula and lens maker's formula.
Assume that the eye lens is equiconvex lens. Neglect the distance between eye lens and the
spectacle lens.
13. Minimum focal length of eye lens of a normal person is
A) 25 cm B) 2.5 cm
C) 25/9 cm D) 25/11 cm
14. A nearsighted man can clearly see object only upto a distance of 100 cm and not beyond
this. The number of the spectacles lens necessary for the remedy of this defect will be.
A) + 1 B) – 1
C) + 3 D) – 3
JEE (ADVANCED) _2021 PART-TEST_08_PAPER-II
PARAGRAPH-I FOR QUESTION NOS. 15-16

Chromatic Aberration

The image of a white object in white light formed by a lens is usually coloured and blurred.
This defect of image is called chromatic aberration and arises due to the fact that focal length of
a lens is different for different colours. As μ of lens is maximum for violet while minimum for
red, violet is focused nearest to the lens while red farthest from it as shown in figure.

As a result of this, in case of convergent lens if a screen is placed at FV centre of the image will
be violet and focused while sides are red and blurred. While at FR , reverse is the case, i.e.,
centre will be red and focused while sides violet and blurred. The difference between fV and
f R is a measure of the longitudinal chromatic aberration (L.C.A), i.e.,

L.C. A.  f R  fV  df with df  fV  f R ……. (1)

However, as for a single lens,

1 1 1 
 (      ……… (2)
f  R1 R2 

df 1 1 
   d    ……… (3)
f2  R1 R2 

Dividing Eqn. (3) by (2);

df d  d 
     (     dispersive power ……….. (4)
f (    

And hence, from Eqns. (1) and (4),

L.C.A = df   f

Now, as for a single lens neither f nor ω can be zero, we cannot have a single lens free from
chromatic aberration.
JEE (ADVANCED) _2021 PART-TEST_08_PAPER-II
Condition of Achromatism:

In case of two thin lenses in contact

1 1 1 dF df df
  i.e.,   1  2
F f1 f 2 F2 f12 f 22

The combination will be free from chromatic aberration if dF  0

df1 df 2
i.e.,  0
f12 f 22

which with the help of Eqn. (4) reduces to

1 f1 2 f 2  
 0 i.e., 1  2  0 ………. (5)
2 2 f1 f 2
f1 f2

This condition is called condition of achromatism (for two thin lenses in contact) and the lens
combination which satisfies this condition is called achromatic lens, from this condition, i.e.,
from Eqn. (5) it is clear that in case of achromatic doublet:

(1) The two lenses must be of different materials.

1 1 1
Since, if 1  2 ,  0 i.e., 0 or F 
f1 f 2 F

i.e., combination will not behave as lens, but as a plane glass plate.

(2) As 1 and 2 are positive quantities, for Eqn. (5) to hold, f1 and f 2 must be of opposite
nature, i.e., if one of the lenses is converging the other must be diverging.

(3) If the achromatic combination is convergent,

fC  f D

f 
and as  C  C , C  D
f D D

i.e., in a convergent achromatic doublet, convex lens has lesser focal length and dispersive
power than the divergent one.
JEE (ADVANCED) _2021 PART-TEST_08_PAPER-II
15. A combination is made of two lenses of focal lengths f and f ' in contact; the dispersive
powers of the materials of the lenses are  and ' . The combination is achromatic when:

A)   0 , '  20 , f '  2 f B)   0 , '  20 , f '  f /2

C)   0 , '  20 , f '   f /2 D)   0 , '  20 , f '  2 f

16. The dispersive power of crown and flint glasses are 0.02 and 0.04 respectively. An
achromatic converging lens of focal length 40 cm is made by keeping two lenses, one of
crown glass and the other of flint glass, in contact with each other. The focal lengths of
the two lenses are :

A) 21 cm and 40 cm B) 21 cm and – 40 cm

C) – 21 cm and 40 cm D) 10 cm and – 21 cm
JEE (ADVANCED) _2021 PART-TEST_08_PAPER-II
SECTION-IV (Maximum Marks: 12)
This section contains THREE (03) questions.
•The answer to each question is a NON-NEGATIVE INTEGER.
•For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen virtual numeric keypad
in the place designated to enter the answer.
•Answer to each question will be evaluated according to the following marking scheme:

Full Marks : +4 If ONLY the correct integer is entered;


Zero Marks : 0 In all other cases.

17. Two flat mirrors form an angle close to 180o as shown in figure.

A source of light S is placed at equal distances b from the mirrors. The interval between
adjacent interference bands on screen MN at a distance OA  a from the point of
 a  b
intersection of the mirrors is . Find x. The length of the light wave is known and
xb
equal to λ . Shield C does not allow the wavelength of light wave to pass directly from the
source to the screen.

18. A thin equiconvex lens of radius 60 cm is placed over a plane mirror. What should be the
refractive index of the material of the lens so that the image formed of an object at a
distance 5 cm from it (as shown) coincides with the object.
JEE (ADVANCED) _2021 PART-TEST_08_PAPER-II
19. A liquid of refractive index 0 is filled between slits and screen. With no slabs in front of
slits the central maximum is at point O on screen. Now two slabs of refractive indices 1
and 2 with thickness t1 and t2 respectively are placed in front of slits as shown. Find the
t
ratio of 1 , if the position of central maxima does not change.
t2

[ 0  1.5, 1  1.8, 2  2.1]


JEE (ADVANCED) _2021 PART-TEST_08_PAPER-II
PART-II CHEMISTRY
SECTION-I (Maximum Marks: 32)

This section contains SIX (06) questions.


• Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is (are) correct
answer(s).
• For each question, choose the option(s) corresponding to (all) the correct answer(s).
• Answer to each question will be evaluated according to the following marking scheme:

Full Marks : +4 If only (all) the correct option(s) is(are) chosen;


Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both of which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks : 0 If unanswered;
Negative Marks : −2 In all other cases.
• For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers, then
choosing ONLY (A), (B) and (D) will get +4 marks;
choosing ONLY (A) and (B) will get +2 marks;
choosing ONLY (A) and (D) will get +2marks;
choosing ONLY (B) and (D) will get +2 marks;
choosing ONLY (A) will get +1 mark;
choosing ONLY (B) will get +1 mark;
choosing ONLY (D) will get +1 mark;
choosing no option(s) (i.e. the question is unanswered) will get 0 marks and
choosing any other option(s) will get −2 marks.

20. Column – I Column – II

a) Glyoxal p) Fehling’s solution

b) pentane-2, 4-dione q) Tollen’s reagent

c) Glucose r) I2 / NaOH

d)1  hydroxybutanone s) NaHSO3

Correct matching of the substance given in Column-I with the reagents mentioned in
Column - II is/are

A) a-q, s B) b-r, s

C) c-p, q D) d-p, q, r, s
JEE (ADVANCED) _2021 PART-TEST_08_PAPER-II
21. A cubical crystal is such that the corners atoms are occupied by P atoms, face centers are
occupied by Q atoms, alternate tetrahedral voids are occupied by R atoms and edge
centers are occupied by S atoms. Based on this info identify the correct option.

A) If there are no defects in the crystal, then the formula should be PQ3R4 S3 .

B) If all the atoms lying on one of the body diagonal are missing, then formula should be
PQ4 R8/3S4

C) If all the atoms lying on a line connecting opposite edge centers of a face are missing,
then formula should be P2Q5 R8S5

D) If all the atoms lying on a line passing through body center and connecting opposite
face centers are missing, then formula will be PQ2 R4 S3 .

22. The activation energies of two reactions I and II are Ea and 2 Ea respectively. If the
temperature of the reacting systems is increased from T to T ' , predict which of the
following alternatives is/are correct?
k 'I k 'II k'I k'II k'I k'II
A) 1 B) 1 C)  D) 2
kI k II k I k II kI k II
23. Which of the following statements is/are incorrect?

A) Clemmensen reduction shouldn’t be carried out for base-sensitive compounds.

B) Benedict’s test can be used to distinguish between formaldehyde and benzaldehyde.

C) Increasing order of nucleophilic addition reaction:acetophenone < p-tolualdehyde <


benzaldehyde < p-nitrobenzaldehyde

D) Rate of haloform reaction is independent of the nature of halogen.


JEE (ADVANCED) _2021 PART-TEST_08_PAPER-II
24. Consider the following nuclear reaction:

90 Th
228

83 Bi 212

Which of the following is/are true about the above reaction?

A) A total of 4 and 1 particles are emitted per nucleus of Th

228
B) 90 Th is above the band of stability

C) A total of 5 and 3 particles are emitted per nucleus of Th

228 212
D) 90 Th is decaying to 83 Bi because latter is the most stable isotope

25. Silicones are a group of organo silicon polymer, select correct statement(s) about them:
A) R3SiCl produce very complex cross linked polymeric silicons on hydrolysis
B) Their water repellency arises because a silicon chain is surrounded by organic side
groups.
C) Their strength and inertness are related to their stable silica like skeleton of
| | |
Si O Si O Si
| | |
D) Hydrolysis product of CH3SiCl3 will block the end of the straight chain produce by
hydrolysis of (CH3 )2SiCl2
JEE (ADVANCED) _2021 PART-TEST_08_PAPER-II
SECTION-II (Maximum Marks: 18)
This section contains THREE (03) question stems.
There are TWO (02) questions corresponding to each question stem.
• The answer to each question is a NUMERICAL VALUE.
•For each question, enter the correct numerical value corresponding to the answer in the designated place using the mouse and the
on-screen virtual numeric keypad.
•If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
•Answer to each question will be evaluated according to the following marking scheme:

Full Marks: +2 If ONLY the correct numerical value is entered at the designated place;
Zero Marks: 0 In all other cases.

Question Stem for Question Nos. 26 and 27


Question Stem
Silicates are a very important class of compounds. The SiO44 tetrahedral units may occur singly
or may share one, two, three or four oxygen atoms through corners giving rise to cyclic groups,
chains, infinite layers or infinite three dimensional framework.

26. Anion is present in the mineral benitoite which is a cyclic silicate. is :

27. In the double chain silicate, the number of oxygen atoms present per silicon atom is .
Report .

Question Stem for Question Nos. 28 and 29


Question Stem
Only those atoms which form four covalent bonds produce a repetitive three dimensional
structure using only covalent bonds, e.g., diamond structure. The latter is based on a FCC
lattice where lattice points are occupied by carbon atoms. Every atom in this structure is
surrounded tetrahedrally by four others. Germainium, silicon and grey in tin also crystallize in
the same way as diamond. (Given : NA  6  1023 ) ( 2  1.41, 3  1.73)

28. If edge length of the cube is 3.60Å , then radius of carbon atom in Å is

29. If the edge length is 3.60Å , density of diamond crystal in g/cc is”
JEE (ADVANCED) _2021 PART-TEST_08_PAPER-II
Question Stem for Question Nos. 30 and 31
Question Stem
Decomposition of H2O2 is a first order reaction. A solution of H2O2 labelled as 22.4 volume
was left open. Due to this some H2O2 decomposed. To determine the new volume strength
after 6 hr, 10 mL of this solution was diluted to 100 mL. 10 mL of this diluted solution was
titrated against 25 mL of 0025 M KMnO4 acidified solution. [log10 2  0.30, loge x  2.3 log10 x]

Assume STP to be 1 atm & 0o C.

30. Calculate the half-life for the decomposition of H2O2 in hours.

31. What will be the volume strength of H2O2 solution (labeled as x V H2O2 ) after 54
hours?
JEE (ADVANCED) _2021 PART-TEST_08_PAPER-II
SECTION-III (Maximum Marks: 12)
•This section contains TWO (02) paragraphs. Based on each paragraph, there are TWO (02) questions.
•Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
•For each question, choose the option corresponding to the correct answer.
•Answer to each question will be evaluated according to the following marking scheme:

Full Marks: +3 If ONLY the correct option is chosen;


Zero Marks: 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: −1 In all other cases.

Paragraph-I for Questions 32 and 33:

Five isomeric para-disubstituted aromatic compounds (P) to (T) with molecular formula
C8H8O2 were given for identification. Based on the following observations, give structures of
the compounds:
(i) Both (P) and (Q) form a silver mirror with Tollens’ reagent; also, (Q) gives a positive test
with FeCl3 solution but (P) not.

(ii) (R) gives positive iodoform test.


(iii) (S) is readily extracted in aqueous NaHCO3 solution.

(iv) (T) on acid hydrolysis gives 1, 4-dihydroxybenzene.


32. The compound (P) can be:

(I) (II) (III) (IV)

A) I, II, III B) I, II, III, IV

C) I, II D) I, IV

33. Which of the following is not matched correctly?

A) S is B) T is C) Q is D) R is
JEE (ADVANCED) _2021 PART-TEST_08_PAPER-II
Paragraph-II for Questions 34 and 35:

Orthoboric acid, B(OH)3 , is the normal end product of hydrolysis of most boron compounds.
It forms flaky, white, transparent crystals in which a planar array of BO3 units is joined by
unsymmetrical H-bonds. In contrast to the short O  H---O distance of 272 pm within the plane,
the distance between consecutive layer in the crystal is 318 pm, thus accounting for the
pronounced basal cleavage of the waxy, plate-like crystals and their low density (1.48 g cm3 ).

34. Which of the following reaction produce boric acid?


(I) Hydrolysis of BCl3
(II) Reaction of H2SO4 with aqueous solution of borax
(III) Reaction of water with B2H6
A) I, II, III B) I, II
C) I, II D) II, III

35. Select incorrect statement.


A) Boric acid acts as hydroxyl donar in water rather than proton donar.
B) Its acidity is considerably enhanced by cis 1, 2-diols.
C) H3BO3 on heating at high temperature produces B2O3 .
D) H3BO3 when reacts with aqueous NaOH, produces Na  B(OH)4 .
JEE (ADVANCED) _2021 PART-TEST_08_PAPER-II
SECTION-IV (Maximum Marks: 12)
This section contains THREE (03) questions.
•The answer to each question is a NON-NEGATIVE INTEGER.
•For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen virtual numeric keypad
in the place designated to enter the answer.
•Answer to each question will be evaluated according to the following marking scheme:

Full Marks: +4 If ONLY the correct integer is entered;


Zero Marks: 0 In all other cases.

36. Total no. of moles of hydrochloric acid react with one mole of borax to converts all
borons to boric acid:

37. A substance AB crystallizes in cubic closest packing (C.C.P.) with B occupying half the
tetrahedral voids. One litre of the crystal is doped with 1 mole atoms of C some of which
replace the B atoms and remaining occupy few interstitial voids without affecting the
dimensions of cubic crystal lattice. If density of crystal before doping is 4.8 gm/millilitre
and density after doping is 4.795 gm /ml, then calculate % of C to nearest whole no. added
which replace B atoms.

(Given: Atomic weight: A, B and C: 40, 30, 15)

38. Consider the following Cannizaro reaction,

O
|| (i) Conc. NaOH
H 2CO  D C D 


(ii) H3O

How many different products can be formed?


JEE (ADVANCED) _2021 PART-TEST_08_PAPER-II
PART-III MATHEMATICS
SECTION-I (Maximum Marks: 32)

This section contains SIX (06) questions.


• Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is (are) correct
answer(s).
• For each question, choose the option(s) corresponding to (all) the correct answer(s).
• Answer to each question will be evaluated according to the following marking scheme:

Full Marks : +4 If only (all) the correct option(s) is(are) chosen;


Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both of which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks : 0 If unanswered;
Negative Marks : −2 In all other cases.
• For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers, then
choosing ONLY (A), (B) and (D) will get +4 marks;
choosing ONLY (A) and (B) will get +2 marks;
choosing ONLY (A) and (D) will get +2marks;
choosing ONLY (B) and (D) will get +2 marks;
choosing ONLY (A) will get +1 mark;
choosing ONLY (B) will get +1 mark;
choosing ONLY (D) will get +1 mark;
choosing no option(s) (i.e. the question is unanswered) will get 0 marks and
choosing any other option(s) will get −2 marks.

4  x2 A(4  x 2 )3/2 ( Bx 2  6)
39. 20  dx   C , then
6 5
x x
1 1
A) A  B) B  1 C) A   D) B  1
120 120
n 1
40. Let, A1   (min{| x  n |,| x  (n  1) |})dx,
n
n 2
A2   (| x  n |  | x  (n  1) |)dx,
n 1
n 3
A3   (| x  (n  4) |  | x  (n  3) |)dx
n 2
and g ( x)  A1  A2  A3, then
9
A) A1  A2  A3  9 B) A1  A2  A3 
4
100 100
C)  g ( x)  225 D)  g ( x)  300
n 1 n 1
JEE (ADVANCED) _2021 PART-TEST_08_PAPER-II
41. Let f ( x) be a cubic polynomial with leading coefficient unity such that f (0)  1 and all
1
the roots of f '( x)  0 are also roots of f ( x)  0. If  f ( x)dx  g ( x)  C, where, g (0) 
4
and C is constant of integration, then
A) g (3)  64 B) g (1)  4 C) g (1)  0 D) g (2)  16
   
 
sin x
42. If ( x cos x  1)e dx  m and ( x sin x  1)ecos x dx  n then,
0 0

A) m  e B) m = eπ/2 C) n     D) n    
43. The equation of the curve passing through (3, 4) and satisfying the differential equation
2
 dy  dy
y    ( x  y )  x  0 can be:
 dx  dx

A) x  y  1  0 B) x 2  y 2  25 C) x2  y 2  5x  10  0 D) x  y  7  0
44. Let C be the family of curves f ( x, y, c)  0 (no member of C is x-axis) such that length of
subnormal at any point P( x, y) on the curve C is equal to four times that of the length of
subtangent at the same point. Which of the following statement(s) is(are) correct?
A) Equation of the line with positive y-intercept passing through (4, 2) and perpendicular
to the curve C is x  2 y  8
B) Orthogonal trajectory of C is family of parallel lines having gradient  2
C) Order and degree of the differential equation of family of curves C are 1 and 2
respectively
D) Differential equation of family of curves is 2 y'  x  0
JEE (ADVANCED) _2021 PART-TEST_08_PAPER-II
SECTION-II (Maximum Marks: 18)

This section contains THREE (03) question stems.


There are TWO (02) questions corresponding to each question stem.
•The answer to each question is a NUMERICAL VALUE.
• For each question, enter the correct numerical value corresponding to the answer in the designated place using the mouse and the
on-screen virtual numeric keypad.
• If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
• Answer to each question will be evaluated according to the following marking scheme:

Full Marks : +2 If ONLY the correct numerical value is entered at the designated place;
Zero Marks : 0 In all other cases.

Question Stem for Question Nos. 45 and 46


Question Stem
 3 
 sin x   x  sin x  aA
If    dx  A and    dx  , where a and b are relative prime natural number
0
 x 
0  x 3
 b

45. The value of a is

46. The number of factors of a3  b3 , which are natural number, is


Question Stem for Question Nos. 47 and 48
Question Stem
Let a polynomial ‘f ’ satisfies the relation f ( f ( f ( x)))  (1  p) f ( x)  3 x  R where pR.
d
47. If leading coefficient of f ( x) is 2 then the value of ( f ( f ( x))) at x  p is:
dx
1
48. If leading coefficient of f ( x) is negative and f (0)  4 then  f 1( x) dx is equal to:
1
Question Stem for Question Nos. 49 and 50
Question Stem
3 points O(0, 0), P(a, a 2 ), Q(b, b2 )(a  0, b  0) are on the parabola y  x 2 . Let S1 be the area
bounded by the line PQ and the parabola and let S2 be the area of the triangle OPQ,
S
49. If a  1, b  2. Find 1
S2

6S1
50. Find the minimum value of
S2
JEE (ADVANCED) _2021 PART-TEST_08_PAPER-II
SECTION-III (Maximum Marks: 12)
• This section contains TWO (02) paragraphs. Based on each paragraph, there are TWO (02) questions.
• Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
• For each question, choose the option corresponding to the correct answer.
• Answer to each question will be evaluated according to the following marking scheme:

Full Marks : +3 If ONLY the correct option is chosen;


Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases.

PARAGRAPH-I FOR QUESTION NOS. 51-52

Let f : R  R be a functions as f ( x)  ( x  1)( x  2)( x  3)( x  6)  100 . If g ( x) is a polynomial


g ( x)
of degree  3 such that  f ( x) dx does not contain any logarithm function and g (2)  10. Then
51. The minimum value of f ( x) is
A) 136 B) 100
625
C)  84 D) 
4
g ( x)
52.  f ( x) dx, equals
 x2  x 1
A) tan 1  c B) tan 1  c
 2   1 

C) tan 1( x)  c D) None of these


JEE (ADVANCED) _2021 PART-TEST_08_PAPER-II
PARAGRAPH-II FOR QUESTION NOS. 53-54

Let f be a differentiable function satisfying


f ( x) x
1
 f (t ) dt   (cos t  f (t )) dt  0 and f (0)  1
0 0

f (2 x) f ( x)
53. The number of solution(s) of the equation  0 in (0, 2  is:
sin x 2
A) 2 B) 3 C) 4 D) 5
  cos x   cos 2 x   cos3x   cos(100 x)  
54. The value of lim   
  
    ......   f (100 x)   is equal to:
x 0   f ( x)   f (2 x)   f (3x)   
[Note: where [k] denotes integer less than or equal to k.]
A) 0 B) 4950 C) 5049 D) 5050
JEE (ADVANCED) _2021 PART-TEST_08_PAPER-II
SECTION-IV (Maximum Marks: 12)
This section contains THREE (03) questions.
• The answer to each question is a NON-NEGATIVE INTEGER.
• For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen virtual numeric keypad
in the place designated to enter the answer.
• Answer to each question will be evaluated according to the following marking scheme:

Full Marks : +4 If ONLY the correct integer is entered;


Zero Marks : 0 In all other cases.

x 2009 1  x2 
55. If the primitive of the function f ( x)  w.r.t. x is equal to    C , then
(1  x 2 )1006 n  1  x 2 
n
is equal to……..
m

    1 
56. If 0 f ( x) dx 
2
and f ( x) is an even function, then 0  x  k . Find k
f x  dx 

1 1  1
 1  1
lim n 2  n  .(11  22  33.......nn ) n  ek . Find
2
57.
n k2

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